Series ONS SET-1

·¤æðÇU Ù´.
Code No. 56/1/C
ÚUæðÜ Ù´. ÂÚUèÿææÍèü ·¤æðÇU ·¤æ𠩞æÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU
Roll No. ÂÚU ¥ßàØ çܹð´Ð
Candidates must write the Code on the
title page of the answer-book.

· ·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-˜æ ×ð´ ×éçÎýÌ ÂëcÆU 16 ãñ´Ð
· ÂýàÙ-˜æ ×ð´ ÎæçãÙð ãæÍ ·¤è ¥æðÚU çΰ »° ·¤æðÇU ِÕÚU ·¤æð ÀUæ˜æ ©žæÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU ÂÚU çܹð´Ð
· ·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-˜æ ×ð´ 26 ÂýàÙ ãñ´Ð
· ·ë¤ÂØæ ÂýàÙ ·¤æ ©žæÚU çܹÙæ àæéM¤ ·¤ÚUÙð âð ÂãÜð, ÂýàÙ ·¤æ ·ý¤×æ´·¤ ¥ßàØ çܹð´Ð
· §â ÂýàÙ-Â˜æ ·¤æð ÂɸÙð ·ð¤ çÜ° 15 ç×ÙÅU ·¤æ â×Ø çÎØæ »Øæ ãñÐ ÂýàÙ-Â˜æ ·¤æ çßÌÚU‡æ Âêßæüq ×ð´
10.15 ÕÁð ç·¤Øæ Áæ°»æÐ 10.15 ÕÁð âð 10.30 ÕÁð Ì·¤ ÀUæ˜æ ·ð¤ßÜ ÂýàÙ-Â˜æ ·¤æð Âɸð´»ð ¥æñÚU §â
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· Please check that this question paper contains 16 printed pages.
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on the title page of the answer-book by the candidate.
· Please check that this question paper contains 26 questions.
· Please write down the Serial Number of the question before attempting
it.
· 15 minute time has been allotted to read this question paper. The question paper
will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will
read the question paper only and will not write any answer on the answer-book
during this period.

ÚUâæØÙ çߙææÙ (âñhæç‹Ì·¤)

CHEMISTRY (Theory)

çÙÏæüçÚUÌ â×Ø Ñ 3 ƒæ‡ÅðU ¥çÏ·¤Ì× ¥´·¤ Ñ 70

Time allowed : 3 hours Maximum Marks : 70

56/1/C 1 P.T.O.
âæ×æ‹Ø çÙÎðüàæ Ñ

(i) âÖè ÂýàÙ ¥çÙßæØü ãñ´Ð

(ii) Âýà٠ⴁØæ 1 âð 5 Ì·¤ ¥çÌ Üƒæé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 1 ¥´·¤ ãñÐ

(iii) Âýà٠ⴁØæ 6 âð 10 Ì·¤ ܃æé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 2 ¥´·¤ ãñ´Ð

(iv) Âýà٠ⴁØæ 11 âð 22 Ì·¤ Öè ܃æé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 3 ¥´·¤ ãñ´Ð

(v) Âýà٠ⴁØæ 23 ×êËØæÏæçÚUÌ ÂýàÙ ãñ ¥æñÚU §â·ð¤ çÜ° 4 ¥´·¤ ãñ´Ð

(vi) Âýà٠ⴁØæ 24 âð 26 Ì·¤ Îèƒæü-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 5 ¥´·¤ ãñ´Ð

(vii) ØçÎ ¥æßàØ·¤Ìæ ãæð, Ìæð Üæò» ÅðUÕÜæð´ ·¤æ ÂýØæð» ·¤Úð´UÐ ·ñ¤Ë·é¤ÜðÅUÚUæ𴠷𤠩ÂØæð» ·¤è ¥Ùé×çÌ Ùãè´ ãñÐ

General Instructions :

(i) All questions are compulsory.

(ii) Questions number 1 to 5 are very short answer questions and carry 1 mark each.

(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.

(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.

(v) Question number 23 is a value based question and carry 4 marks.

(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.

(vii) Use log tables, if necessary. Use of calculators is not allowed.

56/1/C 2
1. Øæñç»·¤ C4H9Br ·ð¤ °·¤ °ðâð â×æßØßè ·¤è â´ÚU¿Ùæ çÜç¹° Áæð SN1 ¥çÖç·ý¤Øæ ·ð¤ ÂýçÌ 1

âßæüçÏ·¤ ç·ý¤ØæàæèÜ ãñÐ

Write the structure of an isomer of compound C4H9Br which is most reactive
towards SN1 reaction.

2. Pb(NO3)2 ·¤æð »×ü ·¤ÚUÙð ÂÚU °·¤ ÖêÚðU Ú´U» ·¤è »ñâ çÙ·¤ÜÌè ãñ çÁâ·¤æð Æ´UÇUæ ·¤ÚUÙð ÂÚU çmÜ·¤è·¤ÚU‡æ 1
ãæð ÁæÌæ ãñÐ »ñâ ·¤è Âã¿æÙ ·¤èçÁ°Ð
Pb(NO3)2 on heating gives a brown gas which undergoes dimerization on
cooling ? Identify the gas.

3. °·¤ ¥æ‡æçß·¤ ÆUæðâ ¥æñÚU °·¤ ¥æØçÙ·¤ ÆUæð⠷𤠩ÎæãÚU‡æ ÎèçÁ°Ð 1

Give an example each of a molecular solid and an ionic solid.

4. çΰ »Øð Øæñç»·¤ ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ× ÎèçÁ° Ñ 1

Write the IUPAC name of the given compound :

5. ·¤æðÜæ§ÇUè âæòÜ ·¤è çSÍÚUÌæ ·¤æ €Øæ ·¤æÚU‡æ ãñ? 1

What is the reason for the stability of colloidal sols ?

56/1/C 3 P.T.O.
6. (i) â×æÙ Ìæ ÂÚU »ñâ (A) ¥Âðÿææ·ë¤Ì »ñâ (B) ·ð¤ ÁÜ ×ð´ ¥çÏ·¤ ƒæéÜÙàæèÜ ãñÐ §Ù ÎæðÙæð´ 2

»ñâæð´ ×ð´ âð 緤ⷤæ KH (ãðÙÚUè çSÍÚUæ´·¤) ©“æÌÚU ãñ ¥æñÚU €Øæð´?

(ii) °·¤ ¥ÙæÎàæü çßÜØÙ ×ð´ ç·¤â Âý·¤æÚU ·¤æ çß¿ÜÙ, ¥çÏ·¤Ì× €ßÍÙæ´·¤è °ðçÁ¥æðÅþUæ ·ð¤
çÙ×æü‡æ ·¤æð ÎàææüÌæ ãñ?
(i) Gas (A) is more soluble in water than Gas (B) at the same temperature.
Which one of the two gases will have the higher value of KH (Henry’s
constant) and why ?

(ii) In non-ideal solution, what type of deviation shows the formation of

maximum boiling azeotropes ?

7. çِ٠·¤è â´ÚU¿ÙæØð´ çÜç¹° Ñ 2

(i) BrF3 (ii) XeF4

¥Íßæ

€Øæ ãæðÌæ ãñ ÁÕ Ñ

(i) Fe31 Üß‡æ ·ð¤ ÁÜèØ çßÜØÙ ×ð´ âð SO2 ·¤æð ÂýßæçãÌ ç·¤Øæ ÁæÌæ ãñ?

(ii) XeF4 ç·ý¤Øæ ·¤ÚUÌæ ãñ SbF5 ·ð¤ âæÍ?

Write the structures of the following :

(i) BrF3 (ii) XeF4

OR

What happens when :

(i) SO2 gas is passed through an aqueous solution Fe31 salt ?

(ii) XeF4 reacts with SbF5 ?

56/1/C 4
8. ÁÕ °·¤ ©Ââã â´ØæðÁ·¤ Øæñç»·¤ CoCl3.6NH3 ·¤æð AgNO3 ·ð¤ âæÍ ç×ÜæØæ ÁæÌæ ãñ Ìæð 2

Øæñç»·¤ ·ð¤ °·¤ ×æðÜ ·ð¤ âæÍ AgCl ·ð¤ ÌèÙ ×æðÜ ¥ßÿæðçÂÌ ãæðÌð ãñ´Ð çÜç¹Øð Ñ

(i) ·¤æòŒÜð€â ·¤æ â´ÚU¿Ùæ âê˜æ

(ii) ·¤æòŒÜð€â ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ×

When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of

AgCl are precipitated per mole of the compound. Write

(i) Structural formula of the complex

(ii) IUPAC name of the complex

9. °·¤ ¥çÖç·ý¤Øæ Ñ H2 1 Cl 2 

→ 2HCl
hv
·ð¤ çÜØð 2

ÎÚU5k

(i) §â ¥çÖç·ý¤Øæ ·¤è ·¤æðçÅU ¥æñÚU ¥æ‡æçß·¤Ìæ çÜç¹°

(ii) k ·¤è ØêçÙÅU çÜç¹°Ð

hv
For a reaction : H2 1 Cl 2  → 2HCl

Rate5k

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

56/1/C 5 P.T.O.
10. çِ٠¥çÖç·ý¤Øæ¥æð´ âð â´Õç‹ÏÌ ÚUæâæØçÙ·¤ â×è·¤ÚU‡ææð´ ·¤æð çÜç¹° Ñ 2

(i) ãæȤ×ñÙ-Õýæð×ð×æ§ÇU ¥ßÙ×ÙÙ ¥çÖç·ý¤Øæ

(ii) ·¤æçÕüÜñ×èÙ ¥çÖç·ý¤Øæ
Write the chemical equations involved in the following reactions :
(i) Hoffmann-bromamide degradation reaction
(ii) Carbylamine reaction

11. 500pm ·¤æðÚU ܐÕæ§ü ·ð¤ âæÍ °·¤ Ìˆß b.c.c. ÁæÜ·¤ ×ð´ ç·ý¤cÅUçÜÌ ãæðÌæ ãñÐ Ìˆß ·¤æ ƒæÙˆß 3
7.5g cm23 ãñ´Ð Ìˆß ·ð¤ 300 g ×ð´ ç·¤ÌÙð ÂÚU×æ‡æé ßÌü×æÙ ãæðÌð ãñ´?
An element crystallizes in a b.c.c. lattice with cell edge of 500pm. The density
of the element is 7.5g cm23. How many atoms are present in 300 g of the
element ?

12. ÂýÍ× ·¤æðçÅU ·¤è ©c×èØ ç߃æÅUÙ ¥çÖç·ý¤Øæ ·ð¤ çÜØð çِ٠¥æ¡·¤Ç¸ð ÂæØð »Øð Ñ 3
C2H5Cl(g) ® C2H4(g) 1 HCl(g)

Time/sec ÅUæðÅUÜ ÎæÕ/atm

0 0.30
300 0.50

ÎÚU çSÍÚUæ´·¤ ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð

(çÎØæ »Øæ Ñ log 250.301, log 350.4771, log 450.6021)
For the first order thermal decomposition reaction, the following data were
obtained :
C2H5Cl(g) ® C2H4(g) 1 HCl(g)
Time / sec Total pressure / atm
0 0.30
300 0.50
Calculate the rate constant
(Given : log 250.301, log 350.4771, log 450.6021)

56/1/C 6
13. çِ٠ÂÎæð´ ·¤æð ÂçÚUÖæçáÌ ·¤èçÁ° Ñ 3

(i) ÜæØæðçȤçÜ·¤ ·¤æðÜæ§ÇU

(ii) ÁèÅUæ çßÖß
(iii) â´»éç‡æÌ ·¤æðÜæ§ÇU
Define the following terms :
(i) Lyophilic colloid
(ii) Zeta potential
(iii) Associated colloids

14. (i) çÙ·¤Ü ·ð¤ ÂçÚUc·¤ÚU‡æ ·¤è çßçÏ ·¤æ Ùæ× ÎèçÁ°Ð 3

(ii) °ðÜé×èçÙØ× ·ð¤ çÙc·¤áü‡æ ×ð´ ·ý¤æØæðÜæ§ÅU ·¤è €Øæ Öêç×·¤æ ãæðÌè ãñ?
(iii) ¥æØÚUÙ ¥æ€âæ§ÇU âð ¥æØÚUÙ ·ð¤ çÙc·¤áü‡æ ×ð´ ¿êÙð ·ð¤ ˆÍÚU ·¤è €Øæ Öêç×·¤æ ãæðÌè ãñ?
(i) Name the method of refining of nickel
(ii) What is the role of cryolite in the extraction of aluminium ?
(iii) What is the role of limestone in the extraction of iron from its
oxides ?

15. ÁÕ MgSO4 (M5120 g mol21) ·ð¤ 4 g ·¤æð 100 g ÁÜ ×𴠃æéÜæØæ ÁæÌæ ãñ ÌÕ ÂýæŒÌ 3
çßÜØÙ ·ð¤ €ßÍÙæ´·¤ ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°, Øã ×æÙ·¤ÚU ¿çÜ° ç·¤ MgSO4 ·¤æ Âê‡æüÌÑ
¥æØÙè·¤ÚU‡æ ãæð ÁæÌæ ãñÐ
(Kb ÁÜ ·ð¤ çÜØð 50.52 K kg mol21)

Calculate the boiling point of solution when 4 g of MgSO4 (M5120 g mol21)

was dissolved in 100 g of water, assuming MgSO4 undergoes complete
ionization.
(Kb for water50.52 K kg mol21)

56/1/C 7 P.T.O.
16. ·¤æÚU‡æ ÎèçÁ° Ñ 3

(i) SO2 °·¤ ¥Â¿æØ·¤ ãñ ÁÕç·¤ TeO2 °·¤ ©Â¿æØ·¤ ãñÐ

(ii) Ùæ§ÅþUæðÁÙ Âð‹ÅUæãñÜæ§ÇU Ùãè´ ÕÙæÌæ ãñÐ

(iii) I2 ·¤è ¥Âðÿææ ICl ¥çÏ·¤ ç·ý¤ØæàæèÜ ãñÐ

Give reasons :

(i) SO2 is reducing while TeO2 is an oxidizing agent.

(ii) Nitrogen does not form pentahalide.

(iii) ICl is more reactive than I2.

17. çِ٠¥çÖç·ý¤Øæ¥æð´ ×ð´ ÂýˆØð·¤ ·¤æ ¥´çÌ× ©ˆÂæÎ çÜç¹° Ñ 3

(a)

(b)

(i) CHCl 1 aq.NaOH

(c) C6H52OH
3
1 →
(ii) H

56/1/C 8
 Write the final product (s) in each of the following reactions :

(a)

(b)

(i) CHCl 1 aq.NaOH

(c) C6H52OH
3
1 →
(ii) H

18. çِ٠·ð¤ ·¤æÚU‡ææð´ ·¤æð ÎèçÁ° Ñ 3

(i) °ðçÙÜèÙ Èý¤æ§ÇðUÜ-·ñý¤ÅU ¥çÖç·ý¤Øæ Ùãè´ ÎðÌæ ãñÐ

(ii) ÁÜèØ çßÜØÙ ×ð´ (CH3)3 N ·¤è ¥Âðÿææ (CH3)2 NH ¥çÏ·¤ ÿææÚUèØ ãñÐ

(iii) ÅUçàæüØÚUè °×èÙæð´ ·¤è ¥Âðÿææ Âýæ§×ÚUè °ð×èÙæ𴠷𤠀ßÍÙæ´·¤ ©‘¿ÌÚU ãæðÌð ãñ´Ð

Give reasons for the following :

(i) Aniline does not undergo Friedal-Crafts reaction.

(ii) (CH3)2 NH is more basic than (CH3)3 N in an aqueous solution.

(iii) Primary amines have higher boiling point than tertiary amines.

56/1/C 9 P.T.O.
19. ¥æ ·ñ¤âð M¤Âæ´ÌçÚUÌ ·¤Úð´U»ð Ñ 3
(i) €ÜæðÚUæðÕð‹ÁèÙ ·¤æð Õæ§üÈð¤çÙÜ ×ð´
(ii) ÂýæðÂèÙ ·¤æð 1- ¥æØÇUæðÂýæðÂðÙ ×ð´
(iii) 2-Õýæð×æðŽØéÅðUÙ ·¤æð ŽØéÅU-2-§üÙ ×ð´
¥Íßæ
çِ٠×ð´ ×éØ ©ˆÂæÎæð´ ·¤æð çÜç¹° Ñ

(i)

(ii)

(iii)
How do you convert :
(i) Chlorobenzene to biphenyl
(ii) Propene to 1-iodopropane
(iii) 2-bromobutane to but-2-ene
OR
Write the major product(s) in the following :

(i)

(ii)

(iii)

56/1/C 10
20. (i) ÚUÕÚU ·ð¤ ßË·¤Ùè·¤ÚU‡æ ×ð´ âËȤÚU ·¤è €Øæ Öêç×·¤æ ãæðÌè ãñ? 3

(ii) çِ٠ÕãéÜ·¤ ×ð´ °·¤Ü·¤æð´ ·¤è Âã¿æÙ ·¤èçÁ° Ñ

(iii) ©Ù·ð¤ ¥´Ì¥æü‡æçß·¤ ÕÜ ·ð¤ ¥æÏæÚU ÂÚU çِ٠ÕãéÜ·¤æð´ ·¤æð ÃØßçSÍÌ ·¤èçÁ° Ñ

ÅðUÚUèÜèÙ, ÂæÜèÍèÙ, Ùè¥æðÂýèÙ

(i) What is the role of Sulphur in the vulcanization of rubber ?

(ii) Identify the monomers in the following polymer :

(iii) Arrange the following polymers in the increasing order of their

intermolecular forces :

Terylene, Polythene, Neoprene

21. (i) SÅUæ¿ü ¥æñÚU âðÜéÜæðâ ·ð¤ Õè¿ ·ð¤ â´ÚU¿Ùæˆ×·¤ ¥´ÌÚU ·¤æð çÜç¹°Ð 3

(ii) ‹Øéç€Ü·¤ ¥Ü ×ð´ ç·¤â Âý·¤æÚU ·¤æ çÜ´·ð¤Á ßÌü×æÙ ãæðÌæ ãñ?

(iii) ÚðUàæðÎæÚU ÂýæðÅUèÙ ¥æñÚU »æðÜæ·¤æÚU ÂýæðÅUèÙ ·ð¤ çÜØð ÂýˆØð·¤ ·ð¤ °·¤ °·¤ ©ÎæãÚU‡æ ÎèçÁ°Ð
(i) Write the structural difference between starch and cellulose.

(ii) What type of linkage is present in Nucleic acids ?

(iii) Give one example each for fibrous protein and globular protein.

56/1/C 11 P.T.O.
22. (a) ·¤æòŒÜð€â [Fe(H2O)6]31 ·ð¤ çÜ° â´·¤ÚU‡æ, ¿éÕ·¤èØ ÃØßãæÚU ¥æñÚU çSÂÙ çÜç¹°Ð 3

(Â.â´. Fe526)
(b) ·¤æòŒÜð€â [Pt(en)2Cl2]21 ·¤æ °·¤ ’Øæðç×ÌèØ â×æßØßè çÜç¹° Áæð Âý·¤æàæ·¤èØ çÙçc·ý¤Ø
ãæðÐ
(a) For the complex [Fe(H 2O)6 ]31, write the hybridization, magnetic
character and spin of the complex. (At. number : Fe526)
(b) Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]21 which
is optically inactive.

23. ¥ˆØ´Ì ÃØSÌÌæ ·ð¤ ·¤æÚU‡æ Ÿæè×æÙ÷ çâ´ã ÎæðÂãÚU ×ð´ âǸæ ãé¥æ ¹æÙæ ¹æÙð Ü»ð ¥æñÚU ÏèÚðU ÏèÚðU 4
¥çÙØç×Ì M¤Â âð °ðâð ãè ¹æÙ ·¤æ ¥æÎÌ ÂǸ »§üÐ °·¤ çÎÙ ©‹ãð´ ÀUæÌè ×ð´ ÁæðÚU ·¤æ ÎÎü ãé¥æ
¥æñÚU ßð ç»ÚU ÂǸðÐ ç×.çâ´ã ·ð¤ °·¤ ÙÁÎè·¤è ç×˜æ Ÿæè. ¹‹Ùæ Áè ©‹ãð´ ÇUæò€ÅUÚ ·ð¤ Âæâ Üð »ØðÐ
ÇUæ€ÅUUÚ Ùð ©Ù·¤è Áæ¡¿ ·¤è ¥æñÚU ÂæØæ ç·¤ ç×. çâ´ã °ðâèÇUèÅUè âð ÂèçÇ¸Ì ãñ´ ç×.¹‹Ùæ Ù𠩋ã𴠃æÚU
·¤è ÕÙè ¿èÁð´ ¹æÙð ·¤è ¥æñÚU âæÍ ãè Øæð»æâÙ Øæð» ¥æñÚU àææÚUèçÚU·¤ ÃØæØæ× ·¤ÚUÙð ·¤è âÜæã
ÎèÐ ¥ÂÙð ç×˜æ ·¤è âÜæ㠷𤠥ÙéâæÚU ç×.çâ´ã ·¤æ× ·¤ÚUÙð Ü»ð ¥æñÚU ÍæðǸð ãè çÎÙ ×ð´ ÕðãÌÚU
×ãâêâ ·¤ÚUÙð Ü»ðÐ
©ÂÚUæð€Ì ·¤æð Âɸ·¤ÚU çِ٠·ð¤ ©žæÚU ÎèçÁ° Ñ
(i) ç×.¹‹Ùæ ×ð´ ç·¤Ù ×êËØæð´ (·¤× âð ·¤× Îæð) ·¤æð ÎàææüØæ?
(ii) °ð‹ÅUæ°çâÇU €Øæ ãñ? °·¤ ©ÎæãÚU‡æ ÎèçÁ°Ð
(iii) €Øæ °ð‹ÅUæ°çâÇU ¥çÏ·¤ çÎÙ Ì·¤ ÜðÙæ ¿æçã°? ·¤æÚU‡æ ÕÌÜ槰Ð
Due to hectic and busy schedule, Mr. Singh started taking junk food in the
lunch break and slowly became habitual of eating food irregularly to excel in
his field. One day during meeting he felt severe chest pain and fell down.
Mr. Khanna, a close friend of Mr. Singh. took him to doctor immediately.
The doctor diagnosed that Mr. Singh was suffering from acidity and prescribed
some medicines. Mr. Khanna advised him to eat home made food and change
his lifestyle by doing yoga, meditation and some physical exercise. Mr. Singh
followed his friend’s advice and after few days he started feeling better.
After reading the above passage, answer the following :
(i) What are the values (at least two) displayed by Mr. Khanna ?
(ii) What are antacids ? Give one example.
(iii) Would it be advisable to take antacids for a long period of time ? Give
reason.

56/1/C 12
24. (a) çِ٠¥çÖç·ý¤Øæ ·ð¤ çÜØð 298K ÂÚU E8cell ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ° Ñ 5

2Al(s)1 3Cu21(0.01M) ® 2Al31 (0.01M) 1 3Cu(s)

çÎØæ »Øæ : Ecell 5 1.98 V

(b) A ¥æñÚU B ·ð¤ E8 ×æÙæð´

·¤æ ©ÂØæð» ·¤ÚUÌð ·¤è Üæðãð ÂÚU Á´» Ü»Ùð âð Õ¿æÙð ·ð¤ çÜ° 緤ⷤæ
ÜðÂÙ âãè ãæð»æ ¥æñÚU €Øæð´? [E8(Fe21/Fe)520.44V]
çÎØæ »Øæ Ñ E8(A21/A)522.37V : E8 (B21/B)520.14V

¥Íßæ
(a) CH3COOH ·ð¤ 0.001 mol L21 çßÜØÙ ·¤è ¿æÜ·¤Ìæ 3.90531025 S cm21 ãñÐ
§â·¤è ×æðÜÚU ¿æÜ·¤Ìæ ¥æñÚU ç߃æÅUÙ ÇUè»ýè (a) ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð
çÎØæ »Øæ l0 (H1)5349.6 S cm2 mol21 ¥æñÚU l0 (CH3COO2)540.9 S cm2 mol21
(b) çßléÌ÷ÚUæâæØçÙ·¤ âðÜ ·¤æð ÂçÚUÖæçáÌ ·¤èçÁ°Ð €Øæ ãæðÌæ ãñ ÁÕ çßléÌ ÚUæâæØçÙ·¤ âðÜ
·ð¤ E8cell âð Ü»æØæ »Øæ Õæs çßÖß ¥çÏ·¤ÌÚU ãæð ÁæÌæ ãñ?
(a) Calculate E8cell for the following reaction at 298K :

2Al(s)1 3Cu21(0.01M) ® 2Al31 (0.01M) 1 3Cu(s)

Given : Ecell 5 1.98 V

(b) Using the E8 values of A and B, predict which is better for coating the
surface of iron [E8(Fe21/Fe)520.44V] to prevent corrosion and why ?

Given : E8(A21/A)522.37V : E8 (B21/B)520.14V

OR

(a) The conductivity of 0.001 mol L 21 solution of CH 3 COOH is

3.90531025 S cm21. Calculate its molar conductivity and degree of
dissociation (a).

Given l0 (H1)5349.6 S cm2 mol21 and l0 (CH3COO2)540.9 S cm2 mol21

(b) Define electrochemical cell. What happens if external potential applied

becomes greater than E8cell of electrochemical cell ?

56/1/C 13 P.T.O.
25. (a) çِ٠·¤æð ·¤æÚU‡æ âçãÌ â×Ûæ槰 Ñ 5

(i) ¥æ€âèÁÙ ·ð¤ âæÍ Mn ©‘¿Ì× ©Â¿ØÙ ¥ßSÍæ17 ÎàææüÌæ ãñ ÁÕç·¤ Üé¥æðÚUèÙ
·ð¤ âæÍ ©‘¿Ì× ©Â¿ØÙ ¥ßSÍæ14 ãè ÎàææüÌæ ãñÐ
(ii) Cr21 °·¤ ÂýÕÜ ¥Â¿æØ·¤ ãñÐ
(iii) Cu21 Ü߇æ Ú´U»èÙ ãæðÌð ãñ´ ÁÕç·¤ Zn21 Ü߇æ âÈð¤Î ãæðÌð ãñ´Ð
(b) çِ٠â×è·¤ÚU‡ææð´ ·¤æð Âê‡æü ·¤èçÁ° Ñ
D
(i) 2MnO2 1 4KOH 1 O2 →

(ii) Cr2O722 1 14H1 1 6I2 →

¥Íßæ
3d â´·ý¤×‡æ Ÿæð‡æè ·ð¤ Ìˆß Ùè¿ð çÎØð ÁæÌð ãñ´ Ñ
Sc Ti V Cr Mn Fe Co Ni Cu Zn

çِ٠·ð¤ ©žæÚU ÎèçÁ° Ñ

(i) ©â Ìˆß ·¤æð çÜç¹° Áæð ¥çÏ·¤Ì× ©Â¿ØÙ ¥ßSÍæ ÎàææüÌæ ãñÐ ·¤æÚU‡æ ÎèçÁ°Ð
(ii) ·¤æñÙ âð Ìˆß ·¤æ »ÜÙæ´·¤ ©‘¿Ì× ãñ?
(iii) ·¤æñÙ âæ Ìˆß ·ð¤ßÜ 13 ©Â¿ØÙ ¥ßSÍæ ÎàææüÌæ ãñ?
(iv) ·¤æñÙ âæ Ìˆß 13 ¥ßSÍæ ×ð´ ÂýÕÜ ©Â¿æØ·¤ ãñ ¥æñÚU €Øæð´?
(a) Account for the following :
(i) Mn shows the highest oxidation state of17 with oxygen but with
fluorine it shows the highest oxidation state of 14.
(ii) Cr21 is a strong reducing agent.
(iii) Cu21 salts are coloured while Zn21 salts are white.
(b) Complete the following equations :
D
(i) 2MnO2 1 4KOH 1 O2 →

(ii) Cr2O722 1 14H1 1 6I2 →

56/1/C 14
 OR
The elements of 3d transition series are given as :
Sc Ti V Cr Mn Fe Co Ni Cu Zn
Answer the following :
(i) Write the element which shows maximum number of oxidation states.
Give reason.
(ii) Which element has the highest m.p ?
(iii) Which element shows only 13 oxidation state ?
(iv) Which element is a strong oxidizing agent in 13 oxidation state and
why ?
26. (a) çِ٠¥çÖç·ý¤Øæ ×ð´ A ¥æñÚU B ·¤è â´ÚU¿Ùæ°¡ çÜç¹° Ñ 5

(i) H ,Pd2BaSO H N2OH

CH3COCl 
2 4 → A 
2 → B
1. CO2 PCl
(ii) CH3 MgBr → A 
5→ B
2. H3O1

(b) çِ٠·¤è Âã¿æÙ ·¤èçÁ° Ñ

(i) C6H52COCH3 ¥æñÚU C6H52CHO ×ð´
(ii) CH3COOH ¥æñÚU HCOOH ×ð´
(c) çِ٠·¤æð ©Ù·ð¤ ÕɸÌð ãé° €ßÍÙæ´·¤ ·ð¤ ·ý¤× ×ð´ çÜç¹° Ñ
CH3CHO, CH3COOH, CH3CH2OH
¥Íßæ
(a) ßéËȤ-ç·¤àÙÚU ¥Â¿ØÙ ×ð´ çÙçãÌ ÚUæâæØçÙ·¤ ¥çÖç·ý¤Øæ ·¤æð çÜç¹°Ð
(b) çِ٠·¤æð ‹Øêç€ÜØæðçȤçÜ·¤ »é‡ææˆ×·¤ ¥çÖç·ý¤Øæ ·ð¤ ÂýçÌ ©Ù·ð¤ ÕɸÌð ãé° ·ý¤× ×ð´ ÃØßçSÍÌ
·¤èçÁ° Ñ
C6H5COCH3, CH32CHO, CH3COCH3
(c) ·¤æÕæðüç€ÁçÜ·¤ ¥Ü ·¤æÕæðüçÙÜ, »éý ·¤è ¥çÖç·ý¤Øæ €Øæð´ Ùãè´ ÎðÌæ?
(d) çِ٠¥çÖç·ý¤Øæ ·ð¤ ©ˆÂæÎ ·¤æð çÜç¹° Ñ
1. (i2Bu) AlH

CH3CH2CH5CH2CH2CN 2.
2 →
H2O

(e) C3H6O ·ð¤ Îæð ç·ý¤Øæˆ×·¤ â×æßØßè ãñ´ A ¥æñÚU B Ð NaOH ¥æñÚU I2,·ð¤ âæÍ »×ü ·¤ÚUÙð
ÂÚU B ¥æØÇUæðȤæ×ü ·¤æ ÂèÜæ ¥ßÿæð ÕÙæÌæ ãñ ÁÕç·¤ A ·¤æð§ü ¥ßÿæð Ùãè´ ÕÙæÌæ ãñÐ
A ¥æñÚU B ·ð¤ âê˜æ çÜç¹°Ð

56/1/C 15 P.T.O.
 (a) Write the structures of A and B in the following reactions :

(i) H ,Pd2BaSO H N2OH

CH3COCl 
2 4 → A 
2 → B
1. CO2 PCl
(ii) CH3 MgBr → A 
5→ B
2. H3O1

(b) Distinguish between :

(i) C6H52COCH3 and C6H52CHO

(ii) CH3COOH and HCOOH

(c) Arrange the following in the increasing order of their boiling points :

CH3CHO, CH3COOH, CH3CH2OH

OR

(a) Write the chemical reaction involved in Wolff-Kishner reduction.

(b) Arrange the following in the increasing order of their reactivity towards
nucleophilic addition reaction :

C6H5COCH3, CH32CHO, CH3COCH3

(c) Why carboxylic acid does not give reactions of carbonyl group ?

(d) Write the product in the following reaction

1. (i2Bu) AlH

CH3CH2CH5CH2CH2CN 2.
2 →
H2O

(e) A and B are two functional isomers of compound C3H6O. On heating with
NaOH and I2, isomer B forms yellow precipitate of iodoform whereas
isomer A does not form any precipitate. Write the formulae of A and B.

56/1/C 16