ve Y ASPIRE CHEMICAL ENGINEERING REVIEW CENTER Aad ae of ASPIRE SUCCESS REVEW AND TRAINING CORP 20. teh nota Sore. Cyt Cental he, Marden Cy Day 1 Refresher Exam - Physical and Chemical Principles Aston ppd by ino ans (tn 0 rte sen ule 20 Catete the malay of bemenein the son ro Z) 1 ee wan mer Calne he mas ecm aren inh soon TE] nom cos CS vos 091 Cotte the mle aco banan th ltn, «oi 020 [J] voase 4.025% Cota be ml of bese nh ltt) nan ‘ pena sean a pein ore he sno 304 oh eerie cc icon neh 200) now coat 3 me) (= mos Oc saade [Eo sanss EO arsaors ‘A cckta was prepared by ming 20g ethanol 0 150 gwar a 250C. Pre wate as ayer presire of 23.7 tort What would be the iw vapor pressure? i TO 220mmns [ED c 2a mmig TH bat mts 1 a 25mmne © 10 grams of salt aC i added to 100 ml of water. What are the ne freezing? (Mb = 0.51 C kg/m, KI=1.86Cka/mol) Bit- Tred Tsao] «946 fer bp, elevation AT, = tym avadec What isthe new boiling point? Ol er Tratehion Ty cavent J owe «me wane [Ol ame Catatethe presrnededts prevent oes when 10.04 Cais aed 300 mf water? CO nea MET 228m [J beam CO arsam ‘test bottle containing ust seeded dition water has its DO level drop by 1.0 mg in a five-day test. A 300m BOD fate ied with 1 mo watt aod he vex sede ton water (onetines exressed so ton of 320) ‘spencer of 72mg nth same ne period What would ete veda 00 fhe wate? I] semen enon Z] 9225 men CE «nomen A sample of municipal sewage is cllted to 1% by volume prior to running a fve-day BOD test. After S days, the oxygen ‘consumption s determined to be 2 mg/L. Whats the five-day BOD ofthe sewage? [2] = 200men [] «ome [] 2 20m [J «200m Awosteater treatment lant ring ty 200,00 dacharges 110 m/s of rested eluent having an ultimate BOD ‘of 50.0 mg/L into a stream that has a flow of 8.70 m3/s and 3 BOD of is own equal to 6.0 mg/L. The decnygenation constant, kis 20/4 tHE T# day Assuming complete and Instantaneous mixing estimate the ultimate 800 ofthe river just downstream from the outal, ‘ay Retresher Exam Pye and Chemical Principles Prin Page 43 4. 1s. uv 20 a 2 2 21090 c8amen CO seamen 75 mat 1 tam ha cntane cot wt 10 Ut flow «fd bee equal 030 mh sna te 800 ‘aman area os ance 390m downs fa 868 me © 6.33 met 2» AS2it Cy a sasmen Aastha aoe nae concentration 2.0 qa Schr ate 110 mi whe he rN 00 OF 83 mg/L at a rate of 8.7 m/s at 20 degC, Assuming complete and instantaneous mixing, estimate the inal ‘Sesolved orygen deft of the mitue at downstream. The saturated vale of isohved oxygen at 20 de. C 9.09 mg/L. [Btn «ssmen basmet asm — Toms ‘The vopor prt ropa 19448 298 Kon 86a at 0X Wat the ete aprons Cf 79Man? Bie mcy AT Oy sees Ere ake] caesar bes hu/mot c5 F-06409. 4, 108.6 Ky/mot _ Ugh, Awd russe th pot wae citi dchrgeof plated at mw ir hut BO 10.8 ma an400%7Snft Tether and anette fa olemperlue 1S estas cat {0 nar ow 050m anon rags depth a Pode tne nec ows a wih be ‘nye efi s at mani. As, he inmuan vlu f BOD, [Oo 2 2074p can Samet OT Chicos ioatn samen 5) 2 sizes ana, 62 mat ye datdgy asain asian ‘Which of the flings asacted with the coroion of satay sewers? & nas [] «tava 4 800 [J ems ine (orceairedsteum ete owe ts, ol SO ems mt comment ced 2 Unasonting «econ ston cathe comerion 4. cao alin ‘A community generates 50,000 bay of sold waste tha i posed of na sanitarylndfil. The mass ratio of refuse to ‘overis 3 to 1. The in-place deny of the il refuse pus cover) 1,000 by. The rcessary volume (v3) of i (refuse plus cover fora 10 year operation period i most near: 730000 83000 243000 [] « 61000 ‘You have been selected to design a secondary wastewater treatment plant (WWTP) for Location X, municipalty of 15,000 people which has some ndurtry that cicharges wastewater to the municipal sewer system. The average daily ‘wastewater flow is2:1 Mega Gallons per Day [MGD) and the raw sewage entering the WWTP has an average BODS of 240 mg/L and average suspended soit of 260 mel tthe average domestic per capita sewage flow is 115 gallons/person-day, what Ii the average fw ofthe Industral wastewater (in MDI? sc0smco CO coars mao TB eorsueo © coasmao lf the average BOOS lad from the domestic sewage s 0.18 bs/capita-dey, what the average daly BODS loding (in "ea/day fom the industrial wastewater? What the population equvalent to this BODS loading? 5352 ©7352 6352 4. m352 ‘Primary treatment achieves 65% suspended solids removal and 38% BODS removal. Whats the BOD Loading (/4)? C] wa CJ com 4735 =] a.2ns ‘What the Theoretical Oxygen Demand for Phenol (6HSOH|? Z] 2 715meit b730meht ‘What isthe Tota) Organic Carbon for Phenol? © 750.me/L 4.775 mah. Dy 1 Reesher fam Phys ans Chemie Pnces Pnt Page2+ 20m. CO crm 2 250mef, 4 290mg 25 Ammonia is ondized to trom nite, hen further oxidation ofthe product to produce nitrate Calculate forthe Ntrogeneous oxygen demand forthe conversion of ammonia tonite, when 92 gf ities produced? [[] a. ome CO om Cems 26 Calculate forthe Nkrogenous oxygen demand forthe conversion ofrutite to nitrate, When 124 df trate Produced? 2306 ome Clem meen 27 Ttolonng aware ctanedin the nays ofan Intl wos Ate 5 days feb a 20° the resid ‘esc nyer bart wr 7 80 mq! ardins 01 pera atone we was 280 me Wha ty B00 orine wane? asco man CO cssc0men $0 mat Ey « ecoomen 28 Asami ot wanaterhtan st mate 902mg dy 80 ogc 0-909 te [J a 25m (Oc msm b, 280 mg/t > pag ae 4 saz a mpage ‘const of pathogenic bacteria by consists of undesirable substances ‘rendering unt for drinking and domestic 21 Which ofthe few ot a water besene a dsemey «pod CO beats rato 32 Tecoma cae of any waters LZ] = exten te «onan 8. Onyen 4. hrogen 23 Standard TA otine ado dteine te LE] » bardnes of water sched gen in water 2. tiny tater 4 et rin ter 34 tries of wat eater tan tt any he corte aos wl bea [Z] + toanatiney TO < tot sand (rattan [EJ « non catnste Hades 25. Thedavohedonpen lin antral unpoted water roma enowatie ak CO sme [J <20men [2] ». 108 ED «omen 36 The chemical most commonly used to Increase speed of sedimentation of sewage i oo oo 8d nips [A «ime CE cna ntote [L) rte commie 317 Dinlecon of watereutsia [+ roma iay «ttn ne bac ome tharos 4. complet station 38 Inchlornation, with the rise ln temperature of water, death ate of bacteria meee ZZ rie nt b, decreases 4, none ofthe above Day Rarasher Exam Pra and Crema Princes Pint Page 3a a a “6 ” ry 5 st 5 ar ‘ctv Carbon sed for |. disinfection '. removing hardness ‘8 Thoo>Bo0>coo ‘8. mop»co0>800 Facutative Bacteria are able to workin HB 1. presence of cnygen only absence of oxrgen only treatin i of nkzogen compound [Z] 2 owdstion »,neduetion cadmium These are all common preciptants except Ea [Ey une sn Ar Fehon seo ed rom ei actors be lea AAt oth Pins mee CE omen Clan Water et oft Piones esos pmasao 2. ProaryPotzant RATIO VA ', Watar code ofthe Phitppines Cola nanan th Papp a russ [Ey 6 rss cata chang et of 208 a. nas7e2 be rAgT29 Environmental Awareness and Education Act of 2008, \Lewstation that presents the revised water usage and cassicatio 1, DAO No, 34 b, DAO Ho. 43 A ‘ay Relreshe Exam -Physial and Cami Pincpes_Print ‘The correct relation between theoretical oxygen deman biologi ON OO [2 « remonn ads 4. removing corosveness mygen demand and chemical oxygen demand is? ‘00>ThoD>coo 4. cop>moo>s00 presence and absence of orygen presence of water «Both Aang 8 4, None ofthe Above Both And 8 4, None of the Above * 4. Feri Sulphata 2 §0O G0 ON ON ON OO aa Caer { 4. Non- Criteria Poutan naam ‘dinabiof the above cRASTAD 4. None ofthe Above «_ (reatlon of National water and ie Polltin Control Commisoning 4. Crested the Metro Manila Commision POSs68 [7] 4. None ofthe Above H Oy moss TE mon tn stow RASIST 4, None ofthe Above DAD No. 35 4. DAO No. 53 q ‘A lobal treaty that aims to protect human health and the environment from persistent organ pollutants, Page 437 6. a. cy 67. 4, Baek Convention Assuig that he hydrogen molecules Dave 8 rot mesn- square peed 1.270 m/s 200K cute terms at 600 Stockholm Comvetion «Kyoto Treary , Montreal Convention © asm CO «819m 8.1796 mvs TE aiserms ‘Winans as expands abt is volume i oud we ts Kein emperaure fs cen by afer of 1.32. ‘eate the nimber of degrees teed othe go molec Ba Oe Co es (as Calelate the latent eat of vaporization of wae rom the folowing dt: T= 373:2K v= Lend, v2 #1674 em, $0161 =2.71 mot mercary/ assem - (O cssscu b.s953.cave 5 assay Find the change in boling it whe the presi on wate at 100 deg i increase by 2 tmospheres. (k= S40 cali, volume of got stam 1677 cl 50. ge Oc woatene be SsAdect TE c osacege Vf wter frets inte, the change ns specie volume 0:91. Cala ha pestre required tobe apped to feet 10 gol water at eae CO 220mm Cc eeraem TS saz TE) 42am. ‘Caculate the change of meling point of naphthalene per atmospheric cha ‘degC, latent heat = 35.5 calf, deity of sold = 1.145 gc and density of qui oy 20.0063 eae g « 0.346 deg TE b oowse dere 4. 0.0036 deat Ante conan les neg washed rn emparatr T1+ 200 pera T= 00K The tural enrgyofthe princes U 801 Mow em eta ever 3 794) ese: ZI +571 CO ees, The change Inthe Gibbs energy during the oxidation of one mole of fucose, according tothe reaction (61206 + 602 = 6c02 + 6420 's delta G = -2870 bj mol-1. How high can a parton weighing 75 ke climb i hy she has eaten one mole (186 g) of, ‘ducose? The blologlal efficiency is 25%. Assume that a human body aes as an iothermal and isobaric system in which ‘eerste processes gz and doesnot perform any volume wor, ym (gresur, given melting pont = 20 CO sem crm 2 976 DD sm ‘heat of» 100, was supe to a system for achric hating oa substance fro 300K wo 305K Estimate he value ater. CO aw «201% Do osm Co asm |sthe given data Inthe previous problem enough for uso estimate Cp if we know thatthe substance fan Kea as? aves amount of substance Is known, bNo 4. Cannot be determined {Knowing the values ofthe molar Gibbs energy of carbon doxide = -53 183 /mol at T= 350K and p= 10 MPa, and its ‘molar Gibbs energy nan ideal gaseous states ~65 675.14 I/mol calulate Its fugacity coefficient at 350K and 10 MPa. Ey noms cosur veers ES coisa Using the relation following from the van der Waals equation, estimate jhe Inversion temperature _at zero pressure fr Hllum usiog its critical temperature Aeee Tense 27ers (Pas) (et) oO 375K a E} a assx ah % 4.399K ‘Using the van der Waals equation of state, calculate the compressibility factor of substance whose etical temperature | 800% and critical pressure is 8.314MPa, ata temperature of 1000K and 3 molar volume of 1100 em3/mel Dey Reeser Exam - Phys and Chemical Principles Pit Page §6. 10. n. n n 7. %6. n. ” a. 2 a, GB 20.4055 Oy coe oass cose The compresibilly factor of butane at temperature of 523.15K and a pressure of 13.25 MPa ist = 0.6093. What temperature and pressure wi) butadiene have the same compres factor? (2) = tes28k pesaas mee 6 T#523K P4156 mF (2) & tes26x pets.t6 mre 4.125234, P #1325 Me 's I possible to caleulate the change inthe Helmholts energy during a nonsothermal process ifn addition to U and ‘we also know the intial and ral temperatures? Dawe [7 « Herange in work is defined also [2] aw TH «connote determined ‘Whats the work during expansion ito vacuum? ssi TB eum [Eo «comet determine Ma atm exhage ny whine wok wh is sururngs daring an abt procs, shat work me tai chore TZ] sate tsthan Tone a Euston hat common apie rate st ow reduced press andi retucetarerature = teatcrnong £08 TT veraeranseos [ET + cieounam eos 4 deals EoS / | & perpetual motion machine of the Best ype perpetual mation machine of the second, L_| * type A mpthetel yay woring man at ees at am io a. perpetual motion machine of the first type « oon = mechine ofthe tid 7] teart nen rant aor gy meet 20 ml of benzole acid of unknown concentration Is thrated with potassium hydroxide whose concentration i 0.095M. Caleta the He concentration at 25% degree of tiation. Up to the equnalence point, 13.56 mi of KOH solution Is consumed a «6.29 1085) TO e2mains ; ET Gains Os toasts (Oo a serio 100 mi of formic acd whose concentration is 0. 010M Is titrated by sodium hydroxide solution of 010M concentration. Cateulate the pH before tration. Ka= 1.771104 B 32905 5 e362 2059 4.3% Cale the pi afer the addin of 0m of NAO ohition. CO a seer casu © vam aase Calculate the pH after the addition of 9.90 ml of NaOH solution. [EJ «5256 5 cama DC ess aan Calculate the pH at equivalence point CO ass CO eres Ey oras6 © ens evo he folowing process, lof the following wil produce an akane from analy! halide except (7) a Werte symtnesis Aymmtucad asharet — «Hydrogenation 1 ts edueton with 2ne Tc coreptouse Sintess Win folowing ection wl rd an tu alsa trom Eaten? aati ate et «taro Deen [1 «> strcpetan- oon Eo] «settee Th oe rc raed ect & ‘a. Sethylpentane B ‘& Nemethylbutamide teen 5 Comoe ‘ay 1 Reeser txam- Physical and Chemica Princpes Print Pagef fu ss. 7. 1. - "Her ode acho canbe prepared rom carbon compounds wing fom TE) cara escent 1b tine metab CS cetter ‘Aromatic compunds ae characteristics of macaopie substation ait halide '. mucteophicadtion ‘The number of primary hydrogen ethane asi fj ss « electrophie substnution ; 4. ectopic otdiion Contengt ormpvnel os Ge: a6 Wht the olowng compounds the est eg pl? (1 a mpentane « reopentane 1 hopentane TB « trobutane Which ofthe folowing ane woul yields monohaagenates praia? 1 + propane ( coane Elo etae oc retane \When met: dutaa underneath mar oa = zeit s-otene 0 cate 2 meth bute 6 testene The folowing ay has wl produce 2athyropee upon acon wihalahae KOM exc eatury-ctorice [hr tortie torise E21 > ctorobutane TE 4 tetere 2 titane ih fooving acon wl ylé an aol tom ahans? [= cnymereurtion oemereraton Oc tee [1 puanedhtnaae [Fl cmaothege tent anes gt alan a alse com Bis Ais Aion olgentn anes ing opt sont vis 3 1 exminal dale < wrnaagis ». wena datise 4 natomaie' Marko atone Ht ayes dina prades I + eemnat arate TO wera Ed & wii ate 4. mtorr retire 2» enoude « atcotot 8 0. tetone A sie lection of leona 1 «rearrangement « hpereonjuestion Ob ttomersn B 4 onan mong chery, wa reaton? 1 = ainotetecrone 1 tosotetecrone [1 & oecreace in ondsvon number 2] tomasnas Whats te funcional goup atch to benzene when ki eomerted ue? Ly + carton ove a «vn om 1 6 amide group 4. methy group \Wichis ot benzene erate? [] o pharantivene [Ey < tromouthane TO & entracone Se captatne ow any marae posse for propane? g aa Oe na Eco ‘ay 1 Retesher Exam. Physical and Cham Princes Print Page 7