STD: XII TERM EXAMINATION MARKS:35

DATE:18.10.2021 SUB: CHEMISTRY HRS: 1 ½Hours

SECTION-A
Q.1. Select and write the correct answer with option:: [5]
i. The optically inactive compound is
(a) Glucose (b) Lactic acid
(c) 2-chloropropane (d) 2- chlorobutane

ii. The rate constant unit for a zero order reaction is

(a) time-1 (b) mol L-1time-1
(c) mol-1 L time-1 (d) mol-2 L time-1

iii. For which of the following substance fH is zero

(a) CH3 OH( ) (b) C6 H6( )
(c) O2( ) (d) CH4( )

iv. In Crystal lattice formed by BCC unit cell, the void volume is
(a) 68% (b) 74% (c) 32% (d) 26%

v. Which is the best reagent

for carrying out the
CH3 CH3
following conversion? OH

(a) LiAlH4 (b) Conc. H2SO4, H2O

(c) H2|Pd (d) B2H6, H2O2– NaOH

Q.2. Answer the following: [4]

i. Write the two uses of Teflon
ii. Write structural formula for pentane -1, 4- diol.
iii. How many electrons would have a total charge of 1 coulomb?
iv. State the first law of thermodynamics.

SECTION-B

Attempt any three. [6]

Q.3. Write short note on Schottky defect.

Q.4. A certain reaction occurs in the following step

i) Cl(g) + O3(g)ClO(g) + O2(g)
 ii) ClO(g) + O(g)Cl(g) + O2(g)
Identify (a) Reaction intermediate (b) Catalyst

Q.5. Write the structural formula of the monomer used for the preparation of
(a) Terylene (b) Buna – S

Q.6. Derive the relation H–  U = ngRT

Q.7. Construct a galvanic cell from the electrodes

Co | Co and Mn |Mn
E∘ = 1.82V, E∘ = −1.18V Calculate E∘ cell.

SECTION-C

Attempt any Four [12]

Q.8. How is nylon–6, 6 prepared? Write any two uses of it.

Q.9. Derive the expression for Maximum work.

Q.10. Calculate the number of atoms present in 2.0 gram of crystal which has Body
Centered Cubic (BCC) crystal lattice having edge length of 100pm and density
10g/cm3.

Q.11. What is salt bridge? Write any four application of electrochemical series.

Q.12. Discuss the mechanism of alkaline hydrolysis of methyl bromide with energy
profile diagram.

Q.13. Complete the following reaction :

i) CH − CH− CH + KOH ∆
| (alc. )

ii) CH − CH − Br + SbF

iii) CH
|
CH − C −CH Cu/573K
|
OH

SECTION-D

Attempt any Two [8]

Q.14. a) Define (i) Enthalpy of atomization (ii) Entropy

b) One mole of an ideal gas is compressed from 500cm3 against a constant pressure of
1.2 × 10 pa. The work involved in the process is 36.0J. calculate the final volume.
Q.15. What is Frenkel defect. Calculate the packing efficiency of a metal crystal that has
Body – centered cubic structure.

Q.16. a) Obtained the relationship between rate constant and half-life of a first order
reaction.
b) How will you convert propanone to 2–Methyl propan–2–0l.