Qi Q2 Qs a4 Qs a6 Qs Qo Quo Qui qu Qu3 CHEMISTRY CHAPTER 7 + 8 (2% YEAR) The best source of organic compounds is (a) Minerals (b) Coal (©) Natural gas (€) Rocks ‘When coal is heated in absence of air then which one is not produced (@) Carbon black (b) Coke (©) Coal tar (4) Coal gas ‘The octane number is 100 for (a) 2.44-trimethyl pentane (©) 234trimethyl hexane (4) 2.24-timethy! pentane Which of the following has a bond formed by overlap of sp?—sp" hybridized orbitals (@CHs-C=C-H1 (b) CHa = CH-CH= Cl (©) CHs-CH=CH-CH ‘The hybridization of nitrogen atom in dimethy! amine is (sp (sp Osx (@) dsp” Tsomerism exhibited by CHsCOOH and HCOOCT is = (2) Position __ pone — ain (@ Functional ‘The isomerism shown by alkane is 4a Chain (b) Position (Functional group nels Syston | (A) Alt ofthese ‘The element that is least likely Co be fond in an aromatic organic compound is (@) Oxygen () Sulpar (©) Nitrogen (4) Chlorine Saturated alicyclic compoulité® have same general forznula as (@) Alkane (0) Alkene (©) Aikyne, (@) Benzene ‘The fractional distillation of petroteum yiekds only @w (20 os so Cracking of higher atkane at high temperature produce most number of moles of (@) Alkane () Alkene (6) Alkyne (arene Best method for the production of gasoline is (a) Thermal cracking, (b) Catalytic cracking (6) Steam cracking (@)Allof these Catenation isa property of earbon atom which deseribe its ability to (@) Bond with other carbon atoms (b) Form double and triple bond {6 Bond with other atoms {(@) Bond with hydrogen atoms Tn propene there are, bonds (@6oand2x (b)Toand x (©6oand Ix (Sand 1x ‘Which ofthe following isa planar motecule (@ Methanal (b) Acetone (© Acetic acid (6) Bihanol_.,, Page 1of4 For more Entry Test books and MCQS visit PAKGET.PKQ.16 Quy Qus Qs Q.20 Qn Qn 23 Qa 25 26 Q27 Q.28 Q29 Q30 Which molecule has non-zero dipole moment (@) Marsh ges () Toluene (© Chlorofrom (4) Neo-pentane Best quality of coa (2) Peat (©) Lignite (c) Bituminous coal (d) Anthracite Which fractions of petroleum are used as cleansing fluid (@) Petroleum ether and Ligroin (b) Petroleum ether and gasoline (©) Ligroin and gas oil (@) Light naphtha and kerosene ‘Which heterocyclic organic compound does not have nitrogen as heteroatom (@) Aniline (b) Pyrrole (6) Pyridine (d) All have Nitrogen as heteroatom Selegt the incorrect pair (a) Formy! — Alkanal (b) Carbonyl — Alkanone (c) Carboxyl — Ether (d) Hydroxyl — alkanol Bond angle of unbybridized orbital with hybrid orbitals in propene (@) 180° () 120° © 10" (90° How many isomeric aliphatic hydrocarbons are possible for CsHlz @3 2 @4 @s ‘Which compound is not isomer of other three @nPentane OS OS (b) Methyl butane = S$ ~* (©)2,2-Dimethyl propane © > ¢-¢ ()23-Di Alkenes show geometric isomerism due to (@ Asymmetry (b) Rotation around a single bond (6) Resonance (@) Restricted rotation around C=C bond ‘The isomers of a substange must have same (2) Chemical properties () Functional group. (© Physical properties (@ Molecular formula ‘Which of the following compound will not show geometric isomerism (@ BrCH=CH Br (@BrCH=CHCI a cH, Following type of compounds are studied under which type of isomerism ? Wk Thy Cih=CH-OH and oy, bon bee (2) Metamerism (©) Tautomerism (©) Geometric (oP h chlorination of alkanes, the first step in which chlorine free radicals are produced is called (@) Initiation (b) Activation (©) Propagation (@) Termination 2,3 Dimethyl -2-butene undergoes catalytic hydrogenation to give (@)2,3-Dimethylbutane (0) 2-Methylpentane (©)2,2-Dimethylbutane (4) Methyl pentane How many monochlorinated products are possible inthe reaction of butane with chlorine in presence of light? (a2 (3 4 6 Page? or 4 For more Entry Test books and MCQS visit PAKGET.PKQat Q32 Q33 34 Q35 Q36 937 Q38 Q39 40 Qa 43 4 as ‘Which halogen does not appreci ‘substitution reaction {a) Chlorine (b) Bromine ©lodine (@ Fluorine Kolbe's electrolysis of sodium butyrate gives @) Cats () CoH ©CeHs (CH Total number of tertiary hydrogens in 2,3-Dimethy! butane 2 3 4 6 ‘Acetone can be obtained by ozonolysis of (@ 1-Butene (b)Iso-Butene (©) 2-Butyne (@)2-Butene Baeyer’s reagent i used in the laboratory for (a) Reduction (6) Position of double bonid (©) Detection of double bond (@) Detection and position of double bend Thereaction C,H, +H,—3->C,H,,.. This reaction is known as (@ Wurte's reaction (6) Clemmeniéh reaction (6 Sabatier and sendern’s reaction _. “() Kobe's reaction ‘Viedibalides on treatment with Zn-dust give alkenes in_ solvent {a Acetone (Ether (6) Acetic acid {(@) Chloroform {In which solvent all alkenes are moststable (@) Water (b) Ammonia (© Ethanol (€) Carbon tetrachloride In the reaction of ethytene-with H20 in the presence of sulphuric acid which one adds across the double bond first @H (by Hr om (@ Sulphate ion Propene reacts with bromine to form 1,2-Dibromopropane. This is an example of (@Nu-addition (b) E* - addition (©) Nu- substitution (@ E%-substtution 2-Methyl propene reacts with HBr to give (@)Ter-Buyy bromide “H-GA=Cis | (b) o-Butane (c) n-Butyl bromide My (d) Sec-Butyl bromide Propadiene HC = C= CH) (@) Planar compound (©) Non-planar compound {) Conjuated compound (@) Planar and conjugated Propene reacts with Clin 10 to give (@) 1-Chloro-2-Propanol (b)2-Chioro-2-Propanol (©) l-Chloro-1-Propanol (@) 2-Chloro-1-Propanol Lindlar'seatalystis (@)Za-HpfHcl (@) NiH/KOH corey es line) (@) Lig. NHy/Na_ ofthe following hydrocarbon has acid en (a) 1-Butene " fone (@) 1-Butyne (©) Acetic acid (@) Both 1-Butyne and Acetic acid For more Entry Test hooks and MCQS visit PAKGET.PK P#t?0f40.46 Qa Qs Qs 50 Qst Qsz Qs ss Qs Q56 Qst 58 Qs9 60 ‘The monomer of neoprene is (a) Isoprene (b) Acrylonitrile (©) Chloroprene (@) Acetylene ‘Which of the following does not react with ammonical AgNOs solution? (a) Acetylene (b) I-Butyne (©) Propyne (@)2-Pentyne ‘Acetylene reacts with water in the presence of 20% Sulphuric acid and Mercurie Sulphate to give (@) Acetone (@) Formaldehyde (© Acetic acid (@) Acetadehyde Maximum age of “s” characteris present in (@) Alkane (6) Alkene (© alkyne (@) Benzene ‘Addition of -moles of HCI to propyne gives (@)22-Dichloropropane (©) 13}:Diehloropropane (©) 1.2-Dichloropropane (@)23-Diehloropropane ‘Which ofthe compound on hydrolysis gives acetylene (2) Cats (bysic (c) AUCs (d) CuxCh Hybridization of Sulphur atom in mustard gas is (a) sp Cima © (b) sp osx reef (@) dsp? Select the least reactive family of organic compounds (@) Alkane ()Alkene (© Alkyne (@) Benzene ‘Choose the correct order of decreasing bond length 1% (@) Benzene > Alkyne > Alkane > Alkene »(b) Alkene > Benzene > Alkane > Aikyne (©) Alkane > Benzene > Alkene> Alkyne . (¢) Alkane > Alkene > Benzene > Alkyne In the following reaction ° CH, + [0] S82 ocHyOn + [OJ FHCHO 7d, “The hybrid state of the carbon atom changes from (9) sp-sp sp" (0) sp°— sp*— sp? (©) 9p — sp — sph (@) sp - sp —sp* ‘Which of the folowibg compound is assigned the octas: (9) n-octane (@) n-heptane © isoretane (@)iso-heptane ‘Which ofthe following compound is used as an anti-knock compound (TEL, (6) TNT (Pvc (PVA Tn he given compound total number of primary carbons are cH, N cH, -C ~ CH-CH,-CH, ot cH, CH, @3 wa @s On ‘Select the correct IUPAC name of compound cH, CH, f I CH, -CH= CH-CH-C=CH (8) 3-5-Dimethyl-4-hexen-I-yne (b) 3-5-Dimethyl-I-hexyn-4-ene (©)2,4Dimethyl-2-hexen-S-yne (@ S-methyl-4-hepten-I-yne ‘Total number of chain isomers of butane are i SRY S477-786- 63 For more Entry Test books and MCQS visit PAKGET.PK 17 Page 4 of 4 Ben