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HYDROGEN
1. IDENTIFICATION OF SUBSTANCE

Trade name (Formula) : Hydrogen (H2)

Common Names : Hydrogen compressed, Hydrogen gas, DiHydrogen

2. Composition/Data on components:

Ingredient Percent U.N. CAS No.

Hydrogen > 99% 1049 01333-74-0

3 HAZARDS IDENTIFICATION

Emergency Overview:

CAUTION! Pressurized gas.

Odorless, colorless, flammable gas may cause Flash Fire. Simple asphyxiant. It poses a immediate fire and
explosive hazard if the concentrations exceed 4%. Lighter than air and burns with an invisible flame.

NFPA HMIS RATINGS SYSTEM

Health : 0 0 0 = No Hazard

Flammability : 4 0 1 = Slight Hazard

Reactivity : 0 2 = Moderate Hazard

Special : SA* 3 = Serious Hazard

*(CGA recommends this to designate Simple 4 = Severe Hazard

Asphyxiant.)

POTENTIAL HEALTH EFFECTS

OSHA PEL ACGIH, 2001 Carcinogenicity Hazard Evaluation

None currently Simple asphyxiant Hydrogen is not listed by None known

established NTP, OSHA, or IARC.

ROUTE OF ENTRY

INHALATION

Asphyxiant. Effects are due to lack of oxygen. Moderate concentrations may cause
nausea, difficulty in Breathing, headaches, dizziness, irregular hearthbeats, dizziness, disorientation, mood
swings, loss of coordination, convulsions, vomiting, and unconsciousness. Lack of oxygen can cause loss
of consciousness, eventually leading to convulsions, coma & death.
INGESTION:

Ingestion of gas is unlikely (Both Short and long term).

SKIN CONTACT:

No information on adverse significant effects

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EYE CONTACT:

No information on adverse significant effects.

The toxicology and the physical and chemical properties of Hydrogen suggest that overexposure is unlikely
to aggravate existing medical conditions.

4 FIRST AID MEASURES

INHALATION:
Immediately remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, qualified
personnel may give oxygen. . Keep victim warm and at rest. Call a physician. Advise the physician that the
victim has been exposed to a high concentration of Hydrogen

INGESTION:

If large amount is inhaled consult Medical practitioner

SKIN CONTACT:

Wash affected areas with water. Seek medical attention if discomfort persists.

EYE CONTACT:

Flush eyes with Plenty of water. Hold the eyelids open and away from the eyeballs to ensure that all
surfaces are flushed thoroughly. Get medical attention if discomfort persists.
NOTES TO PHYSICIAN: There is no specific antidote. Treatment of overexposure should be directed at
the control of symptoms and the clinical condition of the patient.

5 FIRE FIGHTING MEASURES

Conditions of Flammability: Flammable

Flash point: Flash point Test Method: Not Applicable Auto ignition Temperature:
Flammable Gas 752F(400C)
LEL(%): 4 UEL(%): 75

Hazardous combustion products: None

Fire & Explosion Hazards: Severe Fire Hazards, severe Explosion Hazards. Pressure Vessels may rupture
or explode if exposed to sufficient heat.

FIRE EXTINGUISHING MEDIA:

Carbon Dioxide, DCP powder. For large Fire, flush with large amount of water.
SPECIAL FIRE FIGHTING PROCEDURES: CAUTION! Pressurized gas . Asphyxiant

Lack of oxygen can kill.

Evacuate all personnel from danger area. Immediately deluge Storage Tank with water from maximum
distance until cool; then move them away from fire area if without risk. Shut off flow if you can do so without
risk. Self-contained breathing apparatus may be required by rescue workers ( See Section 16). Consider
downwind side for evacuation if the gas is leaking.

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 UNUSUAL FIRE AND EXPLOSION HAZARDS

Heat of fire can build pressure in Tank and cause it to rupture. No part of Tank should be subjected to a
temperature higher than 125°F (52°C). Hydrogen Tanks are equipped with a pressure relief device.

6 ACCIDENTAL RELEASE MEASURES

CAUTION! Pressurized gas. Asphyxiant.

Lack of oxygen can kill. Evacuate all personnel from danger area. Use self-contained
breathing apparatus where needed. Shut off flow if you can do so without risk. Ventilate area . Test for
sufficient oxygen, especially in confined spaces, before allowing re-entry.. Avoid Heat, Flames, spark and
other sources of ignition.

WASTE DISPOSAL METHOD: Prevent waste from contaminating the surrounding environment.
Keep personnel away. Discard any product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with federal, state, and local regulations.
If necessary, call your local supplier for assistance.

7 HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING:

Should conform to NFPA 50A standard.

Wear stout Gloves while handling. Wear suitable eye and face protection PPE’s.
Protect Tank from damage
Use check valve or trap in the Tank discharge line to prevent hazardous backflow.
Use a pressure reducing regulator when connecting Tank to lower pressure piping or systems
Open valve slowly. If valve is hard to open, discontinue use and contact your supplier.
Close valve after each use and when empty.

PRECAUTIONS TO BE TAKEN IN STORAGE :

Store in a cool, dry area with adequate ventilation, away from heat or direct sunlight..
Storage area should be kept clean and access should be restricted to authorized personnel only.
Protect against physical damage. Follow Safety Guide lines given by Supplier
STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125F (52C).

8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

VENTILATION/ENGINEERING CONTROLS:

LOCAL EXHAUST–Use a local exhaust system, if necessary, to prevent oxygen deficiency i.e. to prevent
accumulation of high concentrations so as to reduce the oxygen level in the air to less than 19.5%.

MECHANICAL (general)– General exhaust ventilation may be acceptable if it can maintain an adequate
supply of air.

SPECIAL–None

OTHER–None

RESPIRATORY PROTECTION

None required under normal use. Air-supplied respirators must be used in confined spaces or in an oxygen-
deficient atmosphere. Respiratory protection must conform to OSHA rules as specified in 29 CFR
1910.134.
Positive pressure air line with mask or self-contained breathing apparatus should be available for
emergency use.

SKIN PROTECTION:
 Wear work gloves when handling Valves

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EYE PROTECTION:

Wear safety glasses when operating. Select in accordance with OSHA

29 CFR 1910.133.

OTHER PROTECTIVE EQUIPMENT:

Select shoes in accordance with OSHA 29 CFR 1910.132 and 1910.133.

Regardless of protective equipment, never touch live electrical parts.

9. PHYSICAL AND CHEMICAL PROPERTIES:

PARAMETER VALUE

Physical state (gas, liquid, solid) : Gas

Molecular Weight : 2

Boiling point at 1 atm : -423.00°F (-253.0°C)

Freezing point at 1 atm: : -434.0°F (-259°C)

Specific gravity (Air = 1) at 70°F (21.1°C) and 1 atm: : 0.069

Solubility in water vol/vol at 32°F (0°C) : 0.019

Auto ignition temperature : 571Deg C

Appearance, Odor, and State: : Colorless, odorless, tasteless gas at normal

temperature and pressure.

10. STABILITY AND REACTIVITY:

STABILITY:

Stable

HAZARDOUS DECOMPOSITION PRODUCTS:

None Known

HAZARDOUS POLYMERIZATION:

Will not occur

INCOMPATIBILITIES:

Metals, Oxidising materials, metal oxides, halogens , metal salts

11. TOXICOLOGICAL INFORMATION :

Hydrogen is a simple asphyxiant

12. ECOLOGICAL INFORMATION

No adverse ecological effects expected. Hydrogen does not contain any Class I or Class II ozone-
depleting chemicals. Hydrogen is not listed as a marine pollutant by DOT.
13. DISPOSAL CONSIDERATIONS:

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WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused quantities.

For emergency disposal, slowly discharge gas to the atmosphere. in a well-ventilated area or outdoors.
The stack should be in an isolated area away from ignition sources.

14. TRANSPORT INFORMATION

Domestic (U.S.A, D.O.T.)

Proper Shipping Name
Hazard Class
Identification Number
Shipping Label
Placard (when required)
Special Information
Hydrogen, compressed
:
2.1( Flammable Gas)
:
UN 1049
:
: FLAMMABLE GAS
: FLAMMABLE GAS or HYDROGEN
: Tank should be maintained in a secure UPRIGHT position, in a well-
ventilated area. An enclosed, non-ventilated area can present serious
safety hazards. Operating of the hydrogen Plant without proper
authorization is a violation & can amount to a Safety Breach.

15. REGULATORY INFORMATION

U.S. Federal Regulatory Information : EPA (Environmental Protection Agency)

SECTIONS 311/312: Require submission of MSDS’s and reporting of chemical inventories with
identification of EPA hazard categories.

IMMEDIATE: No PRESSURE: Yes

DELAYED: No REACTIVITY: No
FIRE: Yes
MANUFACTURE, STORAGE & IMPORT OF HAZARDOUS CHEMICALS RULES, 1989 as Amended
upto 2000:
Rule 17 (2): “to develop information in the form of a safety data sheet (Schedule 9 of above rules:
Safety data Sheet).”
Rule 17 (4): The supplier is also to clearly LABEL or Mark every container of hazardous goods with the
following information
(a) the contents of the container;
(b) the name and address of the manufacturer or importer of the hazardous chemical; and
(c) the physical, chemical and toxicological data of the hazardous chemical.
(5) In terms of sub-rule (4) of this rule where it is impractical to label a chemical in view of the size of the
container or the nature of the package, provision shall be made for other effective means like tagging or
accompanying documents. "

16. OTHER INFORMATION:

Pressurized gas. Use piping and equipment adequately designed to withstand pressures to be
encountered.
Gas can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation.
Close valve after each use; keep closed even when empty.
Never work on a pressurized system. If there is a leak, close the Tank valve. Blow the system down
in a safe and environmentally sound manner in compliance with all federal, state, and local laws; then
repair the leak. Never store a compressed gas storage Tank where it may become part of an
electrical circuit.
MIXTURES: When you mix two or more gases or liquefied gases, you can create additional,
unexpected hazards. Obtain and evaluate the safety information for each component before you
produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end
product. Remember, gases and liquids have properties that can cause serious injury or death.

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