>>>>>>>>>>>>>>>>>>……………………made by lovish bansal …………………..>>>>>>>>>>>>>>>>>.

Write the working principle of Hollow Cathode Lamp with its neat and well labelled diagram. (5)

b. Differentiate between "laminar flow burner" and "total consumption burner". (5)

c. Write the principle of Flame Emission Spectroscopy (FES). What do you mean by atomization? (5)
Write the sequence of events up to atomization in atomic spectroscopy.

d. Describe the role of chopper in AAS.

With the help of a well-labeled diagram, explain the working principle of hollow cathode lamp
(HCL).

Q.1(b) Give an example of a fuel and an oxidant used to produce flame in flame photometry. Give
three differences between laminar flow burner and total consumption burner.

Q.1(c) (i) Explain the role of chopper in atomic absorption spectrophotometer.

(ii) Potassium atom absorbs at 600 nm. Calculate the energy gap between the ground and excited
states in Joules. Q

Give three differences between AAS and AES. What are the main limitations of AAS?

(d) Explain the principle of atomic absorption spectrophotometry

What are the essential differences between atomic absorption spectrophotometry [5] and flame
photometry

(a) Give the sequence of events that would take place when a sample solution of the salt is (5)
introduced into the flame in Flame Emission Spectrophotometer.

(b) During the analysis of a sample for Na, wavelength corresponding at 589 nm was found (5)
missing. Predict the wavelength that you may observe in the emission spectra of the same sample.

Provide a schematic diagram for flame emission spectrophotometer indicating the name of each
component.

(c) In case of atomic absorption spectrophotometer, give the functions of the following parts: (5) (i)
Hollow cathode lamp (ii) Atomizer (iii) Monochromator

(d) Sodium atom absorbs at a wavelength of 589 nm. What is the energy difference (in J) between
the ground and excited state? At a temperature of 2000 K, what is the ratio of excited (5)

state to ground state population (N*/No) ? (Given A = g*/go = 2; and k = 1.4 x 10 -23 JK -1 ).

Q.2 (a) What is the difference between a molecular absorption spectrum and an atomic absorption
(5) spectrum and why does this difference exist?

\\\ ………………….sure that about 20 to 25 marks paper will come from these questions…….……….. \\\