11/7/2018 Chemistry: Atomic Structure and Chemical Bonding - - Unit 9 - Week 6

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Unit 9 - Week 6

Course
outline Assignment 6
The due date for submitting this assignment has passed. Due on 2018-09-12, 23:59 IST.
How to access
the portal Assignment submitted on 2018-09-12, 19:14 IST

Pre-requisite 1) The d-orbital function from the imaginary part of the spherical harmonic Y
−2
2
(θϕ) will be 1 point
Assignment designated as

Lecture Materials
dxz

Week 1
dxy

Week 2
dyz
Week 3

dx2 −y 2
Week 4
Yes, the answer is correct.
Week 5 Score: 1
Accepted Answers:
Week 6
dxy

Quiz :
2) The spherical harmonic whose angular part is given by 2 cos
3
θ − 3 cos θ sin
2
θ is denoted 1 point
Assignment 6
by the symbol
Lecture 28 -
Hermite’s
Differential 3
Y (θϕ)
Equation 3

Lecture 29 - Y
2
(θϕ)
3
Legendre and
Associated
1
Legendre Y
3
(θϕ)
Equation
0
Lecture 30 - Y
3
(θϕ)

Born-
Oppenheimer Yes, the answer is correct.
Approximation Score: 1

Week 6 Accepted Answers:

Feedback Y
0
3
(θϕ)

Week 7 3) The d orbital from the spherical harmonic Y

0
2
(θϕ) is represented correctly as 1 point

Week 8

https://onlinecourses.nptel.ac.in/noc18_cy19/unit?unit=58&assessment=59 1/4
11/7/2018 Chemistry: Atomic Structure and Chemical Bonding - - Unit 9 - Week 6
d2z 2 −x2 −y 2
Week 9

dz 2
Week 10

dx2 −y 2
Week 11

Week 12 d z 2 −y 2

DOWNLOAD No, the answer is incorrect.

VIDEOS Score: 0
Accepted Answers:
d2z 2 −x2 −y 2

4) The orthogonality of two spherical harmonics Y

l
−m
(θϕ) and Y
l
−m
(θϕ) is represented 0 points
correctly by the integral

π 2π

∗
m −m
∫ sin θdθ ∫ [Y (θϕ)] Y (θϕ)dϕ
l l

0 0

π 2π

∗
m −m
∫ dθ ∫ [Y (θϕ)] Y (θϕ)dϕ
l l

0 0

π 2π

m −m
∫ dθ ∫ [Y (θϕ)] Y (θϕ)dϕ
l l

0 0

π 2π

m −m
∫ sin θdθ ∫ [Y (θϕ)] Y (θϕ)dϕ
l l

0 0

No, the answer is incorrect.

Score: 0
Accepted Answers:
π 2π

∗
m −m
∫ sin θdθ ∫ [Y (θϕ)] Y (θϕ)dϕ
l l

0 0

5) The number of nodes in a f function is 1 point

Yes, the answer is correct.

Score: 1
Accepted Answers:
3

6) The number of nodes in a 5f orbital is 1 point

https://onlinecourses.nptel.ac.in/noc18_cy19/unit?unit=58&assessment=59 2/4
11/7/2018 Chemistry: Atomic Structure and Chemical Bonding - - Unit 9 - Week 6

Yes, the answer is correct.

Score: 1
Accepted Answers:
4

7) The total number of degenerate orbitals for principal quantum number n is 1 point

2
n

n−1

n+1

3
n

Yes, the answer is correct.

Score: 1
Accepted Answers:
2
n

8) The hydrogen atom wave functions with radial and angular parts together are given in the 1 point
lecture notes. Study the trends. This and the next two questions will be to identify the quantum numbers
and energies associated with the hydrogen atom wave functions. The wave function
−−− 3/2 2
1 Z Zr
ψ
nlm
(r, θ, ϕ) = ∓√ ( ) ( ) e
−Zr/3a0
cos θ sin θe
±iϕ
is correctly labeled as
3π 3a0 3a0

3p
y

3px

3d±1

3pz

Yes, the answer is correct.

Score: 1
Accepted Answers:
3d±1

9) 1 5/2
1 point
The wave function ψnlm (r, θ, ϕ) =
− −
(
1

a0
)
−r/2a0
re sin θ sin ϕ is correctly
4√ 2π
labeled as

2s

2p
x

https://onlinecourses.nptel.ac.in/noc18_cy19/unit?unit=58&assessment=59 3/4
11/7/2018 Chemistry: Atomic Structure and Chemical Bonding - - Unit 9 - Week 6

2py

2pz

No, the answer is incorrect.

Score: 0
Accepted Answers:
2py

10)The probability density function 1 point

7
2
2
1 1
|ψ
nlm
(r, θ, ϕ)| sin θ r
2
= ( ) r e
6 −2r/3a0 2
(3cos θ − 1) sin θ corresponds to the
2
81 × 2π
2 a0

orbital labeled as

3d(2z 2 −x2 −y 2 )

3dx2 −y 2

3dxz

3dyz

Yes, the answer is correct.

Score: 1
Accepted Answers:
3d(2z 2 −x2 −y 2 )

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