STD: XI CHEMISTRY FULL SYLLABUS MARKS: 80 TIME: 2.5 Hrs.

PART-I
Choose the correct alternative from those given under each question: (40M)
(1)What will the value of 450C in terms of Fehrenheit?
(a)1130F (b)1830F (c)3800F (d)3180F
(2)Which of the following changes with temperature?
(a)molality (b)molarity (c)%w/w (d)mole-fraction
(3)Which of the following is the correct formula for one einstein?
𝑁𝑐 ℎ𝑐 𝑁ℎ𝑐 𝑁ℎ
(a) 𝜆 (b) 𝜆
(c) 𝜆
(d) 𝜆𝑐
(4)Which of the following is a pair of isoelectronic ion?
(a)𝐶𝑙 − , P3-, Ca2+ (b)Mg2+, Al3+, S2- (c)K+, Si4+, P3- (d) 𝐶𝑙 − , Al3+, Ca2+
(5)Which two atoms out of the following are isotones?
59 59
(a) 27𝐶𝑜, 28 𝑁𝑖 (b) 40 40
20𝐶𝑎, 18𝐴𝑟 (c) 24 27
12𝑀𝑔, 13𝐴𝑙 (d) 30 32
14𝑆𝑖, 16𝑆
(6)Which of the following is the acceptable electronic configuration of chromium element?
(a)[Ar]3d54s1 (b)[Ar]4d24p4 (c)[Ar]3d44s2 (d)[Ar]4s14p5
(7)_____________ saw regularity in the characteristics of X-ray spectrum of elements.
(a)Mendeleev (b)Newland (c)Lother Meyer (d)Henry Moseley
(8)Elements of group-16 and 17 are known as _____________ and ____________ respectively.
(a)Halogen, chalcogen (b)Chalcogen, alkali (c)Halogen, alkaline (d)Chalcogen, halogen
(9)In the reaction H2 + Br2 → 2HBr, which of the following gets oxidized?
(a)H2 (b)Br2 (c)HBr (d)Both H2 and Br2
(10)What will be the change in electron transfer when a rod of cobalt metal is dipped in nickel sulphate solution?
(a)Co atom will lose two e- (b)Co atom will lose only one e-
(c)Ni atom will gain one e- (d)Ni atom will lose two e-
(11)What is the oxidation state of chlorine in HOCl?
(a)-1 (b)+1 (c)+3 (d)+2
(12)Give the oxidation state of C in CH2Cl2.
(a)+2 (b)+4 (c)-4 (d)0
(13)In superoxide, what is the oxidation state of oxygen?
−1 +1
(a) 2 (b) 2 (c)-1 (d)+1
(14)In a reaction CH3CHO + Ag2O → CH3COOH + 2Ag, which substance is reducing agent?
(a)CH3COOH (b)Ag2O (c)CH3CHO (d)Ag
(15)___________ is the relative abundance of tritum and protium atoms.
(a)18:1 (b)1:1018 (c)1018:1 (d)1:1810
(16)99.96% pure dihydrogen is obtained by electrolysis of warm aqueous solution of Ba(OH)2 using ____ electrodes.
(a)Cu (b)Pt (c)Ni (d)Zn
(17)Which of the following alkaline earth metal carbonates is thermodynamically most stable?
(a)MgCO3 (b)CaCO3 (c)SrCO3 (d)BaCO3
(18)Which of the following is not a mineral of sodium metal?
(a)borax (b)sylvine (c)rock salt (d)carnallite
(19)Bond length of C-C and C-H bond in ethane is respectively ___________ and ____________.
(a)145 pm, 112 pm (b)112 pm, 154 pm (c)154 pm, 112 pm (d)112 pm, 145 pm
(20)Which type of isomers are ethanal and vinyl alcohol?
(a)position isomers (b)functional group isomers (c)tautomers (d)metamers
(21)Identify the free radical from the following.
(a)H2 (b)Cl (c)Cl- (d)Cl+
(22)Which of the following is the functional group isomer of but-1-yne?
(a)but-2-ene (b)but-1-ene (c)but-2-yne (d)1,3-butadiene
(23)Which of the following shows maximum –I effect?
 (a)-COOH (b)-NO2 (c)-OH (d)-OCH3
(24)Choose the correct IUPAC name of the compound HO-CH2-CH2-CO-CH3.
(a)1-hydroxy-butan-3-one (b)4-hydroxy-butan-2-one
(c)2-butanone-4-ol (d)1-butanol-3-one
(25)Melting point of nitrogen is lower than phosphorous due to
(a)hydrogen bond (b)ionic bond (c)van der waal attraction force (d)covalent bond
(26)Which of the following exhibits the lowest bond length according to molecular orbital theory?
(a)𝑂22+ (b) 𝑂2+ (c) 𝑂2− (d) 𝑂22−
(27)What is the shape of ClF3?
(a)See-saw (b)T-shape (c)bent (d)trigonal pyramidal
(28)What is the number of non-bonding electron pair on central atom in SO2?
(a)1 (b)2 (c)3 (d)4
(29)Which of the following molecules do not show hydrogen bonding?
(a)liquid NH3 (b)H2O (c)HF (d)CH4
(30)What is the energy of 1 mol hydrogen bond?
(a)10 k cal (b)10 k joule (c)100 k cal (d)10-100 k joule
(31)Which of the following liquids undergo diffusion when in contact?
(a)water-kerosene (b)water-benzene (c)water-petrol (d)water-ethyl alcohol
(32)Which of the following is Lewis acid?
(a)HCl (b)CH3COOH (c)H2O (d)BF3
(33)What is the necessary condition for precipitation in any reaction?
(a)Ip<Ksp (b) Ip=Ksp (c) Ip>Ksp (d)Ksp>Ip
(34)Which complex is obtained when KCNS is added to FeCl3 solution?
(a)[Fe(SCN)3]3+ (b) [Fe(SCN)3]3- (c) [Fe(SCN)]2+ (d) [Fe(SCN)]2-
(35)Which colour is given by Cr3+ with borax bead?
(a)green (b)pink (c)brown (d)blue
(36)Which gas is used to purify sugarcane juice in production of sugar?
(a)CO (b)CO2 (c)NO2 (d)O2
(37)Which of the following is an example of ring silicate?
(a)spodumene (b)zircon (c)beryl (d)Muscovite
(38)Which of the following functional groups is m-directing?
(a)-OH (b)-OCH3 (c)-OCOCH3 (d)-COCH3
(39)Which mixture is used as Lindlar’s catalyst?
(a)Pt+Pd (b)Ni+Pt (c)Pd+charcoal (d)Pd/Ni
(40)What is the value of resonance energy in benzene?
(a)119.66 kJ (b)208.36 kJ (c)150.63 kJ (d)358.49 kJ

PART-II
Section-A
Answer the following questions(2 marks each): (16M)
(1)Calculate the mole fraction of NaOH and water in a solution formed by dissolving 4 gram of NaOH in 180 gram of
water. (molar mass of NaOH = 40 g mol-1, H2O = 18 g mol-1)
(2)Give two points of difference between orbit and orbital.
(3)Why oxygen has lower first ionization enthalpy than nitrogen?
(4)Explain ion exchange method for removal of permanent hardness of water.
(5)Explain expansion of an ideal gas in vacuum and change in entropy.
(6)Write a note on Gibbs’ free energy and useful work.
(7)Derive relation between Kp and Kc.
(8)Define homogeneous and heterogeneous equilibrium with one example of each.
 Section-B
Answer the following questions(3 marks each): (12M)
(9)Describe Solvay ammonia soda method for obtaining sodium carbonate.
(10)Draw molecular orbital diagram of O2 molecule. Calculate its bond order and state its magnetic property.
(11)At 500 K temperature in 2 liter vessel, 0.32 gram O2 is collected over water. If the vapour pressure of water is 32
bar at 500 K, find the partial pressure of dry O2 gas.(atomic mass of O=16 u)
(12)Derive the relation ΔH = ΔU + Δn(g) RT.
Section-C
Answer the following questions(4 marks each): (12M)
(13)What are silicones? Write preparation, two properties and two uses of silicones.
(14)Convert: (i) benzene to phenol (ii)benzene to m-xylene.
(15)Explain photochemical smog. Write its harmful effects. How can it be controlled?