Solutio Time Observ S2O82 S2O32-

Group [S2O82-] I- (mL) [I-] [S2O32-]

n# (sec) ation (mL) (mL)
Case 1
1 95 Yellow 5 0.01 10 0.02 1 0.0002
2 63 Yellow 7.5 0.015 10 0.02 1 0.0002
3 39 Yellow 10 0.02 10 0.02 1 0.0002
4 28 Yellow 12.5 0.025 10 0.02 1 0.0002
1
5 23 Yellow 15 0.03 10 0.02 1 0.0002
Case 2
1 178 Yellow 5 0.01 5 0.01 1 0.0002
2 108 Yellow 5 0.01 7.5 0.015 1 0.0002
3 76 Yellow 5 0.01 10 0.02 1 0.0002
Case 1
1 164 Yellow 5 0.02 10 0.02 1 0.0002
2 106 Yellow 7.5 0.015 10 0.02 1 0.0002
3 57 Yellow 10 0.02 10 0.02 1 0.0002
4 38 Yellow 12.5 0.025 10 0.02 1 0.0002
5 29 Yellow 15 0.03 10 0.02 1 0.0002
2
Case 2
1 164 Yellow 5 0.02 10 0.02 1 0.0002
2 106 Yellow 7.5 0.015 10 0.02 1 0.0002
3 57 Yellow 10 0.02 10 0.02 1 0.0002
4 38 Yellow 12.5 0.025 10 0.02 1 0.0002
5 29 Yellow 15 0.03 10 0.02 1 0.0002

[S2O82-] log([S2O
2
Grou Solution log(Rate - 8 -] -
Rate 2 log([I-]) Sum Slope
p # ) ([S2O3 - ([S2O32-
]/2) ]/2))
Case 1
- - -
1.05263E- -
1 06
5.97772360 0.0099 2.00436480 1.69897000
3.70333481
5 5 4
- - - -
2 1.5873E-06 5.79934054 0.0149 1.82681373 1.69897000 3.52578373
9 2 4 6
- - - - 1.330
3 2.5641E-06 5.59106460 0.0199 1.70114692 1.69897000 3.40011692 08267
7 4 4 8
- - - -
6
3.57143E-
4 06
5.44715803 0.0249 1.60380065 1.69897000 3.30277065
1 3 4 7
1 - - - -
4.34783E-
5 06
5.36172783 0.0299 1.52432881 1.69897000 3.22329881
6 2 4 6
Case 2
- - -
5.61798E-
1 07
6.25042000 0.0099 2.00436480 -2 4.00436480
2 5 5
- - - - 1.228
9.25926E-
2 07
6.03342375 0.0099 2.00436480 1.82390874 3.82827354 10050
5 5 1 6
- - -
9
1.31579E- -
3 06
5.88081359 0.0099 2.00436480 1.69897000
3.70333481
2 5 4
 Case 1
- - - -
6.09756E-
1 07
6.21484384 0.0199 3.40229384 1.69897000 5.10126385
8 7 4 2
- - - -
9.43396E-
2 07
6.02530586 0.0149 3.65362746 1.69897000 5.35259746
5 3 4 8 1.060
- - - -
1.75439E- 76041
3 06
5.75587485 0.0199 3.40229384 1.69897000 5.10126385
6 7 4 2 8
- - -
2.63158E- -
4 06
5.57978359 0.0249 3.20760130 1.69897000
4.90657131
7 6 4
- - - -
3.44828E-
5 06
5.46239799 0.0299 3.04865762 1.69897000 4.74762762
8 3 4 8
2
Case 2
- - -
5.07614E-
1 07
6.29446622 0.0099 4.00872961 -2 6.00872961
6 1 1
- - - -
7.63359E-
2 07
6.11727129 0.0099 4.00872961 1.82390874 5.83263835
6 1 1 2
- - - - 1.068
9.34579E-
3 07
6.02938377 0.0099 4.00872961 1.69897000 5.70769961 22932
8 1 4 5
- - - -
9
4 1.2987E-06 5.88649072 0.0099 4.00872961 1.60205999 5.61078960
5 1 1 2
- - - -
1.69492E-
5 06
5.77085201 0.0099 4.00872961 1.52287874 5.53160835
2 1 5 6

Temperatur [S2O82 [S2O32 Timeav

1/T - [I-] - Rate k ln k
e, K ] ] e
-
0.00347041 4.329E- 0.00218
288.15 231 6.1255
5 07 6
1
0.00341122 7.11744E 0.00359
293.15 140.5 -5.6283
3 -07 5
0.0 0.000
0.01 -
0.00335401 2 2 9.61538E 0.00485
298.15 104 5.3274
6 -07 6
9
-
0.00329869 1.38889E 0.00701
303.15 72 4.9597
7 -06 5
6

Slope -6733.692871
Activation energy 55.98392253
Arrhenius constant 31848028.38

Solu [Na [Na2

Tim [Na+ [NO 2[N [S2 [K2S 2[K+ [S2
tion NO3 3- S2O [KI] [K+] [I-]
e ] ] a+] O32-] 2O8] ] O82-]
# ] 3]
0.00 0.00 0.00
1 54 0 0 0 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02
 0.00 0.00 0.00
2 165 0 0 0 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02
0.00 0.00 0.00
3 112 0.01 0.01 0.01 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02
0.00 0.00 0.00
4 93 0.02 0.02 0.02 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02
0.00 0.00 0.00
5 82 0.04 0.04 0.04 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02
0.00 0.00 0.00
6 80 0.06 0.06 0.06 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02
0.00 0.00 0.00
7 79 0.08 0.08 0.08 0.01 0.02 0.01 0.02 0.02 0.02
02 04 02

u of u of
u of
Solut Na2 Na2 u of Tota
NaN Rate k x y
ion # S2O S2O KI lu
O3
3 8
0.0093527 -
0.00 0.01 0.05 1.851852E 0.2249444
1 0 0.02 87130564 2.0290589
03 5 06 -06 38
91000 5
0.0030609 -
0.00 0.01 0.05 6.060606E 0.2249444
2 0 0.02 12151821 2.5141491
03 5 06 -07 38
24000 34
0.0045093 -
0.00 0.01 0.15 8.928571E 0.3880721
3 0.01 0.02 79509379 2.3458832
03 5 06 -07 58
51000 13
0.0054306 -
0.00 0.01 0.07 1.075269E 0.2657066
4 0.02 0.02 50591940 2.2651481
03 5 06 -06 05
91000 39
0.0061591 -
0.00 0.01 0.09 1.219512E 0.3009983
5 0.04 0.02 52500615 2.2104790
03 5 06 -06 39
92000 43
0.0063131 -
0.00 0.01 0.11 1.250000E 0.3325657
6 0.06 0.02 31313131 2.1997551
03 5 06 -06 83
31000 77
0.0063930 -
0.00 0.01 0.13 1.265823E 0.3613862
7 0.08 0.02 44367727 2.1942922
03 5 06 -06 2
91000 82