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Article history: Using solar chimney in desert areas like El Paso city in Texas, USA, with high intensity solar radiation is
Received 8 May 2015 efficient and environmental friendly. However, one of the main challenges in terms of using solar chim-
Accepted 21 July 2015 neys is poor electricity generation at night. In this paper, a new power plant plan is proposed which
Available online 13 August 2015
simultaneously generates heat and electricity using a solar chimney with solid oxide fuel cells and solid
oxide electrolysis cells. In one hand, the solar chimney generates electricity by sunlight and supplies a
Keywords: part of demand. Then, additional electricity is generated through the high temperature electrolysis which
Solar chimney
produces hydrogen that is stored in tanks and converted into electricity by solid oxide fuel cells. After
Solid oxide electrolysis cell
Solid oxide fuel cell
designing and modeling the cycle components, the economic aspect of this power plant is considered
Economic analysis numerically by means of genetic algorithm. The results indicate that, 0.28 kg/s hydrogen is produced
at the peak of the radiation. With such a hydrogen production rate, this system supplies 79.26% and
37.04% of the demand in summer and winter respectively in a district of El Paso city.
Ó 2015 Elsevier Ltd. All rights reserved.
1. Introduction production have been analyzed by Lebbi et al. [3]. Numerical calcu-
lations have been conducted for determination of air behavior in
Initial driver of solar chimney power plant is temperature dif- different geographical conditions. Lebbi et al. [3] have shown that
ference (that causes density difference) between ambient temper- dimension of the tower has an important role in the rate of air
ature and temperature inside the chimney. The chimney acts like a passing through the tower. Also, the hydrodynamic part of the
heat engine in solar chimney power plant which converts heat tower is controlled by the dimensions of the tower, and its thermal
(generated by a collector) into kinetic flow and turbine pressure section by system temperature. Li et al. [4] presented a different
drop (potential energy) [1]. Since warm air is lighter than cold model to calculate the costs required for building a solar chimney
one, lift force is arisen. In other word, a pressure difference in north China. Patel et al. [5], have carried out a computer fluid
between collector output (chimney base) and the ambient is cre- dynamics analysis to optimize the geographical conditions to
ated so the collector is leaned a few meters above ground level cov- improve air behavior in a solar chimney by ANSYS software.
ered by a transparent glass. Main task of the collector is to absorb Kasaeian et al. [6] have also optimized the geographical conditions
sun ray for heating air. Buoyancy force conducts warm air into the of solar chimney built in the University of Tehran.
chimney located in the middle of collector. A turbine is also Fuel cells are used to convert chemical energy stored in fuel into
installed in airflow direction to generate electricity [1]. The collec- electrical. High efficiency and very low emission rate are among
tor top surface is made of a semitransparent material like glass that fuel cells advantages [7]. Currently, there are several types of fuel
is impervious subject to long wavelengths. Several studies have cells. Solid oxide fuel cell (SOFC) is the only type able to work at
been carried out for modeling and optimizing solar chimney high temperature around 1000 °C [8]. Fuel cells also can be tubular
hydrogen production systems. Sangi et al. [2] have modeled and or planar. The tubular design is more appropriate for large-scale
numerically simulated a solar chimney power plant. A hybrid solar applications in comparison with planar one [9,10]. As mentioned
chimney system with electrolysis and a station for hydrogen before, since SOFC operating temperature is high, the hot outlet
gas can be used in gas turbine or heat recovery systems.
⇑ Corresponding author. Tel.: +61 8 9266 7707. Preliminary studies on integrated power systems point out 70%
E-mail addresses: omid.joneydis@curtin.edu.au, omid.joneydi@gmail.com higher efficiency of such systems [11,12]. In recent years, much
(O. Joneydi Shariatzadeh). effort has been made to combine devices such as solid oxide fuel
http://dx.doi.org/10.1016/j.enconman.2015.07.054
0196-8904/Ó 2015 Elsevier Ltd. All rights reserved.
424 O. Joneydi Shariatzadeh et al. / Energy Conversion and Management 105 (2015) 423–432
Nomenclature
cells with CHP (Combined Hear & Power) [12]. Lots of attempts In this paper, a new design for the combination of a solar chim-
have been carried out to commercialize SOFC systems and related ney with solid oxide fuel cells, solid oxide electrolysis cells and a
technology, from 20 kW pilot plants on landfills [13] to 6 MW heat recovery steam generator (HRSG) has been provided. One of
power plants [14]. Today, economic analysis of SOFC systems run the initiatives applied in this article is the use of hydrogen pro-
by biogas has become very sufficient in comparison to old tradi- duced by the solid oxide electrolysis cell into supply electricity in
tional power plants. Santangelo and Tartarini [15] have compared residential area where solar chimney is not able to generate elec-
efficiency of SOFC systems in combined thermal cycles with tradi- tricity during night time.
tional power generation cycles. Chung et al. [16] in 2008 have As mentioned before, two major factors for electricity produc-
investigated the effective factors such as fuel utilization factor tion by solar chimney are the quantity of solar radiation and high
and air-to-fuel ratio on the productivity rate of SOFC power plants. temperature of the air. If the amount of solar radiation and air tem-
Xu et al. [17] have modeled a 1 kW CHP working on the basis of perature are not sufficient, the solar chimney will not generate
SOFC and concluded power generation efficiency of 52% and simul- electricity resulting a very low efficiency. The solar chimney sys-
taneous power generation efficiency about 80% is attainable in tem that is proposed in this article generates electricity surplus
such systems. Choi et al. [18] have studied a SOFC system along to meet residential area need, on a summer day. During day, the
with a gas turbine and have determined that the power generation surplus electricity is stored as hydrogen and entered into a solid
efficiency of the cycle is up to 70%. oxide fuel cell. Then, it generates electricity to meet residential
Combining solid oxide electrolysis cell (SOEC) with fuel cells is area demand when solar chimney does not operate at night.
another promising system. Iora et al. [19], studied a new system Namely, the outlet hot exhaust can be entered from SOFC into
including solid oxide fuel cells and solid oxide electrolysis cells. HRSG to generate steam and finally, the generated steam is used
An appropriate sample was developed by Iora et al. to produce in heating and supplying hot water or in heating residential area
maximum oxygen or hydrogen, especially for small dimensions. in winter.
Iora et al. [20] have proposed a new combined system which Electricity and hydrogen generation have been analyzed every
includes solid oxide fuel cells as well as solid oxide electrolysis. hour during a year in order to elaborate and reveal the accuracy
Ni et al. [21] modeled a solid oxide electrolysis cell where effi- of results and applicability of the system. A thermodynamic model
ciency is enhanced by increasing the operating temperature of of the hybrid system has been developed to predict system perfor-
SOEC and molar fraction of steam. Sanz-Bermejo et al. [22] studied mance and electric energy and hydrogen production. Analysis of
a combination of SOEC with solar tower. They have concluded that the hourly electricity and hydrogen generation during a year is
the aforementioned combination enhances the efficiency of solar then performed in order to check the accuracy of results and the
tower power plant by five percent. One of the major concerns in feasibility of the system application. The system design parameters
simple solar power plants is inability in supplying electricity at will be optimized using genetic algorithm to minimize cost. These
night. Therefore, the combination of solar energy with SOFC and/or parameters include SOFC cell number, SOFC cell diameter and
SOEC may solve the energy supply problem in the next genera- length, HRSG pressure, approach point, pinch point, steam temper-
tions. Ural et al. [23] designed a hydrogen production unit parallel ature, solar chimney height and diameter, collector diameter, SOEC
with a solar cell in a fuel cell. They resulted that the use of PV (pho- cell number as well as SOEC cell diameter and length.
tovoltaic) is not sufficient to supply the electricity requirement and
thus, auxiliary components such as fuel cells should also be
included. Dincer et al. [24] examined a PV-water electrolysis com- 2. Mathematical modeling
bined with SOFC. Energy and exergy analysis conducted by
Hosseini et al. [24] showed the maximum energy efficiency of 2.1. Description of the system
55.7% and exergy efficiency of 49%. Akikur et al. [25] applied
SOFC and SOEC with a solar power plant. They studied the combi- The schematic of the solar chimney power plant combining
nation of different components such as PV and SOFC and demon- with SOFC and SOEC is illustrated in Fig. 1. DC power generated
strated that the amount of hydrogen generated in days is by solar chimney, marked by (1) is entered into load controller
consumed at night and is converted into electricity by SOFC. (2) for appropriate distribution of electricity in building complex,
O. Joneydi Shariatzadeh et al. / Energy Conversion and Management 105 (2015) 423–432 425
Fig. 1. The schematic of solar chimney co-generation power plant combined with solid oxide electrolysis/fuel cell.
solid oxide electrolysis cell as well as pump and compressors. reduces and tends to rise moves upward from chimney and makes
When the solar chimney is active during day, electricity demanded the turbine generates electricity. Then, the heated air is exited
for building complex enters into a DC/AC converter (3) to convert through chimney to atmosphere [26]. Total efficiency of solar
DC power into AC power which is suitable for power load. The sur- chimney is obtained by multiplying the collector efficiency by
plus electricity i.e. the difference between the amount of electricity tower efficiency by turbine efficiency as follow:
generated by solar chimney and the demanded electricity enters
into SOEC (4) to produce H2.
gplant ¼ gcoll gtower gturbine ð1Þ
The oxygen generated by solid oxide electrolysis cell could be where gcoll is the collector efficiency, gtower is the tower efficiency
used for different purposes. Therefore, according to Fig. 1, after and gturbine is the turbine efficiency. The collector efficiency is
electrolyzing, hydrogen gas is transferred to the hydrogen tank obtained from dividing the amount of heat transferred to the air
(5) until the buffer tank sensors determine the amount of hydrogen through collector (Q) by the amount of solar radiation, (G) in the
available in the buffer tank reached 75% volume. A control panel collector area (Acoll):
automatically turns on hydrogen compressor (6), and hydrogen is
sent to the compressor. After compression and before storage in Q_
composite tanks, in order for purification, the hydrogen passes
gcoll ¼ ð2Þ
Acoll G
through a heat exchanger (7) to cool down steam existing in gas
By writing the energy equation for the earth which is heat
and condense it. Water is also supplied for the heat exchanger by
absorber and also for the collector, the transferred heat can be cal-
a pump (8). Then pure condensed hydrogen gas is stored in com-
culated as follows:
posite tanks (9) by a high pressure compressor (10). The rest of
separator content is discharged to the atmosphere. In the next step, Q_ ¼ mc
_ p DT ¼ aAcoll G bDT 0 Acoll ð3Þ
the stored hydrogen enters to the fuel cell power plant (11) at
night when solar chimney does not work due to the lack of solar _ is mass flow rate calculated as follows:
In Eq. (3), m
radiation, to generate electricity and meet the demand power at _ ¼ qcoll Ac V c
m ð4Þ
this time. Oxygen requirement for SOFC stack is also supplied by
a compressor (12) and an air preheater (13). Smoke and exhaust In Eq. (4), V c is exhaust air speed from collector obtained as
heat enter to a HRSG system (14). From one side, water is pumped following:
to the HRSG (15) and on the other side, steam is eliminated. HRSG
exhaust gas is discharged to atmosphere and HRSG output steam
aAcoll G bDT 0 Acoll
Vc ¼ ð5Þ
(16) is consumed for heating as well. qcoll Ac cp DT
where qcoll denotes the density of output air from solar collector
2.2. Energy analysis and Ac represents cross-sectional area of the tower. By substituting
Eq. (3) in Eq. (2), the collector efficiency is calculated by:
2.2.1. Solar chimney
bDT 0
Solar chimney power plant is a power plant working in the basis gcoll ¼ a ð6Þ
G
of solar radiation; it has a long chimney about 800 m and a
large-area collector about 1800 m in diameter, and also a turbine where DT 0 stands for temperature difference between surface (heat
which is next to the chimney. It works with solar radiation to the absorbent) and ambient temperature and b is heat loss coefficient
collector which heats the air underneath. Density of heated air from solar collector. The above equation indicates that the collector
426 O. Joneydi Shariatzadeh et al. / Energy Conversion and Management 105 (2015) 423–432
efficiency is reduced by temperature difference increase. Tower effi- as partial pressure and temperature are selected according to
ciency is obtained by: Chan et al. [28]. Ref. [28] clearly represents the complete and
detailed modeling of SOFC. Electrochemical reactions occurring
P
gtower ¼ tot ð7Þ within the cell are:
Q_ At the anode:
In which Ptot is obtained by Negrou et al. [27]. Another equation
1
that can help to calculate efficiency in an easier way is as follow: O2 þ 2e ! O ð14Þ
2
gH At the cathode
gtower ¼ ð8Þ
cp T 0
1
Eq. (8) shows the tower efficiency is dependent on the height of H2 þ O2 ! H2 O þ 2e ð15Þ
2
the tower i.e. tower efficiency can be increased by increasing the
height of the tower. According to the Eq. (7), ptot can be calculated With the overall cell reaction:
by multiplying the transferred heat in tower efficiency. Now, the 1
following valuable equation is achieved by placing tower efficiency H2 þ O2 ! H2 O ð16Þ
2
from Eq. (8) and the transferred heat from combining Eqs. (3) and
(4).
2.2.4. Compressor
g Htower Compressor isentropic efficiency (gc) is specified as below:
Ptot ¼ gtower Q_ ¼ qcoll cp V c DT Ac ð9Þ
cp T 0
ho;s hi
As Eq. (9) indicates, P tot (total power) is dependent on different
gc ¼ ð17Þ
ho hi
parameters such as the height of the tower and the density of col-
To obtain compressor work, it is necessary to know outlet fluid
lector exhaust air. According to Negrou et al. [27], the above equa-
temperature (T0) from compressor; the following relation repre-
tion can be changed into the following form:
sents it:
DT i
DPtot ¼ qcoll g Htower ð10Þ 1 h K1
T0 T0 ¼ Ti 1 þ r cK 1 ð18Þ
gc
Eq. (10) can be used to calculate the amount of electricity pro-
duction by solar chimney which is dependent on collector effi- _ AC Þ, the following equation is
To achieve air compressor work ðW
ciency, turbine efficiency and height of the tower as well as used:
collector surface. However, the important effect of solar radiation _ AC ¼ mC pa ðT 0 T i Þ
W ð19Þ
which is one of the principal parameters in this equation cannot
be neglected. In this article solar radiation is considered for differ- To obtain Cpa, the below equation is applied [29]:
ent hours per day in a year to conduct more accurate calculation !
and consequently optimization. 3:83717T 9:453T 2
C pa ðTÞ ¼ 1:04841 þ
104 107
2.2.2. Solid oxide electrolysis cell ! !
One of the equipment used in fuel cell power generation and 5:49031T 3 7:9298T 4
10
þ ð20Þ
generally CHP and CCHP systems is SOEC. This system generates 10 1014
hydrogen from electrical energy and water vapor and hydrogen
can be stored and used as fuel afterward. In SOEC, water vapor goes
2.2.5. Heat recovery steam generator (HRSG)
to cathode, and electrical energy required for splitting water mole-
Here, a single pressure HRSG is regarded as a common type sys-
cules is applied to electrode part of the SOEC. At this time, water
tem. Gas temperature and water properties will be computed by
molecules are fragmented at the common border of electrolyte
applying energy balance for gas and water in each part of the
and cathode to produce hydrogen gas and oxygen ions. The pro-
HRSG, as well as solving the below equations:
duced hydrogen is collected along cathode channel/bar. Through
Low-pressure super heater:
the holes existing in the electrolyte, oxygen ions go towards the
anode and are oxidized to form oxygen molecules again. _ 11 C p DT sup ¼ m
m _ 16 Dhsup ð21Þ
Electrochemical reactions at SOEC are as follow:
Low-pressure evaporator:
H2 O þ 2e ! H2 þ O2 ð11Þ
_ 11 C p DT eva ¼ m
m _ 16 Dheva ð22Þ
1 Low-pressure economizer:
O2 ! O2 þ 2e ð12Þ
2
_ 11 C p DT eco ¼ m
m _ 16 Dheco ð23Þ
The equilibrium reaction occurred at SOEC is expressed as
follows: The combinations of energy and mass balance equations are
numerically solved, and the temperature profile in the gas and
1 water/steam side of the HRSG is predicted.
H2 O ! H2 þ O2 ð13Þ
2
Ref. [21] shows detailed and complex modeling of SOEC. 2.3. Economic analysis
2.2.3. Solid oxide fuel cell Economic analysis is applied to show whether investment in
As mentioned, SOFC is a device to convert chemical energy into such projects is affordable or not. Knowing the price of all compo-
electrical energy. The SOFC modeled in the present study is tubular nents used in the system and also the costs related to maintaining
type, and all geometric properties related to length and diameter and fuel consumption of the system is needed for economic analy-
values of the cells and also system performance parameters such sis. Cost function for all components is observed in Table 1 [30,31].
O. Joneydi Shariatzadeh et al. / Energy Conversion and Management 105 (2015) 423–432 427
In above equation, i is interest rate and n represents lifetime of In this article, in order to verify the validation and clarification
the system. of the modeling, the diagrams of cell voltage in terms of current
Table 2
Input parameters used for modeling of the system.
Parameter Value
Solid oxide electrolysis cell
Cell pressure (bar) 1
Stack temperature (K) 1273
Area of each cell (cm2 ) 1036
Cell current density (mA cm2 ) 300
Air properties
Composition (percent by volume) N2 (79%), O2 (21%)
Molar weight (kg kmol
1
) 28.97
Table 3
List of constraints used in optimization and the range of variation of design
parameters.
Constraints Item
2500 < nSOFC < 29,000 Number of cells for SOFC
3 < dSOFC < 6 Diameter of cells for SOFC (cm)
240 < LSOFC < 360 Length of cells for SOFC (cm)
1.2 < PHRSG < 2 Pressure of HRSG (bar)
Approach > 2 Approach point temperature (K)
Pinch < 7 Pinch point temperature (K)
130 < Tsteam < 200 Steam temperature (output of HRSG) (K)
700 < Htower < 10,000 Height of solar chimney (tower) (m)
1850 < dcollector < 1900 Diameter of solar chimney collector (cm)
100 < dtower < 120 Diameter of the tower (cm)
2500 < nSOEC < 29,000 Number of cells for SOEC (electrolyser) Fig. 4. Verification of present modeling for SOEC based on Ref. [21].
1.5 < dSOEC < 3 Diameter of cells for SOEC (cm)
120 < LSOEC < 180 Length of cells for SOEC (cm)
Table 4
The optimum values of system design parameters.
Fig. 11. Hydrogen generation, hydrogen demand and suggested distribution of Fig. 12. Electricity demand and electricity generated by SOFC using stored
hydrogen in June. hydrogen in January.
O. Joneydi Shariatzadeh et al. / Energy Conversion and Management 105 (2015) 423–432 431
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