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Fire Safety Journal 44 (2009) 370–375

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Fire Safety Journal


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Performance of olive waste ash concrete exposed to elevated temperatures


Nabil M. Al-Akhras a,, Khaled M. Al-Akhras a, Mousa F. Attom b
a
Civil Engineering Department, Jordan University of Science and Technology, Irbid, Jordan
b
Civil Engineering Department, American University of Sharjah, Sharjah, UAE

a r t i c l e in f o a b s t r a c t

Article history: This study explores the influence of olive waste ash (OWA) on the performance of concrete exposed to
Received 18 March 2008 elevated temperatures in the range from 400 to 600 1C. The performance of concrete to elevated
Received in revised form temperature was evaluated using compressive strength and electrical charge of concrete. Three OWA
16 August 2008
levels were used in the study: 7%, 15%, and 22% by weight of cement. The other experimental parameters
Accepted 25 August 2008
investigated in the study were elevated temperature (400 and 600 1C), aggregate type (crushed basalt
Available online 18 October 2008
and volcanic tuff), w/c ratio (0.5 and 0.7), and air content (non-air and air entrained). After the initial
Keywords: moist curing period of 90 days, concrete specimens were exposed to elevated temperatures for a period
Olive waste ash of 2 h using an electric furnace.
Elevated temperatures
The study showed that the performance of OWA concrete to elevated temperatures is higher than
Concrete
that of the control concrete. Additionally, the performance of OWA concrete to elevated temperature
Compressive strength
Electrical charge increased when the OWA content was increased. The resistance of OWA concrete containing tuff
aggregate to elevated temperatures was observed higher compared to OWA concrete containing basalt
aggregate. The OWA concrete at w/c ratio of 0.5 was found to be more resistant to elevated temperatures
than that of OWA concrete at w/c ratio of 0.7. The performance of the air entrained OWA concrete to
elevated temperature was observed higher compared to the non-air entrained OWA concrete.
& 2008 Elsevier Ltd. All rights reserved.

1. Introduction temperatures. The resistance of concrete incorporated ultra-fine


cementing materials such as silica fume and metakaolin to
Exposing concrete structures to high temperatures (above elevated temperatures were found lower compared to control
200 1C) from accidental fire or elevated temperatures from concrete [1–5].
industrial plants produce high internal tensile stresses that cause The use of volcanic ash and fly ash in concrete mixes was
cracking and damage of concrete structures. The compressive reported to enhance the performance of concrete to elevated
strength of concrete decreases significantly upon exposing to temperatures (especially below 500 1C) compared to control
elevated temperatures. Therefore, the residual compressive concrete [6–11].
strength (RCS) is an important factor to assess the strength of Many relatively new supplementary cementing materials such
concrete after exposed to accidental fire. It is vital to have a high as rice husk ash, wheat straw ash, and tire rubber ash were
RCS of concrete exposed to fire to preserve the integrity of the utilized in concrete mixtures that increased the performance and
whole concrete structure. Many features affect the performance of strength of concrete material [12–18].
concrete to elevated temperatures such as mix proportions, curing Olive waste ash (OWA) is a new supplementary cementing
period, aggregate type, and presence of supplementary cementing material that is acquired by incinerating huge amounts of olive
materials. mill waste and collecting the resulting ash. The olive mill waste
The use of supplementary cementing materials such as silica materials are the materials that left after the olive oil had been
fume, fly ash, and blast-furnace slag in concrete mixtures had extracted from the olive fruits and contains olive pulp, husk, and
been observed an efficient technique to improve the strength and residual oil. However, no research studies are reported in the
properties of concrete material. Many research studies are found literature concerning the effect of OWA on the resistance of
in the literature pertaining the influence of supplementary concrete to elevated temperatures.
cementing materials on the resistance of concrete to elevated The main objective of this study is to investigate the influence
of OWA on the performance of concrete to elevated temperatures
under different experimental parameters including: OWA content
 Corresponding author. (0%, 7%, 15%, and 22%), aggregate type (crushed basalt and
E-mail addresses: alakhras@just.edu.jo (N.M. Al-Akhras), volcanic tuff), w/c ratio (0.5 and 0.7), and air entrainment (non-
mattom@aus.edu (M.F. Attom). air entrained and air entrained).

0379-7112/$ - see front matter & 2008 Elsevier Ltd. All rights reserved.
doi:10.1016/j.firesaf.2008.08.006
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N.M. Al-Akhras et al. / Fire Safety Journal 44 (2009) 370–375 371

2. Experimental program

2.1. Materials

Ordinary portland cement was used in preparing the concrete


mixtures. The physical properties and chemical composition of
the cement are presented in Tables 1 and 2, respectively.
Two types of aggregates (crushed basalt and volcanic tuff)
were used in the study. The physical properties of the coarse and
fine aggregates used are presented in Table 3.
OWA was obtained by incinerating large amounts (250 kg) of
olive mill waste in an oven at a temperature of about 800 1C for
8 h. The OWA (about 30 kg) that resulted from incinerating the
olive mill waste materials was collected from the oven and finely
ground for 3 h. Olive mill waste materials contain about 12% OWA.
The resulting OWA is finer than type I cement, contains 42% lime
and 25% amorphous silica, had gray color and Blaine fineness of
410 m2/kg. Fig. 1 shows a scanning electron micrograph of OWA
particles. Most particles of OWA are irregular in shape and some
particles are rounded. The physical properties and chemical
composition of the OWA are presented in Tables 1 and 2,
respectively.
The superplasticizer used (Daracem SP6) was based on
Fig. 1. Scanning electron micrographs of OWA particles.
sulfonate naphthalene formaldehyde and had a dark brown color,
solid content of 33%, and specific gravity of 1.22. The super-
plasticizer was incorporated in all concrete mixtures to obtain investigate the effect of air entrainment on the resistance of
workable concrete mixtures. OWA concrete to elevated temperatures.
An air entraining admixture (Darex AE3) was utilized in one
concrete mixture to obtain air entrained concrete and to 2.2. Mixtures details

Seven concrete mixtures were used to explore the influence of


OWA on the resistance of concrete to elevated temperatures.
Table 1 Details of the concrete mixtures are presented in Table 4.
Physical properties of the cement and OWA used in the study
Concrete mixtures 1, 2, 3, and 4 were designed using w/c ratio
Property Cement OWA
of 0.5, basalt aggregate and the OWA contents levels were 0%, 7%,
15%, and 21% by weight of cement, respectively. These concrete
Specific gravity 3.15 2.13 mixtures were used to investigate the effect of OWA on the
Blaine fineness (m2/kg) 330 410 resistance of OWA concrete to elevated temperatures.
Average particle size (mm) 12 10
Concrete mixture 5 was designed using w/c ratio of 0.5, tuff
Color Gray Gray
aggregate, and 15% OWA content. This concrete mixture was used
to investigate the effect of aggregate type on the resistance of
Table 2 OWA concrete to elevated temperatures.
Chemical composition of the cement and OWA used in the study Concrete mixture 6 was designed using w/c ratio of 0.7, basalt
aggregate, and 15% OWA content. This concrete mixture was used
Compound (%) Cement OWA
to investigate the effect of w/c ratio on the resistance of OWA
SiO2 20.5 25.3
concrete to elevated temperatures.
Al2O3 5.6 7.4 Concrete mixture 7 was designed as air entrained using basalt
Fe2O3 3.8 4.6 aggregate and 15% OWA content. An air entraining admixture was
MgO 2.1 3.2 incorporated in this concrete mixture to obtain air entrained
CaO 64.5 42.4
concrete and to investigate the effect of air entrainment on the
Na2O 0.2 0.45
K2O 0.2 3.3 resistance of OWA concrete to elevated temperatures.
SO3 2.1 3.7
Loss on ignition 0.8 9.5
2.3. Specimen preparation

Table 3 Two types of concrete specimens were used in the study:


Physical properties of the aggregates used in the study 10 cm cubes and 10  20 cm cylinders. The compressive strength
of concrete mixtures was measured using the cubic specimens.
Aggregate Dmax BSG Absorption FM (%) Unit
The electrical charge of concrete was measured using slices (5 cm
(mm) (%) weight
(kg/m3) in height  10 cm in diameter) cut from the cylindrical specimens
(20 cm in height  10 cm in diameter). Casting of concrete speci-
Basalt CA 12.5 2.55 2.2 – 1470 mens was conducted in three layers. Each layer was consolidated
Basalt FA 4.75 2.57 2.7 2.6 – using a vibrating table to decrease the entrapped air voids. After
Tuff CA 12.5 2.30 6.8 – 880
Tuff FA 4.75 2.20 8.1 2.5 –
vibrating the filled molds, the concrete surface was finished
smooth using a steel trowel and left in the casting room for 24 h.
FM: fineness modulus, Dmax: maximum aggregate size, BSG: bulk specific gravity. The concrete specimens were demolded, labeled as to the mixture
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372 N.M. Al-Akhras et al. / Fire Safety Journal 44 (2009) 370–375

Table 4
Proportions of concrete mixture (kg/m3) used in the study

Mix OWA (%) w/c Cement (kg) OWA (kg) W (kg) CA (kg) FA (kg) Aggregate SP (%) AE (%)

1 0 0.5 460 0 230 920 730 Basalt 1.2 –


2 7 0.5 428 32 230 920 730 Basalt 1.4 –
3 15 0.5 391 69 230 920 730 Basalt 1.5 –
4 22 0.5 359 101 230 920 730 Basalt 1.6 –
5 15 0.5 391 69 230 530 520 Tuff 1.5 –
6 15 0.7 280 49 230 920 730 Basalt 0.7 –
7 15 0.5 391 69 230 920 680 Basalt 0.7 0.8

SP: superplasticizer, AE: air entraining admixture, CA: coarse aggregate, FA: fine aggregate.
Dosages of SP and AE admixtures are reported as percent by weight of cement.

Table 5 800
Compressive strength (MPa) of the concrete mixtures used after 90 days of curing 400 C

Elevated Temperature (C)


Mixture 1 2 3 4 5 6 7
600 C
600
Compressive strength 34.7 34.1 33.6 33.2 24.3 23.5 31.7

Average of three specimens.


400

type and cured in a water tank for an initial moist curing period of
90 days. Three concrete specimens (cubes and cylinder slices) 200
were prepared and tested in the study for each test condition
to obtain average values. Table 5 shows the compressive
strength of the concrete mixtures used in the study after 90 days 0
of moist curing. 0 2 4 6 8 10 12 14 16 18 20 22
Time (hour)
2.4. Test procedures
Fig. 2. A schematic diagram for the thermal treatment used in the study.

The concrete mixtures were mixed and prepared using a tilting


drum mixer of 0.04 m3 capacity according to ASTM C192-02. The elevated temperatures experience cracks and deterioration that
workability of concrete mixtures was measured using the slump increase the porosity of concrete. Therefore, the electrical charge
test according to ASTM C143-03. The workability of all concrete passed through concrete is a good indication of the cracks and
mixtures was comparable with a slump values ranging from 5 to deterioration of concrete exposed to elevated temperatures. The
10 cm. The air content of the fresh concrete was measured using rapid chloride permeability test was performed on cylindrical
the pressure method according to the ASTM C231-04. slices (10 cm in diameter  5 cm in height) cut from cylindrical
The compressive strength of concrete cubes was measured specimens. The cylindrical slices were placed in the chloride
using a universal testing machine at a stress rate of 0.4 N/mm2/s. permeability test cell that has two faces. The first face of the
The RCS was calculated using the following equation: concrete specimen was saturated with sodium hydroxide and
the second face was saturated with sodium chloride. A potential
selev voltage of 60 V was applied through the concrete specimen and
RCS ¼  100
s23 the electrical charge passed was calculated from the product of
where selev is the compressive strength of concrete cubes (MPa) the current and the time (modified ASTM C 1202-05).
exposed to elevated temperature of 400 and 600 1C, and s23 is
the compressive strength of concrete cubes (MPa) at ambient
temperature of 23 1C.
After the initial moist curing period of 90 days, concrete 3. Results and discussion
specimens were removed from the water tank and left in the
laboratory air for one week. After which, concrete specimens were 3.1. OWA content
exposed to thermal treatment at different elevated temperatures
of 400 and 600 1C using an electrical furnace. Fig. 2 shows a The study investigated the effect of three OWA contents (7%,
schematic diagram for the thermal treatment of the concrete 15%, and 22%) on the performance of concrete to elevated
specimens used in the study. The elevated temperatures used temperatures. The effect of OWA content on the RCS of concrete
were selected to simulate an actual concrete structures subjected is shown in Fig. 3.
to accidental fire. The thermal treatment regime used consists The RCS of OWA concrete decreased significantly with
of a heating ramp of 4 h for the elevated temperature of 400 1C and increasing the elevated temperature. The OWA concrete exposed
6 h for the elevated temperature of 600 1C at a heating rate of to elevated temperatures showed cracks and deterioration that
1.67 1C/min, followed by a hold time at the specified temperature increased with increasing the elevated temperature. The increase
(400 or 600 1C) for 2 h, followed by a cooling ramp of 8 h for the of the damage of OWA concrete with increasing the exposed
elevated temperature 400 1C and 12 h for the elevated tempera- elevated temperature is attributed to the following factors: (1) the
ture of 600 1C at a cooling rate of 0.83 1C/min. build up of vapor pressure due to the evaporation of the free,
The rapid chloride permeability test was used in the study adsorbed and, chemically bound water in the hydrated cement
to measure the electrical charge passed through concrete that paste matrix of the OWA concrete and (2) the degradations of the
indicate indirectly the porosity of concrete. Concrete exposed to CSH gel in the cement paste matrix of the OWA concrete.
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Residual Compressive Strength (%) N.M. Al-Akhras et al. / Fire Safety Journal 44 (2009) 370–375 373

100 100

Residual Compressive Strength (%)


400 C 600 C Basalt Tuff

80 80

60 60

40 40

20 20

0 0
0 7 15 22 0% at 400 C 15% at 400 C 0% at 600 C 15% at 600 C
OWA Content (%) Percent OWA at Exposed Temperature

Fig. 3. Effect of OWA content on the residual compressive strength of OWA Fig. 5. Effect of aggregate type on the residual compressive strength of plain and
concrete exposed to elevated temperatures. OWA concrete exposed to elevated temperatures.

10000 to 600 1C decreased from 8600 C for control concrete to 3400 C for
400 C 600 C the 22% OWA concrete.
Electrical Charge (Coulomb)

The increase in the performance of OWA concrete to


8000
elevated temperatures with increasing the OWA replace-
ment level is attributed to the pozzolanic effect and filler action
6000 of OWA that increased the resistance of OWA to elevated
temperatures.
4000
3.2. Aggregate type
2000 The study investigated the effect of two aggregate types
(crushed basalt and volcanic tuff) on the performance of plain and
0 OWA concrete to elevated temperatures. The effect of aggregate
0 7 15 22 type on the RCS of concrete exposed to elevated temperatures is
OWA Content (%) shown in Fig. 5.
The plain and OWA concrete with tuff aggregate showed higher
Fig. 4. Effect of OWA content on the electrical charge passed through OWA performance to elevated temperature than the OWA concrete with
concrete exposed to elevated temperatures.
basalt aggregate. The RCS of plain and OWA concrete including
tuff aggregate increased significantly compared to plain and OWA
concrete including basalt aggregate. The RCS of plain concrete
The performance of OWA concrete to elevated temperatures is exposed to 400 1C increased from 52% for plain concrete contain-
found more than that of control concrete. Additionally, the ing tuff aggregate to 63% for plain concrete containing basalt
performance of OWA concrete to elevated temperature increased aggregate. However, the RCS of OWA concrete exposed to 400 1C
with increasing the OWA contents from 7% to 22%. The RCS increased from 64% for OWA concrete containing tuff aggregate to
increased from 52% to 71% while increasing the OWA content from 83% for OWA concrete containing basalt aggregate. The effect of
0% to 22% for OWA concrete exposed to elevated temperature of aggregate type on the RCS of concrete exposed to elevated
400 1C. However, for OWA concrete exposed to elevated tempera- temperatures is more pronounced for OWA concrete than that
ture of 600 1C, the RCS increased from 23% to 43% when the OWA for plain concrete.
replacement level was increased from 0% to 22%. Fig. 6 shows the effect of aggregate type on the electrical
Fig. 4 shows the effect of OWA content on the electrical charge passed through plain and OWA concrete exposed to
charge passed through concrete exposed to elevated tempera- elevated temperatures. The plain and OWA concrete containing
tures. The electrical charge of OWA concrete increased signifi- tuff aggregate showed lower electrical charge (representing
cantly (indicating more cracks and damage) when the elevated higher performance to elevated temperatures) than that of plain
temperature was increased. The electrical charge increased and OWA concrete containing basalt aggregate. The electrical
significantly from 5400 to 8600 C for control concrete and from charge decreased significantly for plain and OWA concrete
1800 to 3400 C for the 22% OWA concrete exposed to 400 and with tuff aggregate compared to plain and OWA concrete
600 1C, respectively. The increase in the electrical charge of OWA with basalt aggregate. The percent decrease in the electrical
concrete with increasing exposed temperature is explained by the charge was 20% and 22% for plain concrete exposed to elevated
increase of cracks and damage in concrete specimens exposed temperature of 400 and 600 1C, respectively. Meanwhile, the
to elevated temperature that increased the electrical charge of electrical charge showed higher decrease for OWA concrete
OWA concrete. with tuff aggregate compared to OWA concrete with basalt
The electrical charge passed through OWA concrete exposed aggregate. The percent decrease in the electrical charge was 45%
to elevated temperatures decreased (indicating less cracks and and 43% for OWA concrete exposed to elevated temperature
damage) with increasing the OWA content from 7% to 22%. The of 400 and 600 1C, respectively. The effect of aggregate type
electrical charge of OWA concrete exposed to 400 1C decreased on the electrical charge of concrete exposed to elevated tempe-
from 5400 C for control concrete to 1800 C for the 22% OWA ratures is more pronounced for OWA concrete than that for
concrete. However, the electrical charge of OWA concrete exposed plain concrete.
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374 N.M. Al-Akhras et al. / Fire Safety Journal 44 (2009) 370–375

10000 10000
Basalt Tuff w/c = 0.5
Electrical Charge (Coulomb)

Electrical Charge (Coulomb)


w/c = 0.7
8000 8000

6000 6000

4000 4000

2000 2000

0 0
0% at 400 C 15% at 400 C 0% at 600 C 15% at 600 C 400 600
Percent OWA at Exposed Temperature Exposed Temperature (C)

Fig. 6. Effect of aggregate type on the electrical charge passed through plain and Fig. 8. Effect of w/c ratio on the electrical charge passed through OWA concrete
OWA concrete exposed to elevated temperatures. exposed to elevated temperatures.

Residual Compressive Strength (%)


Residual Compressive Strength (%)

100 100
w/c = 0.5 Non-Air Entrained
80 w/c = 0.7 80 Air Entrained

60 60

40 40

20 20

0 0
400 600 400 600
Exposed Temperature (C) Exposed Temperature (C)

Fig. 7. Effect of w/c ratio on the residual compressive strength of OWA concrete Fig. 9. Effect of air content on the residual compressive strength of OWA concrete
exposed to elevated temperatures. exposed to elevated temperatures.

The increase in the performance of OWA concrete including charge (indicating more resistance at elevated temperatures) than
tuff aggregate to elevated temperatures compared to OWA that of OWA concrete at w/c ratio of 0.7. The electrical charge
concrete including basalt aggregate is attributed to the low unit decreased significantly for OWA concrete at w/c ratio of 0.5
weight and specific gravity of the tuff aggregate compared to that compared to OWA concrete at w/c ratio of 0.7. The percent
of the basalt aggregate. Therefore, the porosity of the tuff decrease in the electrical charge was 58% and 52% for OWA
aggregate is higher than that of basalt aggregate. Upon exposing concrete exposed to elevated temperature of 400, and 600 1C,
concrete including tuff aggregate to elevated temperatures, the respectively.
vapor pressure built up will escape to the pores of the tuff The increase in the performance of OWA concrete exposed
aggregate and relieving the pressure induced in the concrete. to elevated temperatures at w/c ratio of 0.5 compared to the
OWA concrete at w/c ratio of 0.7 is explained that the OWA
concrete at w/c ratio of 0.7 had large capillary pores that filled
3.3. Water to cement ratio
with water compared to OWA concrete at w/c ratio of 0.5. Thus,
the vapor pressure induced in the OWA concrete at w/c ratio of 0.7
The study investigated the effect of two w/c ratios (0.5 and 0.7)
was increased significantly compared to OWA concrete at w/c
on the resistance of OWA concrete to elevated temperatures. The
ratio of 0.5.
effect of w/c ratio on the RCS of OWA concrete exposed to elevated
temperatures is shown in Fig. 7.
The OWA concrete at w/c ratio of 0.5 showed higher 3.4. Air entrainment
performance to elevated temperature than that of OWA concrete
at w/c ratio of 0.7. The RCS of OWA concrete exposed to elevated The study investigated the effect of two air contents (non-air
temperatures at w/c ratio of 0.5 increased significantly compared entrained and air entrained) on the resistance of OWA concrete to
to OWA concrete at w/c ratio of 0.7. The RCS of OWA concrete elevated temperatures. The effect of air content on the RCS of OWA
exposed to 600 1C decreased from 36% for OWA concrete at w/c concrete exposed to elevated temperatures is shown in Fig. 9.
ratio of 0.5–19% for OWA concrete at w/c ratio of 0.7. The air entrained OWA concrete showed higher performance to
Fig. 8 shows the effect of w/c ratio on the electrical charge elevated temperature than the non-air entrained OWA concrete.
passed through OWA concrete exposed to elevated temperatures. The RCS of the air entrained OWA concrete increased significantly
The OWA concrete at w/c ratio of 0.5 showed lower electrical compared to the non-air entrained OWA concrete. The RCS of OWA
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N.M. Al-Akhras et al. / Fire Safety Journal 44 (2009) 370–375 375

10000 improved by inclusion of OWA into the concrete mixtures. Earlier


Non-Air Entrained studies have shown that the utilization of fly ash and volcanic ash
improved the resistance of concrete exposed to elevated tem-
Electrical Charge (Coulomb)

Air Entrained
8000
peratures. Nevertheless, the incorporation of other supplementary
cementing materials such as silica fume and metakaolin reduced
6000 the resistance of concrete exposed to elevated temperatures.
Based on the outcomes obtained from this study, the following
4000
conclusions may be drawn:

1. The performance of OWA concrete exposed to elevated


2000 temperatures was observed to be better compared to control
concrete. Moreover, the performance of OWA concrete exposed
0 to elevated temperatures increased while the OWA content
400 600 was increased from 7% to 22%.
Exposed Temperature (C) 2. The plain and OWA concrete containing tuff aggregate showed
higher performance to elevated temperatures than that of
Fig. 10. Effect of air content on the electrical charge passed through OWA concrete plain and OWA concrete containing basalt aggregate.
exposed to elevated temperatures.
3. The performance of OWA concrete exposed to elevated
temperatures at w/c ratio of 0.5 was observed to be better
concrete exposed to 400 1C increased from 64% for the non-air compared to OWA concrete at w/c ratio of 0.7.
entrained OWA concrete to 78% for the air entrained OWA 4. The performance of the air entrained OWA concrete to elevated
concrete. temperatures was observed to be better compared to the non-
Fig. 10 shows the effect of air entrainment on the electrical air entrained OWA concrete.
charge passed through OWA concrete exposed to elevated
temperatures. The air entrained OWA concrete exposed to
elevated temperatures showed lower electrical charge (indicating
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