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Long-term forest fire retardants: A review of quality, effectiveness,


application and environmental considerations

Article  in  International Journal of Wildland Fire · January 2004


DOI: 10.1071/WF03001

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CSIRO PUBLISHING
www.publish.csiro.au/journals/ijwf International Journal of Wildland Fire, 2004, 13, 1–15

Long-term forest fire retardants: a review of quality, effectiveness,


application and environmental considerations

Anna GiménezA,B , Elsa Pastor A , Luis ZárateA , Eulàlia PlanasA and


Josep ArnaldosA
A CERTEC: Centre d’Estudis del Risc Tecnològic (Centre for Studies on Technological Risk)
Department of Chemical Engineering, Universitat Politècnica de Catalunya, Av. Diagonal,
647, E-08028 Barcelona, Catalonia (Spain).
B Corresponding author. Telephone: +34 93 4016675; fax: +34 93 4017150;

email: anna.gimenez@upc.es

Abstract. Since the beginning of the 1930s research has been directed towards improving the effectiveness of
water as a forest fire extinguishing agent. Throughout this time various chemical substances have been added to
the water, and this is still the case today. Among these substances are the various types of long-term forest fire
retardant, which maintain their ability to alter combustion when the water has been removed by evaporation. In
order to provide an account of the current state of development of studies on long-term forest fire retardants,
we carried out a bibliographic analysis with special attention to work done after 1976 on the different aspects
that influence the final effectiveness of forest fire retardant: quality (programs and evaluation), effectiveness,
application and environmental impact on streams and aquatic organisms, vegetation and humans. The scope of this
work covers the wide subject of fire retardants and it introduces the significant works related to all the aspects of fire
retardant use.

Introduction the mass of residue in fuel beds treated with AS and DAP.
Long-term fire retardants have been used extensively for The fuel treated with DAP gave a significant reduction in
several years in different countries. Since the first stud- Er , and a greater amount of char was observed. A further
ies (Barret 1931; Truax 1939; Tyner 1941), research has study by George and Blakely (1972) showed that DAP was
been carried out on the large number of parameters that more effective than AS in reducing the parameters studied as
influence their effectiveness and use. As different mixtures regards flammability. George and Sussot (1971) studied the
of fire retardant were tried, new aspects arose in rela- thermal behavior of ammonium sulfate and phosphate and
tion to their operational use. For example, the corrosive treated fuels in order to identify their effects on combustion
effects and environmental impact of the retardants were and pyrolysis. They found that the thermal behavior of these
observed during Operation Firestop (1955a, 1955b). Nev- two retardants was different, which may explain why phos-
ertheless, these aspects were not studied more extensively phates have a greater impact on glowing combustion than
until after the works that focused on how to evaluate the sulfates and the differences observed by George and Blakely
effectiveness of mixed products and on the use of thicken- (1970, 1972).
ing agents were carried out (Davis et al. 1962; Johansen and While the effectiveness studies were developed, the
Shimmel 1963). study of the aerial application of fire retardant began. The
Hardy et al. (1962), as a result of a study to test new mix- experimental works consisted of drop tests in which a
tures of retardants, showed that ammonium sulfate (AS) and fire chemical was delivered aerially over a cup-and-grid
diammonium phosphate (DAP) reduced the rate of spread and system. This was to determine the coverage level pro-
the radiant energy flux most effectively. From that moment, duced for each drop type (Storey et al. 1959; Davis 1960;
research was dedicated to comparing the effectiveness of Grigel 1970, 1971, 1972; Newstead 1973). The data pro-
sulfates and phosphates, studying their effects on the com- vided by various drop tests allowed modeling of the aerial
bustion, pyrolysis and flammability of cellulose. George and delivery in order to estimate the ground pattern of fire
Blakely (1970) studied the rate of weight loss, which is related retardant in relation to the interaction of fuels (Swanson
to the energy release rate (Er ), the rate of flame spread and and Helvig 1973, 1974; Anderson 1974) and to the

© IAWF 2004 10.1071/WF03001 1049-8001/04/010001


2 A. Giménez et al.

Table 1. Time-line chart of reviewed research


Studies 1977–1979 1980–1989 1990–1999 2000–2002
Quality George et al. (1977) Gehring (1980) Johnson and George (1990) USDA Forest Service (2000)
studies Gehring (1978) USDA Forest Service (1982) NWCG (2000)
Van Meter et al. (1985)
George and Johnson (1986)
Gehring and George (1986)
USDA Forest Service (1986)
Effectiveness Blakely (1983) Blakely (1990)
studies Blakely (1985)
Blakely (1988)
Application Rawson (1977) Van Meter and George (1981) George and Johnson (1990) Johnson and Jordan (2000)
studies Andersen and George (1982) Vandersall (1994) Lovellette (2000)
Wong (1978) Blakely et al. (1982) Robertson et al. (1997a, 1997b) Calogine et al. (2000)
Rees (1983) Vandersall (1998) Xanthopoulos and
Newstead and Noussia (2000)
Lieskovsky (1985)
Loane and Gould (1986)
Northeast Forest Fires
Supervisors (1987)
Environmental Johnson and Larson and Duncan (1982) Labat Anderson Inc. (1994) Kalabokidis (2000)
considerations Sanders (1977) Bradstock et al. (1987) Hamilton et al. (1996) Buhl and Hamilton (2000)
studies Norris et al. (1978) Norris and Webb (1989) Gaikowski et al. (1996) Little and Calfee (2000)
McDonald et al. (1997) Little and Calfee (2002a,
Buhl and Hamilton (1998) 2002b, 2002c)
Adams and Simmons (1999) Little et al. (2002)
Larson et al. (1999)

rheological1 properties (Andersen et al. 1976). In other drop by the National Fire Danger Rating System (NFDRS) of the
tests (George and Blakely 1973; George 1975) the authors Forest Service (USA).
observed differences in drop characteristics and in the ground Sometimes, after extinction operations next to streams,
pattern between retardants that contained gum or clay as high fish mortality was observed which led to the study of the
a thickening agent and unthickened retardants. Generally, acute toxicity of fire retardants to aquatic organisms when it
gum retardants exhibited more cohesiveness under high shear is applied directly in streams (Davis et al. 1961; Dodge 1970;
conditions and allowed obtaining effective retardant cover- Blahm et al. 1974). George (1970) reviewed studies showing
age >2 gpc2 (0.8 L m−2 ) with higher and safer drops. Using the effects of retardants on aquatic organisms and concluded
the data obtained in these two drop tests, Swanson et al. that the toxicity effects of retardants came from the amount
(1975) developed the Pattern Simulation Model (PATSIM) of available ammonia.
to obtain the first guidelines for aerial retardant drop. This The performance of fire retardants during extinction oper-
program was revised 2 years later (Swanson et al. 1977), ations is influenced by several parameters which are very
and validated experimentally by Swanson et al. (1978). This different from each other. Since the early stages of research
work showed the effects of the airtank, gate systems and air on fire retardants, these parameters have been studied sepa-
drop performance on the ground distribution pattern. Dur- rately. In the review of George et al. (1976), the parameters
ing the extinction operations, at a technical level, it was were divided into six categories: product formulation and
significant to know the amount of retardant mixture nec- evaluation; base requirements; retardant cloud characteris-
essary to attack a given type of wildland fire. Rothermel tics; delivery characteristics; fire situation effectiveness; and
and Philpot (1975) developed a model, which was based on environmental impact. Later, Hardy (1977) included, more
the model of Rothermel (1972), to estimate the maximum extensively, all of these parameters in a general work.
useful concentration to reduce fire spread for different fuel The present work reviews the studies (Table 1) carried out
types. The values varied from 0.67 gpc (0.28 L m−2 ) to 13 gpc since the article of George et al. (1976), and it focuses on
(5.34 L m−2 ) and were determined for each fuel type defined the analysis of the most studied parameters that affect the use

1 Those properties, including viscosity and elasticity, affecting the flow characteristics of a fluid. These properties affect the behavior of the retardant as it is
dropped from an airtanker.
2 gpc: gallons per 100 square feet.
Long-term forest fire retardants 3

and application of long-term forest fire retardants: quality, the parameters for the retardants currently used by the Forest
effectiveness, application systems and environmental impact. Service (USDA). The viscosity and the amount of active salts
provide information on the quality but not the effectiveness
Quality of fire retardants: programs and evaluation of of fire retardants. Van Meter et al. (1985) described a method
forest fire retardants for measuring the rate of coverage to determine the amount of
As the different types of forest fire retardant were approved, mixed retardant applied. This was the only aspect associated
various methodologies were introduced to determine the with the effectiveness of the retardants that was evaluated in
chemical properties of the mixtures and concentrates; and the field, under operational conditions.
this allowed the evaluation of their applicability and use in The most extensive study of retardant evaluation was car-
wildland fires. ried out by George et al. (1977) in order to evaluate a new
Standards for the evaluation of commercially available type of retardant: the ammonium polyphosphate (APP) liquid
long-term forest fire retardant products are to be found mixtures (LC), and more specifically Fire-Trol 9313 -L, N, P
in USDA Forest Service (2000). This document defines and Fire Trol 931-L with and without gum or inverter emul-
the essential terms employed in relation to the use of fire sifier thickened. The polyphosphate mixtures are considered
retardants and describes the test procedures followed to anal- to be the most effective (George et al. 1977), as well as the
yse their constituents to evaluate the fire retardant, in the following mixtures: DAP, liquid type ammonium pyrophos-
laboratory or in the field: tests of mammalian toxicity and phate (Pyro) and AS. The evaluation of the APP mixtures
irritation, combustion retarding effectiveness, determina- was based on the study of the following parameters: stor-
tion of optimum mixing and physical properties (active salt age, specific weight, viscosity, corrosion, pH values, abrasion
content, viscosity, density, pH, product stability, corrosion, and erosion, combustion retarding effectiveness (superiority
pumpability, abrasion, air drop characteristics, field visibility factor), color, health and safety, mixing, salt content, sepa-
and operation field evaluation). This publication sets lim- ration, pumpability and air drop characteristics. All of the
its required for each of the measured characteristics that methodologies used to analyse the different parameters of
commercial fire retardants must meet. those products followed strictly the applicable regulations,
The chemical analysis procedures for monitoring the and the corrosion, stability and air drop characteristics were
variety of commercial fire retardant products are based on studied in depth.
methodologies used to test other chemical substances, but The discussion about the corrosion caused by the APP
specific conditions, operations, and procedures have been formulations was due to the lack of studies and specifi-
developed to yield optimum results with normal mixtures of cations in this field. Fire retardants cause several types of
the ingredients present in fire retardants (Van Meter et al. corrosion and effects of different kinds of the equipment
1985). The procedures in the field have to be fast: some alloys; the corrosion studies developed later were centered
of them, for example the amount of retardant salts, require to cover some of these aspects. These studies were signif-
calibration curves or tables relating to other properties. icant because corrosion is one of the characteristics that
Laboratory procedures, on the other hand, have to be exact has an affect on safety during extinction operations, par-
in order to improve on the indirect measures in the field ticularly if we consider the potential hazards and damage
and detect chemicals that are partly absorbed into or react that may be associated with the aerial release of fire retar-
with others and are therefore not detected. Van Meter et al. dants. The types of corrosion detected in the alloys of the
(1985) gave a detailed description of the chemical analysis aerial release and ground equipment and the mix and stor-
procedures in the laboratory to determine the main chemi- age tanks are: uniform corrosion, intergranular corrosion,
cal and physical properties of forest fire retardant mixtures pitting corrosion, galvanic corrosion, fatigue corrosion and
[ammonium polyphosphate (APP), DAP, monoammonium stress corrosion cracking. The maximum allowable corro-
phosphate (MAP), and AS]. sion rates because of uniform corrosion are published in
The amount of active retardant salts is one of the most the specification cited above, USDA Forest Service (2000),
important parameters, as it is these substances that alter the which specifies only the execution of corrosion tests for uni-
process of combustion in a forest fire; this parameter and the form corrosion and intergranular corrosion for four types
viscosity are the characteristics analysed for the evaluation of of alloys.
fire retardants in the field. The sampling and analysis proce- Gehring (1978, 1980) carried out laboratory studies to
dures are described in George and Johnson (1986) and later determine which alloys are most affected by corrosion,
in NWCG (2000). According to the value obtained, George specifically uniform corrosion. Together with previous work
and Johnson gave the corrective actions required in order to of Gehring (1974), this formed the basis for determin-
bring the properties within the range of these two param- ing and checking the approved corrosion values caused by
eters, while another report showed the values for some of commercialized retardant mixtures.
3 The use of trade firm names in this publication is for reader information and does not imply endorsement by the Centre for Studies on Technological Risk.
4 A. Giménez et al.

The results of the works analysing retardant-induced cor- laboratory. The retardant effectiveness cannot be accurately
rosion are used both to determine whether the mixtures with predicted by analysis of total concentration of active salts, but
corrosion-inhibiting agents fall within the limits set, and must be quantified by burning fuels treated with the chemical
also to ascertain which alloys are most affected by a given formulations (Blakely 1988).
retardant mixture. Gehring and George (1986) developed Blakely (1983) corroborated the conclusions of the stud-
guidelines for preventing and reducing the corrosion caused ies of George and Sussot (1971), where it was determined
by fire retardants in airtankers and ground support equipment that the effectiveness of fire retardants associated with the
(storage and mixing tanks). reduction in flammability and combustion was related to the
Johnson and George (1990) evaluated the corrosivity of available P2 O5 in the retardant mixture. Blakely compared
the most frequently used long-term fire retardants (nine the effectiveness of several retardant products containing
types), short-term fire retardants and foams under different MAP obtained by means of different manufacturing pro-
temperature conditions. This study was performed both with cesses and from different manufacturers with the effective-
fresh products and with products that had been stored for ness of DAP, which has been the standard for comparison
some time. The authors studied the damage caused to the since 1970 (George and Blakely 1972), in an attempt to deter-
alloys by uniform and intergranular corrosion. The alloys mine whether the manufacturing process or manufacturer had
used in this study were representative of those exposed in an influence on the effectiveness of fire retardants. The rate
airtankers and helicopters and in use at retardant storage facil- of spread and the rate of weight loss were studied statistically
ities: 2024 T3-aluminium, AISI 4130 steel, yellow brass and and the authors found that the MAP mixtures tested on an
Az-31-B magnesium. The methods were executed accord- equal P2 O5 equivalent basis were as effective as DAP and
ing to the appropriate Forest Service regulations for each therefore fire retarding effectiveness of each MAP and DAP,
case (USDA Forest Service 1969, 1970, 1975a, 1975b, 1982, in a pure form, can be equated on the P or P2 O5 content.
1986). The study was conducted to compare the corrosive- The effectiveness of fire retardant is based on the chemi-
ness of the different products that were being used at the cal ability to hinder or reduce the combustion and it can be
time. The results showed that all the retardants tested were evaluated by the superiority factor (SF), the value of which
within the corrosiveness limits for uniform and intergranu- must be greater than 0.6 for the retardant to be approved by
lar corrosion. The significance of this factor does not relate the Forest Service. Blakely (1988) determined the SF for four
only to safety; a knowledge of the uniform corrosion caused forest fire retardants and compared the effectiveness of the
by the fire retardants also allowed technicians to choose the active salts contained in the long term retardant mixtures. The
most appropriate retardant in relation to the type of equip- salts studied were: MAP, DAP, AS and an MAP–AS mixture
ment and the specific conditions of the determined base. With (the samples had no additives or impurities). For the com-
reference to intergranular corrosion, although the alloys did parison between the fire retardants the amount of active salts
not exhibit this type of corrosion, the tests had to be carried was calculated in DAP equivalents. The MAP–AS mixture
out. This was because, according to the results and other data had more effectiveness than DAP or AS when used alone.
obtained to date (1990), there was no way of predicting which These studies about the effectiveness did not determine for
salt–inhibitor combinations would cause intergranular corro- how long retardant agents maintained their ability to reduce
sion (Johnson and George 1990); just the specification for flaming combustion, when they were insufficient to stop all
long-term retardant USDA Forest Service (2000) determines combustion and then flaming recurred (combustion recov-
within the tests of physical properties. ery). Different retardants may have similar capabilities for
reducing flaming combustion but be very different in their
Effectiveness of fire retardants ability to maintain this effect (Blakely 1985). With this idea in
The increasing use of the long-term fire retardants proposed mind, Blakely (1985) conducted experimental tests to validate
by Hardy et al. (1962) has been accompanied by a steady rise a new method for determining the effectiveness of retardants
in the cost of this use, due in large part to the increasing prices according to their ability to extinguish combustion recovery.
of the chemical products that constitute the active ingredients The assessment was carried out by the study of the effects of
of these fire retardants. This increasing price has prompted different concentrations of retardants and thickening agents
further studies aimed at determining which fire retardant is when the combustion was already under way. The water, fire
the most effective. The effectiveness of a fire retardant, as has retardant and thickening agents were not applied before burn-
been discussed above, is a concept that should include other ing the fuel but when the maximum energy release occurred4 ,
more general parameters involved in the use of fire retardants, thus allowing the effect of the fire retardant on combustion
but to determine its effectiveness experimentally the param- recovery to be studied.
eters to study are the rate of weight loss, the energy release Early tests showed that water was the primary agent con-
rate and the amount of residue after burning fuel beds in the tributing to flame extinction; therefore, to compare the results
4A directional radiometer (Gier-Dunkle) was used to measure the maximum value of energy released.
Long-term forest fire retardants 5

obtained in the experimentation, the amount of water was 13


maintained constant in all the trials, in order to determine the 12
effectiveness of long-term forest fire retardants and thick- 11
ening agents independently. To test the fire retardants, the 10
9
amounts of water and thickening agents were held constant

Time (min)
8
and different weights of chemical treatments were added as 7
a variable and, to determine the effectiveness of the thicken- 6
ers, the amount of the thickening agent was changed while 5
the amount of water and fire retardant remained constant. 4
This study determined the value and duration of the rate of 3 Water ⫹ 24 g MAP
energy release, Er (or the rate of weight loss). By monitoring 2 Water
the evolution of the variables the author was able to desig- 1
100 150 200 250 300 350 400 450
nate eight segments in the resulting weight–time curve. Two Mass of water
steady states of Er were detected in the tests on treated fuel.
The duration and the value of the steady states of Er were used Fig. 1. Time to start of combustion recovery for water, and for water
to evaluate the effectiveness of the different mixtures applied. plus MAP. (Blakely 1990)
The number of tests carried out by Blakely was insufficient
to evaluate the data obtained statistically, but it was shown that 100
Blakely’s method was valid for evaluating the extinguishing
ability of different forest fire retardants.
Blakely (1990) used this methodology with different 80
amounts of MAP and water. This study included a new
Reduction Er (%)

parameter, known as ‘knock-down’, which occurs when the


treatment has just been applied. The ‘knock-down’ is a period 60
of ∼15 s, during which the greatest effect of the fire retardants
and water on flaming combustion is noted. Tests were per-
40
formed with plain water (144, 216, 288, 360 and 432 g) and
Water ⫹ 24 g MAP
with the addition of 24 g of MAP into the 144, 288 and 432 g
Water
of water to obtain solution percentages of 14.3, 7.7 and 5.3%,
20
respectively (by weight). The values of Er and the duration of 100 150 200 250 300 350 400 450
the steady states obtained were compared for the untreated Mass of water
and treated fuels with plain water and water plus fire retar-
dants. The study monitored the behavior over time and the Fig. 2. Combustion recovery energy release rate for water and for
water plus MAP. (Blakely 1990)
value of energy release during the steady-state periods and
at specific points. It analysed the duration of the buildup to
maximum energy release during the first steady-state period the 144 g water treatment, and by 56% when added to the
(time until start), the total time during which the burning fuel 432 g water treatment. The same trend was followed by all
was held at a low Er by the addition of MAP before building the parameters; there was a significant difference between
up to its maximum (time to maximum), and the magnitude the plain water treatment and the treatment with added MAP
of the maximum Er (maximum magnitude). when little water was used, and a smaller difference between
The objective of the study by Blakely (1990) was to deter- a large amount of water and this weight of water plus chemi-
mine the extinguishing ability of plain water and whether cal. This was most notable in the value obtained for maximum
adding small amounts of chemical substances is enough to magnitude (Fig. 2), which was reduced by 62% when 144 g
increase the period of its effect. The study showed that the of water was applied and by 80.3% when 24 g of MAP was
fire retardant used improved the effectiveness of plain water, added. In contrast, the difference between the treatment with
reducing the rate of energy release and extending the dura- the largest amount of plain water and the same amount of
tion of its effects on flaming combustion. Therefore, chemical water plus MAP was only 2.8%.
retardant can be a definite advantage during direct attack in Although chemicals reduced the fire intensity and
fire suppression efforts (Blakely 1990). When chemical prod- extended the time until combustion recovery, water proved
ucts were added to the water, the time until start (during to be the agent with greatest capability to reduce flaming to
the first steady-state) was prolonged, in comparison with smoldering combustion. These improvements in the use of
plain water (Fig. 1). By increasing the water treatment from fire retardant on combustion recovery indicated not only the
144 to 432 g the delay increased about 6-fold, while 24 g of advantages of their use, but allowed better understanding of
MAP increased this period of time by 273% when added to when and how they retarded combustion.
6 A. Giménez et al.

Table 2. Aerial drop tests of long-term forest fire retardant


Agency and country Reference Conditions, observations Results
and factors studied
USDA Forest Service, Johnson and Load size Development of aerial delivery guidelines of fire
United States Jordan (2000) Drop height retardants for several airtankers. (Wildland Fire
Drop speed Chemical Systems)
Three types of fire retardant: water,
foam and gum thickened
Victorian Forests Rawson (1977) Havilland Beaver plane Ground distribution patterns from effective ground
Commission, Australia Air speed constant at 148 km h−1 level concentration (>0.61 or >0.25 L m−2 )
Constant drop heights for studying the influence of canopy
Distribution of aerially applied was
studied in Pinus radiata aged
8, 12 and 15 years
Victorian Forests Rees (1983) Six types of plane Effective length and width of firebreak (>0.61 gpc
Commission, Australia Air speed between 176 and 215 km h−1 or >0.25 L m−2 )
Drop heights were observed
National Bushfire Loane and Project Aquarius The firebreaks built were not effective (0.24–5.4
Unit (CSIRO) Gould (1986) or 0.1–2.2 L m−2 ) for intensity of forest fire
>2000 kW m−1 , in Eucalyptus forest
Canadian Forest Newstead and Four types of airtanker Demonstration and discussion about how physical
Service, Canada Lieskovsky (1985) Load size retardant properties, environmental conditions and
Drop height the type of the tank effect on drop pattern
Drop speed
T ª, wind speed and direction
and the relative humidity
Viscosity

Fire retardant application of retardant) in order to assess the effectiveness of aerial


Fire retardant is usually applied from aerial delivery sys- retardant delivery.
tems, ground application representing less than 1% of the According to Robertson et al. (1997a), these parameters
total fire retardant used each year (Blakely 1990). Within can be divided into factors that affect the ground pattern,
the aerial delivery it has been estimated that 30% is car- the actual firebreak characteristics and the critical firebreak
ried out in direct attack (Gale and Mauk 1983). The ground characteristics. The main parameters determining the ground
application of fire retardant has some disadvantages against pattern are the flight altitude and airspeed, the wind direc-
aerial delivery and requires some planning and specific equip- tion and speed, the tank geometry and the physical properties
ment (Northeast Forest Fires Supervisors 1987); however, the of the additives. The actual effectiveness of the firebreak is
ground application gives better control of the fuel covered. influenced by the vegetation height, the coverage level and
Aerial delivery is much more frequent than ground applica- the thickening agents. Finally, the behavior of the forest fire
tion since the latter presents difficulties in the transport of the and the characteristics of the firebreak (width, length and
chemical products and the problems involved with the use of ground pattern) are the parameters that influence the critical
this application system. firebreak effectiveness.
Aerial delivery and therefore the final ground distribution Experimental drop tests have been carried out in the
are affected by many parameters, each of which influences field to determine the effect of each parameter considered.
retardant drop at different moments. The type of fire retar- Drop tests are usually conducted under a variety of condi-
dant, its rheological properties, the type of airtanker and the tions (flight altitude, airspeed and type of fire retardant),
drop height are some of the factors that have an impact on above a grid of cups. The ground distribution pattern, length,
the ground distribution patterns (length, width, and coverage width, and covered area were calculated from the amount of
level). Studies are usually inconclusive because of the large fire retardant in the cups. Robertson et al. (1997b) gave a
number of variables, many of them interacting, the magnitude detailed explanation of the drop test methodology used in
of the effect of these variables, and the difficulty in quanti- New Zealand.
fying the overall effectiveness of the retardant application Several drop trials have been carried out by forest agen-
(George 1982). For this reason there has been little agree- cies in different countries: the United States, New Zealand,
ment on how to evaluate the most significant parameters Canada and Australia (Table 2). The trials performed in the
(drop height, airspeed, flow rate, load size and elasticity United States by the Forest Service (Johnson and Jordan
Long-term forest fire retardants 7

2000) have yielded operational results and these tests have The computer program developed by Swanson et al.
been used to develop aerial drop guidelines. These guide- (1975) (Pattern Simulation Model), which did not work for
lines associate the ground pattern of the fire retardant with constant flow tank systems, was used to devise the per-
the airspeed and flight altitude and the coverage level for dif- formance guidelines for airtankers by George and Johnson
ferent types of airtankers and water-like fire retardants or gum (1990). The model requires one main input: the flow rates for
thickened. The other studies summarized in Table 2 evaluate each compartment. The methodology to quantify the flow
the effect of some parameters and characteristics of the drop rate was described by Blakely et al. (1982), and is executed
test on the coated vegetation. Table 2 shows that the drop by static testing. The other inputs of the program are related
height and the drop speed were factors included in all the to airtanker characteristics and drop performance, and the
studies as factors that influence the pattern of ground distri- outputs consist of a detailed pattern plot, contour interval
bution. Each study included other factors, depending on their summaries and a scaled pattern plot. If it is necessary to per-
ability to be measured and the specific aim of the study. The form consecutive releases from a single tank to reach the
parameters affecting drop performance and ground distribu- desired ground pattern, the program will need more input
tion are known, but it is still difficult to determine the ground data and a subroutine (PATADD) is used. The guidelines were
distribution from specific known parameters. developed for 35 different types of airtankers (representing
The rheological properties of the fire retardants are con- around 90% of fire retardant aerial delivery tankers in 1990
sidered to exert a strong influence on the ground distribution and now are not 100% applicable). The guidelines provide
pattern (Van Meter and George 1981; Vandersall 1994, 1998). information about the characteristics of the tank, the coverage
It is known that the viscous nature of the solution during level, strategic charts from the PATADD option, and finally,
periods of extreme and relaxed shear and its elasticity are the safe drop height. For the fixed wing airtankers, this fac-
important rheological properties (Vandersall 1994). tor is the distance below the airtanker at which the retardant
Viscosity is not directly associated with the characteristics begins to fall vertically, and it has lost its forward momentum.
and behavior of fire retardant during aerial delivery; however, This correlation, obtained by filming drop tests, depends on
its quantification may make it possible to relate these prop- the load size and the peak flow rate, and is expressed as:
erties more appropriately to the retardant’s full-scale field
performance (Van Meter and George 1981). The retardant S = 151 + 0.112L + 0.0202P, (1)
cloud produced just after discharge is torn and rendered into
where S = Safe drop height (feet), L = Load size (gal), and
small droplets because of the interaction of external forces
P = Peak flow rate (gal s−1 ).
(shear stress, wind and gravity). Droplet size will depend on
The above equation to estimate the safe drop height is
the rheological properties of the retardant mixture. Larger
expressed as follows using the metric system:
droplets will be affected by external forces to a lesser extent
than smaller, lighter ones (Vandersall 1994, 1998), and will S = 46.025 + 0.9018L + 1.6265P. (2)
result in less dispersion on the ground. Fire retardant mixtures
that contain clay thickening agents (water-like retardant; no In this case, the units of parameters L and P are m3 and
elasticity) exhibit droplet diameters of 2–3 mm, whereas the m3 s−1 , respectively.
individual droplets of guar gum thickened retardant solutions For the constant flow tank and single airtankers, equations
(gum thickened; elasticity) varied from ∼3.5 up to about (1) or (2) do not provide an accurate representation. The safe
5 mm, depending on the amount of gum contained in the drop heights for most of the fixed wing tankers have been
formulation (Andersen and Wong 1978). calculated by Lovellette (2000), who determined this factor
Van Meter and George (1981) carried out laboratory for full and partial drops.
tests to determine the impact of rheological properties on Other programs have been started up by various research
aerial delivery effectiveness.The trials employed a 17.8 m s−1 centers. The most notable programs have been the ACRE
(maximum speed) wind tunnel air stream; there was a spe- project, a recent European project coordinated by CEREN
cial mechanism to apply fire retardant mixture from different (Centre d’Essais et de Recherche de l’Entente) and the pro-
heights (maximum ∼0.762 m) above an array of cups (103 gram that have been carried out by USDA Forest Service over
cups) to simulate aerial delivery of retardant. Specific weight, several years (since the 1960s). Since 1998, Wildland Fire
viscosity, shear stress, surface tension and the droplet size Chemical Systems took care of most of the factors related
distribution were quantified for three thickening agents and to the use of fire retardants, although Aerial Delivery Sys-
for three fire retardant solutions. By correlating the exper- tems (ADS) was recently created for this purpose. This latter
imental data together with other experimental data from group has developed drop guidelines for fixed and rotary
previous tests, an expression was obtained for the dis- wing tankers on the basis of the drop tests summarized in
persal area pattern. The correlation is valid statistically, Table 2 (Johnson and Jordan 2000). ADS has studied the tank
but the different scale in field experiments must be taken and gating systems, flow rates, drop heights and airspeeds.
into account. These characteristics significantly affect the aerial delivery
8 A. Giménez et al.

of fire retardants. The drop guide developed gave practical Heat received by the fuel on the opposite side of the gap
and operational instructions for the most effective coverage is the factor most heavily affecting whether a fire will cross
in every fire situation, and the characteristics of the tank. the fuel break and ignite this fuel (Xanthopoulos and Noussia
These guidelines considered fixed-wing tanks’ ability to con- 2000), and the parameter to evaluate this is the first temper-
trol flow rates, in order to improve retardant delivery, so as to ature peak; the lowest value recorded for which the flames
obtain a great line length for each coverage level. Although crossed the firebreak was 481K (208◦ C).
this type of airtanker provides an effective coverage, not all
fixed-wing aircraft are equipped with it. Environmental impact of fire retardants
The main objective of the ACRE project was to provide
Fire retardant delivery into the environment could have tox-
greater insight into the effectiveness and the methodology
icity effects on organisms. Initially it was thought that fire
for applying fire-retarding chemical additives (Giraud and
retardants would have no adverse effect on the environment,
Picard 2000). Several studies were carried out to obtain a
as their main active ingredients are agricultural fertilizers;
model for aerial drop performance in various aerial delivery
however, even materials of inherent low toxicity can cause
systems. The ACRE project began in July 1998 and was com-
adverse environmental effects when the rate or intensity of
pleted in October 2000. One of the studies included in this
use is sufficiently great (Norris et al. 1978).
project was the mathematical modeling of aerial retardant
Of the different substances that are present in fire retar-
drop (Calogine et al. 2000). To test this model a simula-
dant mixtures, various corrosion inhibitors and ammonia are
tion was run which provided the results of the length and
toxic components. Ammonia comes from the dissociation
the amount of retardant on the ground. These results are
of ammonium salts, which are present in the majority of
yet to be validated with experimental tests. The model has
long-term retardant products.
several disadvantages, as it does not show the ground dis-
The toxicity studies have been classified by: (a) the effect
tribution and is applicable only to Newtonian fluids. More
on water quality and consequently on aquatic organisms;
work will have to be done to improve and extend the model to
(b) toxicity effects on vegetation; and (c) toxicity effects on
non-Newtonian fluids (such as fire retardants). Nevertheless,
humans. There are three works that review the various studies
this was the first attempt to solve fluid mechanics equations
of the impact of fire retardant use on people and ecosystems,
more precisely than the rough approximation of the Bernoulli
by Labat Anderson Inc. (1994), Adams and Simmons (1999)
equation used in PATSIM on modern computers. This
and Kalabokidis (2000). Kalabokidis’ work has many refer-
work focused on modeling the rheological behavior of fire
ences to studies on the effects of fire retardants on people,
retardants.
whereas the work of Adams and Simmons (1999) presents a
Another phase of the ACRE project was centered on small-
review of the environmental impact of long-term fire retar-
scale study of the effective firebreak width to reduce and stop
dants and foams, with less emphasis on their effects on
fire spread in wildland fires. A new wind tunnel was used to
people. Labat Anderson Inc. (1994) deals with the ecological
carry out two different tests: in the first one retardant-treated
and human risks of the use of fire retardants.
fuel was located after the firebreak, and in the second the
For each long-term fire retardant mixture, the suppliers
treated fuel was located before the firebreak. The firebreak
publish the safety information in relation to its use (MSDS,
was simulated by leaving a gap of varying width (10–50 cm)
Material Safety Data Sheet); primarily human health hazards
in the fuel bed (needles of Pinus halepensis). The retardant
and environmental regulation data are specified along with
product used was a 20% (4 : 1) solution of Fire-Trol LC (Liq-
toxicity tests5, chemical and physical properties of the fire
uid Concentrate), which was applied in two coverage levels:
retardant, storage and handling conditions and reactivity.
1.47 gpc (0.6 L m−2 ) and 2.21 gpc (0.9 L m−2 ). In total, 52
Generally, environmental impact on surface fresh water
burnings (with the treated fuel after the firebreak) were per-
caused by retardant delivery is the topic that has been studied
formed under different wind speed conditions (0.9 m s−1 ,
in most detail, whereas fewer studies have been conducted
0.4 m s−1 and without wind) and different load and depth.
to determine the effects on vegetation and the reduction of
There were three thermocouples along the fuel bed. The tem-
species diversity caused by added nitrogen and phosphorus
peratures recorded and the visual evaluation of the reach of
in soils (Adams and Simmons 1999; Larson et al. 1999).
the fuel after the firebreak by the flame was studied. The
results showed a reduction in the minimum required width of
the firebreak when the fuel was treated. The results obtained Toxicity effects on water and aquatic organisms
when the fuel was treated before the firebreak also showed Evidence shows that the main impact that fire suppression
a reduction in the width of the firebreak; however the num- chemicals have on the environment may be through adverse
ber of burnings (seven) was not enough to lead to consistent effects on water quality and subsequently on freshwater fish
conclusions. and other stream biota (Kalabokidis 2000).

5 The toxicity tests are conducted by the manufacturers themselves or by a contracted laboratory.
Long-term forest fire retardants 9

As mentioned above, ammonium salts are one of the toxic release, the dilution of the retardant as it moves downstream
components of some long-term fire retardants for aquatic and, finally, the effect of the retardant concentrations on
organisms when it is dissociated by water to ammonia. On fish mortality. The first model not only takes into account
the other hand the oxidation of ammonia to nitrate or nitrite parameters that affect the retardant drop, but also introduces
is very low under test conditions, and these are considered stream parameters such as the leaf area index, thus taking
low toxicity agents (Buhl and Hamilton 2000). The amount into account interception by streamside vegetation. To esti-
of ammonia in water does not only depend on the concen- mate the downstream dilution of the retardant the dilution
tration of ammonium sulfate or phosphate delivered, but rate of Phos-Chek XA (DAP) in a stream was compared
also on the pH and the temperature of the water, as these with the dilution of fluorescent dye, in different stretches
are parameters that influence the equilibrium reaction of of stream (Norris et al. 1978). Finally, in the third phase of
ammonium-ammonia. the simulation, the mortality of fishes was related to the retar-
Toxicity studies on aquatic organisms relate the results dant concentration. In this phase a new term was introduced,
obtained in the laboratory to the determined amount of fire the tolerance time, which indicates the maximum length of
retardant and ammonia. The data show that ammonia is the time the organism can be exposed to a given concentration
component which has most impact on these organisms under of ammonia with negligible mortality (Norris et al. 1978).
laboratory conditions (Johnson and Sanders 1977; Hamilton Moreover, the model gives the variation in mortality over time
et al. 1996; McDonald et al. 1997; Buhl and Hamilton 1998, by taking into account changes in ammonia concentration for
2000). The objective of these studies was to establish dose– a specific point and time.
response relationships to evaluate the effects of given levels Norris and Webb (1989) studied the effect of the direct
of fire retardant on specific fishes. release of fire retardant (Phos-Chek XA) in four rivers; the
The acute toxicity tests performed in these works compare results corroborated the model developed by Norris et al.
the toxicity levels of both long-term fire retardants and foams. (1978). Changes in the retardant concentration were regis-
Generally, the results show that foams are more toxic for tered up to a distance of 2700 m downstream, and mortality
the species tested. The methodology and the conditions of was not noticed during the first 24 h for the amount and
the trials followed the guidelines provided by ASTM (1989, release rate of the fire retardant applied in this study.
1998), and the groups of organisms studied were freshwater Recent studies showed that the toxicity of long-term fire
fishes, algae and scuds. The tests were carried out in hard and retardants could be heightened in the presence of UV-B radia-
soft water. Table 3 describes the toxicity tests conducted by tion and water (Little and Calfee 2000). These authors studied
some of these authors. the impact of UV-B radiation on the fire retardant product and
Many of these tests used freshwater fishes, Pimephales its effect on Oncorhynchus mykiss and Rana sphenocephala.
promelas, Oncorhynchus mykiss (Hamilton et al. 1996) and The toxicity of fire retardants caused by UV-B radiation is
Oncorhynchus tshawytscha (Buhl and Hamilton 1998), at dif- due to sodium ferrocyanide (a corrosion inhibitor). This prod-
ferent life stages; it was observed that at the eyed egg stage uct, in the presence of natural solar or laboratory-synthetic
they were less sensitive due to their protective cell layers. UV-B and water, can decompose by photoactivation to yield
The results of the toxicity tests showed that fire retardants HCN. This substance is toxic for aquatic organisms when it
applied directly into streams require great dilution to be non- releases free cyanide; so the toxicity of fire retardants contain-
lethal for aquatic organisms; for example, a dilution in the ing sodium ferrocyanide increased significantly when they
range of 100–1750 times was necessary to approach a safe are exposed to UV-B radiation.
concentration for rainbow trout (Gaikowski et al. 1996). It Further work was carried out (Little and Calfee 2002a)
is essential, therefore, to avoid aerial retardant delivery near on the main toxic components of certain retardant products
streams. (total ammonia, un-ionized ammonia, nitrate and nitrite and
Dose–response studies are important because of their sodium ferrocyanide). The inclusion in these studies of other
application in simulation models developed to estimate the factors served to enhance the knowledge of the effects of
effect of direct aerial delivery on water and fish mortality. fire retardants on the environment. These effects included the
Norris et al. (1978) developed an empirical mathematical environmental persistence of these toxic agents (Little and
model using data from drop tests (Northern Forest Fire Lab- Calfee 2002b) and the ability of organisms to avoid exposure
oratory, USDA Forest Service) and on fish mortality (Blahm (Little et al. 2002). These three studies are reviewed in Little
et al. 1974). According to Norris et al. (1978), the fish mortal- and Calfee (2002c) and some data are summarized in Table 3.
ity caused by direct applications into streams (normally due to These studies carried out by Little and Calfee demon-
an accidental application) depends on three variables: deliv- strated the dangers of using retardants that contain YPS
ery characteristics, the specific characteristics of the area, and (sodium ferrocyanide), and observed that photoenhanced
the properties of the stream. cyanide has a very low LC50 : 50 µg L−1 (Little and Calfee
The simulation of the toxicity effects of aerial delivery 2002b).According to these authors, the environmental impact
requires the construction of three models: the aerial retardant of retardants depends on their environmental persistence and
Table 3. Toxicity tests of aquatic organisms
Authors (year) Species Retardants Method Results

Johnson and Oncorhynchus kisutch (fry and fingerling) Fire-Trol 100 (AS) Toxicity test expressed as LC50 , at Fire-Trol mixtures have less toxicity
Sanders (1977) Salmo gairdneri (fry and fingerling) Fire-Trol 931 (APP) 24 and 96 h. APHA (1971); than Phos-Chek mixtures, for these species
Pimephales promelas (fingerling) Phos-Chek 202 A (DAP) EPA (1975); Mount and Brungs (1967)
Lepomis macrochirus (fingerling) Phos-Chek 259 (DAP)
Micropterus salmoides (fingerling)
Gammarus pseudolimnaeus (mature scud)
Hamilton Pimephales promelas (all life stages) Fire-Trol GTS-R (AS) Toxicity test expressed as LC50 , at Generally these five fire retardants
et al. (1996) 24, 48 and 96 h, in soft and hard water. have the same toxic effect on fishes
ASTM (1989), ASTM (1990)
Oncorhynchus mykiss (all life stages) Fire-Trol LCG-R (APP) Determination of the ammonia, nitrite The Fire-Trol mixtures have more toxicity
and nitrate concentration on algae than invertebrates, as was also
observed in growth tests
Daphnia magna Phos-Chek D75-F (MAP–AS)
Hyalella azteca (invertebrate) Two foams
Selenastrum capricornutum (alga)
Buhl and Oncorhynchus tshawytcha Fire-Trol GTS-R Toxicity test expressed as LC50 , The life stage less sensitive is eyed-eggs for
Hamilton (all life stages) at 96 h, in soft and hard all fire retardant products in soft and hard water
(1998) water (ASTM 1989, 1990)
Fire-Trol LCG-R Determination of the ammonia, For all life stages the most toxic products is
nitrite and nitrate concentration Phos-Check WD-881 and the least is Fire-Trol LCG-R
Phos-Chek D75-F
Two foams
Buhl and Oncorhynchus mykiss Fire-Trol LCA-F (APP) Toxicity test expressed as LC50 , at 96 h, There is an important variability of the
Hamilton (all life stages) in soft and hard water. (ASTM 1989) toxicity values of fire retardant evaluated
(2000) Fire-Trol LCM-R (APP) Determination of the ammonia, Foams have more toxicity than long-term retardants.
nitrite and nitrate concentration The greatest mortality was in the first 24 h
Phos-Chek 259F (DAP)
Five foams and LAS and SDS
(anionic surfactants)
Little and Pimephales promelas Fire-Trol GTS-R (with and Percentage of fish mortality in a field 100% of mortality occurred in sunny conditions (at
Calfee (30–60 days after without sodium ferrocyanide) experimental stream. Determination of 128 mg L−1 of GTS-R with YPS), but no mortality
(2002a) yolk absorption) Phos-Chek D75-R (MAP–AS) the total and unionized ammonia, nitrate, occurred in cloudy conditions. 100% of survival
and WADA cyanide concentration in tests with GTS-R without YPS and D75-R
Little and Pimephales promelas Fire-Trol GTS-R (with and Toxicity test (LC50 at 96 h, ASTM Low LC50 values showed enhanced toxicity
Calfee (60–90 days without sodium ferrocyanide) 1998), under different light treatments. induced by UV photoactivation. Environmental
(2002b) post-hatch) Phos-Chek D75-R (not containing Determination of the ammonia, nitrate persistence of retardants depended on the type of
sodium ferrocyanide) and WAD cyanide concentration and the substrate; persistence was lower when percentage
persistence of retardant when weathered in organic matter was higher. Dilute solutions
different substrates and in diluted solutions were not toxic after 7 days of weathering
Little et al. Oncorhynchus mykiss Fire-Trol GTS-R (with and Avoidance/attractance behaviour of fish Rainbow trout avoided at concentrations 10% of LC50
(2002) (90 days post-hatch) without sodium ferrocyanide or using a counter-current avoidance in water treated with GTS-R and less of 1% with D-75-R.
ferrous oxide colorant) (DeLonay et al. 1996) Fish did not avoid YPS when this was tested
Phos-Chek D75-R (not containing alone. Salinity of the test water might be the sensor
sodium ferrocyanide) that induced avoidance response.
A WAD: weak acid dissociable.
Long-term forest fire retardants 11

their application rate. The first aspect was evaluated by field megalura and Erodium botrys. The area was divided into dif-
tests in two different experiments. First, the retardants Fire- ferent types of plots: unburned plots with DAP, burned plots
Trol GTS-R (AS) and Phos-Chek D75-R (MAP–AS) were with DAP, burned plots without DAP, and unburned plots
watered for several days (up to 45), on different substrates without DAP (these last two types of plots being the control
ranging from non-porous polypropylene surfaces to forest area). During the first year, both area treated with retardant
soils with both low and high organic matter content. Second, yielded 12 000 kg ha−1 , twice as much as the unburned con-
field tests of the persistence of diluted aqueous solutions pre- trol area. In the second year this difference in the yield was not
pared at LC50 were carried out on fish (Table 3) and added maintained, the highest yield being 4171 kg ha−1 , which was
to substrates. As a result, they showed that the soil type and, produced by the treated burned plots, whereas the unburned
above all, the cation exchange capacity (CEC), which deter- plots without DAP had the lowest yield, 2076 kg ha−1 . The
mines the ability of soils to exchange ions with the substances unburned control plots had a higher herbage yield than the
in contact with the soil in such a way that leaching is reduced, unburned, treated one. According to the results of the study,
was likely to be a significant variable in the persistence of the the use of fire retardants increases forage yield in the first
retardants. year after a fire, but causes a drop in native clover production
The behavior of fish was studied by Little et al. (2002). The for 2 years. However, in order to determine the true effect of
results showed an avoidance response to low concentrations the retardant on these plants over a long period of time, long-
of the retardants tested6 (Table 3). This was definitely not in term studies of at least 10 years would be needed. Although
order to discard the hazard of using fire retardant, since many these results might be attributed to the fact that retardants
factors could inhibit this behavior (chemical substances, are fertilizers, this work allowed better understanding of the
temperature of water or pH values). This avoidance behavior role of these products in species richness and the growth of
could affect the habitat negatively, altering aquatic ecosys- vegetation.
tems and causing significant biological and economic injury The most specific study was carried out by Bradstock et al.
to natural resources (Little et al. 2002). This study also tested (1987), and described the toxic effects of a solution of ammo-
a solution of YPS with UV-B, which the fish did not avoid. nium sulfate and Kelzan (an algae-based thickening agent)
The increased toxicity of fire retardants in the presence on a particular vegetation type (Eucalyptus forest). The tests
of YPS has been demonstrated, mainly in the work of Little were conducted in the field and in the greenhouse to deter-
and Calfee (2002a). The absence of mortality during the tests mine the effects of each component of the fire retardant on
with the formulation that did not contain YPS is evidence of leaves and to ascertain to what extent rainfall can reduce
the role of this corrosion inhibitor. On the other hand, the ammonium sulfate damage. The results showed that ammo-
absence of mortality under cloudy conditions while testing nium sulfate is the agent that damages and kills leaves. In the
the formulation with YPS proves that a minimum level is field it was also determined that there had been changes in the
necessary for the release of cyanide from the YPS to occur. coverage level of the vegetation and the number of species,
Finally, other fire-related substances such as ash, which, at but the changes observed over a year were assumed to be
low concentrations clogs gill surfaces and leads to respiratory natural changes (Bradstock et al. 1987).
failure, may have a higher toxicity than the fire retardants Larson et al. (1999) studied the acute toxicity of a long-
themselves. In comparison with ashes, the hazard posed by term fire retardant (Phos-Chek G-75 (MAP–AS)) and foam
fire retardants may be negligible in view of large amounts on bush vegetation in two different habitat types (riparian
of ash that are likely to enter aquatic systems from rainwater and upland), in burned and unburned areas. The parameters
runoff (Little and Calfee 2002b). measured were growth, resprouting, flowering, and incidence
of galling insects mainly on Chrysothamnus viscidif lorus and
Artemisia tridentata, which were not affected by the chemical
Toxicity effects on vegetation product.
When fire retardant is dropped in excess, these chemical prod- Community characteristics (species richness, evenness
ucts can enter plant organisms and soil and have toxic effects and diversity) and the number of stems m−2 in woody and
on the vegetation (Bradstock et al. 1987). Up to now, few herbaceous plants were also measured. The majority of these
studies have been carried out to determine the impact on characteristics showed no response to the chemicals over the
the environment, and each of them deals with different plant course of the application (Larson et al. 1999). The lack of
species and employs different methods. a response in growth during the treatment seemed to dis-
Larson and Duncan (1982) studied the vegetation growth agree with the results obtained by Larson and Duncan (1982).
of a burned area where fire retardant salt (DAP) was air- However, this difference was attributed to the weather, specif-
dropped during extinction operations. The main plant species ically a lack of precipitation. The relatively short duration
present in the plot were Bromus mollis, B. diandrus, Vulpia of the study was a limiting factor in the determination of

6 Fire-Trol GTS-R with and without sodium ferrocyanide or ferrous oxide colorant and Phos-Chek D75-R did not contain sodium ferrocyanide.
12 A. Giménez et al.

the real effect of the application of fire retardants on the gave a detailed account of the amount of time the effect
vegetation. on combustion is maintained in relation to the amount of
water, thickening agent and retardant applied. Blakely (1985)
Toxicity effects on humans corroborated the fact that using a retardant is an improvement
on plain water, but no further studies to determine the mecha-
The majority of the work done to determine the impact of
nism that extinguishes combustion recovery, so as to improve
retardant use on people is reported by Labat Anderson Inc.
the effectiveness of fire retardant use, were carried out.
(1994), where hazard analysis was employed to determine an
Simulation models of aerial delivery of fire retardant were
acceptable dose level for the various commercial fire retar-
carried out to obtain distribution patterns providing a descrip-
dants. This dose level was compared to the estimated doses
tion of several coverage levels. The effective coverage for
to which fire-fighters were exposed. The results of the com-
other fuel types or models linked retardant coverage levels
parison classified the hazard of the fire retardants approved
to effectiveness are defined using the range of NFDRS; even
by the USDA Forest Service as negligible. The risk was con-
so the adaptations do not provide the best basis for aerial
sidered to be significant only when the fire retardant comes
drop guidelines with a view to obtaining a known effective
into direct contact with people. Some cases of skin and eye
coverage for other fuel models.
irritation have been detected.
According to Gale and Mauk (1983), 70% of the aerial
As discussed above, corrosion inhibitors are considered
retardant delivered is by way of indirect attack.Although most
toxic substances; the toxicity test conducted on animals (rats)
of the effectiveness studies were made in indirect attack, the
has determined the lethal dose of fire retardant mixtures. For
results obtained were not evaluated with the purpose of giv-
a fire retardant mixture that contains sodium dichromate7 as a
ing operational and technical data for improving chemical
corrosion inhibitor, the lethal dose considered is 3 L of retar-
firebreaks building; only one study was found about building
dant mixture for a man weighing 90 kg (USA Department of
of firebreaks (Xanthopoulos and Noussia 2000). The results
Health, Education and Welfare Toxic Substance List).
obtained in the laboratory were not transferred to full scale,
which would have provided guidelines for an effective fire-
Conclusions break. In that case the firebreak was simulated by leaving a
This bibliographic analysis has shown that works on long- gap rather than considering aerial delivery of fire retardant.
term forest fire retardants encompass a significant variety of This bibliographic analysis shows that there are no specific
parameters and this fact means that the results obtained from studies on the building of chemical firebreaks even though
these studies were different according to the factor evaluated. in the United States the aerial delivery of fire retardant is
On the other hand, if one considers the number of possible generally for indirect attack.
variables, the works can be considered quite consistent. Each Another issue that must be taken into account with regard
parameter has a different influence on the effectiveness of to the use of fire retardants is their environmental impact. The
long-term forest fire retardants. toxic effects of fire retardants on streams and aquatic organ-
The various methodologies and the parameters to be eval- isms are considered the most significant, and for this reason
uated to determine the quality of a fire retardant (chemical there are a significant number of toxicity studies in compar-
and physical properties) are known, and these procedures are ison with works on the toxic effect on vegetation (Table 1).
established in various internal specifications (USDA Forest The amount of fire retardant and the place where it is deliv-
Service). However, there are differences between the param- ered are the two main parameters determining the degree of
eters evaluated in studies on aerial fire retardant delivery environmental impact. By taking these two factors into con-
due to the difficulty of controlling some of them, and some- sideration it is possible to reduce the fish mortality caused
times external considerations may override the experimental by fire retardants. The most serious environmental impact of
measures affecting the results. fire retardant use can be mitigated by taking preventive action.
The P2 O5 available in the DAP or MAP is known to be For example, the USDA Forest Service recommends avoid-
the substance that makes these retardants more effective than ing aerial delivery of retardant near streams as a performance
AS mixtures on combustion, particularly glowing combus- guideline.
tion. The parameters to be studied in order to evaluate the Lastly, it should be emphasized that most of the envi-
effectiveness of fire retardants during fuel bed burning are ronmental impact and toxic effect studies on long-term fire
also known. Most studies have served to determine the effec- retardants have appeared over the last 10 years (Table 1),
tiveness of retardants during indirect attacks, because this is whereas studies dealing with the effectiveness and applica-
their primary use. The works of Blakely (1985, 1990) con- tion of fire retardants are older. Nowadays, there is not so
tributed a new evaluation methodology, during direct attack, much debate, and few studies aimed at determining the fac-
including new parameters for evaluation. These two papers tors that affect aerial retardant delivery or in studies providing

7 The use of this corrosion inhibitor was discontinued in the early 1970s, and it was never in most retardants.
Long-term forest fire retardants 13

an improvement in their use (Table 1) (when, where and (Oncorhynchus tshawytscha). Environmental Toxicology and Chem-
how to apply retardant) of forest fire retardants and their istry 17(8), 1589–1599.
effectiveness in the extinction of forest fires. Buhl KJ, Hamilton SJ (2000) Acute toxicity of fire-control chem-
icals, nitrogenous chemicals, and surfactants to Rainbow Trout.
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