CONFIDENTIAL* 2

SMK TASEK UTARA, JOHOR BAHRU

UJIAN PENILAIAN PRA-PENTAKSIRAN (2) SEM 3 2017
SUBJECT : CHEMISTRY
Name : ____________________________________ Tingkatan : UPPER 6 ____________
Section A [15 marks]

1 C 6 D 11 C

2 D 7 A 12 C

3 C 8 B 13 A

4 B 9 A 14 D

5 D 10 B 15 C

16.(a) 1: KMnO4 / H+ @ K2Cr2O7 / H+ under reflux [1] - empirical formula : C5H11Cl [1]
2 : Cu at 400oC @ PCC in CH2Cl2 [1] - [5(12.0) + 11(1.0) + 1(16.0)] = 106.5 [1]
(b) each intermediate 2 x [1] [2] - molecular formula : C5H11Cl [1]
(b) Each structure [1] x 5 [5]

(c) Chemical test : Iodoform test [1]

- B shows yellow precipitate while ethanoic acid does not
shows observable changes [1]
- Eq : CH3CH(OH)COOH + I2 + OH- 
-OOC-COO- + CHI3 [1]
17.(a) - 2-aminopentanedioic acid [1]
(b) - amino acid that joined together using amide bond [1]
(ii) Each structure [1] x 2 [2] (c) Each equation(correct reagent and condition) [1] x 6 [6]

(c) - Each structure [1] x 2 [2]

(d) Equation [1]

19.(a) Each reagent / cond [1] intermediate [1] [5]

Application : food flavouring [1]

18 (a) Calculate mol [1]

Element C H Cl
Mass 55.81 10.23 33.03
Mol 4.65 10.23 0.930
Ratio 5 11 1

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TRIAL EXAMINATION STPM SMK TASEK UTARA
 CONFIDENTIAL* 3

(b) each product [1] x 2 x 2 [1] 20 (a) Structure of P, Q, R and S [1] x 4 [4]

- Q is alcohol which contain chiral carbon atom

0 - R is carboxylic acid (or methanoic acid) which oxidised to
(c) (i) - x : NaNO2 + HCl [1] Cond : 0 - 5 C [1]
form CO2 and H2O (or eq)
- y : NaOH [1]
- S contain methyl carbonyl
(ii) Structure of M and N [1] x 2 [2]
- Equations of reaction [1] x 4 [4]

(iii) - electrophilic aromatic substitution reaction [1]

(b)(i) - T : 2-methylbutanoic acid [1]

(ii) - T has higher boiling point than P [1]
- T form dimer by using strong hydrogen bond (or diagram)
[1]
- which increase the mass greatly (or increase by twice) [1]
- strength of weak Van Der Waals in T is much greater than
P [1]

962 / 3 - CHEMISTRY PAPER 3

TRIAL EXAMINATION STPM SMK TASEK UTARA