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1, JANUARY 2013
Abstract—Energy storage has become a key issue for achieving Different authors have described methods to model super-
goals connected with increasing the efficiency of both producers capacitor devices with different resistive–capacitive (RC) net-
and users. In particular, supercapacitors currently seem to be works. These models have been obtained through analyses in
interesting devices for many applications because they can supply
high power for a significant amount of time and can be recharged the time domain or frequency domain. In [12], Zubieta and
more quickly than electrochemical batteries. In different applica- Bonert proposed a model with three RC branches connected
tions, a combination of the two devices, batteries and supercapaci- in parallel. An additional parallel resistor accounts for the self-
tors, could be used to develop a high-efficiency storage system with discharge phenomenon. In this model, the bigger capacitance
a high dynamic performance. Because of the diffusion of super- is not constant but rather linear with voltage. This model is
capacitors, a good model is needed to represent their behavior in
different applications. Some models have been proposed that char- very good for low frequencies, but it is not accurate at high
acterize supercapacitors working at either low or high frequencies. frequencies. In [13]–[15], Belhachemi et al. proposed a model
In this paper, the authors present a full-frequency-range model to address the limits of the model proposed in [12]. They
that can be used to represent all of the phenomena that involve presented a nonlinear transmission line. However, this model
supercapacitors. Moreover, to realize a simple and useful tool, the is complex, and parameter identification is not easy. How-
authors present a simple procedure to identify the parameters
of the model that can be used to characterize a supercapacitor ever, the idea of separating the time constants of the different
before use. branches is interesting and is used in this paper. In [16]–[18],
Gualous et al. proposed simple transmission lines focusing
Index Terms—Double-layer capacitors, parameter identifica-
tion methods, supercapacitor efficiency, supercapacitor perfor- on the effect of temperature on model parameters. In [19],
mance, supercapacitors. Rojat et al. introduced a multipenetrability model to estimate
the supercapacitor behaviors in the different states of health. In
I. I NTRODUCTION [20], Zhang et al. analyzed the quality of different RC models
for power electronic applications. In [21], Du considered a
I N RECENT YEARS, the interest in storage systems has
been growing because their use is becoming more and
more widespread in different applications. For each kind of
parallel branch RC equivalent circuit and proposed a parameter
identification procedure that was mainly based on least-square
application, it is possible to identify the technologies that would error minimization.
be appropriate for realizing an optimal storage system [1]. In this paper, the authors propose a model that is able to
Moreover, the use of more than one technology to fit the goals represent the behavior of supercapacitors at both low and high
of specific applications represents a real solution to achieve frequencies. This new model, described in the next section, is an
a high-performance and high-efficiency storage unit [2]–[6]. extension of the model presented in [22]. Moreover, this model
For example, various applications that use supercapacitors and can be used to take into account the self-discharge and redistri-
electrochemical batteries to realize hybrid storages have been bution phenomena. The model is not completely new because
reported [7]–[11]. it was obtained by joining different models, but it is useful
Because of the wide variety of applications that use super- not only for dynamic simulations but also for evaluating the
capacitors, it is important to realize a model that can represent efficiency of a device. In addition, a very simple, yet innovative,
their behavior in all practical operations. Recently, the different parameter identification procedure is proposed to avoid the use
models of supercapacitors have been developed to match these of least-square error minimization. Previous methods required
exigencies. The proposed models differ because they represent the results of accurate tests, while the proposed procedure
a supercapacitor in a particular application and are designed for provides good parameter estimation using only a few simple
ease of use in that application. measurements.
Manuscript received August 4, 2010; revised February 14, 2011 and II. S UPERCAPACITOR M ODELING
October 31, 2011; accepted January 29, 2012. Date of publication
February 10, 2012; date of current version September 6, 2012. Supercapacitor devices consist of two electrodes with an
V. Musolino is with Dimac Red, 20853 Biassono, Italy (e-mail: v.musolino@ ion-permeable separator between them. The electrodes are im-
dimacred.it).
L. Piegari and E. Tironi are with the Department of Electrical Engineering, mersed in an electrolyte solution, as shown in Fig. 1.
Politecnico di Milano, 20133 Milan, Italy (e-mail: luigi.piegari@polimi.it; The charge separation process, which requires a voltage
enrico.tironi@polimi.it). difference across the electrodes, takes place on the two
Color versions of one or more of the figures in this paper are available online
at http://ieeexplore.ieee.org. electrode–electrolyte interfaces. Thus, supercapacitors are usu-
Digital Object Identifier 10.1109/TIE.2012.2187412 ally known as double-layer capacitors. The double layer is also
parameters with very simple tests and with the information From (4), it is possible to estimate all of the parameters of the
contained in the manufacturer’s datasheets is a very impor- first branch for a fixed voltage. Repeating the tests at different
tant point for the usability of the model. It is clear that the voltages makes it possible to estimate a value for the parameter
parameter values that give the best match between the model k that takes into account the variability of the capacitance with
shown in Fig. 2 and the experimental data can be obtained the voltage.
with least-square error minimization. However, this procedure
is too complex to be performed every time. In fact, it requires B. Parallel-Branch Parameter Identification
the execution of experimental tests at many frequencies to
obtain the experimental curve of impedance versus frequency. First, the number of branches must be chosen as a compro-
Thus, a new easier procedure is proposed in the following. The mise between the required accuracy and the consequent com-
parameters of the first branch and the parallel branches are plexity. The branches represent the supercapacitor’s behavior
identified separately as discussed, in detail, in the following. over a long time scale. Thus, to model the phenomena that occur
at different times, their time constants should be quite different.
It is therefore possible to consider different transient phenom-
A. First-Branch Parameter Identification ena without interference. After a fast charge, all of the energy is
The first branch of the model shown in Fig. 2 is the im- stored in the first branch. Then, leaving the supercapacitor in an
pedance given by (1). In this expression, C and τ are the open circuit causes the energy to be redistributed in the parallel
functions of the voltage. During the experimental tests, it was branches, after which it dissipates in the leakage resistance. If
verified that C and τ vary almost linearly with the voltage the parallel branches with greatly different time constants are
chosen, it is possible to split the discharge time into n + 1
C(V ) = C0 + k V intervals. In interval k, only the branches from 1 to k − 1 are
involved in the energy transfer. All of the other branches are in
τ (V ) = τ0 + kτ V. (2)
a steady state and are not affected by the phenomenon because
they have much higher time constants. In the n + 1 interval, all
From (1), the following result:
of the energy is dissipated on the leakage resistance.
∞
2τ (V ) To make the parameter identification procedure easy, it is
lim e{Zp } = lim Rp = Ri + 2 π 2 C(V ) important for the choice of the time intervals to be free and
ω→0 ω→0
n=1
n
independent of the cell under consideration. The only restric-
τ (V ) tion in the choice of the time intervals is that they have to be
= Ri + = Rdc
3C(V ) sufficiently different from each other that, in each transient,
all of the other branches can be considered to be in the steady
1
lim m{ωZp } = − (3) state. In the analysis of the experimental data, it was observed
ω→0 C(V ) that a good solution in the choice of the time intervals is to set
where Rp indicates the real part of the impedance of the first them equidistant on a logarithmic scale. The logarithmic scale
branch Zp . is obtained by choosing the intervals as follows:
Therefore, the capacitance can be evaluated, for each voltage
V , using a dc test. In particular, it is possible to use the same I1 : τ 0 < t < M τ 0 = τ 1
charging test at a constant current as described in [27]. In con- I2 : τ1 < t < M τ1 = τ2
trast, to experimentally evaluate Rp at zero frequency, it is not
...
possible to use a dc test. Indeed, at frequencies lower than some
tens of millihertz, the parallel branches cannot be neglected, and In : τn−1 < t < M τn−1 = τn (5)
Rp is not directly measurable. The supercapacitor’s datasheet
gives the discharge time Tdc to which the rated capacitance where τ0 is the time necessary to extinguish the transient of
refers. According to the manufacturer’s recommendation [28], the first branch over the second one. So, τ0 is greater than five
Tdc has to be used to estimate the dc resistance. Working times the time constant of the first branch already identified.
at frequency fdc = 1/Tdc , the recombination phenomena do This constant usually ranges from some seconds to some tens
not occur. Thus, the electrochemical capacitor can be modeled of seconds.
using only the first branch of Fig. 2. A resistance measurement In the set of equations in (5), it is necessary to choose a value
at fdc allows the estimation of Rdc . Typically, fdc has a value for M so that each transient can be considered independent
of some tens of millihertz. from the others. As is well known, exponential transients can
For high frequencies, when the supercapacitor behaves like a be considered extinguished after five times the time constant
resistance, Rp becomes constant. Some measurements at high because 99.3% of the steady-state value is reached at this time.
frequencies, when no capacitive behavior is shown, are enough Thus, to guarantee that each transient caused by the parallel
for estimating the high-frequency resistance Ri . However, this branches is finished before the beginning of the next one, it is
value is also available on the device datasheet. Thus, given Rdc necessary for the time constant of the k branch to be more than
and Ri from (3), we get the following: five times the time constant of the k − 1 branch. Thus, M > 5.
From (5), for a fixed time window Tw during which the self-
τ (V ) ≈ 3C(V )(Rdc − Ri ). (4) discharge phenomenon has to be analyzed, the parameter M
MUSOLINO et al.: NEW FULL-FREQUENCY-RANGE SUPERCAPACITOR MODEL 115
TABLE I
PARAMETERS OF THE F IRST B RANCH
TABLE II
C OEFFICIENTS OF D ETERMINATION
TABLE III
PARAMETERS OF THE F IRST B RANCH E STIMATED W ITH THE S IMPLIFIED
P ROCEDURE AND E STIMATION E RRORS
TABLE IV
PARAMETERS OF A F OUR -B RANCH E QUIVALENT M ODEL (M = 45) Fig. 13. Experimental current versus time for a test at 110 A.
Fig. 14. BCAP0140 experimental and simulated voltages during a test at Fig. 17. Experimental current versus time for a test at 110 A.
110 A.
Vincenzo Musolino received the M.S. degree Enrico Tironi received the M.S. degree in electrical
in electrical engineering from the Politecnico di engineering from the Politecnico di Milano, Milan,
Milano, Milan, Italy, in 2007, where he is currently Italy, in 1972.
working toward the Ph.D. degree in electrical engi- In 1972, he joined the Department of Electrical
neering in the Department of Electrical Engineering. Engineering, Politecnico di Milano, where he is cur-
He is also currently a Design Engineer with Dimac rently a Full Professor. His areas of research include
Red, Biassono, Italy. His research interests include power electronics, power quality, and distributed
electrical storage devices, power electronics, and generation.
distributed generation. Dr. Tironi is a member of Italian Standard Author-
ity (C.E.I.), Italian Electrical Association (A.E.I.),
and Italian National Research Council (C.N.R.)
group of Electrical Power System.