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5 - APV Membrane Processing PDF
5 - APV Membrane Processing PDF
Module 1-
Basic information of APV in Membrane Filtration
Membrane team, capabilities and market sector
Module 1
Learning objectives
4
Membrane and MP
- Abbreviations/explanations
5
Membrane filtration and MP
- brief historical update July 07
Late sixties: The Danish Sugar Company DSS (Danisco) invented the
Plate % Frame (P&F) Membrane Technology – UF and RO
1975 DDS takes over Pasilac and Silkeborg becomes the Center of
Membrane Filtration for the world Dairy Industry
– UF Feta and whey processing in Denmark > great success
– The eighties: Intensive application innovation sponsored by DDS
– Alfa Laval (Tetra Filtration) and GEA enters - based on Silkeborg experts
1987 APV takes over Pasilac – expand into Food/other applications
– The nineties: Spiral wound systems + NF and MF applications
Year 2000: DSS, Silkeborg based on 60 % of APV membrane people
– 2003: APV Dairy focused strategy >> Food/other application is closed
– More competitors: Alpma – and local engineering companies
– 2005/06: The APV LeanCreme Process - 11 commercial plants
– 2006: 8” RO and NF is implemented
2006/2007: Market up > Sales up > (+ 60%) > turn around
6
Membrane and MP
- Technology/sales support
List of Key contacts for the Membrane and MP community will be produces*
MP is part of the Membrane portfolio. But MP will be covered in separate presentation
For guidance in who to contact please contact Rikke Haulund
7
The APV membrane team
- dairy technology specialists
8
Membrane Filtration and MP
- Dedicated to the Dairy industry
9
APV Membrane Filtration
- Summary of Dairy References … and others
RO sweet whey/UF perm. (163) 179 188 UF whole milk (121) 140 147
RO skim milk (16) 19 20 UF skim milk (62) 73 77
RO whole milk (12) 13 14 UF fermented milk/cream (65) 77 77
RO buttermilk (3) 3 3 MF milk (18) 37 40
RO acid whey/UF perm. (12) 15 16 MF cheese brine (5) 9 11
RO polishing (5) 14 19 MF Whey - 2 2
NF various purposes (15) 28 37 MP Micropart., incl. PP - 6 18
UF sweet whey (111) 139 142 Various special dairy (10) 10 10
UF acid whey (14) 20 22 Pilot plants (131) 140 141
Module 1 - Questions
1. APV dedicate all our Membrane and MP focus and activity to one
sector/industry. Which sector/industry ?
A. Food Industry
B. Dairy Industry
C. Brewery or others
11
Slide 11
A17 Answers:
1. C
2. C
3. B
4. A
APV, 6/15/2007
APV Academy
Membrane Processing Training Level 1
Module 2-
Principles of Membrane Filtration
Module 2
Learning ojectives
13
What is membrane filtration ?
- Definition
14
Separation Technologies
- Membrane filtration is a molecular
separation technology
15
Dead-End Filtration vs.
Cross Flow Filtration
Dead-end APV systems are based on
filtration Cross flow filtration
Feed
Feed Retentate
Permeate
Permeate
16
The Principles of Membrane
Filtration Processes
Feed
Permeate
Ultrafiltration - UF Microfiltration - MF
Particles, bacteria,
Large molecules Small molecules Salts Water
suspended solids
17
The filtration spectrum
- milk and whey components
40-100 MW
150,000 MW
Ions Immuno-
globulins
2-6µm
100-300 MW Fat
31,000 MW
Salts globules
Rennet
Enzyme 0.1-0.3µm
Casein 5-25µm
50-200 MW
Relative size 18,000- micelles
Yeast, mould
NPN 36,000 MW
of common
Beta-
materials lacto-
342 MW globulin
Lactose 1-5µm
66,000 MW
Bacteria
14,000 MW BSA
Alpha- 10µm
lactal- Somatic
-bumin cells
19
Membranes are the heart
of the Membrane Systems
APV are sourcing the membranes from major producers on
the world market – Performance, quality and price priority
APV is doing its own membrane applications development
– As a result APV has an extensive dairy application knowledge
20
Membrane Filtration Systems
• RO - Reverse osmosis
- RO-P - RO Polisher
• NF - Nanofiltration
• UF - Ultrafiltration
• MF - Microfiltration
6” UF SW system
8” RO/NF and RO_P system
P&F UF system
Retentate
Permeate
Pressure vessel
Feed
Retentate
Permeate
24
2 stage RO / Polisher Plant
- with 8” Modules
25
Ceramic Membranes
27
MF Plant
- Ceramic System
Permeate
Retentate
Feed
28
A18 29
Module 2- Questions
29
Slide 29
A18 Answers:
1. B
2. B
3. A
4. C
APV, 6/15/2007
APV Academy
Membrane Processing Training Level 1
Module 3-
Membrane Applications in the Dairy Sector and
Dairy Segments
Module 3
learning objectives
31
Dairy Applications of
Membrane Filtration
32
RO and NF concentration
- Dairy Application
Concentration and
(demineralisation) of:
– Milk
– Whey
– UF permeate
– White water
Water recovery by
RO Polishing of:
– RO/NF permeate
– Condensate
33
UF - Dairy Applications
Protein concentration
– Whey (WPC, WPI)
– Milk (MPC/MPI)
Protein standardisation
– Cheese milk
– Market milk
– Powder milk
Cheese production
– Feta types
– Fresh cultured types
– Cream cheese
– Queso Fresco
– Other cheeses
34
MF - Dairy Applications
Removal of bacteria
and spores from
– Cheese milk
– Market milk
– Milk for powder
– Cheese whey
Removal of bacteria,
spores, yeast and
mould from cheese
brine
Fractionation of milk
proteins
(Casein/whey protein)
35
Membrane Applications
- in Typical Dairy Segments
Dairy Segments Market milk/fresh
products, drinks, Cheese: Ingredients:
Applications yoghurt, dessert fresh, soft… to hard milk/whey Butter:
MF Debacterisation X X X -
UF Proteinstandardisation X X X -
MF Proteinfractionation X X X -
UF Milk Concentration Yoghurt, dessert Fresh cheese, feta etc. MPC 50/80 Butter milk
RO White Water X X X -
36
MF Brine Purification - X - -
Typical Dairy Applications
- with process parameters
37
Pre-treatment
- Sweet whey from cheese
Compulsory:
– Removal of casein fines and other sediments to a degree that
will give 0.10% or less sediment by centrifugation at 50ºC and
1500 rpm for 5 min. in a Gerber centrifuge
– Fat removal (< 0.06%)
– Pasteurisation*: 72ºC/15 sec. (or equivalent)
Warning: By pasteurisation at temperatures above 80ºC a flux
decrease may be observed. Also milk pasteurisation
temperatures can have this effect. Max. delta T in heat
exchanger: 2ºC
– Inclusion of air must be avoided
Optional:
– pH adjustment (pH 5.9-6.0)
– * If good quality whey Pasteurisation might be optional. However
reservation to quality and running time will be required
38
In line Whey Processing
Process
Cheese water
UF NF RO-P Water
whey CIP water
Process
Cheese water
whey
RO RO-P Water
CIP water
Whey Minerals
concentrate
TS: 1- 2%
TS: 18 %
39
Module 3 –
Preliminary Questions
40
Application of MicroFiltration to
Removal of Bacteria from Milk
Fat standardisation
in line or in tanks
Cream
Retentate
Retentate with bacteria (10%
(10%)
10%)
Pre-
Pre-heater
Skim milk
Raw milk
milk
Psycrotro-
Psycrotro- Total plate Aerobic Anaerobic
Lactobacilli
phic count spores spores
CFU/ml
CFU/ml CFU/ml Spores/ml Spores/l
% Reduction
skim milk/permeate 99.89 99.80 99.68 99.69 98.20
% Reduction
raw milk/cheese milk 99.99 99.94 99.99 98.20 93.00
43
Advantages of MF
Removal of Bacteria from
Milk
Very high retention of bacteria and spores
Cheese milk
– No addition of nitrate => nitrate free cheese
– Removal of spores => no blowing of the cheese
– No lactobacillus => better cheese quality
Market milk: Minimum 50% longer shelf life
– Improved freshness, high and uniform quality
– Improved food safety
– Microfiltered milk can be launched as high quality/high price product
Milk for powder production (Baby Food - and Ingredients)
– No thermophilic bacteria spores in the powder => Improved food safety
– The APV process reduce load of enzymes and endotoxines in the Milk
Powder
Proven and highly reliably APV MF System and Technology
44
UF Milk Processing
- Protein standardisation
- Yoghurt
- Feta, Queso Fresco and Fresh Cultured Cheese
Milk protein
standardisation by UF
Standardised
Whole milk Permeate milk
Standardisation
Separation Ultrafiltration
46 (in line or in tanks)
UF for yoghurt
Advantages:
Standardised protein content Very accurate control of TS
possible: and protein/SNF
– Same protein/SNF ratio all Can operate in-line or batch
year
– Constant product quality Can operate down to 4-5ºC
– Constant product composition Can operate on raw milk (skim
Increased protein/SNF ratio: or whole milk)
– Viscosity / better stability at a No handling of powder
given TS content (storage, dosing, mixing etc.)
47
RO and NF applications
- and RO polishing
RO and NF applications
- and RO polishing
Concentration and/or partiel demineralisation of whey, UF
permeate and milk for:
– Economical transportation
– Pre-concentration prior to evaporation
– Pre-concentration of Whey before UF for
WPC 35 with high TS
– RO recovery of „white“ water
– NF demineralisation (special powder,
baby food)
– NF demineralisation prior to ion-
exchange or ED
– RO polishing of NF and RO Permeate
and evaporation condensate
49
RO white water recovery
Batch tanks
Reverse osmosis
Recirculation of
white water
Permeate:
Recovered
water
Retentate:
Recovered white water
or milk components
50
Fractionation of milk proteins
The APV Pro-Frac™ Concept
Fractionation of Milk Proteins
- molecular separation of casein and
whey proteins
Retentate
Casein rich milk
Skim milk
Permeate
Native “Ideal” whey
Microfiltration
0,1 micron
52
APV Pro-Frac™
53
Advantages of Pro-Frac™
in cheese making
The advantages of protein fractionation in cheese
making are:
– lower cheese milk volume to handle
– lower volume of classical cheese whey (from the cheese
process)
– reduced coagulation time
– reduced amount of rennet
– better firmness of the curd
– increased trapping of casein fines and fat
– slightly higher yield
– innovative processes and cheese types
– incorporation of microparticulated MWPI to achieve higher
yield and low fat cheese with excellent taste
54
New Application for Membrane Processing
APV LeanCremeTM Process
56
Overview of the APV
LeanCremeTM Process
57
New Technology - APV
LeanCremeTM Process
1,000 kg
TOP% 0.80
LAC% 4.49
ACD% 0.15
ASH% 0.50
FAT% 0.06
TS% 6.00
Pre-treatment:
Retentate
- Fines removal Pre-treated
WPC 60
Cheese - Fat removal whey Ultrafiltration
Possible A
whey - Pasteurisation Possible 10°C
storage
72°C/15 sec. storage 8°C
6-8°C
- Cooling 8-10°C
Permeate
60 kg
TOP% 10.08
940 kg LAC% 4.15
TOP% 0.22 ACD% 0.14
LAC% 4.57 ASH% 0.76
ACD% 0.15 FAT% 1.00
ASH% 0.48 TS% 16.13
FAT% 0.00
TS% 4.36
58
New Technology - APV
LeanCremeTM Process
Controlled
shear rate in The heart of the
ASA in order to process is the APV
achieve a Shear
controlled Agglomerator
particle size
distribution
Pre-
Retentate High heating Cooling Cooling in
A heating Holding
WPC 60 in ASA in ASA PHE 5°C
in PHE
60 kg APV LeanCreme™
TOP% 10.08 (can be dried to a
LAC% 4.15 powder product)
ACD% 0.14
ASH% 0.76
FAT% 1.00
TS% 16.13
TOPTS%
62.50
59
New Technology - APV
LeanCremeTM Process
60
Benefits of the APV
LeanCremeTM Process
61
Benefits of the APV
LeanCremeTM Process
62
APV LeanCreme™ - Product Characteristics
63
APV LeanCremeTM Process - Particle
Size Distribution
64
Types and Grades of APV
LeanCreme™
– liquid or powder based
LeanCreme™ Neutral
– Based on sweet cheese whey
LeanCreme™ Lactic
– Based on lactic acid whey or
sweet whey fermented before or after MP or
sweet whey directly acidified before or after MP
LeanCreme™ Plus
– With milk fat/vegetable oil added before or after MP
LeanCreme™ Mix
– Co-precipitate (mix of whey proteins and casein source)
Various grades of above LeanCreme™ products:
– LeanCreme™ 28-35-50-60-70-80 (TOP/TS)
65
Applications of the APV
LeanCremeTM Process
66
Application of APV
LeanCreme™ in Cheese
67
APV LeanCremeTM Process
68
Module 3 –
Final Questions
1. What is LeanCreme?
A. Low calorie fat
B. Microparticulated whey protein
C. An alcoholic beverage
69
APV Academy
Membrane Processing Training Level 1
Module 4 -
Membrane Aftermarket and service
Innovation Centre and Pilot Plant Service
Competition and sales brief
Module 4- Learning
objectives
71
Membrane aftermarket and
service
72
UF of Sweet Whey
Typical (new) enzymatic cleaning procedure
for UF plants with SW membranes
73
APV Innovation Centre
- and Pilot Plants for rental
74
Competition and market size
- systems and membrane after market
Membrane System Players Dairy Industry - Figure 1-5 estimated position. 5 beeing strongest
Membrane System MFB MFF UF NF/RO RO-P MP System . Memb. Total salesRemarks
Company Mio £ Mio £. Mio £
Filt. Engineering Not active Not active 3 3 to 4 2 4,0 0,5 4,5 English spoken countries/India
GEA, US 2 2 4 4 3 5,0 0,8 5,8 Strong in North Am and Austr. NZ
Other players (Kulmus) (Kulmus) 1,5 0,2 1,7 Increased no of small plyers - Very low price
75
Market trends
- key investment drivers
Value added dairy and food products
– Ingredients growth – protein (healthy) food
– Extended shelf life (ESL) milk drinks
Fermented milk products – drinks
– Growing cheese production – 2 - 3 % pa
Increased whey amount… and utilisation. Whey price up!
Legislation issue – not allowed to dump the whey
Increased fast food cheese… and low fat cheese
Water and energy saving – cost and environmental
Advance processing – MF-ESL, ProFrac and MP
– Cost optimisation and more out of the milk
– New innovative products
Emerging membrane markets and markets up!
– Eastern Europe and China.. and and..
– Increased membrane potential, 7 -10 % pa
76
APV Membrane Filtration
- sales brief
78
Module 5 – Questions
79