‘MODULE: Calculating pit Calculating pH during titration ‘Consider diffrent titration types: 4. Strong acid-strong base 2 Strong acld-weak base 3. Strongbese-weak acid * Weak aci-weak base titrations are not feast since the reaction ‘does not proceed to completion. This results to an endpoint that is and thas no eultable indicator may be used. ‘Bx. 50,00 mL of 0.1000 M HCI is titrated with 0.100 M NaOH. Calculate pl when the flowing volume of titrant is added: ‘2 Onl (pH ofa strong acid) 1. 10m (acd is in excess) < S0mL (sak) ‘d. GO, (bases in excess) Tx 50.00 mL of 0.0500 M NaN is titrated with 0.100 M HCL Ka of HCN =62x 10%. ‘2 Write the balanced chemical equation 1b Based on (a) what Keq shouldbe used for (1? © Calculate the pH of the solution when the following volumes of titrant are added: L Oml (treatas weak base) L100 ml (CN + He > what is formed? Treat as buffer system) ‘Mh 25.0. (treat as weak acid) ‘y, 260ml (strong acid trant i in excess) Buffer preparation x Dest the preparation of 09m. 0.10 ast act eae baler with apltor4 Sto 020M acd and OS0M stack sont Solution. Calcuatn total moles of buffer components based ov the ‘ven stock solutions tobe used. “Total mols buffer = (volume of buffer) x (concentration of buffer) ‘mols of acid cormponent + moles salt component += (0200 1)(0.10M) = 0.0200 mol Using the Henderson Hasselbalch equation, determine the mumber of ‘moles ofthe acid and salt tobe used in preparing the buffer: pH = pK, + log Si Required p> 450 = 474+ log ft (note that Kacecsoe=t 8x 10°) log ttl 45 — 474 = 0.24 HEB = enctiog(-0.24) = 0575 or SS = 1.74 eae xtamurotatvonan affor mates ste ‘Wasa Lelia vous bef fr ots eid ™ 0575 ‘There are two working equations and two unknowns used to ‘calculate forthe moles ofthe buffer components: ferences: Hare. Quantative Chemical Anaya. 2007. WH Freeman and Co ‘Cha 17 Lab Manual nut of Chemistry, UP Dimas ‘MODULE: Calelating pit Propared by CMPR| Page of2‘Let S= moles salt A= moles acid S=0575A, a) $¢A=00200 mol (2) > total mol buer Using systems of equations for (1) and (2) to solve for Sand A gives ‘A= 00127 ma '$=00730 mol From the corresponding stock solutions, the volume of acid and salt ‘components can be calculated ‘Volume of 0.20 M acetic eld = 0.0127 mol/0.20M 00635 636m. ‘Volume of 0.50 sodium acetate = 0.00730 mol/0.50 M =00146L 46 mL. Mix 635 mL0.20M acetic seid and 14 ml-of 50 M sodium acetate. Dilute solution to 200 mL with distilled water. Determine the pH ofthe solution witha pH mater. ‘Adjust the pH is necessary, by the addition of ether acid or salt [Ex Describe the preparation of 250 mL. 1.00 M NH-NHet baler solution of pH 100 from ammonium chloride crystals and ‘concentrated ammonium hydride solution Nis=174M. NHcl=53.4917 g/mol Kt, NH = 1.0 10°" ‘it: Calculate needed amount of moles weak base and moles salt From here, calculate the needed amount of ammonium chloride (salt) ‘and ammontum hydroxide (base). Answer Key: 50,00 m.of 0.1000 M HC! Is titrated with 0.100 M NaOH, Calculate ‘pH when the following volume of titrant is added: ‘2 Om (pH of astrong acid) 91. 10m acids inexcess) 94.17 © S0rL (salt) 37 4 60m, (bases inexcess) 911.96 50,00 ml of 0.0500 M NaCN is titrated with 0.100 M HCL Ka of HCN = 62x10". C+ Hs0+ @ HEN + OH 1h Since OH—was produced, Kb should be used Calculate the pH of the solution when the following volumes of tran are added ¥. Oral (treat a weak base) 10.95 ‘vb 100 mL (CN + He-> what is formed? Treat as buffer system) > 9.38 ‘vt 250 ml (treatas weak acd) > 5.34 ‘il. 26.0 ma. (strong acd titrant sn excess) > 2.88 Describe the preparation of 250 ml. 0 M NH-NHe+ buffer solution of pH 10 from ammonium chloride crystals and concentrated ‘ammonium hydroxide solution, NHy=0.212 mol> 122 mL. [NHCl = 0.0385 mal > 2.06 g Ieterences: Mass. Quantitative Chemical Analysis. 2007. Wit Freeman and Co. ‘Chen 17 tab Marl Intute of Chemistry, UP Diiman (MODULE: Calculating pH | Prepared by CMR | Page 2 of2