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L± ≡ Lx ± i Ly . (28)
The commutation relations involving L± and components of angular momentum are derived
using the relations (4),
For the present purpose, let the angular momentum eigenvalue equations be written in the
following form,
L2 f = λ~2 f and Lz f = µ~ f (31)
Just as in SHO, if f is an eigenfunction of L2 and Lz , so also is L± f ,
Z Z
= dτ (Lx f ) + dτ (Ly f )2 using hermiticity of Lx , Ly
2
≥ 0 (34)
where dτ is some appropriate volume element. Comparing (33) and (34), we get,
λ ≥ µ2 . (35)
Therefore, raising or lowering of µ must stop to obey (35). Say raising must stop at some
fmax and maximum value for µ be, say, l~,
1
Using (30), it follows that,
λ = l(l + 1) ~2 (37)
which is exactly what we got by solving angular part of Schrödinger equation in (21).
Similarly, lowering also should end at some fmin and minimum value for µ be ¯l~,
λ = ¯l(¯l − 1) ~2 . (39)
Since eigenvalue λ of L2 does not change with action of L± , comparing equations (37) and
(39), we see that l(l + 1) = ¯l(¯l − 1) and solving for ¯l we get,
¯l = −l and ¯l = l + 1.
But ¯l = l+1 is absurd since minimum eigenvalue cannot be larger than maximum eigenvalue,
so the acceptable solution is
¯l = −l ⇒ −l ≤ µ ≤ +l (40)
which the limit of µ (the magnetic quantum number) we talked about before without actu-
ally showing it. So for a given value of l, there are 2l + 1 different values of µ and, since µ
changes by one unit of ~, it goes from −l to +l (or the other way round) in N (say) integer
steps,
l = −l + N ⇒ l = N/2
i.e. l must be an integer or a half-integer, l = 0, 1/2, 1, 3/2, 2, . . .. However, we have
seen before when angular part of the Schrödinger equation was solved explicity that l is
an integer. Thus here we have determined the eigenvalues of generic angular momentum
operator without even knowing its eigenfunctions.
The ladder operator when acted upon the eigenfunctions of L2 and Lz changes the eigen-
values of Lz by one unit which can be represented as,
2
The coefficient cλµ can be determined as,
L+ fµ = cλµ fµ+1 ⇒
Z Z Z
? ? 2
dτ fµ L− L+ fµ = dτ (L+ fµ ) (L+ fµ ) = |cλµ | dτ |fµ+1 |2 = |cλµ |2
Z Z
?
or, dτ fµ L− L+ fµ = dτ fµ? (L2 − L2z − ~Lz )fµ
Z
2 2 2 2
dτ |fµ |2
= l(l + 1)~ − µ ~ − µ~
= (l − µ)(l + µ + 1)~2
⇒ cλµ = [(l − µ)(l + µ + 1)]1/2 ~ (42)
In the same way we can get dλµ = [(l + µ)(l − µ + 1)]1/2 . In short,
p
cλµ fµ = (l − µ)(l + µ + 1) ~ fµ+1 (43)
p
dλµ fµ = (l + µ)(l − µ + 1) ~ fµ−1 . (44)