CH - CH - O: DPP No. 1 (Part - I)

D.T.
SIR
GOC
DPP No. 1 [PART - I]
1. Resonance involves
(A) Change in the positions of atoms (B) Change in the positions of both  and  electrons
(C) Change in the positions of  electrons (D) Change in the positions of only  electrons
2. (I) CH3  CH  O (II) CH 2  CH – OH (III) CH – CH – O
3
Among these which are canonical structures?
(A) I and II (B) I and III (C) II and III (D) All of these
3. (I) CH 2  CH  CH  CH 2 (II) CH2 – CH = CH – CH2 (III) CH2 – CH = CH – CH2

Among these which are canonical structures?
(A) I and II (B) I and III (C) II and III (D) All of these
4. A resonance hybrid is the one which is contributed by
(A) All canonical structures (B) Only the least stable canonical structure
(C) Only the most stable canonical structure (D) None of these
5. Delocalization of electrons increases molecular stability because
(A) Electrons-nuclei attraction increases (B) Electrons-electrons repulsion increases
(C) Potential energy of the molecule increases (D) Potential energy of the molecule remains unaffected
CH2 = O CH2 – O CH2 – O

6.
I II III
Which of these structures is practically not a valid canonical structure of formaldehyde?
(A) I (B) II (C) III (D) None of these
7. (I) CH2 = CH – CH = CH – NH3 (II) CH2 – CH = CH – CH – NH3 (III) CH2 – CH = CH – CH = NH3

Which of these structures is not a valid canonical structure?
(A) I (B) II (C) III (D) None of these
O NH
O NH O NH
8. (I) (II) C (III)
H H C
H H H H
The correct of stability among these canonical structures is
(A) I > II > III (B) I > III > II (C) II > I > III (D) III > I > II
3 2
9.
1
In this cation,  electron density is more on

(A) C 1 (B) C 2
(C) C 3 (D)  -electron density is same on each C-atom.
2
3
10. 1
4
5
In this anion,  electron-density is maximum on

(A) C 1 (B) C 2 and C 5 (C) C 3 and C 4 (D) same on each C-atom
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D.T.SIR
GOC
DPP No. 1 [PART - II]
S.No. Compound Relative Stability
H3C CH3 H3C CH3 H3C CH3

1.
CH3 CH3 CH3
2.
CH3
CH3 CH3
3. CH3
CH3 CH3
CH3 CH3 CH3

H3C CH3
H3C
H3C
4. CH3 CH3
CH3
H3C H3C H2C

CH3 CH3 CH3
5.
H3C
CH+ C+
6. CH+
CH3 CH3 CH2
7.
CH3 CH3 CH3
CH3
CH3
8.
9.
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D.T.SIR
GOC
DPP No. 1 [PART - III]
Q.1. Give the relative Stability of the following compound.
1.
(i) (ii) (iii) (iv) (v)
Me Me Me
2. Ph – CH2 – CH = CH – C – Me Me – CH – CH = CH – C – Me
Me Me
(i) (ii)
Me Me Me
Ph – CH = CH – C – Me Me – C – HC = CH – C – Me
Me Me Me
(iii) (iv)
Me
3. Me – CH – CH – CH3 Me – CH2 CH3 Me – C – CH2
Me Me
(i) (ii) (iii) (iv)
4.
(i) (ii) (iii) (iv)
5.
(i) (ii) (iii) (iv)
6.
(i) (ii) (iii) (iv)
Me – CH = CH2
7.
(i) (ii) (iii)
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D.T.SIR
GOC
DPP No. 1 [PART - IV]
1.
(i) (ii) (iii) (iv) (v) (vi) (vii)
2.
(i) (ii) (iii) (iv)
CH2 CH2
CH2 CH2
3.
CH3 CD3
CT3
(i) (ii) (iii) (iv)
CH2 CH2
CH2 CH2
4.
(i) (ii) (iii) (iv)
CH2 CH2 CH2 CH2
5.
(i) (ii) (iii) (iv)
CH2 CH2 CH2 CH2
6.
CF3 CCl3 Me
(i) (ii) (iii) (iv)
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D.T.SIR
GOC
DPP No. 1 [PART - V]
1.
(i) (ii) (iii)
2.
(i) (ii) (iii) (iv)
3. CH2 (Et)2CH (Et)3C CH2 CH2
(i) (ii) (iii) (iv)
CH
4.
(i) (ii) (iii) (iv)
5.
(i) (ii) (iii) (iv)
6.
(i) (ii) (iii) (iv)
7.
(i) (ii) (iii)
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D.T.SIR
ANSWERS
Answer Key of DPP No. 1
PART - I
1. C 2. B 3. D 4. A 5. A
6. C 7. C 8. B 9. D 10. D
PART - II
1. b>a>c 2. a>b>c 3. b>c>a 4. c>a>b
5. a>b>c 6. c>a>b 7. a>b>c 8. a=b 9. a> b
PART - III
1. i > ii > iii > iv > v 2. iii > i > ii > iv 3. i > ii > iv > iii
4. i > iii > iv > ii 5. i > iv > ii > iii 6. i > iii > ii > iv
7. iii > i > ii
PART - IV
1. i > ii > iii > iv > v > vi > vii 2. i > ii > iii > iv 3. i > ii > iii > iv
4. i > ii > iii > iv 5. i > ii > iii > iv 6. i > ii > iv > iii
PART - V
1. i > iii > ii 2. iii > ii > iv > i 3. iii > ii > iv > i
4. iii > ii > iv > i 5. i > ii > iv > iii 6. i > ii > iv > iii
7. ii > iii > i
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CH - CH - O: DPP No. 1 (Part - I)

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CH - CH - O: DPP No. 1 (Part - I)

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D.T.

3. (I) CH 2  CH  CH  CH 2 (II) CH2 – CH = CH – CH2 (III) CH2 – CH = CH – CH2

CH2 = O CH2 – O CH2 – O

7. (I) CH2 = CH – CH = CH – NH3 (II) CH2 – CH = CH – CH – NH3 (III) CH2 – CH = CH – CH = NH3

In this cation,  electron density is more on

In this anion,  electron-density is maximum on

S.No. Compound Relative Stability

H3C CH3 H3C CH3 H3C CH3

CH3 CH3 CH3

H3C H3C H2C

CH3 CH3 CH2

(i) (ii) (iii) (iv)

(i) (ii) (iii) (iv) (v) (vi) (vii)

(i) (ii) (iii) (iv)

(i) (ii) (iii) (iv)

CH2 CH2 CH2 CH2

(i) (ii) (iii) (iv)

CH2 CH2 CH2 CH2

(i) (ii) (iii)

(i) (ii) (iii) (iv)

3. CH2 (Et)2CH (Et)3C CH2 CH2

(i) (ii) (iii) (iv)

(i) (ii) (iii) (iv)

(i) (ii) (iii) (iv)

(i) (ii) (iii)

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