JP XII Physical&Inorganic Chemistry (30) - Prev Chaps + Chemical Kinetics + Inorg. Chem PDF

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 48 & 49
This DPP is to be discussed in the week (19.10.2015 to 24.10.2015)

DPP No. # 48 (JEE-ADVANCED)
Total Marks : 71 Max. Time : 45 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.7 (3 marks, 2 min.) [21, 14]
Multiple choice objective ('–1' negative marking) Q.8 to Q.13 (4 marks, 2 min.) [24, 12]
Comprehension ('–1' negative marking) Q.14 to Q.15 (3 marks, 2 min.) [06, 04]
Single Integer type Questions ('–1' negative marking) Q.16 to Q.18 (4 marks 3 min.) [12, 09]
Match the Following (no negative marking) Q.19 (8 marks, 6 min.) [08, 06]
ANSWER KEY
DPP No. # 48 (JEE-ADVANCED)
1. (A) 2. (A) 3. (A) 4. (D) 5. (B) 6. (A) 7. (B)
8.* (BCD) 9.* (AC) 10.* (AB) 11.* (ABC) 12.* (AB) 13.* (ABD) 14. (D)
15. (B) 16. 7 17. 50 18. 18 19. [A – r] ; [B – q] ; [C – r] ; [D – p].
DPP No. # 49 (JEE-MAIN)
1. (A) 2. (C) 3. (A) 4. (B) 5. (D) 6. (C) 7. (B)
8. (B) 9. (B) 10. (A) 11. (C) 12. (C) 13. (A) 14. (A)
15. (B) 16. (D) 17. (D) 18. (A) 19. (D) 20. (C) 21. (D)
1. The accompanying figure depicts the change in concentration of species A and B for the reaction A  B,
as a function of time, the point of intersection of the two curves represents
vfHkfØ;k A  B ds fy, çtkfr;ksa A rFkk B dh lkUnzrk esa ifjorZu dk fuEu vkd`fr irk yxkrh gSa] le; ds Qyu
ds :i esa nks oØ ds çfrNsnu dk fcUnq fuEu çnf'kZr djrk gSaA
(A*) t1/2 (B) t3/4 (C) t2/3 (D) data insufficient to predict
(A*) t1/2 (B) t3/4 (C) t2/3 (D) irk yxkus ds vkWdMsa vi;kZIr gSA
Sol. A  B
t=0 a 0
t=t a–x x
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PAGE NO.- 1
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At intersection, a – x = x
a
 x=
2
so, this time represents half life.

gy % A  B
t=0 a 0
t=t a–x x
vUr% [k.M ij a – x = x
a
 x=
2
bl fy, le; v)Z vk;q dks iznf'kZr djrk gSA
2. For the reaction A  C + D, the initial concentration of A is 0.01 M. After 100 sec, the concentration of A
is 0.001M. The rate constant of the reaction has the numerical value of 9.0. What is the unit of the reaction
rate constant ?
vfHkfØ;k A  C + D ds fy,] A dh izkjfEHkd lkUnzrk 0.01M gSA 100 sec i'pkr~ A dh lkUnzrk 0.001 M gSaA vfHkfØ;k
ds fy, nj fu;rkad dk lkaf[;dh eku 9.0 gSaA vfHkfØ;k ds nj fu;rkad dh bdkbZ D;k gSa \
(A*) M–1s–1 (B) Ms–1 (C) s–1 (D) M–1.5 s–1
Sol. For zero order('kwU; dksfV ds fy, )
C0  C t 0.01  0.001
=k  =k9
t 100
For first order (izFke dksfV ds fy,)

2 .303 C0 2.303 0.01
k= log C = log = 2.303 × 10–2  9.
t t 100 0.001
For second order (f}rh; dksfV ds fy,)
1  1  1  1
  =k  k= [1000 – 100] = 9
t  C t C0  100
so, reaction is 2nd order. Unit of rate constant is M–1s–1.

(bl fy, vfHkfØ;k f}rh; dksfV gSa rFkk nj fu;rkad dh bdkbZ M–1s–1 gS)
3. If the fermentation of sugar in an enzymatic solution, that is 0.12 M , the concentration of the sugar is
reduced to 0.06 M in 10 h and to 0.03 M in 20 h. What is the order of the reaction ?
,d ,Utkbeh foy;u esa ;fn 'kdZjk dk fd.ou esa lkUnzrk 10 ?k.Vs esa 0.12 M ls ?kVdj 0.06 M gksrh gS rFkk 20 ?k.Vs esa
0.03 M gks tkrh gS] rks vfHkfØ;k dh dksfV D;k gksxh \
(A*) 1 (B) 2 (C) 3 (D) 0
Sol. In 1st order Rxn, decrease in % of concentration same in same interval of Time
izFke dksfV dh vfHkfØ;k esa] leku le; vUrjky ds lkFk lkUnzrk % esa deh leku gksrh gSA
 (0.12 – 0.06 )  ( 0.06 – 0.03 )

 100  = 50%  100 = 50%
 0 . 12  0.06
so reaction must be of first order. vr% vfHkfØ;k izFke dksfV dh gSA
PAGE NO.- 2
4. A reaction is catalysed by H+ ion;and in the rate law the dependence of rate is of first order with respect to the
concentration of H+ ions, in presence of HA rate constant is 2 × 10 –3 min–1 and in presence of HB rate
constant is 1 × 10–3 min–1. HA and HB (both strong acids) have relative strength as :
,d vfHkfØ;k H+ vk;u }kjk mRizsfjr dh tkrh gS rFkk blesa osx fu;e H+ vk;u dh lkUnzrk ds lkis{k izFke dksfV dh vfHkfØ;k
gSA HA dh mifLFkfr esa nj fu;rkad 2 × 10–3 min–1 gS rFkk HB dh mifLFkfr esa nj fu;rkad 1 × 10–3 min–1 gS] rc HA
rFkk HB (nksuksa izcy vEy) dk vkisf{kd lkeF;Z gS :
(A) 0.5 (B) 0.002 (C) 0.001 (D*) 2
Sol. We know
Rate = k [conc.]
Given Rxn catalysed by HA and HB
Rate constant k A = k1 [H+]A
k B = k1 [H+]B
Then relative strength of acids A and B is
kA [H ] A 2 [H ] A [ Acid A ]

k B = [H ]B 1
= 
[H ]B
= strength of [ Acid B]
Sol. ge tkurs gS fd
nj = k [lkUnzrk]
fn;k x;k gS fd vfHkfØ;k HA rFkk HB ls mRizsfjr gSA
nj fu;rkad k A = k1 [H+]A
k B = k1 [H+]B
vc vEyksa A rFkk B dh vkisf{kd lkeF;Z
kA [H ] A 2 [H ] A [ A]
= = = [ B] dh lkeF;ZrkA
kB [H ]B 1

[H ]B
5. The gaseous decomposition reaction, A(g)  2B(g) + C(g) is observed to first order over the excess of
liquid water at 25ºC. It is found that after 10 minutes the total pressure of system is 188 torr and after very
long time it is 388 torr. The rate constant of the reaction (in hr–1) is : [Given : vapour pressure of H 2O at 25º is
28 torr (ln 2 = 0.7, ln 3 = 1.1, ln 10 = 2.3)]
(A) 0.02 (B*) 1.2 (C) 0.2 (D) none of these.
25ºC ij nzo ty ds vkf/kD; esa xSlh; fo;kstu vfHkfØ;k A(g)  2B(g) + C(g) ds fy, çFke dksfV çsf{kr dh tkrh
gSA ;g ik;k x;k gS fd 10 feuV i'pkr~ ra=k dk dqy nkc 188 torr rFkk dkQh yEcs le; i'pkr~ ;g 388 torr gS] rks
vfHkfØ;k ds fy, nj fu;rkad (hr–1 esa) gS %
[fn;k x;k gS : 25ºC ij H2O dk ok"i nkc 28 torr gSA (ln 2 = 0.7, ln 3 = 1.1, ln 10 = 2.3)]
(A) 0.02 (B*) 1.2 (C) 0.2 (D) buesa esa ls dksbZ ughaA
Sol. A(g)  2B(g) + C(g)
Let initial pressure P0 0 0

After 10 min. (P0 – x) 2x x
After long time ( t   ) 0 2P0 P0
as per given (P0 – x) + 2x + x + vaour pressure of H2O = 188
PAGE NO.- 3
P0 + 2x = 160 and 3P0 + 28 = 388
so, P0 = 120 and x = 20 torr
1  P0  1  120  1
k = t ln  P  x   10 ln  100   10 × (ln 4 + ln 3 – ln 10)
 0   
= 0.02 min–1 = 1.2 hr–1
gy % A(g)  2B(g) + C(g)
ekuk fd izkjfEHkd nkc P0 0 0

10 feuV ckn (P0 – x) 2x x
yEcs le; ckn ( t   ) 0 2P0 P0
fn;k x;k gS (P0 – x) + 2x + x + H2O dk ok"inkc = 188
P0 + 2x = 160 rFkk 3P0 + 28 = 388
blfy, P0 = 120 rFkk x = 20 torr
1  P0  1  120  1
k = t ln  P  x   10 ln  100   10 × (ln 4 + ln 3 – ln 10)= 0.02 min–1 = 1.2 hr–1
 0   
6. In the following reaction started only with A 8 ,

2A8 (g) 2 A3 (g) + 3 A2 (g) + A4 (g)
mole fraction of A2 is found to 0.36 at a total pressure of 100 atm at equilibrium. The mole fraction of A 8(g) at
equilibrium is :
(A*) 0.28 (B) 0.72 (C) 0.18 (D) None of these
fuEu nh xbZ vfHkfØ;k dsoy A8 , ds lkFk izkjEHk djrs gS %

2A8 (g) 2 A3 (g) + 3 A2 (g) + A4 (g)
lkE; ij dqy nkc 100 atm ij] A2 dk eksy izHkkt 0.36 ik;k x;k gSA lkE; ij A8(g) dk eksy izHkkt gksxkA
(A*) 0.28 (B) 0.72 (C) 0.18 (D) buesa ls dksbZ ugha
Sol. 2A8 2 A3 + 3 A2 + A4
t=0 2 0 0 0
t = teq 2 – 2 2 3 
nT = 2 + 4
given mole fraction of A2 is = 0.36. (fn;k x;k A2 dk eksy izHkkt = 0.36 gSA)
3
0.36 =
2  4
2  2 2  2  0.46
 = 0.46 ; Mole fraction of A 8 (A8 dk eksy izHkkt) = = = 0.28
2  4 2  4  0.46
PAGE NO.- 4
7. Flask A of volume 10 liter containing 20 gram of H2 and flask B of volume 10 litre containing 88 gram CO 2 are
connected by a connector having negligible volume. When valve of the connector is opened what is the
composition of H2 gas in flask B after openening the valve.
QykLd A ftldk vk;ru 10 yhVj gS H2 ds 20 xzke j[krk gS vkSj QykLd B ftldk vk;ru 10 yhVj gS 88 xzke CO2
j[krk gS ;s ,d nwljs ls ux.; vk;ru ds la;kstd ls tqMs+ gq, gSA tc la;kstd ds jks/kd ¼okWy½ dks [kksy rs gS rc jks/kd
[kksyus ds ckn QykLd B esa H2 xSl dk laxBu D;k gksxk \
(A) 10% (B*) 83.33% (C) 15% (D) 20%
20
Sol. (B) nH2 = = 10
2
88
nCO2 = =2
44
After opening of valve of the container mixture will become uniform.
10
Hence, composition of H2 =  100 = 83.33 %
12
20 88
gy . (B) nH2 = = 10 ; nCO2 = =2
2 44
jks/kd dks [kksyus ds ckn] ¶ykLd esa xSl dk feJ.k ,dleku gks tk;sxkA
10
vr% H2 dk laxBu =  100 = 83.33 %
12
8.* Select the correct statement :

lgha dFku pqfu, %&
(A) Rb [ICl2] upon heating will produce RbI & Cl2
(B*) F2 Oxidises water to dioxygen, but Cl2 does not.
(C*) In liquid HF soluvent, mineral acids like H2SO4, HNO3 & HCl behave as bases.
(D*) Compounds like CuI2 & EeI3 do not exist because of strong reducing nature of –
PAGE NO.- 5
(A) Rb [ICl2] xeZ djus ij RbI rFkk Cl2 nsrk gSaA
(B*) F2 ty dks MkbZvkWDlhtu esa vkWDlhtu djrh gSa] ijUrq Cl2 ughaaA
(C*) nzo HF foyk;d esa [kfut vEy tSls fd H2SO4, HNO3 rFkk HCl {kkj dh rjg O;ogkj djrsa gSaA
(D*) ;kSafxd tSls fd CuI2 rFkk EeI3 dh izcy vip;u izo`‘Ùkh ds dkj.k vfLrRo esa ugh gksrs gSaA
Sol : (A) Rb [ICl2]  RbCl + ICl
Monohalide having grater lattice enthalpy will be formed thus, monohalide containing matter amon (Cl–)
will be formed
(B) 2F2 + 2H2O 2HF + O2
Cl2 + H2O HCl + HOCl
(C) Among common mineral acids, only HClO4 behaver as an acid in liquid HF solvent (fact)
(D) Cu2+ & El3+ are reduced to Cu+ & El2+ with –
(A) Rb [ICl2]  RbCl + ICl
mPPk tkyd ,UFksYih okys eksuksgsykbM+ fufeZr gksrs gSA vr% NksVs _.kkRed (Cl–) ;qDr eksuksgsykbM+ cursa gSaA
(B) 2F2 + 2H2O 2HF + O2
Cl2 + H2O HCl + HOCl
(C) lkekU; [kfut yo.kksa esa ls dsoy HClO4 gSa nzOk HF foyk;d esa vEy dh rjg O;ogkj djrk gSa
(D) – ds }kjk Cu2+ rFkk Fe3+ Cu+ rFkk Fe2+ esa vipf;r gks tkrsa gSaA
9.* Choose the correct statement :
(A*) Paper dipped in starch solution + I2 vapours gives blue colour complex.
(B) Paper dipped in KI solution + starch + Br2 vapours gives orange red complex.
(C*) Paper dipped in starch + Br2 vapours gives orange red complex.
(D) Paper dipped in KI solution + starch + Cl2 gives blue colour complex.
lgh dFku dk p;u dhft;s µ
(A*) LVkpZ foy;u esa fHkxk i=k + I2 ok"i  uhys jax dk ladqy nsrs gSA
(B) KI foy;u esa Hkhxk i=k + LVkpZ + Br2 ok"i  yky ukjaxh ladqy nsrs gSA
(C*) LVkpZ foy;u esa Hkhxk i=k + Br2 ok"i  yky ukjaxh ladqy nsrs gSA
(D) KI foy;u esa Hkhxk i=k + LVkpZ + Cl2 uhsys jax dk ladqy nsrs gSA
10.* Select the correct statements if -
Eº Mg2  / Mg  2.4 V , Eº Sn 4  / Sn2   0.1 V , E º MnO 4 – , H / Mn 2   1.5 V , Eº  2 /  –  0.5 V
Here,
(A*) MnO4– is the strongest Oxidizing Agent and Mg is the strongest Reducing Agent.
(B*) Sn4+ + 2–  Sn2+ + 2 is a nonspontaneous reaction.
(C) Mg2+ + Sn2+  Mg + Sn4+ is a spontaneous reaction.
(D) Here, Weakest oxidizing agent is Sn4+ and weakest reducing agent is Mn2+
lgh oDrO; dk p;u dhft;s
Eº Mg2  / Mg  2.4 V , Eº Sn 4  / Sn2   0.1 V , E º MnO 4 – , H / Mn 2   1.5 V , Eº  / –
 0.5 V
2
;gk¡]
(A*) MnO4– izcyre vkWDlhdkjd rFkk Mg izcyre vipk;d gksrk gSA
(B*) Sn4+ + 2–  Sn2+ + 2 ,d vLor% vfHkfØ;k gksrh gSA
(C) Mg2+ + Sn2+  Mg + Sn4+ ,d Lor% vfHkfØ;k gksrh gSA
(D) ;gk¡] nqcZyre vkWDlhdkjd Sn4+ rFkk nqcZyre vipk;d Mn2+ gksrk gSA
Ans. [Hint : Reverse of (B) & (C) is spontaneous ; weakest Oxidizing Agent here is Mg 2+]
[ladsr : (B) rFkk (C) dk foijhr (Reverse) Lor% vfHkfØ;k gS( ;gk¡ nqcZyre vkWDlhdkjd Mg2+ gSA]
PAGE NO.- 6
d [ C]
11.* For the reaction 2A + B  C with the rate law = k [A]1 [B]–1 and started with A and B in
dt
stoichiometric proportion. Which is/are true ?
d [ C]
vfHkfØ;k 2A + B  C ds fy,] nj fu;e = k [A]1 [B]–1 rFkk jllehdj.kfefr lekuqikr esa A rFkk B ds lkFk
dt
izkjEHk fd;k tkrk gS rks dkSulk@dkSuls dFku lR; gS \

(A*) unit of k is Ms–1 (B*) [A], [B] and [C] all will be linear functions of time
(C*) [C] = 2kt (D) [C] = kt
(A*) k dh bdkbZ Ms–1 gSA (B*) [A], [B] rFkk [C] lHkh le; ds lkFk js[kh; Qyu gksxsaA
(C*) [C] = 2kt (D) [C] = kt
Sol. 2A + B  C
t=0 2a a 0
t=t 2a – 2x a–x x
d[C]
= k (2 (a – x) (a – x)–1) = 2k
dt
  d [c] =  k dt
 [C] = 2 kt ; unit of k = Ms–1 ; [A] = 2 (a – x) and [C] = x
[B] = (a – x).
12.* For a certain reaction A  products, the t½ as a function of [A]0 is given as below :
[A]0 (M) : 0.1 0.025
t1/2 (min.) : 100 50
Which of the following is/are true ?
1
(A*) The order is (B*) t½ would be 100 10 min for [A]0 = 1 M
2
(C) The order is 1 (D) t½ would be 100 min for [A]0 = 1 M
,d fuf'pr vfHkfØ;k A  mRikn] ds fy;s t½ dks [A]0 ds Qyu ds :i esa fuEu çdkj ls fn;k x;k gSA
[A]0 (M) : 0.1 0.025
t1/2 (min.) : 100 50
fuEu esa ls dkSulk lR; gSA
1
(A*) dksfV gSA (B*) [A]0 = 1 M ds fy;s t½, 100 10 min gksxkA
2
(C) çFke
dksfV gSA (D) [A]0 = 1 M ij t½, 100 min gksxkA
Sol. A  Products. ¼mRikn½
t1/2 = [conc.]1 – n n  order of reaction.¼vfHkfØ;k dh dksfV½
1– n
100  0.1 
=  
50  0.025 
PAGE NO.- 7
2 = 2 – 2n
 2n = 1.
1
 n= .
2
1
order of reaction is .
2
1
vfHkfØ;k dh dksfV 2
gSA
100 1/ 2
 0.1 
=    t1/2 = 100 10 min for [A0] = 1M.
t1/ 2  1 
13.* Which of the following statements is/are CORRECT ?

(A*) Complex [Co(NH3)4(H2O)Cl]Br2 can show both hydrate as well as ionization isomerism.
(B*) Complex [Co(NH3)5(H2O)](NO3)3 can show hydrate isomerism.
(C) Complex [Pt(NH3)4][PtCl6] cannot show coordination isomerism.
(D*) [Co(NH3)4(NO2)Cl]Cl can show both ionization as well as linkage isomerism.
fuEu esa ls dkSulk@dkSuls dFku lR; gSa %
(A*) ladqy [Co(NH3)4(H2O)Cl]Br2 tyh; leko;ork rFkk vk;uu leko;ork nksuksa dks iznf'kZr dj ldrk gSA
(B*) ladqy [Co(NH3)5(H2O)](NO3)3 tyh; leko;ork iznf'kZr dj ldrk gSA
(C) ladqy [Pt(NH3)4][PtCl6] milgl;ksatd leko;ork iznf'kZr ugha dj ldrk gSA
(D*) ladqy [Co(NH3)4(NO2)Cl]Cl vk;uu leko;ork rFkk fyadst leko;ork] nksuksa iznf'kZr dj ldrk gSA
Sol. (A) [Co(NH3)4(H2O)Cl]Br2 and [Co(NH3)4Br2]Cl.H2O ; ionization as well as hydrate isomers.
(B) [Co(NH3)5(H2O)](NO3)3 and [Co(NH3)5(NO3)](NO3)2H2O hydrate isomers.
(C) [Pt(NH3)4]2+ [PtCl6]2– and [Pt(NH3)4Cl2]2+ [PtCl4]2–
Pt(II) Pt(IV) Pt(IV) Pt(II)
(D) [Co(NH3)4(NO2)Cl]Cl ; [Co(NH3)4(ONO)Cl]Cl linkage isomer and [Co(NH3)4Cl2]NO2 ionization isomer.
gy % (A) [Co(NH3)4(H2O)Cl]Br2 rFkk [Co(NH3)4Br2]Cl.H2O ; vk;uu rFkk tyh; leko;oh
(B) [Co(NH3)5(H2O)](NO3)3 rFkk [Co(NH3)5(NO3)](NO3)2H2O tyh; leko;oh
(C) [Pt(NH3)4]2+ [PtCl6]2– rFkk [Pt(NH3)4Cl2]2+ [PtCl4]2–
Pt(II) Pt(IV) Pt(IV) Pt(II)
(D) [Co(NH3)4(NO2)Cl]Cl ; [Co(NH3)4(ONO)Cl]Cl fyadst leko;oh rFkk [Co(NH3)4Cl2]NO2 vk;uu leko;oh
PAGE NO.- 8
Paragraph for Question Nos. 14 to 15
iz'u 14 ls 15 ds fy, vuqPNsn
In the following graph are presented potential energy curves of H 2 molecule and its cation H 2 . Using the
informations provided on this graph answer the following questions.
fuEu vkjs[k esa] H2 v.kq o blds /kuk;u H2 dk fLFkfrt ÅtkZ vkjs[k iznf'kZr gksrs gaSA bl vkjs[k ls izkIr lwpukvksa dks iz;qDr
dj fuEufyf[kr iz'uksa dk mÙkj nhft,A
14. What is the bond length and bond order of H 2 and H 2 ?
(A) Species : H2 H 2
Bond length : 0.75 Å 1.25 Å
Bond order : 1 3/4
(B) Species : H2 H 2
Bond length : 0.75 Å 1Å
Bond order : 1 1/2
(C) Species : H2 H 2
Bond order : 1 2
(D*) Species : H2 H 2
Bond order : 1 1/2
H2 o H 2 dk cU/k yEckbZ o cU/k Øe D;k gS \
(A) Lih'kht : H2 H 2
cU/k yEckbZ : 0.75 Å 1.25 Å

cU/k Øe : 1 3/4
PAGE NO.- 9
(B) Lih'kht : H2 H 2
cU/k yEckbZ : 0.75 Å 1Å

cU/k Øe : 1 1/2
(C) Lih'kht : H2 H 2

cU/k Øe : 1 2
(D*) Lih'kht : H2 H 2

cU/k Øe : 1 1/2
Sol. For H2 minima is at internuclear distance 0.75 Å and for H2 minima is at inter molecular distance 1.25 Å.
H2 ds fy, vUrukfHkdh; nwjh ij fuEfu"V (minima) 0.75 Å gS o H2 ds fy, vUrj vkf.od nwjh ij fuEufu"V (minima)
1.25 Å gksrk gSA
15. What is the ionisation energy of H atom ?

H ijek.kq dh vk;uu ÅtkZ D;k gS \
(A) 200 kJ/mol (B*) 1300 kJ/mol (C) 1500 kJ/mol (D) 1400 kJ/mol
+
Sol. H  H + e Hioniz
H + H H + H+ + e Hioniz  Hioniz = –1300 – (–2600) = + 1300 kJ/mol
16. How many of the following reactions give yellow ppt.

fuEu esa ls fdruh vfHkfØ;k,¡ ihyk vo{ksi nsrh gS %
(i) NaBr + AgNO3 
(ii) NaI + AgNO3
(iii) NaBr + Pb(NO3)2 
(iv) NaI + Pb(NO3)2 
(v) Na2S + Cd(CH3COO)2 
(vi) K2CrO4 + Pb(CH3COO)2 
(vii) K2CrO4 + (CH3COO)2Ba 
(viii) K2CrO4 + AgNO3 
(ix) NaBr + Chlorine water (excess)  NaBr + Dyksjhu ty ¼vkf/kD;½ 
Ans. 7
Sol. (i), (ii), (iv), (v), (vi), (vii), (viii)
(i) NaBr + AgNO3  AgBr + NaNO3
Pale Yellow gYdk ihyk
(ii) NaI + AgNO3 AgI + NaNO3
Yellow ihyk
(iii) NaBr + Pb(NO3)2  PbBr2 + NaNO3
White lQsn
(iv) NaI + Pb(NO3)2  PbI2 + NaNO3
Yellow ihyk
(v) Na2S + Cd(CH3COO)2  CdS + CH3COONa
PAGE NO.- 10
Yellow ihyk
(vi) K2CrO4 + Pb(CH3COO)2  PbCrO4 + CH3COOK
Yellow ihyk
(vii) K2CrO4 + (CH3COO)2Ba  BaCrO4 + CH3COOK
Yellow ihyk
(viii) K2CrO4 + AgNO3  Ag2CrO4 + KNO3
Brick red bZV ds leku yky
(ix) NaBr + Chlorine water  2BrCl
(excess) ¼vkf/kD;½ Pale yellow gYdk ihyk
17. A metal weighting 1.75 g was dissolved in 50 ml of N H2SO4. After reaction remaining H2SO4 required 15 ml
of N NaOH for neutrilisation. Find out the equivalent weight the metal.
,d /kkrq dk 1.75 g N H2SO4 ds 50 ml esa foys; fd;k tkrk gS vfHkfØ;k ds ckn 'ks"k H2SO4 ds mnklhuhdj.k ds fy, N
NaOH ds 15 ml vko';d gksrs gS rc /kkrq dk rqY;kadh Hkkj Kkr dhft,A
Ans. 50
Sol. 2NaOH + H2SO4 Na2SO4 + 2H2O
Meq. 15 × 1 15 Meq.
Total Meq. of H2SO4 = 50
Meq. of H2SO4 consumed metal = 50 – 15 = 35 Meq. H2SO4 = Meq metal
1.75 1750
35 = Eq. wt. × 1000 Eq. wt. = = 50
35
g y- 2NaOH + H2SO4 Na2SO4 + 2H2O
feyhrqY;kad 15 × 1 15 feyhrqY;kad
H2SO4 ds dqy feyhrqY;kad = 50
H2SO4 ds /kkrq ds lkFk [kpZ gq, feyhrqY;kad = 50 – 15 = 35
H2SO4 ds feyhrqY;kad = M ds feyhrqY;kad
1.75 1750
35 = Eq. wt. × 1000 rqY;kadh Hkkj = 35 = 50
18. 1 mole of each of the following acids exactly neutralize a maximum of how many moles of NaOH, under
required favourable conditions ?
HCl, HNO3, H2SO4, H2SO3, H3PO4, H3PO3, H3PO2, H4P2O5, H3BO3, H3P3O9
vuqdwy ifjfLFkfr;ksa ij izR;sd vEy ds 1 eksy NaOH ds vf/kdre fdrus eksy dh iw.kZ mnklhu vfHkfØ;k ds fy;s vko';d
gS \
HCl, HNO3, H2SO4, H2SO3, H3PO4, H3PO3, H3PO2, H4P2O5, H3BO3, H3P3O9
Ans. 18
Sol. H2SO4, H2SO3, H3PO3, H4P2O5 are diprotic. HCl, HNO 3, H3PO2, H 3BO3 are monoprotic, H3P3O9, H 3PO4
is triprotic
Sol. H2SO4, H2SO3, H3PO3, H4P2O5 f}{kkjh; gSaA HCl, HNO3, H3PO2, H3BO3 ,d {kkjh; gS] H3PO4, H3P3O9 f=k{kkjh;
gSA
PAGE NO.- 11
19. Match the following for a 1st order reaction A  products with time on the x axis.
,d izFke dksfV dh vfHkfØ;k A  mRiknksa ds fy, x v{k ij le; ds lkFk fuEu dks lqesfyr dhft,A
Column I Column II
LrEHk I LrEHk II
(A) [A] v/s time (p)
[A] rFkk le;
 d [A ]
(B) v/s [A] (q)
dt
 d[A]
rFkk [A]
dt
 d [A ]
(C) v/s time (r)
dt
 d [A ]
rFkk le;
dt
(D) log [A] v/s time (s)
log [A] rFkk le;

Ans. [A – r] ; [B – q] ; [C – r] ; [D – p].
Sol. For Ist order reaction,
¼izFke dksfV vfHkfØ;k ds fy,½
[A]t = [A]0 e– K t
d [A ]
– = K [A]t = [A]0 K e– K t
dt
Kt
Kt = 2.303 log [A]0 – 2.303 log [A]t  log [A]t = log [A]0 – .
2 .303
PAGE NO.- 12
DPP No. # 49 (JEE-MAIN)
Total Marks : 66 Max. Time : 42 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.21 (3 marks, 2 min.) [63, 44]
1. In the metallurgy of iron, the upper layer obtained in the bottom of blast furnace mainly contains
yksg /kkrq dk fu"d"kZ.k okR;k Hkêh es djus ij ry es lcls Åijh ijr esa fuEu mifLFkr gksxk
(A*) CaSiO3 (B) FeSiO3 (C) Fe3C (D) Pig iron ¼<yok yksgk½
Ans. Upper layer is slag. (light in weight)
CaO + SiO2  CaSiO3 calcium silicate (slag.)
Ans. Åijh ijr xkyd gS ¼ Hkkj esa gYdh gS ½
CaO + SiO2  CaSiO3 dsfYl;e flfydsV ¼xkyd½ (calcium silicate) (slag.)
2. Chlorine gas is obtained by various reactions but not by–

(A) KMnO4 + Conc HCl  (B) KCl + F2 
 
(C*) KCl + K2Cr2O7 + Conc H2SO4  (D) MnO2 + Conc HCl 
dbZ vfHkfØ;kvks }kjk Dyksfju xSl feyrh gS ij bues ls fdl vfHkfØ;k ls ugh feyrh gS&

(A) KMnO4 + lkUnz HCl  (B) KCl + F2 
 
(C*) KCl + K2Cr2O7 + lkUnz H2SO4  (D) MnO2 + lkUnz HCl 
Ans. (C) Here orange red vapours of CrO2Cl2 [Chromyl chloride] is formed
(C) ;gk¡ CrO2Cl2 ¼Øksekby dkyksjkbM½ [Chromyl chloride] fd yky ukjaxh jax dh ok"i curh gSA
3. Which will give maximum [H+] ion concentration by dissolving equal moles in water
fuEu es ls fdldks ikuh es ?kksyus ij [H+] vk;u dh lkUnzrk vf/kdre gksxhA
(A*) LiOH (B) NaOH (C) KOH (D) RbOH

Ans. (A) LiOH is least basic  [OH ]  min imum
 [H ]  max imum
 [OH ] 
(A) LiOH lcls de {kkjh; gSA
 [H ] 
4. A chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen flame, no distinctive
colour is noticed. The cation is–
,d DyksjkbM BaMs ty esa iw.kZ foys; gS rFkk ;g ,d IysfVue rkj dks cqUlsu Tokyk esa dksbZ fo'ks"k jax çnku ugha djrk gSA og
èkuk;u gS %
(A) Ca2+ (B*) Mg2+ (C) Ba2+ (D) Pb2+
Ans. (B) PbCl2 is insoluble in cold water.
Ca2+ & Ba2+ give bricke red & apple green colours respectively to the Bunsen flame
(B) PbCl2 B.Ms ikuh esa vfoys; gSA
Ca2+ & Ba2+ cqUlsu Tokyk ds lkFk Øe'k% bZaV tSlk yky vkSj lsc tSlk gjk (bricke red & apple green colours ) jax nsrk gSA
5. In electro plating of copper, K [Ag(CN)2] is used instead of AgNO3 because –
(A) Thin layer of Ag is formed on Cu
(B) Higher voltage is required
(C) Ag+ ions are completely removed from solution
(D*) less availability of Ag+ ions, as Cu cannot displace Ag from [Ag(CN)2]– ions.
rk¡cs ds oS|qr ySiu (electro plating) es AgNO3 ds cnys K [Ag(CN)2] dk mi;ksx djrs gS D;ksfd –
(A) Cuij Ag dh iryh ijr cu tkrh gS (B) mPp foHko (voltage) vko';d gSA
+
(C) foy;u ls Ag vk;u iw.kZr% gV tkrs gSA
(D*) Ag+ vk;u dh vYi miyC/krk gS pwafd Cu, Ag dks [Ag(CN)2]– vk;u ls foLFkkfir ugh dj ldrkA
PAGE NO.- 13
6. Which of the following will not be dissolved in aqueous NaOH solution ?
bues ls dkSu tyh; NaOH foy;u es ugh ?kqysxk ?
(A) Al(OH)3 (B) Zn(OH)2 (C*) Mg(OH)2 (D) Be(OH)2
Ans. (C) Mg(OH)2 is not amphoteric & does not react with NaOH
(C) Mg(OH)2 mHk;/kehZ ugh gS vkSj NaOH ls fØ;k ugh djrkA
7. f O – O bond length in H2O2 is x and that in O2F2 is y then–

H2O2 esa O – O dh cU/k yEckbZ x o O2F2 esa y gS rc –
(A) x = y (B*) x > y (C) x < y (D) Nothing can be said.
(A) x = y (B*) x > y (C) x < y (D) dqN ugh dgk tk ldrk
Ans. (B)
8. Which of the following is a peroxide–

fuEu es ls dkSu ijkWDlkbM gS %
(A) KO2 (B*) BaO2 (C) PbO2 (D) ClO2
Ans. (B) Barium peroxide (BaO 2) contains O22–
(B) (Barium peroxide) (BaO 2) csfj;e ijkWDlkbM O22– j[krk gSA
9. Identify the true statement about XeF 4

(A) Its hybridization is dsp2 (B*) Its shape is square planar
(C) Its shape is octahedral (D) its shape is tetrahedral
XeF4 ds ckjs esa lR; dFku igpkfu;s&
(A) bldk ladj.k dsp2 gSA (B*) bldh vkd`fr oxZ leryh; gSA
(C) bldh vkd`fr v"VQydh; gSA (D) bldh vkd`fr prq"Qydh; gS
Ans. (B) XeF4 is square planar with 2 lane pairs
(B) XeF4 es 2 ,dkdh bysDVªkWu ;qXe gS rFkk ;s oxZ leryh; gSA
Hybridization = SP3d2
10. Which of the following property is not similar in the pair of complex [Fe(CN)6]3– and [Co(NH3)6]+3
[Fe(CN)6]3– rFkk [Co(NH3)6]+3 ladqy ;qXe eas fuEu ls dkSulk xq.k leku ugh gS %
(A*) Magnetic moment (B) Geometry (C) Hybridization (D) All of these
(A*) pqEcdh; vk?kw.kZ (B) T;kfefr (C) ladj.k (D) ;s lHkh
–
Ans. (A) Since number of unpaired e are different
(A) v;qfXer e– dh la[;k vyx&vyx gSA
PAGE NO.- 14
11. pH of an aq. KCl solution at 75ºC should be
75ºC rki ij tyh; KCl foy;u dh pH gksuh pkfg;s
(A) 7 (B) >7 (C*) <7 (D) 0
Sol. (C) KCl is neutral solution so its pH will be seven at 25ºC but at temperature > 25ºC, Kw will increase so H +
& OH– concentration will in crease for neutral solution at 75ºC [H+] = [OH –] > 10–7
pH < 7 so pH will less then 7
KCl ,d mnklhu foy;u gS blfy, bldh pH 25ºC ij 7 gksxh ysfdu 25ºC ls vf/kd ij, Kw es o`f) gksxh blfy, 75ºC
ij [H+] = [OH–] > 10–7 ij mnklhu foy;u ds fy,] pH 7 ls de gksxh&
12. Consider the general hypothetical reaction

bl dkYifud vfHkfØ;k ij fopkj djks
A(s) 2B(g) + 3C(g)
If the concentration of C at equilibrium is doubled, then after the equilibrium is re-established, the concentration
of B will be
;fn C dh lkUnzrk lkE; ij nqxquh dj nh tk;s rc lkE; LFkkfir gksus ij B dh lkUnzrk gksxh&
(A) two times the original value (B) one half of its original value
(C*) 1/2 2 times the original value (D) 2 2 times the original value
(A) viusokLrfod (original) eku dh nks xquh (B) vius okLrfod (original) eku dh vk/kh
(C*) vius okLrfod (original) eku dh 1/2 2 xquh (D) vius okLrfod (original) eku dh 2 2 xquh
Sol. (C) K = [B(g)]2 [C(g)]3 = x2y3. If [C(g)] is doubled
i.e. = 2y. Suppose [B(g)] is z. Then
1 2 1 1
K = z2 (2y)3 = x2y3 or z2 = x or z= x= x.
8 8 2 2
K = [B(g)]2 [C(g)]3 = x2y3. ;fn [C(g)] dks nqxuk djs
i.e. = 2y. ekuk [B(g)] , z gS rc
1 2 1 1
K = z2 (2y)3 = x2y3 or z2 = x or z= x= x.
8 8 2 2
13. A complex organic compound contains 21 atoms of carbon per molecule. The percentage of carbon in the
compound is 70%. If 36 gram of the substance is dissolved in 100 mL of water then the molarity of the
solution will be–
,d dkcZfud ladqy ;kSfxd dkcZu ds 21 ijek.kq izfreksy j[krk gSA ;kSfxd esa dkcZu dk 70%. mifLFkr gSA ;fn 36 xzke
inkFkZ dks 100 mL ikuh es feyk;k tk;s rc foy;u dh eksyjrk gksxh %
(A*) 1 (B) 0.1 (C) 1.43 (D) 0.143
Sol. One mole of compound contains 12 × 21 = 252 g carbon
,d eksy ;ksfxd 12 × 21 = 252 g dkcZu gS
100
 eksyj Hkkj = 252 × 70 = 360
36 1000
 eksyjrk = 360  100 = 1
14. A metal exist in BCC structure and has a density of 7.5 g /cc. If edge length of unit cell 5 Aº, how many
atoms are present in 15 g metal ?
,d /kkrq dk; dsfUnzr ?kuh; (BCC) lajpuk j[krh gS rFkk bldk ?kuRo 7.5 g /cc gSA ;fn ,dd dksf”"Bdk dh dksj yEckbZ
5 Aº gSA rks 15 xzke /kkrq eas fdrus ijek.kq mifLFkr gksxsa \
(A*) 3.2 × 1022 (B) 1.66 ×1022 (C) 1.66× 1024 (D) None
ZM 2M
Ans. (A) d = a  N  7.5 = 8 3
A ( 5  10 )  6  10 23
PAGE NO.- 15
7.5  125  10 24  6 3  10 23
M= = 281.25 g mol–1
2
15
 (15 xzke es v.kq dh la[;k½ No of atoms in 15 g = 281.25 × 6 × 1023 = 3.2 × 1022
15. The purification of a colloidal solution cannot be done by

(A) Ultrafiltration (B*) Electro phoresis (C) Dialysis (D) Electrodialysis
dksykWbMh foy;u dk 'kqf)dj.k fdlds }kjk ugh gks ldrk&
(A) vfr lw{e fQYVjhdj.k (B*) oS|qr d.k lapyu (C) viksgu (D) oS|qr viksgu
16. The incorrect statement is – (Regarding temperature coefficient of emf of the cell)
vlR; dFku gS – (rkieku xq.kkad dks lsy ds fo- ok- cy ds lUnHkZ esa ekurs gq,)
 dE 
(A) When  dT  = 0 then H = nFE
 p
 dE 
(B) When  dT  > 0 then nFE > H (Endothermic reaction)
 p
 dE 
(C) When  dT  < 0 then nFE < H (Exothermic reaction)
 p
 dE 
(D*) When  dT  = 0 , then H > nFE (Endothermic reaction)
 p
 dE 
(A) tc  dT  = 0 rc H = nFE gS
 p
 dE 
(B) tc  dT  > 0 rc nFE > H vfHkfØ;k Å"ek'kks"kh (Endothermic reaction) gSA
 p
 dE 
(C) tc  dT  < 0 rc nFE < H vfHkfØ;k Å"ek{ksih (Exothermic reaction) gSA
 p
 dE 
(D*) tc  dT  = 0 , rc H > nFE vfHkfØ;k Å"ek'kks"kh (Endothermic reaction) gSA
 p
17. At which temperature the, reaction will be spontaneous if H = – 176 kJ, S = – 284.5 JK–1
H = – 176 kJ, S = – 284.5 JK–1 gS rks fdl rki ij vfHkfØ;k Lor% gksxh
(A) 380 K (B) 480 K (C) 580 k (D*) 680 K
Ans. (D) The minimum temperature above which the reaction will be spontaneous is given by
H 176  1000J
G = 0  T = = = 619 K
S  284.5JK 1
Hence at 680 K, G < O
(D) mijksDr og U;wuRe rki gS ftl ij vfHkfØ;k Lor% gksxh
H 176  1000J
G = 0  T = = = 619 K
S  284.5JK 1
blfy, 680 K ij G < O
18. The solvent which is better to be used during ebullioscopic, measurement has–
(A*) High Kb (B) Low Kb (C) Kb = Kf (D) Kf < Kb
DoFkukadekih (ebullioscopic) vuqekiu ds nkSjku dkSuls foyk;d dk mi;ksx djuk vPNk gS %
(A*) mPp Kb (B) fuEu Kb (C) Kb = Kf (D) Kf < Kb
Ans. (A) Higher the value of Kb , more will be Tb . Hence, it can be measured more accurately
(A) Kb dk eku T;knk gksxk rc Tb dk eku Hkh T;knk gksxk blfy, ;g vf/kd lgh ekik tk ldrk gSA
PAGE NO.- 16
19. Standard molar enthalpy of formation of CO 2 is equal to -
(A) zero
(B) the standard molar enthalpy of combustion of gaseous carbon
(C) the sum of standard molar enthalpies of CO & O 2
(D*) the standard molar enthalpy of combustion of C(s)
CO2 ds lEHkou dh ekud eksyj ,UFkSYih fdlds cjkcj gS -
(A) 'kwU;
(B) xSlh; dkcZu ds ngu dh ekud eksyj ,UFkSYih ds cjkcj gS
(C) CO vkSj O2 dh ekud eksyj ,UFkSYih ds ;ksx ds cjkcj gS
(D*) C(s) ds ngu dh ekud eksyj ,UFkSYih ds cjkcj gS
20. A 0.1 A sodium acetate solution was prepared. The Kh = 5.6 × 10 –10 . The correct statement is
(A) Degree a hydrolysis is 7.48 × 10–4 (B) [OH –] = 7.48 × 10–5
(C*) [OH–] = 7.48 × 10–6 M (D) pH is approximately 7
,d 0.1 A dk lksfM;e ,flVsV dk foy;u cuk;k tkrk gSA ftldk Kh = 5.6 × 10–10 gSA
(A) ty vi?kVu dh ek=kk 7.48 × 10–4 gS (B) [OH –] = 7.48 × 10–5 gSA
(C*) [OH–] = 7.48 × 10–6 M gSA (D) pH yxHkx 7 ds cjkcj gSA
Sol. CH3COO– + H2O CH3COOH + H–
0.1 (1 – h) 0.1 h 0.1 h
0.1 h2
 5.6 × 10–10 0.1 h2  h = 7.48 × 10
︲
5
Kh =
1 h
︲
 [OH ] 0.1 × 7.48 × 10–5 = 7.48 × 10–6 M
21. For the reaction

2H(g) H2(g) + I2(g), the degree of dissociation () of HI(g) is related to equilibrium constant k p by
expression-
fuEu vfHkfØ;k
2H(g) H2(g) + I2(g) ds fy, HI(g) ds fo;kstu dh ek=kk dk lkE; fu;arkd kp ls lEcU/k fdl O;atu ls irk pysxk
-
1  2 kp 1  2k p 2k p 2 kp
(A) (B) (C) (D*)
2 2 1  2k p 1 2 k p
Ans. 2H H2 + 2
1– /2 /2
2
 / 2P 
Kp = or, = 2 Kp
(1   )2 P 2 1 
2 Kp
  = 1 2 K
p
PAGE NO.- 17

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PHY./INO.

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 48 & 49

This DPP is to be discussed in the week (19.10.2015 to 24.10.2015)

so, this time represents half life.

bl fy, le; v)Z vk;q dks iznf'kZr djrk gSA

For first order (izFke dksfV ds fy,)

For second order (f}rh; dksfV ds fy,)

so, reaction is 2nd order. Unit of rate constant is M–1s–1.

 (0.12 – 0.06 )  ( 0.06 – 0.03 )

so reaction must be of first order. vr% vfHkfØ;k izFke dksfV dh gSA

kA [H ] A 2 [H ] A [ Acid A ]

Sol. A(g)  2B(g) + C(g)

Let initial pressure P0 0 0

= 0.02 min–1 = 1.2 hr–1

gy % A(g)  2B(g) + C(g)

ekuk fd izkjfEHkd nkc P0 0 0

6. In the following reaction started only with A 8 ,

fuEu nh xbZ vfHkfØ;k dsoy A8 , ds lkFk izkjEHk djrs gS %

(A) 10% (B*) 83.33% (C) 15% (D) 20%

8.* Select the correct statement :

stoichiometric proportion. Which is/are true ?

izkjEHk fd;k tkrk gS rks dkSulk@dkSuls dFku lR; gS \

(C) The order is 1 (D) t½ would be 100 min for [A]0 = 1 M

13.* Which of the following statements is/are CORRECT ?

informations provided on this graph answer the following questions.

14. What is the bond length and bond order of H 2 and H 2 ?

H2 o H 2 dk cU/k yEckbZ o cU/k Øe D;k gS \

cU/k yEckbZ : 0.75 Å 1.25 Å

cU/k yEckbZ : 0.75 Å 1Å

cU/k yEckbZ : 0.75 Å 1.5 Å

cU/k yEckbZ : 0.75 Å 1.25 Å

15. What is the ionisation energy of H atom ?

16. How many of the following reactions give yellow ppt.

g y- 2NaOH + H2SO4 Na2SO4 + 2H2O

(A) [A] v/s time (p)

[A] rFkk le;

(D) log [A] v/s time (s)

log [A] rFkk le;

7. f O – O bond length in H2O2 is x and that in O2F2 is y then–

8. Which of the following is a peroxide–

9. Identify the true statement about XeF 4

12. Consider the general hypothetical reaction

15. The purification of a colloidal solution cannot be done by

 [OH ] 0.1 × 7.48 × 10–5 = 7.48 × 10–6 M

21. For the reaction

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