Roll No.

Test No – B1
5061 CHEMISTRY

XII-Entrance ISOMERISM, REACTION MECHANISM, Marks: 180

Answer Paper HALOALKANES & HALOARENES ALCOHOLS,
PHENOLS AND ETHERS

1. d) cis and trans isomers of 2,3- Anhyd.ZnCl  HCl

2
o
dimethyl-2-butene CH3CH2CH2  Cl  H2O
2. a) reduction of CO in presence of
10 reacts only on
ZnO . Cr2 O3
heating.
6. d) CH3 CHCH2 CH2 CH2 OH
2

3. c) benzoic acid 7. c) p-methylphenol, phenol, m-

nitrophenol, p-nitrophenol

8. b) salicylic acid

4. a) C 2H 5OH

5. c) 2-Hydroxy-2-methylpropane
CH3 3
C  OH  HCl

Anhyd.ZnCl  HCl
2
o
CH3 3
C  Cl  H2O

30 reacts
immediately.
CH3 CH  OH  HCl 9. c)
2

Anhyd.ZnCl  HCl
2 10. c) n-propyl alcohol
o
CH3 2
CH  Cl  H2O

20 reacts after 5 11. d)

min.
CH3CH2CH2  OH  HCl
12. b)
 ISOMERISM, REACTION MECHANISM, HALOALKANES & HALOARENES–(B1 – 5061)

18. a)

13. b)

3o alcohol

14. c)

19. c)

20. b) IV > III > I > II

21. c)

22. d) All of these

23. a) CH 3 CH2CH CHCH CH2
Conjugation increases stability.
15. c) 24. a) 1-Bromo-2-methylbutane

a) elimination product 25. a)

b) vinyl–halide reaction is not

possible
c) required product is formed
16. c) RCH2 CH2 OH

17. b)

26. a) V > III > I > IV > II

27. d) C6 H5 3
CCl

2
 ISOMERISM, REACTION MECHANISM, HALOALKANES & HALOARENES–(B1 – 5061)

most stable carbocation functional group also take in

28. c) will remain constant numbering. So C3H7CN is
x
29. b) butane nitrile.
BrCH2 C HCH3
37. a) IV < II < III < I
38. d) Benzyl alcohol
30. d)

31. b) I < II < III < IV

Due to –I-effect, Cl destabilizes
the carbocation. Further, more
the number of Cl atoms, lesser
is the stability of the
carbocation. Thus, option b is
correct. 39. a) CH 3 CHOHCH3

32. d) CH3 CH2 CH.Br.CH2 CH3 40. c) 2-methylbut-2-ene

2

33. a) II < I < II < IV

34. b) Benzene 41. c)

42. c)

alcohol is most basic reacts with

conc. HCl forming white
precipitate.
43. c) 2,3-dimethyl-2-butene

is symmetrical thus same

product is formed in the
presence or absence of peroxide.
35. b) CH3 CH OH CH OH CH3
44. b) isobutylene
* *
CH3 C H OH C H OH CH3 has

two identical chiral C-atoms and

hence can have a meso-form.
36. a) C3 H7 Br  KCN

C3H7Br  KCN o C3H7 CN  KBr

In IUPAC system the carbon of

3
 ISOMERISM, REACTION MECHANISM, HALOALKANES & HALOARENES–(B1 – 5061)

CH2 CH  Cl

methoxide ion CH3O is a Vinyl

Chloride

strong base, therefore it abstract The halogen atom in vinyl

proton from 30 alkyl halide and
favours elimination reaction.
45. b)
chloride is not reactive as in
other alkyl halides. The non-
reactivity of chlorine atom can
participate in delocalization
(Resonance) to give two
canonical structure.

46. d) 4
Because

has four methyl groups on the

corner so it can produce for
derivatives.

47. b)

48. d) All of the above are correct

statements.
49. c) III, V
50. d) CH2 CH  Cl