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PUBLISHED ONLINE: 13 OCTOBER 2013 | DOI: 10.1038/NGEO1954

Continental-root control on the genesis of


magmatic ore deposits
W. L. Griffin1*, G. C. Begg1,2 and Suzanne Y. O’Reilly1

Giant magma-related ore systems are prime targets for modern mineral exploration, yet it is unclear what controls their
formation. The magmas originate in Earth’s convecting mantle. To reach the surface, they must pass through the stagnant
sub-continental lithospheric mantle, but the role of this mantle in ore genesis is vigorously debated. In one view, the ascending
magmas are already metal-rich and the sub-continental lithospheric mantle acts only as a passive, buoyant raft on which the
continental crust — the final store for the ore deposits — rides. Here we argue that the sub-continental lithospheric mantle may
actually contain ore-forming elements that could be entrained by ascending magmas, and that it therefore plays a significant
role in the genesis of magmatic ore. Specifically, we suggest that some types of magma pick up ore-forming components, such
as diamonds and gold, and possibly platinum-group elements, during their passage through the mantle lithosphere, and that
the three-dimensional structure of the lithosphere helps to focus deposition of the ore. We therefore suggest that models for
ore genesis and exploration need to incorporate the entire lithosphere to be effective.

T
he sub-continental lithospheric mantle (SCLM; Box 1) formed were bordered by subduction zones at some stage of their evolution,
in the mid–late Archaean eon1–5 and changed the face of the because subduction zones provide a supply of fluids. Progressive
Earth. By providing stable continental shelves, or cratons, on refertilization has changed the concentrations of major elements
an Earth floored by oceanic crust, the SCLM forced a significant and trace elements (as well as their isotopic compositions10,11) in the
reorganization of plate tectonics. The regions surrounding the cra- SCLM. The most common rocks of the deep SCLM (garnet lherzo-
tons became fractured to form peri-cratonic basins, and disconti- lites) are strongly metasomatized, and carry little information that
nuities in the SCLM acted as physical guides for magma upwelling could be used to support a shallow origin for the SCLM.
from the convecting mantle below. The SCLM provided a durable, Ongoing studies12,13 are integrating geophysics with mantle geo-
buoyant and rigid reservoir for ore-forming elements, and enabled chemistry and geochronology to map the distribution and age of
the preservation of the overlying crust and attendant ore deposits. upper-lithospheric domains to depths ≥100 km (Fig. 1). The results
The role of the SCLM in generating giant ore deposits is strongly imply that at least 70% of all SCLM worldwide was formed in a short
debated. Here we review the characteristics of some diamond, plati- period 3.0 to 3.5 Gyr ago1,2 (billion years ago; Ga) and has resided
num-group elements (PGE), Ni-Cu-(PGE) and (Cu-)Au ore depos- beneath the continents ever since. Similarly, Hf-isotope analyses of
its worldwide, and argue that the history, structure and evolution of crustal zircons14 indicate that >60% of existing continental crust
the SCLM may be directly relevant to the genesis and localization was generated >2.5  Ga, and has been progressively re-melted and
of some of these deposits. We therefore suggest that mapping of the reconstituted in later tectonic episodes. Physical and temporal links
SCLM structure, age and composition should form a key compo- between crust and mantle1,5,12 suggest that large-scale mantle melt-
nent of mineral exploration programmes. ing produced not only the cratonic SCLM but much of the original
continental crust too.
The sub-continental lithospheric mantle
The origins of the SCLM are controversial1,6–9. A common view 7,8 Ore deposit links with SCLM structure and composition
suggests that SCLM was built up mostly from subducted oceanic Diamond deposits. Primary diamond deposits provide a compel-
slabs that were depleted in many elements, because of shallow ling example of SCLM control on magma emplacement, and hence
melting at ocean ridges and in subduction zones. A newer view 5,9, on the distribution of ore deposits. The diamonds occur in dykes
however, suggests that the SCLM formed from the residues of very and pipes of highly alkaline magmas (kimberlites and lamproites)
high-degree melting, either in plumes rising from the deep man- that are generated by low-volume melting near or below the base
tle1,5 or through high-temperature melting of the ambient upper of the SCLM. The magmas pick up diamonds from the deep SCLM
mantle4. Evidence for formation of the SCLM by high-degree melt- (>150 km) during their eruption7.
ing is provided by observations of the Fe-depleted compositions Blocks of cratonic SCLM can be imaged by seismic tomography
(FeO  <  7  wt%) of many kimberlite-borne, SCLM-derived perido- and magnetotelluric surveys15,16 as volumes with high seismic veloc-
tites that have no counterparts in modern oceanic mantle1,9. ity (due to Fe depletion) and high electrical resistivity. On the large
The initial SCLM was highly depleted in magmaphile elements scale (Fig. 2a), kimberlites and other low-volume mantle melts are
and has been preserved largely due to the buoyancy imparted by concentrated near the edges of cratonic blocks. High-resolution
its low iron-to-magnesium ratio. Since the SCLM formed, fluids seismic tomography (Fig. 2b) shows even more striking correlations;
and magmas derived from the convecting mantle have ponded at most kimberlites cluster on the edges of high-velocity domains in
its base or ascended via weak zones such as craton boundaries and the deep SCLM. The correlation is easily understood in geochemi-
large faults. These magmas and fluids have progressively replenished cal and geophysical terms. Diamond formation requires the metaso-
the SCLM (a process known as metasomatic refertilization) in mag- matic re-introduction of carbon into the originally depleted SCLM.
maphile elements, including components of ore deposits, such as The carbon is typically accompanied by elements such as Ca, Al,
Cu and Au. Refertilization may be especially intense where cratons K, Na and Fe (refs 10,11), producing lower seismic velocities in the

1
ARC Centre of Excellence for Core to Crust Fluid Systems/GEMOC, Macquarie University, NSW 2109, Australia, 2Minerals Targeting International PL,
17 Prowse St, West Perth, Western Australia 6005, Australia. *e-mail: bill.griffin@mq.edu.au

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PERSPECTIVE | FOCUS NATURE GEOSCIENCE DOI: 10.1038/NGEO1954

plume melting was focused by a transition from thick to thinner


Box 1 | Glossary SCLM during periods of tectonic extension; the rapid, unhindered
ascent means the magmas will arrive highly sulphur-undersatu-
Cratons. The ancient, relatively stable cores of continental masses.
rated. High-MgO deposits are thus commonly found in peri-cra-
Kimberlites. Small-volume ultramafic magmas highly enriched in fluids tonic basins developed over SCLM (cratonic) boundaries; these
and alkaline elements; major host rock for diamonds. basins are more likely to contain the sulphur-rich sediments essen-
Komatiite. Ultramafic lavas, products of high-degree melting; almost tial for sulphur saturation (such as the Kambalda camp, Western
all of Archean age (>2.5 Ga); erupted along craton margins and within Australia, and the Raglan camp, Canada)23.
continental rift zones. Low-MgO systems are also associated with trans-lithospheric
faults at cratonic margins, but not with peri-cratonic basins20. They
Large igneous provinces (LIPs). Voluminous outpourings of mainly
basaltic lavas; some host major Ni(Cu) sulfide deposits.
are intrusion-hosted, and occur where magma ascent was hindered
by thick crust or a compressive tectonic environment. In such set-
Magmaphile elements. Elements that are partitioned into silicate melts tings, melt fractionation and chemical interaction with the litho-
during partial melting processes; for example, Ca, Al, Fe, Na and K. sphere (at all depths) are likely to be enhanced. Sulphur saturation
Mantle wedge. The volume of mantle trapped between an upper plate may occur at depth22 (relative to the eventual deposit), with sul-
and a subducting lower plate; this may be oceanic mantle in intra-ocean phide melts expelled from deeper (crustal) magma chambers at a
subduction zones (for example, Tonga-Kermadec in the Pacific) or late stage of the crystallization of the host melts (such as in Norilsk,
continental mantle where subduction takes place along a continental Voisey’s Bay)24,25. Although many low-MgO ores show evidence for
margin (for example, the Andes). assimilation of sulphur-bearing country rocks26,27, others show no
Metasomatism. Compositional changes induced in pre-existing rock addition of crustal sulphur (for example, the Nebo-Babel deposit,
volumes by interaction with fluids or melts. Western Australia28). The assimilation of silica could also lead to
sulphide saturation22,28.
Orogeny. A mountain-building event, usually involving compression,
PGE deposits generally share similar settings and LIP associa-
deformation and uplift of the crust.
tions with the Ni-Cu-(PGE) deposits, but they tend to lie along
Platinum-group elements (PGEs). Os, Ir, Ru, Rh, Pt and Pd; typically trans-lithospheric fault corridors that are slightly further inboard
concentrated in alloys and sulfide minerals in mantle-derived peridotites. of craton margins than their Ni-Cu-(PGE) counterparts (Fig. 1)29.
Sub-continental lithospheric mantle (SCLM). The uppermost, non- They also more commonly occur as narrow sulphide-poor reefs
convecting part of Earth’s mantle beneath continents. within major layered intrusions rather than within associated
feeder intrusions.
Subduction zones. Sites where (mainly) oceanic plates are carried down
into the mantle beneath the edges of other plates (both oceanic and
continental); sites of volcanism and fluid movement through the mantle
wedge above the subducting plate.
Xenolith. Literally means ‘foreign rock’; in this context, it refers to a 30° N
fragment of the SCLM or the deeper crust, carried to the upper crust or
surface in a magma (for example, basalt or kimberlite).

refertilized zones. The zones of weakness on the margins of cratonic


blocks, and in fractures within these blocks, provided channels for
the carbon-bearing fluids, and later controlled the emplacement of
the kimberlites17.

Magmatic Ni-Cu-(PGE) and PGE deposits. Large Ni-Cu-(PGE)


sulphide deposits are genetically linked to large igneous prov-
inces (LIPs) and komatiites, and the accumulation of metal-rich, T
immiscible sulphide melts in mafic or ultramafic magmas18. These T/P
magmas are produced by high-degree melting in rapidly ascend- T/P/A
ing plumes that transport deep mantle rocks with temperatures of P
≥1,500 °C to depths of 100 km or less19. There is a clear relationship P/A
30° S
between the magmas and the SCLM structure; the required high- A
temperature, low-pressure melting occurs only in areas of relatively
0° 30° E
thin lithosphere, and the melts access the crust through large faults.
The spatial and temporal distribution of Ni-Cu-(PGE) and PGE
deposits implies that tectonically active craton margins represent a Figure 1 | Upper-lithospheric domains (0–100 km) derived from integrated
favourable conjunction of these factors (Fig. 1)20. mapping of geological and geophysical data. A, archons (lithospheric
Sulphur saturation (at constant sulphur content) decreases as blocks formed >2.5 Ga); P, protons (formed 2.5–1.0 Ga); T, tectons (formed
the magma ascends21; mantle-derived magmas may reach the upper <1 Ga). Others represent episodes of significant lithospheric reworking:
crust in a sulphur-undersaturated state, but they can assimilate for example, P/A represents a block generated in Archaean time, but
sulphur-rich continental crust to reach sulphur saturation and the significantly modified in Proterozoic time. The cratonic nuclei (A and P/A)
resulting sulphide immiscibility 18,22 necessary to form ore deposits. are underlain by high-velocity SCLM (Fig. 2a). The Bushveld Complex and
Ni-Cu-(PGE) deposits can be divided into two geodynamically Great Dyke are outlined by thick black lines (southern Africa). PGE deposits
controlled end-member styles based on the composition of co- (blue circles) and Proterozoic Ni-Cu(-PGE) deposits (white circles; located
genetic rocks: Ultramafic (high MgO; generally komatiitic to pic- around the margins of the cratonic nuclei) are denoted by size (larger size
ritic lavas and intrusions) and mafic (low MgO; generally gabbro or indicates higher significance). Adapted with permission from ref. 12, © 2009
norite intrusions)20. High-MgO magmas erupt at the surface where Geological Society of America.

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NATURE GEOSCIENCE DOI: 10.1038/NGEO1954 FOCUS | PERSPECTIVE
a b c
20° E Subducting plate
20° S
Butte Cu-Mo-Ag
30° N Yellowstone Hotspot
Or Lim 45° N
Homestake Au
Carlin Wyoming
District craton
Au Grouse
Jwa Creek
Bingham Canyon
Cu-Au
Cameroon Prem Colorado
0° volcanic

W
line Mother Mineral

al k
Lode Belt

er
Au

L
Kimb Colorado

an
block

eZ
NL

on
30° S

e
CM 30° S 35° N
Arizona Cu
(Mo, Au, Ag)
30° S

0° 30° E 30° E 115° W

Figure 2 | Vs tomography of the lithospheric mantle. Red to white, high Vs; blue, low Vs. a, Africa (100–150 km depth), showing distribution of low-volume
magmatic rocks along the boundaries of high-velocity blocks. White dots, kimberlites; green circles, carbonatites; yellow, young rift basins. b, Detailed
seismic tomography, Kaapvaal craton (200 km depth), showing kimberlites around the margins of high-velocity volumes. Major diamond-rich kimberlite
provinces: Kimb, Kimberley; NL, Northern Lesotho; Prem, Premier; Jwa, Jwaneng; Or, Orapa; Lim, Limpopo Belt, including kimberlites such as Venetia. CM,
craton margin. c, Vp tomography (90 km depth) of western USA, showing main Precambrian to Tertiary (magmatic-)hydrothermal ore deposits by size
(supergiant, giant and major) and dominant metals (yellow, Au; green, Cu-Au-Mo; pink, Cu-Mo-Ag-Au; orange, Mo; light blue, REE; light grey, W(-Sn);
dark grey, Fe). Main lithospheric blocks, defined at sub-crustal depths from multidisciplinary data, are outlined. Deposits concentrate along prominent
lithospheric structures, particularly in lower-velocity regions (blue) or on the flanks of highs, where lower velocities reflect refertilization of the SCLM and/
or higher temperature. Part a adapted with permission from ref. 12, © 2009 Geological Society of America. Part b adapted with permission from ref. 12
(© 2009 GSA) and ref. 15 (© 2004 Geological Society of South Africa). Part c adapted with permission from ref. 50, © 2010 Elsevier.

Competing models for Ni-Cu-(PGE) and PGE deposits. The role Au-rich (±Cu) deposits. There is evidence that SCLM that has been
of the SCLM in the generation of magmatic Ni-Cu-(PGE) and PGE metasomatized by hydrous melts and fluids above subducting slabs
(sulphide) deposits is controversial. The structural role of the SCLM may play an important role in the genesis of some gold-rich (mag-
in focusing magma intrusion is clear, but its compositional role is matic) hydrothermal deposits34. This includes porphyry Cu-Au,
less obvious. The orthodox view is that the SCLM contributes essen- epithermal Au, iron oxide Cu-Au (ref. 35) and intrusive-related oro-
tially nothing to magmas, and that most mantle magmas are equally genic Au (ref.  36) deposits. This relationship could possibly even
endowed in Ni, Cu and PGEs18,23. In this view, the genesis of an ore extend to Carlin-type Au (ref. 37) and classic orogenic gold depos-
deposit simply reflects local factors, especially contamination with its34, contrary to models for a purely upper- to mid-crustal origin38.
crustal sulphur. However, traditional asthenospheric-melt mod- Models for generating Au-rich magmas from lower-crustal rocks or
elling explains neither the high PGE levels in some magmas (for subducting slabs fail geological and geochemical tests34. In seismic
example, at the Bushveld Complex), nor the provinciality of PGE images, these (and other magma-related) deposits are coincident
enrichment evidenced by both Ni-Cu-PGE and PGE reef depos- with medium- and lower-velocity SCLM (Fig. 2c). This suggests a
its29. Interestingly, LIPs and komatiites intruded into areas without holistic model embracing three common features: a mantle source
ancient SCLM roots are not known to contain significant deposits30. region carrying (Cu-)Au; trans-lithospheric faults; and a tectonic,
Some studies of PGEs in mafic and ultramafic rocks31 have found possibly thermal trigger 34.
no conclusive evidence for SCLM involvement. However, ‘fertile’ Both the asthenosphere (about 1  ppb Au; parts  per  109) and
(mineralized and continental) flood basalts show a distinctive high- non-refertilized lithospheric mantle are depleted in Au relative to
Os signature (Fig. 3a) that may reflect the interaction of melts with refertilized upper mantle, such as the Lanzo (Western Alps) and
SCLM (ref. 30). The high contents of metal (PGE, Cu and Ni) alloys Ronda (Spain) peridotite massifs39. Xenoliths of arc-related mantle
and sulphur in metasomatized xenoliths from the SCLM (refs 2,32), from near the giant Lihir gold deposit in Melanesia show metaso-
and the relative PGE enrichment of cratonic versus off-craton man- matic enrichment in Cu and Au (refs 40,41), and SCLM xenoliths
tle32, also raise the question of how much SCLM-derived metals and in China carry up to 14 ppb Au (ref. 42), with up to 5 ppm Au in
sulphur might be contributed to rising magmas. This issue is most sulphide minerals43. Gold enrichment has also been found in SCLM
pertinent for PGEs and low-MgO Ni-Cu-PGE deposits. Perhaps the xenoliths from the Kaapvaal (South Africa) and Karelian (Finland)
most intriguing evidence comes from isotopic studies, which show cratons44. Mantle gold enrichment can be related to trapping of
that ‘fertile’ LIPs have interacted with rocks that had a long-term earlier low-degree melts; gold behaves as an incompatible element
enrichment in Rb/Sr and depletion in Sm/Nd and Re/Os (ref. 30), during melting, concentrating in the melts34. Even such metasoma-
typical of ancient metasomatized SCLM. Several major LIPs tized SCLM is relatively durable, and may store (Cu-)Au until a later
define Re-Os ‘isochrons’ reflecting their eruption ages, with ini- melting event is triggered, leading to deposit formation; overlying
tial 187Os/188Os below that of the asthenospheric mantle, implying crust may experience multiple mineralizing events of this type45.
derivation of Os from older SCLM (Fig. 3b). The Re-Os systemat- Gold-productive primitive magmas are low-degree partial melts
ics of the Bushveld intrusion and sulphides in coeval diamonds33 of refertilized mantle (generally SCLM), or asthenospheric melts
imply interaction between melts and the SCLM (harzburgites and that have assimilated low-melting-point distillates from the SCLM,
eclogites); SCLM may be a “critical component in the genesis of the and hence are alkaline34. This is consistent with the common asso-
Bushveld complex and similar PGE-ore-bearing intrusions”33. This ciation between gold mineralization and alkaline magmas, some of
is clearly a fertile field for further investigation. which have mixed with crustal melts36.

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PERSPECTIVE | FOCUS NATURE GEOSCIENCE DOI: 10.1038/NGEO1954

a b
10 6 10
Bushveld i Bushveld
Re (ppb) Mid-continent Mid-continent
Siberia 5

10
Emei Mt Siberia

s=
Karoo 4 Emei Mt

/O
Ferrar Karoo

Re
Parana Ferrar
Kerguelen 3
Parana
1 Deccan ii Kerguelen
2 Deccan

Os/188Os
Re (ppb)

1
1
0

187

00

0
0

00

00
50

1,5
1,0
0.1

2,
0.01 0.1
0.0001 0.001 0.01 0.1 1 10 100 0.1 1 10 100 1000
Os (ppb) 187
Re/188Os

Figure 3 | Re-Os data for LIPs and other magmas. a, Re and Os contents of mafic rocks from provinces with known Ni-Cu(-PGE) sulphide deposits (pink
field) and provinces lacking known deposits (blue field). b, 187Re/188Os vs 187Os/188Os in flood-basalt suites. Main figure, log–log scale; inset, linear scale.
The plots in the inset correspond to: i, Ferrar dolerites, 177±2 Myr ago, intercept 0.125±0.033 (γOs = -0.6±0.26); ii, Deccan traps, 65.6±0.3 Myr ago,
intercept 0.12843 (γOs = 1.5±0.3). Data from ref. 30 and references therein.

a b
Ni-Cu±PGE Porphyry Cu (Mo,Au), W-Sn Au-rich deposits
Diamonds

Crust PGE

Depleted Melt–SCLM
interaction
SCLM

Refertilized SCLM Oc
ea
High-degree melting nic
pla Low-degree melting
Low-degree melting te
Water lost from ‘sl
ab
slab triggers high-degree ’
melting in mantle wedge
Plume

Figure 4 | Interactions between magmas and the SCLM. a, Plume triggers kimberlite formation and flows to area of thinner SCLM where melting is
focused. Variable interaction of melts with crust and SCLM influences Ni-Cu and PGE deposit genesis. b, Generalized convergent-margin setting. Au-poor
magmatic-related deposits form from dominantly asthenospheric or crustal melts (such as Cu-rich or W-Sn porphyry, respectively). Low-degree melting
of asthenosphere, particularly in retro-arc settings, can produce Au-rich metasomatic refertilization of the SCLM. Subsequent melting (which may be
much later) contributes Au to magmatic systems, forming deposits of porphyry Cu-Au, epithermal Au, iron oxide Cu-Au, intrusive-related orogenic Au,
and possibly also Carlin-type Au and classic orogenic Au.

In New Guinea, the Grasberg and Ok  Tedi porphyry Cu-Au Significance for mineral exploration
deposits and the Porgera epithermal Au deposit are connected by Geophysical imaging 12,15,16,50 and studies of mantle-derived xenoliths
deep faults46 to underlying SCLM of the Australian plate, refertilized show that the SCLM, especially in cratonic areas, preserves strong
by earlier subduction. Despite the absence of a coeval magmatic arc, lateral compositional heterogeneity. Large magmatic and hydro-
tectonic reactivation has given rise to intrusions of calc-alkaline to thermal ore systems are concentrated along the margins of depleted,
alkaline affinity 47 and co-genetic Au-rich deposits. The location and high-velocity mantle volumes, but rarely occur directly above such
timing of such deposits imply that the SCLM may have stored met- volumes. This observation applies across the deposit types discussed
als that were scavenged by later magmas. here, suggesting the possibility of a fundamental role for whole-lith-
Isotopic studies of giant Eocene porphyry Cu-Au and (Cu-)Mo ospheric architecture in their genesis (Fig. 4).
deposits in the western USA show the presence of Archaean Pb The emplacement of diamondiferous kimberlites is demonstrably
(ref. 48) in the mineralizing fluids. This is consistent with evidence controlled by the details of lithospheric architecture (Figs 2b and 4a);
for the widespread presence of relict Archaean lithosphere beneath the magmas use weak metasomatized zones around blocks of less
younger upper-crustal rocks in the southern and western USA modified SCLM, and these zones host diamonds formed from
(Fig. 2c)13,49. We suggest that the Archaean SCLM has been meta- metasomatically introduced carbon. Lithospheric architecture also
somatically enriched over time in Cu and Au, and then tapped by controls the location of focused high-degree melting of upwelling
mantle melting related to the post-Laramide tectonism, connected mantle20, variable contamination of these melts with (generally
with rollback or foundering of the Eocene slab. sulphur-rich) crust and the generation of Ni-Cu-(PGE) and PGE

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NATURE GEOSCIENCE DOI: 10.1038/NGEO1954 FOCUS | PERSPECTIVE
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PERSPECTIVE | FOCUS NATURE GEOSCIENCE DOI: 10.1038/NGEO1954

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Author contributions
All of the authors contributed to the lithospheric mapping and geochemical analysis
of the Carajas Mineral Province, Southern Amazon Craton, Brazil: varying for this paper. G.C.B. assembled much of the information on metallic ore deposits;
styles of Archaean through Paleoproterozoic to Neoproterozoic base- and W.L.G., S.Y.O’R. and G.C.B. synthesized the information on lithosphere composition and
precious-metal mineralisation. Ore Geol. Rev. 33, 451–489 (2008). structure and diamond deposits. Most of the manuscript has been written by W.L.G. and
46. Hill, K. C., Kendrick, R. D., Crowhurst, P. V. & Gow, P. A. Copper-gold G.C.B., with important contributions by S.Y.O’R.
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37, 247–250 (2009). Correspondence should be addressed to W.L.G.
48. Pettke, T., Oberli, F. & Heinrich, C. A. The magma and metal source of giant
porphyry-type ore deposits, based on lead isotope microanalysis of individual Competing financial interests
fluid inclusions. Earth Planet. Sci. Lett. 296, 267–277 (2010). The authors declare no competing financial interests.

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