ch16 Ques 2013 PDF

Chapter Sixteen
Topic: Introduction to NMR

Section: 16.1
Difficulty Level: Easy
1. Which of the following can not be probed by an NMR spectrometer?
A) nucleus with odd number of protons & odd number of neutrons

B) nucleus with odd number of protons &even number of neutrons
C) nucleus with even number of protons & odd number of neutrons
D) nucleus with even number of protons & even number of neutrons
E) none of these
Ans: D

Section: 16.1
2. How many nuclear spin states are possible for the 1H nucleus?
A) 1
B) 2
C) 4
D) 5
E) none of these
Ans: B

Section: 16.1
3. Which of the following electromagnetic radiation is used in NMR spectroscopy?
A) UV
B) IR
C) visible
D) γ-rays
E) radio wave
Ans: E

Section: 16.1
Difficulty Level: Medium
4. _______ protons experience a net magnetic field strength that is smaller than the applied
magnetic field.
A) deshielded
B) shielded
C) paramagnetic
D) diamagnetic
E) none of these
Ans: B

Section: 16.1
5. _______ protons experience a net magnetic field strength that is higher than the applied
magnetic field.
A) deshielded
B) shielded
C) paramagnetic
D) diamagnetic
E) none of these
Ans: A
Topic: Acquiring a 1HNMR spectrum

Section: 16.2
6. Which of the following is true about the relationship between the energy gap (ΔE)
between the spin states for a 1H nucleus and the strength of the external magnetic field?.
A) they are inversely proportional
B) they are directly proportional
C) there is no relationship
D) the magnetic field is slightly less
E) none of these
Ans: B

Section: 16.2
7. The strength of the magnetic field is a determining factor for the range of _______that
must be used for NMR spectrometer.
A) temperature
B) frequencies
C) tesla
D) spin states
D) none of these
Ans: B

Section: 16.2
8. Which of the following is not a common solvent used for acquiring a 1H NMR
spectrum?
A) CDCl3
B) CCl4
C) CD3CN
D) CH3OH
E) D2O
Ans: D
Topic: Characteristics of a 1HNMR spectrum

Section: 16.3
9. Which of the following is true about the number of signals in a 1H NMR spectrum?
A) it indicates the number of neighboring protons

B) it indicates the electronic environment of neighboring protons
C) it indicates the number of different kinds of protons
D) it indicates the electronic environment of absorbing protons
E) it indicates the number of protons in the signal
Ans: C

Section: 16.3
10. Which of the following is true about the location of signals in a 1H NMR spectrum?

C) it indicates the number of different protons
Ans: D

Section: 16.3
11. Which of the following is true about the area under each signal in a 1H NMR spectrum?

Ans: E

Section: 16.3
12. Which of the following is true about the shape of the signal in a 1H NMR spectrum?

Ans: A
Topic: Number of signals

Section: 16.4
13. Which of the following type of protons are chemically non equivalent?
A) homotopic
B) enantiotopic
C) diastereotopic
D) A&B
E) B&C
Ans: C

Section: 16.4
14. Which of the following type of protons are chemically equivalent?
A) homotopic
B) enantiotopic
C) diastereotopic
D) A&B
E) B&C
Ans: D

Section: 16.4
15. Protons Ha and Hb in the following compound are _________.

Ha Hb
A) homotopic
B) enantiotopic
C) diastereotopic
D) mesotopic
E) none of these
Ans: A

Section: 16.4
Ha Hb
A) homotopic
B) enantiotopic
C) diastereotopic
D) mesotopic
E) none of these
Ans: B

Section: 16.4

Ha
Hb
A) homotopic
B) enantiotopic
C) diastereotopic
D) mesotopic
E) none of these
Ans: C

Section: 16.4
Br H
Hb
Ha
A) homotopic
B) enantiotopic
C) diastereotopic
D) mesotopic
E) none of these
Ans: C

Section: 16.4

OH
Ha
Hb
A) homotopic
B) enantiotopic
C) diastereotopic
D) mesotopic
E) none of these
Ans: C

Section: 16.4
Ha
Hb
A) homotopic
B) enantiotopic
C) diastereotopic
D) mesotopic
E) none of these
Ans: C

Section: 16.4
21. How many signals would you expect to find in the 1H NMR spectrum of
CH3OCH2CH3?
A) 1
B) 2
C) 3
D) 4
E) 5
Ans: C

Section: 16.4
CH3OCH2CH2OCH3?
A) 1
B) 2
C) 3
D) 4
E) 5
Ans: B

Section: 16.4
(CH3)2CHCH2CH2CH3?
A) 1
B) 2
C) 3
D) 4
E) 5
Ans: E

Section: 16.4
HOCH2CH2CH2CH2OH?
A) 1
B) 2
C) 3
D) 4
E) 5
Ans: C

Section: 16.4
25. How many signals would you expect to find in the 1H NMR spectrum of the following
compound?
A) 4
B) 5
C) 6
D) 7
E) 8
Ans: D

Section: 16.4
compound?
O
A) 4
B) 5
C) 6
D) 7
E) 8
Ans: B

Section: 16.4
compound?
O OH
A) 4
B) 5
C) 6
D) 7
E) 9
Ans: D

Section: 16.4
compound?
O
Ans: 4
Section: 16.4
compound?
O O
Cl
Ans: 6

Section: 16.4
compound?
O O
Ans: 3
Topic: Chemical shift

Section: 16.5
31. The 1H NMR spectrum of bromoethane shows a signal at 3.5ppm when the spectrum is
recorded using a 60-MHz spectrometer. Where do you expect to see the signal if a 300-
MHz instrument is used instead?
A) 3.5 ppm
B) 7.5 ppm
C) 6.8 ppm
D) 5.8 ppm
E) none of these
Ans: A

Section: 16.5
32. ______is used as a reference for recording NMR spectroscopy and is assigned a
chemical shift value of zero.
Ans: Tetramethylsilane (TMS)/ (CH3)4Si
Section: 16.5
33. Which of the indicated protons in the following compound would appear most
downfield in the 1H NMR spectrum?
III
OH
I
II IV
A) I
B) II
C) III
D) IV
Ans: D

Section: 16.5
34. Which of the indicated protons in the following compound would appear most
downfield in the 1H NMR spectrum?
I II III
H H H IV
H
C C C CH3
H F
H
A) I
B) II
C) III
D) IV
E) V
Ans: E

Section: 16.5
Difficulty Level: Hard
35. Which of the indicated protons in the following compound would appear most upfield in
the 1H NMR spectrum?
O II O IV
O F
I III
A) I
B) II
C) III
D) IV
E) I & III
Ans: A

Section: 16.5
36. Which of the following is a correct prediction of the chemical shifts for the signals in
the 1H NMR spectrum for the following compound?
I O
HO
II III
A) I=3.7 ppm, II=2.7 ppm, III=1.9 ppm
B) I=3.7 ppm, II=2.2 ppm, III=1.9 ppm
C) I=3.9 ppm, II=2.7 ppm, III=1.9 ppm
D) I=3.9 ppm, II=2.2 ppm, III=2.4 ppm
E) none of these
Ans: C

Section: 16.5
II
O
O
I
III IV
A) I=3.9 ppm, II=4.2 ppm, III=2.2 ppm, IV=3.4 ppm
B) I=3.4 ppm, II=2.2 ppm, III=2.2 ppm, IV=3.4 ppm
C) I=3.4 ppm, II=2.2 ppm, III=4.2 ppm, IV=3.4 ppm
D) I=3.4 ppm, II=4.2 ppm, III=4.2 ppm, IV=3.4 ppm
E) none of these
Ans: D

Section: 16.5
I III O
II IV
E) none of these
Ans: A

Section: 16.5
I III
O O
II
IV
E) none of these
Ans: B

Section: 16.5
40. Predict the chemical shifts for the signals in the 1H NMR spectrum for the following
compound.
II IV
O O
III
I
Ans: 4.4 ppm 1.9 ppm
O
5.7 ppm O
5.2 ppm

Section: 16.5
41. Predict the chemical shifts for the signals in the 1H NMR spectrum for the following
compound?
O O
O
Ans: O 4.2 ppm O 1.4 ppm
1.9 ppm 2.7 ppm 2.2 ppm 0.9 ppm

Section: 16.5
42. Aromatic protons produce signal in the range of 7-8 ppm, due to the _________effect of
π electrons
A) diamagnetic anisotropy
B) paramagnetic anisotropy
C) diamagnetic isotropy
D) paramagnetic isotropy
E) none of these
Ans: A

Section: 16.5
43. Which of the following protons appear most upfield in the 1H NMR spectrum?
II III
H H
IV
I H
A) I
B) II
C) III
D) IV
E) none of these
Ans: D
Topic: Integration
Section: 16.6
44. A compound with molecular formula C8H14 has the following 1H NMR spectrum.
Which of the following is the correct number of protons giving rise to each signal?
I
I
I
III
8 7 6 5 4 3 2 1 0
PPM
A) I-3H, II-9H, III-2H

B) I-2H, II-9H, III-3H
C) I-4H, II-6H, III-4H
D) none of these
Ans: A
Topic: Integration
Section: 16.6
45. A compound with molecular formula C6H11N has the following 1H NMR spectrum.
II
III
8 7 6 5 4 3 2 1 0
PPM
A) I-6H, II-3H, III-2H

B) I-5H, II-4H, III-2H
C) I-6H, II-4H, III-1H
D) none of these
Ans: C
Topic: Integration
Section: 16.6
46. A compound with molecular formula C8H10O has the following 1H NMR spectrum.
III
II
IV
SDBS: National Institute of Advanced Industrial Science and Technology
Ans: I-3H, II-2H, III-3H, IV-2H
Topic: Multiplicity
Section: 16.7
47. Which of the following four compounds gives a 1H NMR spectrum consisting of only a
singlet?
A) 1,1-dichloropropane
B) 1,3-dichloropropane
C) 1,2-dichloropropane
D) 2,2-dichloropropane
E) none of these
Ans: D
Topic: Multiplicity
Section: 16.7
48. How many 1H NMR signals will 2-chloro-3-methyl-2-butene exhibit?
A) 1
B) 2
C) 3
D) 4
E) none of these
Ans: C
Topic: Multiplicity
Section: 16.7
49. Which of the following compounds will display two triplets and a singlet in the
1
H NMR spectrum?
A) CH3CH(OCH3)2
B) CH3OCH2CH2OCH3
C) CH3OCH2CH(OH)CH3
D) CH3OCH2CH2CH2CH2OCH3
E) none of these
Ans: D
Topic: Multiplicity
Section: 16.7
50. Which of the following compounds will display a singlet, a triplet and a quartet in the
1
H NMR spectrum?
A) 2-chloro-4-methylpentane
B) 3-chloro-2-methylpentane
C) 3-chloropentane
D) 1-chloro-2,2-dimethylbutane
E) 3-chloro-3-methylpentane
Ans: E
Topic: Multiplicity
Section: 16.7
51. Determine the multiplicity of each signal in the expected 1H NMR spectrum of the
following compound.
O
Ans: doublet septet quartet
triplet
O
Topic: Multiplicity
Section: 16.7
following compound.
O
N
H
Ans: sextet singlet

O
N
H singlet
triplet
triplet singlet
Topic: Multiplicity
Section: 16.7
following compound.
O
O
Ans: multiplet doublet
singlet
doublet
O
Topic: Multiplicity
Section: 16.7
following compound.
O
O
Ans: doublet
O singlet
sextet
H
singlet
O
singlet doublet
Topic: Multiplicity
Section: 16.7
following compound.
O
HO O NH2
Ans: triplet singlet
O
singlet
HO O NH2
singlet
triplet
Topic: Multiplicity
Section: 16.7
56. Determine the multiplicity of each signal in the expected 1H NMR spectrum of 2,3-
dimethyl-2-pentanol.
Ans: singlet
OH quintet
singlet
triplet
sextet
doublet
Topic: Multiplicity
Section: 16.7
57. The coupling constant (J) for bromoethane is 7 Hz when the 1H NMR spectrum is
acquired at 250 MHz. What is the coupling constant between these protons when the
spectrum is acquired at 500 MHz?
A) 3.5 Hz
B) 7 Hz
C) 14 Hz
D) 21 Hz
E) none of these
Ans: B
Topic: Multiplicity
Section: 16.7
58. Which of the following is the maximum multiplicity observed for Hc protons in the
following compound? Assume that Jcd and Jcb values are different.
H c
N
a d
b
A) 5
B) 6
C) 8
D) 12
E) none of these
Ans: D
Topic: Multiplicity
Section: 16.7
59. Which of the following is the maximum multiplicity observed for Hb protons in the
following compound? Assume that Jab and Jbc values are different.
a
b O
a d
c
A) 9
B) 12
C) 21
D) 24
E) none of these
Ans: C
Topic: Multiplicity
Section: 16.7
60. Presence of which of the following protons is confirmed by D2O exchange?
A) OH
B) NH2
C) CH
D) A&B
E) none of these
Ans: D
Topic: 1H NMR spectrum

Section: 16.8
61. Determine the multiplicity and predict the chemical shifts of each signal in the expected
1
H NMR spectrum of the following compound.
I III O
II IV
Ans: 0.9 ppm 3.9 ppm
triplet triplet O
sextet singlet
1.7 ppm 2.4 ppm

Section: 16.8
1
O O
Ans: sextet
septet
1.4 ppm
3.2 ppm O O
doublet O
1.1 ppm
triplet triplet
2.7 ppm 0.9 ppm

Section: 16.8
1
O
O O
Ans: doublet singlet
1.9 ppm
4.4 ppm
O
triplet O
singlet 5.7 ppm
5.2 ppm
Topic: 1H NMR spectroscopy to distinguish between compounds

Section: 16.9
64. How would you use 1H NMR spectroscopy to distinguish between the following two
compounds?
O O O
H H
O II
I
A) I=3 & II=2 signals
B) I=4 & II=3 signals
C) I=5 & II=3 signals
D) none of these
Ans: B

Section: 16.9
compounds?
O O
O O
I II
Ans: Both compounds will have three signals.

Compound I: a triplet, a quartet and a singlet
Compound II: a singlet, a triplet and a quintet

Section: 16.9
compounds?
O O
O O
I II
Ans: Both compounds will have five signals.
Compound I: a doublet, a septet, two triplets and a sextet.
Compound II: a doublet, a multiplet, a quartet and a triplet.

Section: 16.9
compounds?
O
O
O
I II O
Ans: Both compounds will have five signals. The Ha proton in compound I will appear
more downfield than the Ha proton in compound II.
O
O
O
I a O
a
II
Topic: Analyzing a 1H NMR spectrum
Section: 16.10
68. A compound with a molecular formula C9H12 has the following 1H NMR spectrum.
Which of the following structures is consistent with this spectrum?
7 6 5 4 3 2 1 0
PPM
II III IV
I
A) I
B) II
C) III
D) IV
E) none of these
Ans: C

Section: 16.10
69. Which of the following structures is consistent with this 1H NMR spectrum?
1 1
O O O
I II III IV
A) I
B) II
C) III
D) IV
E) none of these
Ans: B

Section: 16.10
70. A compound with a molecular formula C9H10O2 has the following 1H NMR spectrum.
12 10 8 6 4 2 0
PPM
H OH O
O O
IV
II III
I
A) I
B) II
C) III
D) IV
E) none of these
Ans: B

Section: 16.10
71. A compound with a molecular formula C5H10O has the following 1H NMR spectrum.
Propose a structure for this compound.
10 8 6 4 2 0
PPM
Ans:
H

Section: 16.10
72. Propose a structure for a compound with molecular formula C5H11Cl, that fits the
following spectroscopic data:
1
H NMR: 0.9δ (triplet, I=3), 1.3δ (sextet, I=2), 1.5δ (quartet, I=2), 1.6δ (doublet, I=3),
3.6δ (sextet, I=1)
Ans: Cl

Section: 16.10
73. Propose a structure for a compound with molecular formula C8H14O3 that fits the
following spectroscopic data.
IR:1820cm-1, 1760cm-1
1
H NMR: 1.0δ (triplet, I=6), 1.6δ (sextet, I=4), 2.2δ (triplet, I=4)
O O
Ans:

Section: 16.10
74. Propose a structure for a compound with molecular formula C10H12O that fits the
IR:1680cm-1
1
H NMR: 1.0δ (triplet, I=3), 1.5δ (sextet, I=2), 2.6δ (triplet, I=4), 7.4δ (triplet, I=2),
7.5δ (triplet, I=1), 7.9δ (doublet, I=2)
O
Ans:

Section: 16.10
75. A compound with a molecular formula C8H16O has the following 1H NMR spectrum.
Provide a structure that is consistent with this spectrum?
6
2 2 2
2 1 0
PPM
Ans: O

Section: 16.10
76. A compound with a molecular formula C10H12O2 has the following HNMR spectrum.
3
2 2 2 2
1
11 10 9 8 7 6 5 4 3 2 1 0
PPM
O
O O O
CH O COH COH
II III IV
O
I
A) I
B) II
C) III
D) IV
E) none of these
Ans: C
Topic: 13C NMR spectroscopy

Section: 16.11 & 16.12
77. How many signals would you expect to find in the 13C NMR spectrum of the following
compound?
O
A) 6
B) 7
C) 8
D) 9
E) none of these
Ans: B

Section: 16.11 & 16.12
compound?
O O
A) 2
B) 3
C) 4
D) 5
E) none of these
Ans: C

Section: 16.11 & 16.12
compound?
A) 6
B) 7
C) 8
D) 9
E) none of these
Ans: D

Section: 16.11 & 16.12
compounds?
Cl
I II CH2CH3
A) I-5, II-8
B) I-3, II-6
C) I-4, II-8
D) I-5, II-6
E) none of these
Ans: D

Section: 16.11 & 16.12
81. Which of the following carbon atoms will display the signal most downfield in the 13C
NMR spectrum?
O F
C N
C C C C
C
I III V
II IV
A) I
B) II
C) III
D) IV
E) none of these
Ans: B

Section: 16.11 & 16.12
82. Which of the following compounds will display four signals in the 13C NMR spectrum?
A) 2,6-dimethylheptane
B) 2,4-dimethylheptane
C) 3,5-dimethylheptane
D) 4,4-dimethylheptane
E) none of these
Ans: A

Section: 16.11 & 16.12
83. Which of the following compounds will display five signals in the 13C NMR spectrum?
Br Br
Br
Br Br
Br Br
II III IV
I Br
A) I
B) II
C) III
D) IV
E) none of these
Ans: A

Section: 16.11 & 16.12
84. Which of the following 13C NMR chemical shifts corresponds to Ca in the following
compound?
a
O
A) 120 ppm
B) 145 ppm
C) 159 ppm
D) 200 ppm
E) none of these
Ans: C

Section: 16.11 & 16.12
85. Which of the following compounds is consistent with the following 13C NMR spectrum?
200 180 160 140 120 100 80 60 40 20 0

PPM
O O
O O
I II III IV
A) I
B) II
C) III
D) IV
E) none of these
Ans: A

Section: 16.11 & 16.12
80 70 60 50 40 30 20 10 0
PPM
OH OH
HO
I II IV
III OH
A) I
B) II
C) III
D) IV
E) none of these
Ans: D

Section: 16.11 & 16.12
60 50 40 30 20 10 0
PPM
Cl
Cl
Cl
I II III
A) I
B) II
C) III
D) none of these
Ans: C

Section: 16.11 & 16.12
80 70 60 50 40 30 20 10 0
PPM
OH OH
HO
I II III IV
OH
A) I
B) II
C) III
D) IV
E) none of these
Ans: C
Topic: DEPT 13C NMR spectroscopy

Section: 16.13
89. Which of the following display a signal in the DEPT-90 13C NMR spectroscopy?
A) CH3
B) CH2
C) CH
D) C
E) none of these
Ans: C

Section: 16.13
90. Which of the following displays a negative signal in the DEPT-135 13C NMR
spectroscopy?
A) CH3
B) CH2
C) CH
D) C
E) none of these
Ans: B

Section: 16.13
91. Which of the following does not display a signal in the DEPT-135 13C NMR
spectroscopy?
A) CH3
B) CH2
C) CH
D) C
E) none of these
Ans: D

Section: 16.13
92. Which of the following compounds will not display a carbonyl carbon signal in the
DEPT-90 and DEPT-135 13C NMR spectroscopy?
O O O
H O N
I II III H
A) I
B) II
C) III
D) II & III
E) none of these
Ans: D

Section: 16.13
DEPT-90
DEPT-90
DEPT-135
DEPT-135
93. A compound with molecular formula C5H10Br2 displays the following 13C NMR along
with the DEPT-90 and DEPT-135 13CNMR spectrum. What is the structure for this
Broadband decoupled
compound?
Broadband decoupled
Ans: BrCH2CH2CH2CH2CH2Br

Section: 16.13
94. A compound with molecular formula C7H7Br displays the following 13C NMR along
with the DEPT-90 and DEPT-135 13CNMR spectrum. What is the structure for this
compound?
Ans:
Br
Topic: Integrated Spectroscopy
Section: 15.6, 16.10, 16.12
95. A compound with molecular formula C11H14O displays the following IR, 1HNMR and
13
CNMR spectrum. Propose a structure for this compound.
220 200 180 160 140 120 100 80 60 40 20 0

PPM
Three spectra above: courtesy of SDBS: National Institute of Advanced Industrial Science and Technology
O
Ans:

Section: 15.6, 16.10, 16.12
6

3
96. A compound with molecular formula C7H14O2 displays the following IR, 1HNMR and
13
CNMR spectrum.
1 Propose a structure
2 for2 this compound.
180 160 140 120 100 80 60 40 20 0

PPM
Three spectra above: courtesy of SDBS: National Institute of Advanced Industrial Science and Technology
Ans: O

Section: 15.6, 16.10, 16.12
97. A compound with molecular formula C5H7NO2 displays the following IR, 1HNMR and
13

Ans: O
N
C
O

Section: 15.6, 16.10, 16.12
IR:1720cm-1
1
H NMR: 1.1δ (doublet, I=6), 2.1δ (singet, I=3), 2.7δ (septet, I=1)
13
C NMR: 15, 22, 45, 210
Ans:

Section: 15.6, 16.10, 16.12
99. Propose a structure for a compound with molecular formula C8H19N that fits the
IR: 3400cm-1
1
H NMR: 0.9δ (triplet, I=6), 1.1δ (singlet, I=1, exchanges with D2O), 1.3δ (sextet, I=4),
1.4δ (quintet, I=4), 2.6δ (triplet, I=4)
13
C NMR: 13.7, 20.5, 30.4, 49.2
Ans:
N
H

Section: 15.6, 16.10, 16.12
100. Propose a structure for a compound with molecular formula C5H12O2 that fits the
IR: 1200cm-1
1
H NMR: 1.4δ (singlet, I=6), 3.2δ (singlet, I=6)
13
C NMR: 28, 45, 100
Ans:
O O

Section: 15.6, 16.10, 16.12
IR: 3400 cm-1(broad), 3250 cm-1(sharp), 2150 cm-1
1
H NMR: 1.0δ (triplet, I=3), 1.5δ (singlet, I=3), 1.6δ (quartet, I=2), 2.5δ (singlet, I=1),
3.4δ (singlet, I=1)
13
C NMR: 5, 26, 35, 67, 69
Ans: OH

Section: 15.6, 16.10, 16.12
102. Propose a structure for a compound with molecular formula C8H15ClO3 that fits the
IR: 1780 cm-1, 1150 cm-1
1
H NMR: 1.1δ (triplet, I=6), 1.9δ (quartet, I=2), 2.8δ (triplet, I=2), 3.4δ (quartet, I=4),
4.2δ (triplet, I=1)
13
C NMR: 15, 31, 38, 57, 100, 173
Ans: O
O
Cl

Section: 15.6, 16.10, 16.12 & 16.13
DEPT-90
DEPT-135
103. A compound with molecular formula C3H6O2 displays the following IR, 1HNMR and
13
Broadband decoupled
Ans: O
OH

DEPT-90
DEPT-135
Section: 15.6, 16.10, 16.12 & 16.13
Broadband decoupled
104. A compound with molecular formula C6H12O displays the following IR, 1HNMR and
13
CNMR spectrum. 1Propose a structure for this compound.
Ans:
O

DEPT-90
DEPT-135 Section: 15.6, 16.10, 16.12 & 16.13

105. A compound with molecular formula C6H4Cl2O displays the following IR, 1HNMR and
Broadband decoupled 13
Cl
Ans:
OH
Cl

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Chapter Sixteen

Topic: Introduction to NMR

1. Which of the following can not be probed by an NMR spectrometer?

A) nucleus with odd number of protons & odd number of neutrons

Topic: Introduction to NMR

Topic: Introduction to NMR

3. Which of the following electromagnetic radiation is used in NMR spectroscopy?

Topic: Introduction to NMR

Topic: Introduction to NMR

Topic: Acquiring a 1HNMR spectrum

Topic: Acquiring a 1HNMR spectrum

Topic: Acquiring a 1HNMR spectrum

Topic: Characteristics of a 1HNMR spectrum

A) it indicates the number of neighboring protons

Topic: Characteristics of a 1HNMR spectrum

A) it indicates the number of neighboring protons

Topic: Characteristics of a 1HNMR spectrum

A) it indicates the number of neighboring protons

Topic: Characteristics of a 1HNMR spectrum

A) it indicates the number of neighboring protons

Topic: Number of signals

Topic: Number of signals

14. Which of the following type of protons are chemically equivalent?

Topic: Number of signals

15. Protons Ha and Hb in the following compound are _________.

Topic: Number of signals

Topic: Number of signals

17. Protons Ha and Hb in the following compound are _________.

Topic: Number of signals

Topic: Number of signals

19. Protons Ha and Hb in the following compound are _________.

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Number of signals

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

Topic: Chemical shift

1.9 ppm 2.7 ppm 2.2 ppm 0.9 ppm

Topic: Chemical shift

Topic: Chemical shift

A) I-3H, II-9H, III-2H

A) I-6H, II-3H, III-2H

SDBS: National Institute of Advanced Industrial Science and Technology

Ans: I-3H, II-2H, III-3H, IV-2H

Ans: sextet singlet

60. Presence of which of the following protons is confirmed by D2O exchange?

Topic: 1H NMR spectrum

Topic: 1H NMR spectrum

Topic: 1H NMR spectrum