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Environment

I N F O R M A T I O N F R O M K O D A K J-300 $10.00

Environmental Guidelines for Amateur


Photographers
Kodak’s health, safety,

and environmental

publications are available

to help you manage your

photographic processing

operations in a safe,

environmentally sound

and cost-effective

manner. This publication

will help amateur

As a photographer, you have a photographers know


photographer and charge for your
unique sensitivity to the environ- services, you are required by law to
ment around you. But, as an comply with certain environmental
how to safely handle
amateur photographer, you don’t and workplace safety regulations
have to worry about the (some of which are covered in this and dispose of
environmental and safety publication). As an amateur
regulations that apply to photographer, you are not required photographic
commercial businesses and by law to follow those regulations
professional photographers. but we are providing processing chemicals.
But you still need to know how to recommendations on safe handling
safely handle and dispose of and waste management practices.
photographic processing chemicals.

SAFETY
AMATEUR OR
PROFESSIONAL? Chemicals are safe when handled
properly—that’s why it’s important
An amateur is someone who to know and understand the
engages in an activity as a pastime chemicals you’re working with and
rather than a profession. An the appropriate protective measures
amateur photographer does not you should use when handling
generate (or try to generate) revenue them.
from the use of photography. When
you become a professional

©Eastman Kodak Company, 1999


have a fresh-air supply duct to • Handling and Storage: special
PERSONAL PROTECTIVE your darkroom, set your exhaust personal precautionary measures
EQUIPMENT rate slightly higher than the and storage information.
supply rate. This produces a slight • Exposure and Personal
When working with photographic negative pressure and reduces the Protection: ventilation and what
processing chemicals, you should chance of vapors or gases personal protective equipment is
wear protective clothing to ensure escaping to an adjoining room. needed, such as gloves, goggles,
your safety. Whenever the potential To determine how much exhaust etc.
exists for chemicals to get in your per hour is required for your • Physical and Chemical Properties:
eyes, wear safety glasses with side darkroom: such as pH, color, and odor.
shields. When mixing chemicals, • Determine room volume
wear tight-fitting goggles. Wear • Stability and Reactivity:
(h x l x w)
impervious gloves, such as those incompatibility with other
• Multiply by 10 chemicals.
made with Neoprene or Nitrile, to
prevent contact with skin. You • Divide by 60 minutes • Health Information: such as
should also wear an apron, or other Most darkrooms are 10’ h x 10’ l x symptoms of overexposure.
protective clothing that is 8’ w which equals 800 cubic • Disposal Information: waste
impervious to chemicals, to prevent feet (ft3). Therefore, management options for the
chemicals from coming in contact product.
with your clothing. Exhaust rate of
800 ft3 x 10 133 ft3 min for
x 10 = 10 room
OBTAINING MSDSs
VENTILATION 60 min/hr
changes
To get a copy of an MSDS for a
per hour
Some Kodak photographic Kodak product, see your dealer or
processing solutions may release retail store, or call us at
vapors or gases that can irritate the MATERIAL SAFETY DATA 1-800-242-2424, ext. 25, or fax us at
eyes and respiratory tract and have SHEETS 716-724-9656. Please provide the
unpleasant odors. When processing catalog number (CAT No.) of each
solutions are warm, they may A Material Safety Data Sheet Kodak product and your address.
generate more vapors. In addition, (MSDS) is available for every Kodak Or visit Kodak Environmental
temperature affects processing chemical you purchase. The MSDS Services on-line at
times. Therefore, it is important that tells you how to use, handle, and www.kodak.com/go/kes.
you work with solutions at the store the product safely. The content
proper temperatures. For your own of MSDSs varies from one product
to the next. Among the topics MANAGING WASTE
personal comfort and good health
practices, you should minimize the covered are:
There are two types of waste—solid
concentration of these chemicals by • Product Information: identifying
the name of the product and any wastes and processing effluent.
controlling ventilation. We Most solid wastes are packaging
other trade names.
recommend using a room with a materials. The waste produced from
source of fresh air for darkroom use. • Component Information:
processing photographic films and
Here are some ventilation identifying what ingredients are
in the product. papers is called photographic
guidelines for manual sink-line or effluent; it includes developer, fixer,
open tray processing areas: • Hazard Identification: hazardous bleaches, and wash water. There are
• Supply tempered fresh air to the components in the product and
many different ways to manage
darkroom above the processing safe handling information.
solid and effluent waste materials.
solutions. Position the supply of • First Aid Measures: appropriate
fresh air so that it will not affect emergency procedures and other
the capture of vapors or gases by information.
the exhaust opening.
• Fire-Fighting Measures.
• Exhaust the room air from the
• Precautions to take if a spill
processing chemical area to the
occurs.
outdoors at a minimum rate of
10 room volumes per hour1 If you

1. For 10 x 10 x 10-foot room

2 Environmental Guidelines for Amateur Photographers • J-300


REDUCING WASTE PHOTOGRAPHIC
EFFLUENT
The best way to help the
environment—and yourself—is to Before you can decide how to
use photographic processing dispose of photographic processing
solutions efficiently. You can chemicals, you need to know what
accomplish this by: type of waste disposal system you
• Buying only the supplies you have. The type of system you have
need. This way, you won’t be and the types of materials you need
storing unused photoprocessing to dispose of will determine how
chemicals past their you dispose of your waste. There are
recommended shelf life and later, two types of waste disposal
having to dispose of them. systems—sewer and septic.
• Mixing only the amount of
photographic processing
chemicals you need; this way, you
won’t have to dispose of
additional materials.

Amateur or Professional?

You are likely a business selling


some or all of your work and
No
Are you an amateur photographer therefore are covered by additional
Start
who does not sell your work? requirements. See “More
Information” at the back of this
publication.

Yes

If you process work at a school,


Do you have a darkroom at home No studio, or other business, disposal
where you process films and responsibility falls on the business
papers? owner. See “More Information” at the
back of this publication.

Yes

You are likely using a septic system


for disposal of wastewater. Certain No
Are you using a sewer for disposal of
materials should not be sent to the
your wastewater?
septic system. See “Septic Systems”
for more details.

Yes

Most common photographic


chemicals may be safely disposed to
the sewer. See “Sewer Systems” for
more details.

Environmental Guidelines for Amateur Photographers • J-300 3


and state regulatory limits photographic chemicals can be sent
SEWER SYSTEMS established under the Clean Water to the sewer. They include:
Act. In order to comply, the local • Developers
The majority of wastewater
POTW must establish pretreatment • Stop baths
generated in our communities
guidelines (commonly referred to as
travels through the sewer system to • Fixers (after silver recovery)
sewer codes) that impact businesses.
a Publicly Owned Treatment Works • Wash waters
As a domestic user—an amateur
(POTW). The POTW is responsible
photographer—you are excluded Do NOT send:
for treating the wastewater that
from these regulations. Most • Selenium toners
comes through its facility. The water
that leaves the POTW after • Solvents
treatment must comply with federal • Other materials that are
prohibited, i.e., flammable
materials

Your House

City Disposal

Trash
Bin

Sewer

POTW

H O
2

4 Environmental Guidelines for Amateur Photographers • J-300


WASTE MANAGEMENT SEPTIC SYSTEMS WASTE MANAGEMENT
OPTIONS ALTERNATIVES FOR
Septic tank systems are designed SEPTIC SYSTEMS
If you are on a sewer system, the best and used for the disposal of
way—and the most appropriate—is to domestic waste, primarily in areas Kodak does not recommend the use of
dispose of your photographic processing where municipal sewers are septic systems for disposal of
effluent through the sewer system. Most unavailable. They operate with photographic processing chemicals
photographic processing solutions anaerobic (without oxygen) because the disposal of
are biodegradable and are effectively biological action to treat the wastes photographic processing solutions
treated when discharged to POTWs. discharged. This also includes leach may affect the proper operation of
POTWs that have secondary fields and cesspools. the septic system. Other disposal
(biological) wastewater treatment can Septic systems do not have the options are available for septic
effectively treat the waste stream ability to properly treat system users, including household
through the use of biological action, photographic processing solution waste collection facilities, discharge
such as bacteria nutrients and waste. Regulations have been to a nearby municipal treatment
aeration, to break down the waste it established by the United States plant, or a licensed hazardous waste
receives so that it may be safely Environmental Protection Agency hauler. Table I provides a summary
discharged to a body of water. (USEPA) and many states to of waste management options
Photographic processing effluent minimize the potential of adversely which are available for Kodak
includes developer, fixer, bleach, and affecting sources of underground products.
wash water involved in processing drinking water. Although these
films and papers. Two key regulations typically do not impact
characteristics of photoprocessing domestic users, such as amateur
effluent are pH and the concentration photographers, we recommend that
of silver. Developer has a high pH you contact your local health
and is therefore alkaline or caustic. department to determine whether
Fixer has a low pH and is therefore discharging photographic
acidic. When fixer and developer are processing effluents into your septic
combined as the total process system is appropriate for your
effluent, the effluent is neutralized, location.
resulting in a better compatibility
Table I. General Guidelines
with drain pipes and treatment at the
POTW. Sewer
Other
Another key characteristic of System
Alternatives
Options
photoprocessing effluent is the silver
concentration found in photographic KODAK Products Household
Discharge Discharge KODAK
fixer or bleach-fix effluent. Although Hazardous Trash
to Sewer to nearby RELAY
the form of silver (silver thiosulfate) (POTW)
Waste
POTW Program
Disposal
found in photographic processing Collection
effluent is not harmful and is Developer
✓ ✓ ✓ ✓ —
removed during secondary treatment unused/used
at the POTW, it is a good practice to
Fixer/Bleach-Fix
recover silver before discharging the unused ✓ ✓ ✓ ✓ —
effluent. See page 6 for information
on silver recovery. used ✓* ✓ ✓* — —
If you do not want to recover silver Stabilizers ✓ ✓ ✓ ✓ —
from used photographic fixer or
Sepia Toner ✓ ✓ ✓ ✓ —
bleach-fix, you may choose to utilize
other disposal options, such as Rapid Selenium
— ✓ — — —
household hazardous waste Toner
collection. Refer to the section on Indicator Stop Bath ✓† ✓ ✓ ✓ —
Waste Management Alternatives for
PHOTO-FLO Solution ✓ ✓ ✓ ✓ —
Septic Systems for additional
information. * Recommended after silver recovery is performed.
† Recommended after neutralization.

Environmental Guidelines for Amateur Photographers • J-300 5


Most communities have local
household hazardous waste DISPOSAL OF OTHER SILVER RECOVERY
collection facilities. These facilities KODAK PRODUCTS
You can find silver in a number of
are available to the public to collect
Used KODAK Rapid Selenium Toner different materials when you
items from domestic use that should
is regulated as a hazardous waste process photographic materials. The
not be disposed of through
under the USEPA Resource original source of silver is
municipal trash, septic, or sewer
Conservation and Recovery Act photographic films and papers.
systems. This option is available if
(RCRA) regulations for commercial Once processed, silver can be
you generate less than 220 pounds
users. We recommend that domestic retained in the photographic
(100 kilograms) of hazardous waste
users do not discharge this material material or transferred to solutions
per calendar month. Most home
to the sewer or discard it in the used to process the photographic
hobbyist photographers fall well
municipal trash. Use a household materials. Commercial business and
below this limit. See Appendix A for
hazardous waste collection facility or photographers must recover silver
the listing of state household
a licensed hazardous waste hauler to from photoprocessing effluent to
hazardous waste collection
manage this material. meet sewer discharge limits
coordinators. You may contact your
KODAK Indicator Stop Bath established by POTWs. Amateur
state coordinator for information on
contains acetic acid. It has a very low photographers are not required to
the household hazardous waste
pH (1.0). Neutralize this solution recover silver. But whether you are a
collection facility nearest you.
with sodium bicarbonate (baking professional or amateur
You can also discharge your
soda) solution prior to sending the photographer, silver recovery
photographic wastes to a local
material to the sewer. This will help provides environmental benefits,
municipal sewer authority, often
protect your drain pipes. Add the conserves a natural resource, and
referred to as a Publicly Owned
sodium bicarbonate slowly to the may provide a source of revenue.
Treatment Works (POTW). Contact
solution because it will cause The amount of silver found in
the POTW directly to see if they will
foaming. Neutralize the solution in a photoprocessing effluent will
accept your waste.
well ventilated area using proper depend upon the amount of film or
The third option available is to
personal protective equipment paper you’ve processed. See Table II
contract with a licensed hazardous
(gloves, goggles, and apron). for typical silver concentrations. For
waste hauler to manage your
If you do not want to neutralize the small volume users like amateur
photographic processing wastes for
Indicator Stop Bath prior to disposal, photographers, metallic replace-
off-site disposal. Kodak offers the
you may choose to utilize other ment is usually a good method for
RELAY Program, in conjunction
disposal options, such as household recovering silver from photographic
with Safety-Kleen Corporation, to
hazardous waste collection. Refer to processing effluent. In this method,
properly handle, treat, and dispose
the previous section on Waste iron metal (steel wool) reacts with
of photographic processing wastes.
Management Alternatives for Septic the silver in the fixer solution. The
For more information on the
Systems for additional information. iron replaces the silver in solution,
KODAK RELAY Program, see
while the less active metal (silver)
Appendix D. You may also check the
settles out as a solid sludge. To bring
yellow pages of your local phone DISCONTINUED KODAK the silver in contact with the iron,
book for a list of waste management PRODUCTS the used fixer passes through the
companies in your area. (There is a
container filled with steel wool. The
fee for this service.) For information on managing
steel wool provides the source of
discontinued Kodak products, please
iron to replace the silver.
contact Kodak Environmental
MUNICIPAL TRASH Services at 716-477-3194 for
DISPOSAL assistance.
We do not recommend that you dispose of
used or unused photographic processing Table II. Silver Concentrates Found in Photoprocessing Solutions
solution in your regular trash. This is to
ensure the safety of the trash Solution Amount
collectors who would not know that Developer Contains negligible amounts of silver
this material is in the trash and could
Fixer/Bleach-Fix 3000–5000 milligrams/litre
possibly come into contact with it.
Wash Water/Stabilizer 1–5 milligrams/litre

6 Environmental Guidelines for Amateur Photographers • J-300


The advantages to using metallic
replacement cartridges are the low TIPS FOR RECOVERING REFINING
initial cost (approximately $50 each), SILVER
After the metallic replacement
and the simplicity of installing cartridge is exhausted, you have to
To use metallic replacement
them—all you have to do are a few send it to a refiner to reclaim the
cartridges as efficiently as possible,
simple plumbing connections. The silver that is present in the form of a
fill them with water before you use
disadvantage of metallic sludge in the cartridge. For a list of
them. This will allow the solution to
replacement is that the silver is refiners, see Appendix B.
come into contact with the greatest
recovered as a sludge, which makes
surface area of steel wool and
it more difficult to determine the
prevent “channeling.” Regardless of
exact amount of silver recovered
the amount of effluent passed
SOLID WASTE
and requires more costly refining.
through it, never use a cartridge for
Also, you cannot reuse cartridges; You can choose from several options
more than six months. The cartridge
you must replace them when they for managing the solid waste
is used to remove silver from the
become exhausted. For small- associated with processing Kodak
fixer/bleach fix solution only. Do
volume users, such as amateur films and papers. Refer to Table III
not add developer or any other
photographers, metallic for guidelines on what to do with
chemical to the cartridge. Adding
replacement cartridges usually last these materials.
developer or other chemicals will
about six months.
destroy the cartridge and inhibit the
You can recover silver from small
silver-recovery process.
batches of fixer by pouring the
solution into a metallic replacement
cartridge. You can use the KODAK
Chemical Recovery Cartridge,
Junior Model II.

Table III. General Guidelines

Product Component Material Option

Film Carton/Box 100% recycled fiberboard Discard in regular trash

35 mm Body Plastic* Recycle†


Canister
Cap Plastic* Discard in regular trash

35 mm magazine Steel Recycle†

35/120/220 spool Plastic* Recycle†

126/110 cartridge Plastic* Recycle†

Film Emulsion, base Discard in regular trash

Paper Carton/Box 100% recycled fiberboard Discard in regular trash

Core Fiberboard Recycle‡

Photochemical Container Bottles Plastic* or glass Recycle**

Caps Plastic* Discard in regular trash

Carton 100% recycled fiberboard Recycle or


Discard in regular trash

‡ Check with your community recycling program for details or ask your
* Refer to Appendix C for resin codes and descriptions. local photographic processing lab if they participate in the
† Check with your community recycling program for details or ask your local photographic
KODAKprocessing labRecycling
Paper Core if they participate
Program.in the KODAK Film Container
Recycling Program. ** Refer to Appendix E for information on photochemical bottle
recycling in community recycling programs.

Environmental Guidelines for Amateur Photographers • J-300 7


APPENDIX A
HHW Management State Agency Contacts, 1995
Source: The Waste Watch Center

Alaska California Kansas


Geoff Kany Judi Frantz Kathleen Nyquist
Hazardous Waste Program Manager Environmental Education Coordinator HHW Program Manager
Alaska DEC Cal/EPA Dept. of Toxic Substances Kansas Dept. of Health & Environment
410 Willoughby Avenue Control Forbes Field, Building 740
Juneau, AK 99801-1795 P.O. Box 806 (MS HQ-15) Topeka, KS 66620
907-465-5150 P Sacramento, CA 95812-0806 913-296-1611 P
907-465-5164 F 916-324-3614 P 913-296-1592 F
916-327-0978 F
Arkansas Florida
Robert Finn Connecticut Jan Kleman
Hazardous Waste Division Paul Franson Environmental Specialist II
AR Dept. of Pollution Control/Ecology Senior Environmental Analyst FL DEP, Bureau of Solid and Haz.
P.O. Box 8913 Connecticut DEP Waste Bureau Waste
Little Rock, AR 72219 165 Capital Avenue 3804 Coconut Palm Drive
501-570-2861 P Hartford, CT 06424 Tampa, FL 33619-8218
203-566-5277 P 813-744-6100 P
California 203-566-5255 F 813-744-6125 F
Fernando Berton
Senior Waste Management Specialist Delaware Hawaii
California Integrated Waste Mgmt. N.C. Vasuki Jane Dewell
Board Chief Executive Officer Solid & Hazardous Waste Branch
8800 Cal Center Drive Delaware Solid Waste Authority Hawaii Dept. of Health
Sacramento, CA 95826 P.O. Box 455 5 Waterfront Plaza
916-255-2470 P Dover, DE 19903-0455 919 Ala Moana Blvd., 3rd Floor
916-255-2220 F 302-739-5361 P Honolulu, HI 96814-4912
302-739-4287 F 808-586-4226 P
Colorado
Scott Doyle Georgia Idaho
Hazardous Waste Manager Pam Thomas Jaime Fuhrman
Larimer County Dept. of Natural Hazardous Waste Management Idaho Department of Health
Resources Program Hazardous Materials Bureau
P.O. Box 1190 Georgia Dept. of Natural Resources 1410 North Hilton
Fort Collins, CO 80522-1190 205 Butler St., Floyd Tower East 1258 Boise, ID 83706
303-498-5771 P Atlanta, GA 30334 208-334-5879 P
303-498-7985 F 404-656-4713 P
Indiana
Alabama Iowa Tom Neltner
Terry Shipman Roy Dewitt Assistant Commissioner, OPPT
Land Division Program Planner Indiana Dept. of Environmental Mgmt.
AL Dept. of Environmental Management Iowa Dept. of Natural Resources 100 N. Senate Avenue, P.O. Box 6015
1751 Congressman Dickinson Drive Wallace State Office Building Indianapolis, IN 46206-6015
Montgomery, AL 36130 Des Moines, IA 50314 317-232-8603 P
205-271-7726 P 515-281-8646 P
Kentucky
Arizona Illinois Annette Hayden
Tammy Shreeve David Walters Program Coordinator
AZ Dept. of Environmental Quality Manager, Solid Waste Reduction Unit Kentucky Division of Waste
3033 N. Central Avenue Illinois DEP Management
Phoenix, AZ 85012 2200 Churchill Road 18 Reilly Road
602-207-4119 P Springfield, IL 62794-9276 Frankfort, KY 40601
217-785-8604 P 502-564-6716 P
217-524-4193 F

8 Environmental Guidelines for Amateur Photographers • J-300


Louisiana Michigan New York
Vince Sagnibe Lucille Scotti Sharon Rehder
Manager, Tech Services/Haz. Waste Michigan Dept. of Natural Resources Environmental Engineer
Louisiana DEQ Office Solid & Haz. P.O. Box 30241 New York State, DEC,
Waste Lansing, MI 48909 Haz. Substances Reg.
79290 Blue Bonnett, P.O. Box 82178 517-373-2730 P 50 Wolf Road
Baton Rouge, LA 70884 Albany, NY 12233-7253
Missouri
504-765-0355 P 518-485-8988 P
June Sullens
504-765-0617 F 518-457-0629 F
Environmental Specialist
Massachusetts Missouri Dept. of Natural Resources North Dakota
Nancy Wrenn P.O. Box 176 Christine Roob
Regional Planner, Haz. Waste Jefferson City, MO 65102 Environmental Scientist
Prevention 314-751-3176 P Division of Waste Management
Massachusetts Dept. of Env. Protection P.O. Box 5520
Montana
One Winter Street Bismark, ND 58502-5520
Lara Dando
Boston, MA 02108
Environmental Specialist New Hampshire
617-292-5587 P
Solid & Hazardous Waste Bureau Ken Stuart
617-556-1049 F
Cogswell Building Environmentalist
Maine Helena, MT 59620 New Hampshire DES, Waste Mgmt. Div.
Sam Morris 406-444-1430 P 6 Hazen Drive
Maine Waste Management Agency 406-444-1499 F Concord, NH 03301-6509
State House Station 154 603-271-2047 P
North Carolina
Augusta, ME 04333 603-271-2456 F
Lula Melton
207-287-5300 P
North Carolina DEHNR New Jersey
207-287-5425 F
Solid Waste Section Mike Winka
Minnesota P.O. Box 27687 Executive Assistant
Leslie Goldsmith Raleigh, NC 27611-7687 New Jersey DEP, Div. of Solid Waste
Supervisor, Special Wastes Unit 919-733-0692 P Mgmt.
MPCA—Hazardous Waste Division 840 Bear Tavern Road—CN414
Nebraska
520 Lafayette Road Trenton, NJ 08625-0414
Teri Swarts
St. Paul, MN 55155-3898 609-530-8115 P
Compliance Specialist
612-297-8368 P 609-530-8899 F
Nebraska Dept. of Environmental
612-297-8676 F
Quality Nevada
Mississippi 1200 N. Street, Suite 400 Krisyten Kuyper
Thomas E. Whitten Lincoln, NE 68508 Environmental Management Specialist
Waste Minimization Director 402-471-4217 P Nevada Division of Env. Protection
Mississippi Dept. of Environmental 402-471-3185 F 333 W. Nye Lane
Quality Carson City, NV 89710
New Jersey
P.O. Box 10385 702-687-4670 P
Ralph G. Davis
Jackson, MS 39289-0385
New Jersey DEP, Bureau of Hazardous Ohio
601-961-5241 P
Waste Ildi Pallos
Massachusetts Regulation & Classification Environmental Specialist
Barbara Kelley 401 E. State Street, CN 028 Ohio EPA DSIWM
Office of Technical Assistance Trenton, NJ 08625 1800 Water Mark Drive, P.O. Box 1049
Massachusetts Dept. of Environmental 609-292-8341 P Columbus, OH 43266-0149
Mgmt. 609-777-0769 F 614-728-5353 P
100 Cambridge St., Room 1904
New Mexico Oklahoma
Boston, MA 02202
Patrick Hoermann Bryce Hulsey
617-727-3260 P
HHW Coordinator Oklahoma Dept. of Health/Solid Waste
617-727-2754 F
Solid Waste Bureau/Environment Dept. 1000 NE 10th Street
Maryland 1190 St. Francis Drive, P.O. Box 261 Oklahoma City, OK 73117-1299
Robert Murphy Santa Fe, NM 87503 405-271-7353 P
Program Administrator 505-827-2653 P
Maryland Dept. of the Environment 505-827-2836 F
2500 Broening Highway
Baltimore, MD 21224
410-631-3344 P

Environmental Guidelines for Amateur Photographers • J-300 9


Pennsylvania Rhode Island Vermont
William Apgar Richard Enander John Miller
Waste Management Division Pollution Prevention Program Manager Recycling Specialist
Pennsylvania Dept. of Environmental Rhode Island Dept. of Env. Mgmt. Vermont Agency of Natural Resources,
Resources 83 Park Street DEC
P.O. Box 2063 Providence, RI 02903-1037 103 South Main St., Laundry Building
Harrisburg, PA 17120 401-277-3434 P Waterbury, VT 05671-0407
717-787-6239 P 401-277-2591 F 802-241-3444 P
717-787-0884 F 802-241-3273 F
South Dakota
South Carolina Vonni Kallemeyn Wisconsin
Pam Bergstrand Office of Air Quality & Solid Waste Tim Mulholland
South Carolina Dept. of HEC, Department of Health Bureau of Solid Waste Mgmt.
Div. of Hydro. Joe Foss Building, Room 217 Haz. Waste
Bureau of Solid and Hazardous Waste Pierre, SD 57501 Department of Natural Resources
2600 Bull Street 605-773-3153 P 101 S. Webster St., GEF II, Box 7921
Columbia, SC 29201 Madison, WI 53707-7921
Texas
803-896-4041 P 608-266-0061 P
Ingrid Dierlam
803-896-4292 F
Project Coordinator Wyoming
Tennessee Texas Water Commission Tim Link
Don Manning 1700 N. Congress Avenue Solid & Hazardous Waste Specialist
Tennessee Div. of Solid Waste Mgmt. Austin, TX 78711-3087 Wyoming Dept. of Environmental Quality
701 Broadway, Custom House, 4th Floor 512-239-4747 P 122 West 25th St., Herschler Bldg.
Nashville, TN 37247-3530 512-463-6648 F Cheyenne, WY 82002
615-532-0076 P 307-777-7752 P
Virginia
Utah Alan Lassider Washington
Dorothy Adams Dir. Div. of Litter Control & Recycling William P. Green
Waste Reduction Specialist Virginia Dept. of Solid Waste Hazardous Waste Program Planner
Salt Lake City County Health Dept. 101 N. 14th, Monroe Bldg., 11th Floor Solid & Hazardous Waste, Ecology
610 South 200 East Richmond, VA 23219 Dept.
Salt Lake City, UT 84111 804-225-2945 P P.O. Box 47600
801-534-4526 P Olympia, WA 98504-7600
801-534-4502 F 206-407-6109 P
206-407-6102 F
Oregon
Maggie Conley West Virginia
HHW Coordinator Randy Hoffman
Oregon DEQ Environmental Analyst
811 SW 6th Avenue Division of Waste Management, DNR
Portland, OR 97204 1356 Hansford Street
503-229-5106 P Charleston, WV 25301
503-229-6124 F 304-558-6350 P
304-348-0256 F

10 Environmental Guidelines for Amateur Photographers • J-300


APPENDIX B
Silver Refiners and Buyers
This list has been compiled from various sources. Inclusion on this list does not imply any endorsement or
recommendation by Eastman Kodak Company.

Company Name Telephone Number Company Name Telephone Number


Academy Corporation 1-800-545-6685 Mar_Cor Environmental Services (800) 323-9785
6905 Washington, N.E. (505) 345-1805 11221 Melrose Street (847) 288-0800
Albuquerque, NM 87109 Franklin Park, IL 60131 Fax (847) 288-0818
Capital Silver Service (615) 452-3574 Morris Recovery Systems (919) 772-7924
1340 Airport Blvd. 819-D Purser Dr.
Gallatin, TN 37066 Raleigh, NC 27603
Century Refining (612) 985-9995 Noble Silver (317) 891-0559
21630 Hanover Ave. 259 S. Countyline Rd.
Lakeville, MN 55044 Cumberland, IN 46229
Commodity Resource & (818) 843-2811 Pyromet (610) 497-1743
Environmental, Inc. 5 Commerce Drive
116 East Prospect Ave. Aston, PA 19014
Burbank, CA 91502
Sabin Metal Corp. (716) 538-2194
Degussa Corporation (908) 561-1100, 1647 Wheatland Center Rd
3900 South Clinton Ave. ext. 505 Caledonia, NY 14546
South Plainfield, NJ 07080
Safety-Kleen Corp. (714) 435-9225
Drew Resource Corporation (510) 527-7100 2110 South Yale Street
1717 Fourth Street Santa Ana, CA 92704
Berkley, CA 94710-1783
San Antonio Silver (210) 647-4111
Eastern Smelting & Refining Corp. 1-800-343-0914 7514 Reindeer Trail
37-39 Bubier Street San Antonio, TX 78238
Lynn, MA 01901-1794
S.E. Environmental Services 1-800-329-2245
Encore Resources (214) 350-9345 925 W. Adams Street
2619 Brenner Jacksonville, FL 32204
Dallas, TX 75220
Silver Enterprises 1-800-777-4583
Environmental Svcs. (303) 690-1414 77 Cliffwood Ave.
4174 A.S. Parker Road Cliffwood, NJ 07721
Ste-132
Aurora, CO 80014 Southern Silver (615) 793-6168
400 Buchanan
Hallmark Refining Corp. 1-800-255-1895 LeVergne, TN 37086
1743 Cedardale Road, Unit 4 (206) 428-5880
P.O. Box 1446 SPM (540) 947-5407
Mount Vernon, WA 98273 Montvale Industrial
Montvale, VA 24122
Handy & Harmon 1-800-421-0411
300 Rye Street (203) 289-4327 Springfield Silver Service (513) 834-2293
South Windsor, CT 06074-1220 Fax (203) 289-6494 10815 State Route 161
P.O. Box 189
Heraeus Enright Processing Co. (201) 589-5273 Mechanicsburg, OH 43044
65 Euclid Ave.
Newark, NJ 07105 USI Environmental Reclamation Div. (414) 334-3000
P.O. Box 43 Fax (414) 334-6222
825 Schoenhaar Drive
West Bend, WI 53095-2633

Environmental Guidelines for Amateur Photographers • J-300 11


APPENDIX C
Resin Codes
Today, plastics are among the easiest types of waste to
recycle. Responding to requests from recyclers, the
Society of the Plastics Industry, Inc. created the
following codes to identify plastic packaging by resin
types. These codes are typically imbedded in the
bottoms of plastic bottles or containers and allow easy
sorting of plastic waste.

Code Resin Type Examples

PETE—Polyethylene terephthalate Beverage containers, boil-in food pouches, processed meat packages

Film trays, chemical bottles, plastic lids for anesthetics


HDPE—High-density polyethylene and many other products, barrier envelopes, milk bottles, detergent
bottles, oil bottles, toys, plastic bags

Film packet outer wraps, food wrap, vegetable oil bottles, “blister”
V—Vinyl (PVC or polyvinyl chloride)
packaging

LDPE—Low-density polyethylene Shrink-wrap, plastic bags, garment bags

Margarine and yogurt containers, caps for containers,


PP—Polypropylene
some wraps

PS—Polystyrene Egg cartons, fast food trays, disposable plastic silverware

OTHER—Other types Multi-resin containers

12 Environmental Guidelines for Amateur Photographers • J-300


APPENDIX D
KODAK RELAY Program

Q. What is the KODAK RELAY Program? Q. Are there any other costs associated with the program?
A. The RELAY Program is for managing photographic A. Safety-Kleen charges a small fee upon initial sign-up of
processing wastes generated by customers using Kodak any new RELAY customer. Customers who participated
photographic chemicals. Kodak is committed to in the 55-gallon RELAY Program prior to January 1994
providing the best products, methods, and services to who want to switch to the smaller container service do
meet your photographic processing needs. The RELAY not have to pay the fee.
Program, offered by Kodak in conjunction with Safety-
Kleen Corporation, is a service you can choose to help Q. Will Safety-Kleen pick up partially filled containers?
you comply with waste management regulations. A. Safety-Kleen’s service price applies to full or partially-
filled containers. Containers are available in various
Q. Is the RELAY Program available worldwide? sizes to accommodate your needs, and empty containers
A. The RELAY Program is currently available only are stackable to decrease the amount of storage space
throughout the continental United States and Puerto needed.
Rico. Canadian customers who need help with waste
management can call 1-800-465-6325. Q. I use storage tanks, not containers. Can I make
arrangements for pick-up by tanker truck?
Q. How do I sign up for the RELAY Program? A. Yes, you can negotiate the RELAY service price for
A. To sign up for the RELAY Program, simply contact your pick-up by tanker trucks directly with Safety-Kleen.
Kodak sales representative, or call Kodak
Environmental Services at (716) 477-3194. Q. Can I store my processing waste in the plastic 15-, 30-
or 55-gallon containers that originally contained Kodak
Q. How soon can I expect to hear from Safety-Kleen? photographic chemicals?
A. Immediately after a Kodak representative has called you A. In order to ensure container and chemical compatibility,
to confirm your interest in the RELAY Program and obtain prior approval from Kodak Environmental
answer any questions you may have, your name will be Services by calling (716) 477-3194 before storing waste
forwarded to Safety-Kleen. You can then expect to in any empty Kodak container.
receive a telephone call from a Safety-Kleen Note: Most empty plastic drums that previously
representative within 2 to 3 business days. contained Kodak photographic chemicals can be
returned for reconditioning and reuse. For more
Q. Who pays for the RELAY Program and how much does information on the KODAK Returnable Drum Program,
it cost? contact your local Kodak sales representative or call the
A. You will be billed for each container of waste picked up Kodak Information Center at 1-800-242-2424.
by Safety-Kleen. The price depends on the size of
container and includes the cost of analysis and
containers. For pricing information, contact Kodak at
(716) 477-3194.

Environmental Guidelines for Amateur Photographers • J-300 13


Q Will I get credit from Safety-Kleen for any silver
recovered from my waste streams?
A. Currently you will not receive credit from Safety-Kleen
for any silver recovered from your waste streams.

Q. What happens to the waste after it is picked up by


Safety-Kleen?
A. The waste is transported to a Safety-Kleen facility for
treatment and/or disposal in accordance with applicable
State and Federal regulations. You will receive a Safety-
Kleen’s written assurance that the waste has been
received and properly managed.

Q. What is an EPA identification (ID) number? Why do I


need one, and how do I get one?
A. An EPA ID number is a number assigned by the United
States Environmental Protection Agency or authorized
state agency to each person (by site) who generates,
transports, treats, stores, or disposes of hazardous waste.
Photographic solutions that contain silver at or above
5 mg/L are considered hazardous waste when placed in
containers for transportation to off-site treatment
facilities. Federal and State hazardous waste regulations
and the volume of hazardous waste generated by your
site will dictate your need for an EPA ID number.
Safety-Kleen can help you obtain an ID number if you
need one.

Q. What if I use other manufacturers’ chemicals or a


combination of Kodak and non-Kodak chemicals?
A. Only waste generated from the use of Kodak
photographic chemicals or Kodak-published bulk-mix
formulas, qualifies for the KODAK RELAY Program.
You can, however, make arrangements with Safety-
Kleen for waste generated from non-Kodak (or
combined Kodak and non-Kodak) solutions by calling
1-800-669-5740, or contacting your local Safety-Kleen
branch.

14 Environmental Guidelines for Amateur Photographers • J-300


APPENDIX E
Recycling KODAK Photochemical Containers

PREPARING KODAK PHOTOCHEMICAL Q. What type of plastic are the containers made from?
CONTAINERS FOR RECYCLING
A. Most of the plastic Kodak photochemical
You can help minimize solid waste by participating in containers are manufactured from high density
your local community recycling program. The polyethylene, the Society of Plastics Industry (SPI)
following information will help you in preparing code number 2 or low-density polyethylene, SPI
empty plastic or glass Kodak photochemical containers code number 4. In addition, some Kodak plastic
for recycling in your local recycling program: containers are made of other resins and are coded
number 7 to symbolize layered multi-material
1. Follow the recommendations for personal
plastics.
protection and ventilation, as described in the
product Material Safety Data Sheet (MSDS), while
Q. What is an SPI code and where will I find it?
rinsing the empty container.
2. Empty the container of all residual product, and A. An SPI code is a way to identify what type of
dispose of the residual in accordance with all local, plastic the container is made from. The number
state, and federal regulations. will be located on the bottom of the chemical
bottle, inside the chasing arrows (mobius loop).
3. To minimize splattering and respiratory exposure, For Cubitainers, the SPI code will be located near
slowly rinse caps and empty containers with cold
the neck of the container.
water. In some instances, the chemical residue may
react with water if present in high concentrations.
Q. What SPI code numbers will the recycler accept?
Dispose of the rinsate (rinse water) in accordance
with all local, state, and federal regulations. A. You will need to contact your local recycler for the
4. Repeat the rinsing of the containers two more information on what recyclable plastics they
times; you can use warm water (approximately accept. Each recycler may have different market
100° F) for the final rinse to increase the solubility outlets for the plastics which determine what
of any remaining chemicals. recyclables they can collect.
5. Once you no longer need the caps, rinse and
Q. How do I contact my local recycler?
discard them. Do not place them in the recycling
container. A. Call your local or state recycling coordinator,
municipal waste collection agency, or your local
6. If the containers have visible stains or residue after
triple rinsing, do not recycle them. Dispose of waste disposal company. If these agencies cannot
them in accordance with local regulations. assist you, you can call the American Plastics
Council (APC) at 1-800-243-5790 for information
7. If the rinsed container is plastic, slit it so it cannot on plastic recyclers in your area.
be used again and place it into your recycling
collection container.
Q. What information will I have to provide to the recycler
Answers to some frequently asked questions about when inquiring about recycling my containers?
recycling Kodak photochemical containers: A. It would be helpful for the recycler if you provided
Q. Does Kodak accept back the empty plastic or glass a sample of the rinsed containers that you would
photochemical containers? like to recycle; a count of how many containers you
A. Kodak does not accept back the empty plastic or generate per week, month, or year; the Material
glass photochemical containers. Local recyclers are Safety Data Sheets for the photochemical product
best equipped to recycle these containers. that was sold in the original container; and a copy
of this Appendix. You may be asked to sign a form
stating you will make sure the containers have
been properly rinsed before you send them to the
recycler.

Environmental Guidelines for Amateur Photographers • J-300 15


Q. Why do some local recyclers not accept the containers? The recycling information in this publication applies to
empty Kodak plastic or glass containers used for the
A. Some recyclers may not understand the nature of
following Kodak photochemical products only and is
the contents of the containers. Most Kodak not intended for containers that were reused for other
photographic chemicals are water soluble. purposes.
Properly rinsed photochemical containers with no
visible stains or residue are expected to pose no KODAK EKTACOLOR PRIME Chemicals
greater health concerns for customers or recyclers
than properly rinsed household chemical KODAK EKTACOLOR PRIME Developer
containers. Some recyclers may only be able to Replenisher / RA-4
process specific sizes of containers, types of KODAK EKTACOLOR PRIME Developer
materials (plastic and glass), and colors of glass at Regenerator
their facility. As a result, they may not be able to KODAK EKTACOLOR PRIME Bleach-Fix and
accept every container that you would like to Replenisher
recycle.
KODAK EKTACOLOR PRIME Stabilizer and
Replenisher / RA-4
Q. Can I recycle the 15-, 30-, and 55-gallon Kodak plastic
drums that my photographic chemicals are shipped in? KODAK EKTACOLOR RA Chemicals
A. Yes, this is possible provided you have located a KODAK EKTACOLOR RA Developer Starter
recycler of such drums in your area. However,
KODAK EKTACOLOR RA Developer Replenisher
these drums are part of the KODAK Returnable
RT, Part A
Drum Program and can be sent to the Kodak-
approved drum reconditioner, then back to Kodak KODAK EKTACOLOR RA Developer Replenisher
for reuse. If you need further information about RT, Part B
the KODAK Returnable Drum Program, call KODAK EKTACOLOR RA Developer Replenisher
Kodak at 1-800-242-2424. RT, Part C
KODAK EKTACOLOR RA Developer Replenisher
Q. Whom may I contact at Kodak for additional
KODAK EKTACOLOR RA 100 Developer
information about the recycling of Kodak photochemical
Replenisher
containers?
KODAK EKTACOLOR RA 100 Developer
A. For additional information, you may contact the Regenerator
Kodak Information Center at 1-800-242-2424,
Monday through Friday, from 9 a.m. until 7 p.m. KODAK EKTACOLOR RA 100 Developer
(Eastern time). Regenerator (WS)
KODAK EKTACOLOR RA Bleach-Fix and
Replenisher
KODAK EKTACOLOR RA 100 Bleach-Fix
Replenisher
KODAK EKTACOLOR RA Stabilizer and
Replenisher / EP-2, RA-4
KODAK FLEXICOLOR Chemicals
KODAK FLEXICOLOR Developer Starter LORR
KODAK FLEXICOLOR Developer Replenisher
LORR
KODAK FLEXICOLOR Developer Replenisher
LORR, Part A
KODAK FLEXICOLOR Developer Replenisher
LORR, Part B
KODAK FLEXICOLOR Developer Replenisher
LORR, Part C
KODAK FLEXICOLOR Bleach III / C-41, Part A
KODAK FLEXICOLOR Bleach III / C-41, Part B
KODAK FLEXICOLOR Bleach III Starter
16 Environmental Guidelines for Amateur Photographers • J-300
KODAK FLEXICOLOR Bleach III Replenisher, KODAK EKTACHROME R-3 Chemicals
Part A
KODAK EKTACHROME R-3 First Developer
KODAK FLEXICOLOR Bleach III Replenisher, Replenisher
Part B
KODAK EKTACHROME R-3 Color Developer
KODAK FLEXICOLOR Bleach III Regenerator Replenisher, Part A
KODAK FLEXICOLOR RA Bleach Replenisher NR KODAK EKTACHROME R-3 Color Developer
KODAK FLEXICOLOR Bleach III NR Replenisher Replenisher, Part B
KODAK FLEXICOLOR RA Fixer and Replenisher KODAK EKTACHROME R-3 Color Developer
Replenisher, Part C
KODAK FLEXICOLOR Fixer and Replenisher
KODAK EKTACHROME R-3 Bleach-Fix and
KODAK FLEXICOLOR Stabilizer and
Replenisher
Replenisher LF
KODAK EKTACHROME R-3 First Developer and
KODAK Chemicals for Process E-6 Color Developer Starter
KODAK First Developer, Process E-6 KODAK EKTACHROME R-3000 Chemicals
KODAK First Developer Replenisher, Process E-6
KODAK EKTACHROME R-3000 First Developer
and Process E-6AR
KODAK EKTACHROME R-3000 Color Developer,
KODAK First Developer Starter, Process E-6
Part A
KODAK Reversal Bath, Process E-6
KODAK EKTACHROME R-3000 Color Developer,
KODAK Reversal Bath and Replenisher, Process Part B
E-6 and Process E-6AR
KODAK EKTACHROME R-3000 Color Developer,
KODAK Color Developer, Process E-6, Part A Part C
KODAK Color Developer, Process E-6, Part B KODAK EKTACHROME R-3000 Bleach-Fix
KODAK Color Developer Replenisher, Process E-6
KODAK Color Developer Starter, Process E-6
KODAK Bleach, Process E-6
KODAK Bleach Starter, Process E-6
KODAK Fixer, Process E-6
KODAK Fixer and Replenisher, Process E-6 and
Process E-6AR
KODAK Defoamer, Process E-6
KODAK Pre-Bleach, Process E-6
KODAK Pre-Bleach and Replenisher, Process E-6
and Process E-6AR
KODAK Final Rinse, Process E-6
KODAK Final Rinse and Replenisher, Process E-6

Environmental Guidelines for Amateur Photographers • J-300 17


J-113 About the OSHA Formaldehyde Standard
J-210 Sources of Silver in Photographic
MORE INFORMATION Processing Facilities

If you have environmental or safety questions J-211 Measuring Silver in Photographic


Processing Facilities
about Kodak products or services, contact Kodak
Environmental Services at 1-716-477-3194, between J-212 The Technology of Silver Recovery for
9 a.m. and 7 p.m. (Eastern time) or visit KES on-line Photographic Processing Facilities
at www.kodak.com/go/kes. J-213 Refining Silver Recovered from
Kodak also maintains a 24-hour health hotline to Photographic Processing Facilities
answer questions about the safe handling of
J-214 The Regulation of Silver in Photographic
photographic chemicals. If you need health-related Processing Facilities
information about Kodak products, call
1-716-722-5151. J-215 Recovering Silver from Photographic
Processing Facilities
For questions concerning the safe transportation
of Kodak products, call Kodak Transportation J-216 The Fate and Effects of Silver in the
Services at 1-716-722-2400. Environment
Additional information is available on the Kodak J-217 Using Code of Management Practice to
website and through the U.S.A./Canada faxback Manage Silver in Photographic Processing
systems. Facilities
The products and services described in this
publication may not be available in all countries. In
countries other than the U.S., contact your local For more information about Kodak Environmental Services,
Kodak representative, or your usual supplier of visit Kodak on-line at:
Kodak products. www.kodak.com/go/kes
The following publications are available from
Many technical support publications for
Kodak Customer Service or from dealers who sell
Kodak products can be sent to your fax machine
Kodak products.
from the Kodak Information Center. Call:
U.S. 1-800-242-2424, Ext. 33 / Canada 1-800-295-5531
J-110 Formaldehyde Use in Photographic —Available 24 hours a day, 7 days a week—
Processing Facilities
If you have questions about Kodak products, call Kodak.
J-111 Determining Workplace Exposure to In the U.S.A.:
Formaldehyde 1-800-242-2424, Ext. 19, Monday–Friday
J-112 Formaldehyde Emergencies 9 a.m.–7 p.m. (Eastern time)
In Canada:
1-800-465-6325, Monday–Friday
8 a.m.–5 p.m. (Eastern time)

EASTMAN KODAK COMPANY • ROCHESTER, NY 14650


Environmental Guidelines for Amateur
Photographers
KODAK Publication No. J-300 Kodak , "e" mark, Ektachrome, Ektacolor, Flexicolor, Photo-Flo, Revised 5/99
CAT 851 8755 Prime, and Relay are trademarks. Printed in U.S.A.

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