FIITJEE

PINNACLE TWO YEAR Chennai Centre

Time: 1.5 Hours Maximum Marks: 60

• Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
• You are not allowed to leave the examination hall before end of the test.

General
1. This booklet is your Question Paper.
2. All questions are single answer type.
3. This Question Paper contains 12 subjective questions.
4. Each question carries +5 marks.

Any Student who indulges in Malpractice will be terminated immediately

Name of the candidate:_________________________________________________

Batch :___________________ Date of Examination:__________
Enrollment Number : ___________________________________________________

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 2 - PCMB

USEFUL DATA
PHYSICS CHEMISTRY
Acceleration due to gravity : g = 10 m/s2 −1 −1
Gas Constant R = 8.314 J K mol
−34
Planck constant : h = 6.6 × 10 J − s = 0.0821 Lit atm
−19 −1 −1
Charge of electron : e = 1.6 × 10 C K mol
Mass of electron : me = 9.1 × 10
−31
kg
= 1.987 ≈ 2 Cal
−1 −1
Permittivity of free space : K mol

ε 0 = 8.85 × 10
−12 2
C /N −m
2
Avogadro’s Number Na = 6.023 × 10 23
−34
Density of water : ρ water 3
= 10 kg / m
3
Planck’s constant h = 6.625 ×10 J .s
5 2 −27
Atmospheric pressure : Pa = 10 N / m = 6.625 ×10 erg .s
Gas constant : R = 8.314 J 1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
K −1 mol −1 −27
1 amu = 1.66 ×10 kg
−19
1 eV = 1.6 × 10 J
Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.
Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,
Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.

1. A ball of mass m hits a wedge vertically with speed v0, which is m

placed, on a smooth horizontal surface. Find the maximum v0

compression in the spring, if the collision is perfectly elastic and no M
friction any where. 0
45

2. A pulley fixed to the ceiling of a lift carries a thread whose ends are attached
to the masses of 4kg and 2kg. The lift starts going down with on acceleration
of a0 = 4 m/s2 relative to ground. Calculate
a0
(a) The acceleration of the load 4kg relative to the ground and relative to
lift.
4 kg 2 kg
(b) The force exerted by the pulley on the ceiling of the lift
(Thread and pulley are massless, g=10 m/s2)

3. A small disc of mass m slides down a smooth hill of height h m

without initial velocity and gets onto a planck of mass M lying
on the horizontal plane at the base of the hill, as shown in the
h
figure. Due to friction between the disc and the plank, the disc
slows down and ultimately, both move together.
(a) Find the common velocity of the disc and the planck. M
(b) Find the work done by the friction
(c) Find the distance moved by the disc with respect to the
planck before they start moving together.

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 3 - PCMB

4. The average person can see the red colour imparted by the complex [Fe(SCN)]2+ to an aqueous
solution if the concentration of the complex is 6 × 10–6M or greater. What minimum concentration of
KSCN would be required to make it possible to detect 1 ppm(by mass) of Fe3+ in a natural water
sample. The instability constant for [Fe(SCN)]2+ Fe3+ + SCN– is 7.142 × 10–3. The density of
natural water can be assumed to be 1g/cc.

5. The type of hybridization and shape of following molecules/ion are

a) ClF2− __________ and __________ (1 Mark)
b) N ( CH3 )3 __________ and __________ (1 Mark)
c) PF2Br3 __________ and __________ (1 Mark)
d) TeCl4 __________ and __________ (1 Mark)
e) XeOF4 __________ and __________ (1 Mark)

6. a) How many number of angular and spherical nodes are present in the following orbitals
4d ______________ (1 mark)
2s______________ (1 mark)
3p______________ (1 mark)

b) Predict total spin for each configuration

i) 1s2 2s2 2p6 ______________ (1/2 mark)
ii) 1s22s22p5 ______________ (1/2 mark)
iii) 1s2 ______________ (1/2 mark)
iv) 1s22s22p3 ______________ (1/2 mark)

7. Let ABC be a triangle with AB = AC. If D is the mid point of BC, E foot of perpendicular drawn from
D to AC and F is mid point of DE. Prove that AF is perpendicular to BE.

8. Ai, Hi, Gi (i = 1, 2, 3, ......, n) are respectively n arithmetic means, n harmonic means and n geometric
means inserted between two positive numbers a and b. Prove that
1

A1 + A 2 + ..... + A n  (G1.G2 ......Gn )  n

2
≥  .
n  H1.H2 ......Hn 

9. Consider two lines L1: a1x + b1y + c1 = 0 and L2: a2x + b2y + c2 = 0, where c1, c2 ≠ 0. Intersecting at a
point P. A line L3 is drawn through the origin meeting the line L1 and L2 in A and B respectively such
that PA = PB. Similarly one more line L4 is drawn through the origin meeting the lines L1 and L2 in
A1 and B1 respectively such that PA1 = PB1. Obtain the combined equations of lines L3 and L4.

10. Explain prophase I of meiosis.

11. Brief note on the digestion of food in the stomach.

12. Explain the process of urine formation with the help of the diagram.

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 4 - PCMB

Space for Rough Work

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 5 - PCMB

KVPY MOCK TEST – PAPER – 2 (SUB) – CLASS – XI –

SOLUTIONS

1.Sol. The ball rebounds horizontally. Let say with speed v

0
and the wedge with V. 45
0
Momentum conservation mv = MV 45
v
MV M V
⇒ v=
m 45
0

Restitution
V cos 45 + v cos 45 v + V
1= =
v 0 cos 45 v0
⇒ v + V = v0
MV
+ V = v0
m
(m + M)V mv 0
= v0 ⇒ V=
m m+M
1 1 M M mv 0
MV 2 = kx 2 ⇒ x= v =
2 2 k k m+M

2.sol. Free body diagrams :

f′1
αA αC f′2

P Q
f1 f2
f1 f2
MAg MCg

Cylinder A Cylinder B Cylinder C

MBg

For the cylinder B

MBg – (f1 + f2) = MB aB
f1 + f2 = 25 – 2.5aB . . . (i)
Taking torque about point P for cylinder A
τP = IP αA = f1 × 2r1 + MAg × r
1
[ × 2 × (0.2)2 + 2 × (0.2)2 ] αA = f1 × 0.4 + 2 × 10 × 0.2
2
0.1 2 αA = 0.4 f1 + 4 . . . (ii)
Taking torque about point Q for cylinder C
τQ = IQ αC = f2 × 2r2 + Mc.g × r2
1
[ × 1× (0.1)2 + 1× (0.1)2 ]α c = f2 × 2 × 0.1 + 1× 10 × 0.1 ]
2
0.015 αc = 0.2 f2 + 1 . . . (iii)
Also, aB = αA × 0.4
1
αA = aB = 2.5aB
0.4
and aB = αC × 0.2

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 6 - PCMB

αC= 5 aB
Putting values of αA ∝ αC in (ii) and (iii) ,
0.12 × 2.5 aB = 0.4 f1 + 4 ⇒ 0.3 aB = 0.4 f1 + 4 . . . (iv)
0.015 × 5aB = 0.2 f2 + 1 ⇒ 0.15 aB = 0.4f2 + 2 . . . (v)
from (iv) and (v)
(0.3 + 0.15)aB = 0.4(f1 + f2) + 6
0.45 aB = 0.4 (25 – 2.5 aB) + 6
16
aB = = 11.03 m/s2
1.45

3.sol. (a) Velocity of the disc at the foot of the N

hill is v0 = 2gh . When it slides on the
plank, friction opposes its motion and f
favours the motion of the plank as shown ms
in the figure. N
f

Let their common velocity be V, then

for m, V = v0 - µgt
µmgt
for M, V=
M
Eliminating t from the above two equations,
mv 0
V=
m+ M
(b) Using Work - Energy theorem
Wf = Kf - Ki
1 1
Wf = (m + M)V2 - mv02
2 2
2
1 mMv 0 mMgh
=- =-
2 m+ M m+ M
(c) Acceleration of the disc w.r.t the plank is
m  m + M
arel = µg + µ g = µg  
M  M 
u 2rel Mv 20 Mh
xrel = = =
2 a rel 2µg( m + M) µ( m + M)

10 −3 g 10 −3
4.sol Initial concentration of Fe3+ = = moles / litre (1 Mark)
1L 56

Let initial concentration of SCN– be ‘a’ M

∴ [Fe(SCN)]2+ Fe3+ + SCN–
Initial 0 1.78 × 10–5 aM
At eqm. x (1.78 × 10–5 – x) (a – x)
–6
x = 6 ×10 M (2 Mark)

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 7 - PCMB

(a − 6 × 10−6 )(1.78 × 10−5 − 6 × 10−6 )

∴ = 7.142×10-3
6 × 10−6

a = 3.637 × 10–3M
(1 Mark)

5.sol a) ClF2− :- Hybridization = sp3 d

shape = Linear F Cl F

b) N ( CH3 )3 :- Hybridization = sp3

shape =Pyramidal N
CH3 CH
CH3 3
c) Br F
PF2Br3 :-Hybridization = sp3 d
shape =Trigonal bi pyramidal

P Br

F
Br
d) TeCl4 : Hybridization = sp3 d Cl
shape =see saw shape Cl

Te

Cl
Cl
(e) XeOF4 :- O
Hybridization sp3d2
Structure octahedral F
Shape:- square pyramidal F
Xe
F F

6.sol a) Angular nodes special nodes

4d (l) (n-l-1)
2 1
2s 0 1
3p 1 1
1 3
b) (i) 0 (ii) ± (iii) 0 (iv) ±
2 2

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 8 - PCMB

 ab 2 a 2b 
7. Coordinates of point E is  ,  A(0, b)
 a2 + b2 a2 + b2 
 
 ab 2
a 2b  E
∴ Coordinates of point F is  , 
 2(a2 + b2 ) 2(a 2 + b 2 ) 
  F
2
ab B(–a, 0) D C(a, 0)
−b
2(a 2 + b2 ) a2b + 2b3 a2 + 2b2
Slope of AF = = − = −
ab 2 ab 2 ab
2 2
2(a + b )
a 2b
2 2 ab
Slope of BE = a 2+ b = 2
ab a + 2b 2
+ a
a2 + b2
As Product of slopes of AF and BE = –1
∴ AF and BE are perpendicular.

A1 + A 2 + ...... + A n a + b
8. We have =
n 2
1
(G1G2......Gn )n = ab
1 1 1 1 1
+ + ....... + +
H1 H2 Hn a+b
and = a b =
n 2 2ab
A + A 2 + ...... + A n a + b 1 1 1 1 2
Hence 1 = ab =  + + .... + [G
 1 2G .......Gn ]n
n 2ab n  H1 H2 Hn 
1 1 1
 + + .... + 1

[ ] [ ]
1 1
H
 1 H Hn  1 1 1  n
= (G1G2 .......Gn ) ≥ (G1G2 .......Gn ) n  .
2 n 2 2
.... 
n  H1 H2 Hn 
1

A + A 2 + ...... + A n  [G1G2 .......Gn ]  n

2
⇒ 1 ≥  .
n  H1H2 .........Hn 

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 9 - PCMB

9. Draw lines L5 and L6 through P parallel to L3 and L4 respectively.

∠A1PM = ∠PAB = ∠PBA (∵ AP = BP)
= ∠B1PM i.e. L5
⇒ PM is the bisector of L1 and L2

B L4
B1
O
A1
N
L6 P

A L1: a1x+ b1y+ c1 =0

L3
L2: a2x+ b2y+ c2 =0
L5

Again ∠APN = ∠PA1B1 = ∠PB1A1 = ∠BPN (∵ A1P = B1P)

⇒PN i.e. L6 is the bisector of L1 and L2
a1x + b1y + c1 a2 x + b2 y + c 2
Now joint equation of L5 and L6 is =±
a12 + b12 a 22 + b 22
a1x + b1y a2 x + b2 y
⇒ Joint equation of L3 and L4 is =± [∵ L3 and L4 are parallel to L5 and L6 respectively and
a12 + b12 a22 + b 22
pass through origin ]
( ) (
⇒ (a1x + b1y)2 a 22 + b22 = (a2x + b2y)2 a12 + b12 . )

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