Chem 32B - Exam 1 February 8, 2006 Prof. W.R. Leenstra 7:00 - 9:00 p.m. Your Name: Ann Serky TA’s Namez Answer each problem in the space provided. You should not need mote, but if you do, indicate in the answering space that you are continuing on the back of the preceding page (i.e., facing the problem being worked on). Do not use the answer spaces or the backs of the pages for seratch paper (see next item). ‘The equations and other information that you need is at the back of the exam, along with the Periodic Table, You can take them off, and use their backs for scratch paper. There are 9 calculational questions, each worth 9 points, as well as 5 descriptive/qualitative questions, each worth 4 points. Please write legibly - for many of you this means to be patient and write slowly, and think about your answers before you get it down on paper. Do not use a red pen. If you use pencil, that’s OK, but we can not re-grade exams written in pencil (for obvious reasons). ‘As with all examinations, document totally all the steps and intermediate calculations, in order to receive the appropriate amount of partial credit, or any credit at all. 1. 19 8. 19 2, 19 9. 19 3, 19 10. 15 4. 19 uM 15 5, 19 12. 15 6. 19 13. 15 2. 19 4 5 TOTAL 1100A new drug of molar mass = 272.8 g/mol is used to treat minor pains. Calculate the molarity of a 4,67 m solution which has a density of 1.107 gimL. 4.67% mol drug 4.6% molal = tooo q Hi0 4.6% mol => 4.64 mel x 272.8 Mol = \2 42.8 % drug(2) mass of solution = [oco 4 11.0 + yr42.B 4 dug = 2272.8 4% solution) oan y volume of solution = 2,272.8 % = 2, OFA mL Q), % ione a a mol. of rug mig ears L. of solution ear" Warts <1 A.bpmel ~|2.227M 2.064 L a pts answer. Melarihy = oe ie Gs xThe mole fraction of potassium nitrate (KNO,) in an aqueous solution is 0.0194. The solution's density is 1.0627 g/mL. Calculate the molarity of the solution. molar mass of K NO, = lol. ! oe molar mass of H,O = 18.0 9/mol = 0.9806 G)K yoo, = OI ko K=O 2S 4 ol KNOs <) 0, 014% m = 0.014 > S 0.0194 mol KNO, + 0.9306 mol HO @) solution's mass = (c. 0194 mel) (101.1 2) ie (0.4306 wet) (18.0 Xa) ution Pile donee celtic vslume of solution = ! Melange 4 cam [epeea me i . 10144 mol KNO3 ( + 45k Ym! 248K oie & , or mol IG ey 5 ee pol K8. (a) Calculate AG? for the combustion of propane: C\H, (@) + 50, (8) + 3CO,(g) + 4H,0(g) using the following information: Substance: CoH (8) 02(g) CO; (8) H,0 (g) AG®, (kJ/mol): 24.5 0 394.4 -228.6 aCe 4leatd)s alone) (ane) 0 23 n HF 14.4 — 1183.2 + 24-5 = > \ hee) of o® (b) The AS? for this reaction at 298 K is 101.1 J/K-mol. Calculate AH? for this reaction. V nce aH-Tas° \ ° kd — 2,073.1 = aH - (248) (010! ! a er et toate ky mol A oN ee oe9. In the industrial process for the production of iron from ore, the following reaction is utilized: 2 FeQ, +3. © = 4 Fe +3 CO, for this reaction, the AH? is +470.5 kJ/mol, and the AS? is +558.4 J/K-mol, (@) Is this reaction spontaneous at 1000 K? ° oa s eee cat 0.5584 Kb (io00 K Ky sete 2 ee eye ria ee rol = 4708 — 6584 X Sg 1 eo meme Yes 6° = rol es ade (b) At what temperature is the reaction changing from being non-spontaneous to spontaneous? so84 5. 490.6 - 7°: are ~ 4708 SJ ~ 0.5984 710. What is the strongest intermolecular force between solute and solvent in each of the following pairs of substances? @ CHO in CHy © [ereston] e [enter] e° x? ua induced dipole - induced dipele (bo) CH,OH in CHCI(®, at dipole - dipole11, Using the figure below, explain how the fundamental colligative property discovered by Raoult results in freezing point lowering and boiling point elevation. ; liquid ne 4 Cue wee A i eee equilib eee line ws ee ea Ne ee x hegher Han 100°C wah) temperature oR suld’s lau states that the pressuice of its vapor 4 tA 7 by the exected bya liquid is ee 9 Flt presen ol a dissolved particle This lowers the Liquid - oaper equal bie line as indi cated above . Seo ak 1 ate the Lee vapor trans itton » Se occurs ak a higher tem pecture. i eimai larly foc Shgatdk solid |12, Which of the ions has the larger AH j,9, ? @ (s) cs" 2gts ) (oe Rb” ayts1B. For the following pairs, circle the system that has a higher entropy, assume P and T are the same for each pair, unless stated otherwise. (a) L mole He co(woe (b) 1 mole O, (g);Q mole O (g), (1 mole CH, coxGonecs@) (@ I mole Xe (g) at 1 atmosphere:14. For each of the two diagrams below, indicate whether the standard enthalpy and the standard entropy of the reaction are negative or positive ° oa Se Gee ae le i : H pes or neq AH’ Decision: When Tao , is 4 p : -} aS! decision! As T increases , does 46" ea we @ i AH’ is positive \et aS is positive pb o 7 ) ° a ; AH ie positive | pe. ae e. Hive | : AS) is negeti