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Part II - Thermodynamic Properties Properties of Pure Materials - Chapter 8
Part II - Thermodynamic Properties Properties of Pure Materials - Chapter 8
U = TS – PV + µ N = f ( S,V, N)
dU = TdS – PdV + µ dN
dG = -S dT +VdP + µ dN
⎛ ∂S ⎞ ⎛ ∂H ⎞
Cp ≡ T ⎜ ⎟ = ⎜ ⎟
⎝ ∂P ⎠P ⎝ ∂P ⎠P
1 ⎛ ∂V ⎞
κT ≡ − ⎜ ⎟
V ⎝ ∂P ⎠T
1 ⎛ ∂V ⎞
αP ≡ ⎜ ⎟
V ⎝ ∂T ⎠P
Constitutive PVTN Volumetric Property Models
1. Ideal gas law
PV = NRT or PV = RT
Z = PV/RT = 1