6910

2014 (TI)
'?'81211 fcJ$1/rt
rrR q?{
'fl'1l71 : 3:00 cit ｾＺ＠ 200 Jfq;

I. 311rR ｾ＠ q;T 'lfT'CZl1r TiT t I ｾ＠ rRte7T ｾ＠ "sf r.;q; y:ff rtrm;f'm (20 '1f7T I A'#+ 50
'm7T 'BI + 75 'm7T 'C' "sf ) ffSC7 fiicm;q rrFf (M CQ) ｾ＠ 7JT{ ｾ＠ I ;mr:rq;T 11T'T 'AI "sf ?t
ｾ＠ 15 JfR- '1f7T 'B # 35 JrFf}' nwr 11T'T 'C' "sf ?t 25 rrFff <t ｾ＠
1
eM ｾ＠ 1 ｾ＠
f.!!tdfffl # ｾ＠ rrFff <5 ｾ＠ (?v 7JT{ 'ffr ctcm 11T'T 'A' # 15, ｾ＠ 'B' 35 rmr 11T'T
#
'C' # 25 ｾ＠ I:JC'f'f# ctt \ifiq <!ft. iii7Vifr I
2. ＳＯｴＮｦ｛ｾ＠ UfiR rp_y 3TWJ # ｾ＠ 1fllT ｾ＠ I 3TfFfT m-r rrTiiV 3ft? R CfiT "fT1f f&.g.t #
rn:<;f w lifiq ｾ＠ frff ｾ＠ # rpo 1fJ 3fR ?rift ｾ＠ nwr Cfflft. # <R-flit 'flff ｾ＠ 1 ｾ＠
ｾ＠ ｾ＠ 'ffr JfTl1 $Pilvflc>ic'< # i3Wt ｾ＠ ctt ｾ＠ ｾ＠ q;r ｾ＠ "fiR ｾ＠ ｾ＠ 1 ｾＡ＠
ｾ＠ # 3/t. f{11.JIR. ｾ＠ rr=l q;T ｾ＠ lifiq c>f I ｾ＠ ｾ＠ # vr5 q;rq Ci>Ff qi fc:/f[
ｾｦＺｆｴ＠ I
3. 3/t. f{11.:37R. ｾ＠ Cj3fCff qi rpo 1 "sf ｾ＠ 7JT{ re!Ff rR JTTFfT m-r ｾ＠ ..,..,. fr2lT ｾ＠ rffllfff
ｾ＠ <PT iff11TC11 ｾ＠ '<'fT2T tt JTTFfT ｾ＠ ｾ＠ JTCml cR I
4. JfTl1 ｾ＠ 3lt.f{11.JIR. ｾ＠ rr:;;;; -sr ?R;r m frrtm em. ｾ＠ c;;R: JtT? R <1iT\5 ｾ＠
ｾ＠ ｾ＠ vm-
<'Iff <liT& ｾ＠ rR # J1Cml qm;rr tR 1 w ｾ｛ｩｦ＠ 1fPj{ rrtterTPff ctt
ｾｵＧｬ｣ｮｦ＠ "! frff ｾ＠ ｾ＠ gffflCfiT Ｂｉｦｾ＠ w Mff q;r f!ft fii4EIRt # wwr cR. ｾ＠ <r
m w ｾ＠ ｾ＠ w wdt fffrqt ?t ｾ＠ rttr q;v Wf!717. ｾ＠ Jtrrrr. :mrlCiiT
ｾ＠ tcrrf/71 37W<iff ｾ＠ ｾ＠ Cfft ｾ＠ ｾ＠ mfirc;r t:, llt ｾ＠ t I
5. 11T'T A I fr2!T '177T 'B' # rTfllq; rwr <5 2 ar<fi 'C' "If ｾ＠
1
rrFr 4 3Tilf <PT t 1 !lfllq; rmn
ｾ＠ <PT '3h.OJIMCfJ ｾ＠ 25 % Cfft <:"? # fitK:rr iJTTV1TT I
6. ｾ＠ rrFr <5 rfTi1 "ilR fiicm;q f?v 7JT{ ff I ｾ＠ # <tern \[iff fitq;c;q tt "mfr 3f2/CfT
ｾ＠ rn· t 1 3l7fl7fiT rTfllq; !1FT q;r ?rift JT2T<ff ｾ＠ rn ｾ＠ t 1
7. "'7lfM m ｾ＠ llT ｾ＠ ｾ＠ CfiT q;7 ffl ｊｾｒ＠
>I7Wr ｃｾｭｴ＠ ｾ＠ ｾ＠3RJｾ＠ ｾ＠ ｾ＠
1Wit ｾ＠ qi {t;rv ＠ｾ 06?TllT lifT ｾ＠ "! I
8. ｾ＠ rm
\3'ffi? llT ?Vi A c5 ｾ＠ ctJtf JfR <tJE1 ｾ＠ ｾ＠ f&Jro ｾ＠ 1
9. tfl<'1f1iHc'< q;r ｾ＠ Cl>F! Clfr ｾ＠ ＠ ｾ t · 1
I0. rRmr_ f/11Tfo . rw ｾ＠ ｾ＠ ffd%G rewr # 3/t. f{11.JTR". \3'ffi? rffl7fi q;f ｾ＠ -q-;VI
ｾ･Ｇ＼＠ ｾ＠ rm
Jff.v-r.JrR. iJfflV rrw; i'l'frT:t $ rmnn ;mer _p:rqft q;YJ'1<4fl ｾ＠
c>i' lifT W<fflt ｾｉ＠
I I. ftrcft 7fT'UT11Ｏ ｾ＠ q; rrFr "If ｾ＠ /rn<) lifFt w 31?lvft ｾ＠ m ff1fTfiJrq; fft7rT I
ctcm rrtterr qfr f!ft J!<f(i)' nq; tio.t <nc-1 ｾ＠ q;t tt rrtterr ｾ＠ '<'fT2T (7 lifFt ctt
JTTf{fr eft vmnft I

VTC7 ｾ＠ ...................... .

S/55 CSI/14-1AH-1A

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S /55 CSI /14- 1AH -18

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 3

ｾ＠

m $A<f{IG1 <iif ?;Ul;:jiG1 9.11 X 10- 31 kg

h t:Nicf; f.;) <kll q:; 6.63 x 10- 34] sec
e $Acti;IG1 CfiT ｾｔ＠ 1.6 x 10-19 C
k Ji<"<;;'HJOJIG1 f.;)lj('1jq; 1.38 X 10- 23}/K
c ｾｦｃｩｭｔ＠ 3.0 x 10 8 m/sec
leV 1.6 X 10-191
amu 1.67 X 10- 27 kg
G 6.67 X 10-11 Nm 2 kg-2
Ry ｾ＠ f.;) <lC'l i q:; 1.097 x 10 7 m- 1
NA ＳＱ｡ｾ＠ II?;) ｾ＠ 6.023 x 1023mole- 1
f.o 8.854 X 10-12 Fm- 1
Jlo 4rr x 10-7 Hm- 1
R ｾ＠ 'lR1 f.;) ll (1 iCh 8.314] K- 1 mole- 1

USEFUL FUNDAMAENTA L CONSTANTS

m Mass of electron 9.11 X 10- 31 kg

h Planck's constant 6.63 x 10-34] sec
e Charge of electron 1.6 x 10-19 c
k Boltzmann constant 1.38 X 10- 23]/K
c Velocity of Light 3.0 x 108 m/sec
leV 1.6 X 10- 191
amu 1.67 X 10- 27 kg
G 6.67 X 10- 11 Nm 2 kg- 3
R, Rydberg constant 1.097 x 10 7 m- 1
N,. Avogadro's number 6.022 x 10 23 mole- 1
f.o 8.854 X 10-12 Fm- 1
Jlo 4rr x 10- 7 Hm- 1
R Molar Gas constant 8.314]K- 1 mole- 1

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 4
LIST OF THE ATOMI C WEIGH TS OF THE ELEME NTS
Element Symbol Atomic Atomic Element Symbol Atomtc Atomic
Number Weight Number Weight
Acttruum Ac 89 (227) Mercury Hg 80
Alumtntum AI
200.59
13 26.96 Molybdenum Mo
Amcnctum 42 95.94
Am 95 (243) Neodymium Nd 60 144.2.4
Anttmony Sb 51 121.75 Neon Ne 10
Argon Ar 20.183
18 39.948 Neptunium
Arsentc Np 93 (237)
As 33 74.92 Ntckel Ni 28 58.71
Astatine At 85 (21 0) Niobium Nb 41 92.91
Banum Ba 56 137.34 Nitrogen N 7 14.007
Berkelium Bk 97 (249) Nobelium No
Beryllium Be
102 (253)
4 9.012 Osmium
Btsmuth Os 76 190.2
Bt 83 208.98 Oxygen 0 8 15.9994
Boron B 5 10.81 Palladium Pd
Bromtne Br 46 106.4
35 79.909 Phospho rus p
Cadmtum Cd 15 30.974
48 112.40 Platinum Pt 78 195.09
Calctum Ca 20 40.08 Plutoruum
Californium Cf
Pu 94 (242)
98 (251) Polonium Po 84 (21 0)
Carbon c 6 12.011
Cerium Potassium K 19 39.102
Ce 58 140.12
Cestum Praseodymium Pr 59 140.91
Cs 55 132.91
Chlorine Promethium RTl 61 (147)
Cl 17 35.453
Chromtum Protactinium Pa 91 (231)
Cr 24 52.00
Cobalt Radium Ra 88 (226)
Co 27 58.93
Copper Radon Rn 86 (222)
Cu 29 63.54
Rhenium Re 75
Cunum em 96 (247) 186.23
Dysprosium Rhodium Rh 45 102.91
Dy 66 162.50
Etnstetruum Rubidtum Rb 37 85.47
Es 99 (254)
Erbium Ruthenium Ru 44 101.1
Er 68 167.26
Europium Eu Samarium Sm 62 150.35
63 151.96
Fermtum Fm Scandium Sc 21 44.96
100 (253)
Fluorine F 9 Selenium Se 34 78.96
19.00
Franctum Fr 87 Silicon Si 14 28.09
(223)
Gadolinium Gd 64 Silver Ag 47 107.870
157.25
Gallium Ga 31 Sod1um Na 11 22.9898
69.72
Germanium Ge 32 stronttum Sr 38 87.62
72.59
Gold Au 79 196.97 Sulfur s 16 32.064
Hafntum Hr 72 178.49 Tantalum Ta 73 180.95
Helium He 2 4.003 Technetium Tc 43 (99)
Holm tum Ho 67 164.93 Tellurium Te 52 127.60
Hydrogen H 1 Terbium Tb 65
1.0080 158.92
Indium In 49 114.82 Thallium 11 81 204.37
Iodine I 53 Thorium Th 90
126.90 232.04
lndtum lr 77 Thulium Tm
192.2 69 168.93
Iron Fe 26 Ttn Sn
55.85 50 116.69
Krypton Kr 36 Titanium 1i
83.80 22 47.90
Lanth anum La 57 138.91 Tungste n w 74 183.85
Lawrenc tum Lr 103 (257) Uranium u 92 238.03
Lead Pb 82 207.19 Vanadium v 23 50,94
Lith tum Li 3 Xenon
6.939 Xe 54 131.30
Lutetium Lu 71 Ytterbium
174.97 Yb 70 173.04
Magnesium Mg 12 Yttrium y
24.312 39 88.91
Mangan ese Mn 25 54.94 Zinc Zn 30 65.37
Mendelevium Md 101 (256) Zirconium Zr 40 91.22
·eased on mass or C 12 at 12.000.. . The ratto or these
weights or those on the order chemica l scale (in which
natural isotopic compos ition was assigne d a mass or 16.0000 oxygen or
... ) Is 1.00005 0. (Values In parenthe ses represen t the most
stable known isotopes .)

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 5

ｾ＠ ｾ＠ I ｾＭｴｆ＠ ｾ＠ cf; ｾ＠ ｾ＠ ｾ＠ ttTft:r

3JT3T 'q;t I PART 'A'
ｾｃｒｉｔ＠
I. ｓｏｾＮｬｦｩ＠ 45 fcf>.lfi.
1. ｾ＠ ｾ＠ em ｾ＠ ｾ＠ -era- ｾﾭ 3. 35 f%.1fi. 4. 1of%.m.
ｾｃｊ［ｔｭ｣ｦ｡＠
2. Two locomotives are running towards each
ｾ＠ ｾ＠ ｾ＠ 3rcr.T ｾｴＺｭｲｯ］＠ ｾｴｵｦ＠ ｾ＠
other with speeds of 60 and 40 krn/h. An
cf; ｾ＠ ｾｩｬｱＬｊｉｦ＠ <IT ｬｩｦｾ＠ ｾ＠ ｾ＠ ｾ＠ .., object keeps on flying to and fro from the
ｾｉ＠ front tip of one locomotive to the front tip of
the other with a speed of 70 km/h. After 30
(a) ｾ＠ ｾ＠ ｬｩｦｾ＠ ｬｩｴＭｾ＠ ｾ＠ "ffirr ｾ＠ minutes, the two locomotives collide and the
mｾＭ＠ cf; ｾ＠ 1lT5I' ｾ＠ ｾ＠ 1 object is crushed. What distance did the
(b) ｾ＠ 9 ｾ＠ ｾ＠ ｾ＠ ｬｩｦｾＺ＠ uft ｾ＠ object cover before being crushed?
I. 50 km 2. 45 krn
"ffirr ｾ＠ I
3. 35km 4. IOkrn
Ｈ｣Ｉｾ＠ ＱＵｾ＠ ｾ＠ ｾ＠ ｾｉｃｦｬ＠ J1t."'ll'l"fo1
ｾｉ＠ 3. ｾ＠ f:l;:rljf.llT c); ｾＮ＠ ｾ＠
.;)
ｾ＠ w
(d) ｾ＠ ｾ＠ .., fJlt'IICfl'l 14 ｊＱｩｦｬｾ＠ ｾ＠ "ffirr ｾＮ＠ ｾＳｒｲｴｭＶＱ＠
ｾｉ＠ fcR:fr <m:;fttoM, ｾ＠ ｾ＠ ｾ＠ ｾ＠ m
.:>
CfiT
m q;r Cf<rr ｾ＠ t.'
I. 18 2. 24 1. :mel;' ｾ＠ 9? q;fcsr c); 6iU6R 61
3. 20 4. 38 2. ｾ＠ .3mrc1af c); .wrtm1 .;)
* 61
1. 3. ｾ＠ f:tT<rr c); .wrtm1 Jl 61
Lunch-runner pattern of a person for m days .;)

is given belo\\ He has a choice of a VEG or 4. ｾ＠ ｾ＠ ｾ＠ tli 3fG1tTI(1

..:>
Jl 61
a NON- VEG meal for his lunch/dinner
(a) If he takes a NON-VEG lunch, he will 3. A sphere is made up of very thin concentric
have only VEG for dinner shells of increasing radii (leaving no gaps).
{b) He takes NON-VEG dinner for exactly The mass of an arbitrarily chosen shell is
9 days I. equal to the mass of the preceding shell
(c) He takes VEG lunch for exactly 15 days 2. proportional to its volume
(d) He takes a total of 14 NON-VEG meals 3. proportional to its radius
4. proportional to its surface area
What ism?
l. 18 2. 24 4.
3. 20 4. 38 A ? Q E

2. 60 CillT 40 f%.1ft' ｾ＠ tit ｾ＠ 1Tfci'm cf; ftnT C M S C

ｾ＠ ｾ＠ lT<f> ¢ ｾ＠ 3ft{ m- ｾ＠ ｾ＠ I lT<f>
E K U A
ｾ＠ \fci;' ｾ＠ cf; mmm ｾ＠ ｾ＠ ＠ｾ ｾ＠
ｾ＠ (iqi', 3fT1)' .tftU; ｾ＠ (1{lii 70 f%.1ft' G W Y
ｾ＠ tit ｾ＠ 1TfR ｾ＠ ｾ＠ ｾ＠ 6 I 30 ｾ＠
GlT?; ｾ＠ ｾ＠ ｾ＠ ｾ＠ CillT ｾ＠ ｾＭ＠ ｾ＠ I. L ") Q
3. N 4. 0

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 6

ＸＭｾ＠ -3fftlT'fr ｾ＠
·1. f-ind the missing letter: 7. '(!Cii
- :rf:b-
ｾ＠
CfiT Rl<rl("tli
"
A ? Q E IJOI6("(1'J\v'l ｾ＠ ｾｆ＠ t I ｾ＠ 'fffim ｾ＠ 8 ｾ＠
ｾ＠
c M s c 1. 12 ｾ＠ ｾ＠ :ffi:r '# c:fr<ri' ｾｲｭ＠ ｾ＠ lmT I
-ｾ＠ ｾ＠ 3in *
'tiT{ ｾｲＮ］ｭ＠
"
ｾ＠
E K u A 2. 11
- lmll
3. 11 ｾ＠
- ｾ＠ 3in *
rfr<rl' ｾｲＮ］ｭ＠
"
ｾ＠ Wfl
G I w y
4. 12 ｾ＠ ｾ＠ 3in ｾ＠ * ｾｆＪ＠
"
ｾ＠ Wfl

1. L 2. Q 7. The least significant bit of an 8-bit binary

3. N 4. 0 number is zero. A binary number whose
value is 8 times the previous number has
5. 'C!c:n ｾ＠ mｾＮｭ＠ ..)
-R ｾ＠ '(!Cii <fit m-1 o35/- I. 12 bits ending with three zeros
Ｊｾ＠ tl ｾ＠ ..) * ｾ＠ ＱＰＥｾ＠ ｾ＠ 2.
3.
II bits ending with four zeros
II bits ending with three zeros
ｾ＠ t Clm ｾ＠ '# 15% q;r ｾ＠ I ｾ＠
4. 12 bits ending with four zeroes
C!i('f ｾ＠ q;r ｾＱＨ＠ q:m t?
*
.!)

I. ＵＥｾ＠ 8. ｾ＠ 3l<ri'Sfi'IJOI' ｾ＠ ｾ＠ ..) q:m t?

2. < I% c>rra:r 2, 3, 4, 7, 6, II, 8, 15, 10 ...

3. ＼ＡＥ ｾ＠ I. 12 2. 13
3. 17 4. 19
4. ｾｭ＠
8. What is the next number of the following
S. A person sells two objects at Rs.l 035/- each. sequence?
On the first object he suffers a loss of I 0% 2, 3, 4, 7, 6, II, 8, 15, I0 .. .
while on the second he gains 15%. What is
I. 12 2. 13
his net loss/gain percentage?
3. 17 4. 19
1. 5% gain
2.
3.
< 1% gain
< 1% loss 9. ｾ＠ <.YR:r ｱｬｾｓｨ＼ｈ＠ ｾ＠ ｾ＠ * ｾ＠ 20%
4. no loss, no gain :mftu'r M ｾ＠ lfcli ｾ＠ ｾ＠ 3kK ｾ＠ q']"(f 6
I ＺｭｦｴｵＧｲｍｾﾢｆ＠
6. ｶ･ｦｩｾＧｑｃｴ＠ ｾ＠ ｾ＠ 'R ｾ＠ 20% ｾ＠ q']"(f 6 I
1600 ｾ＠ ｾ＠ ft:tQ' ｾ＠ m:rr Fvrcnr 3l"TaT ｾ＠ ｾ＠ GITC; 'll1tr 16 fcrtmft iH1-?tJtl{ ｾ Ｎ＠ m
em ｾ＠
ｾ＠
ｾ＠
JOOO/- ｾ＠
t,
Fvrcnr
ｾ＠
ｾ＠
&lffi5f ｾ＠
ｾ＠ 400 ｾ＠
ｾ＠
"
1

'#
ｱｊｯｾｓｨ＼ｈ＠
I.
-
32
* C!it'f
..)
ｾ＠ ｾ＠
2.
:mftu'r tir?
64
ｾ＠ ｾ Ｎ＠

3. 25 4. 100
t,TM1 &lffi5f ｾ＠ ｾ＠
l. 250 2. 183
9. 20% of students of a particular course get
3. 148 4. 190
jobs within one year of passing. 20% of the
remaining students get jobs 'by the end of
6. A bank offers a scheme wherein deposits
made for 1600 days are doubled in value, the second year of passing. If 16 students are still
interest being compounded daily. The interest jobless, how many students had passed the
accrued on a deposit of Rs.l 000/- over the course?
1. 32 2. 64
first 400 days would be Rs.
3. 25 4. 100
1. 250 2. 183
3. 148 4. 190

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 7

10. ｾ＠ d c;m ｾ＠ d/2 <l> "QCfi Jm«i ｾ＠ VCfi 12. "QCii ｾ＠ ｾ＠ ll<fi ｾ＠ 'R ｾ＠ R ('fCfl

iiiT{ ｾ＠ ｾ＠ eli Pit QCf "QCfi art ｾ＠ ｾ＠ mfr f; I W ｾ＠ rnt cnT ｾ＠ rT·
ｾ＠ <l> f7rt qt- ｾ＠ U111<IT aT<1T ｾ＠ ｾ＠ ｣Ｚｲｭｾ･ｬｩＭｯ
" ｾ＠
ｩＡｔｻｈｾｱ［ｲ＠ rT· "QCii ｾ＠ ｾ＠ ｾ＠ ｾＮ＠ VCfi ｾ＠ offi1 eli
* ｾ＠
ｾ＠

I.
3.
I: I
J :3
2.
4.
I :2
I :4
ｭｾ＠ 3fldT(1T t 1 'ilR ｾ＠ s* q1l"
ｾ＠ ｾ＠
ｾ Ｒ＠
ｾｦ［＠ R/2
10. A rectangle of length d and breadth d/2 is ｾｈｊｗ＠
revolved once completely around its length
and once around its breadth. The ratio of
volumes swept in the two cases is
I.
3.
I: I
1:3
2.
4.
I :2
I :4
@
1. .fi ｾ＠ 2. Ｒｾ＠
11. ＠ｾ Jliilctfi1 'I * ｾ＠ :;rcrrc; CfiT ｾ＠ 3. ｺｻｦｾ＠ 4. Ｔｾ＠
gtsjf H ｾ＼ｲ＠ 3'CNr ｾｐｉｔ＠ 1fliT f; I <$
12 . A long ribbon is wound around a spool up to
ｾｲｮＪ＠ a radius R. Holding the tip of the ribbon, a
ｾ＠ 6. m ｾ＠ ｾ＠ *·:m ｾ＠ eli Jm..<r 'R boy runs away from the spool with a constant
speed maintaining the unwound portion of
ｾ＠ ｾｉｃＧｦ＠ cr<lCT1(1J4 tiT?
" t he ribbon horizo ntal. In 4 minutes, the radius
ｾﾷ＠
400
350
of the wound portion becomes In what
(250 ± further time, it will become R/2?
300
75J (200 ±
250
75)
200 [150 ±
150
SOJ
1 (100 +
100 SOJ
50

2000 2001 2002 2003 I. J2 min 2. 2 min

3. 2v'2min 4. 4 min
I. 2000 2. 2001
3. 2002 4. 2003 n. ｾ＠ 1mr * ｾｭＺｲ＠ mrr t. "QCfi tfi"ifr VCfi anm-
11. Average yield of a product in different years
'R nsfr s* 6 I ｾ＠ $ 3i'rtT rM ｾ＠ BR
is shown in the histogram. If the vertical bars veT 8 A ｾ＠ ｾ＠ 6 I JrTtlR 8 ｾ＠ f;, ctt
indicate variability during the year, then
during which year was the percent variability
tfi"ifr Cf1T ｊＱｴＮｾ＠ c ｾ＠ r:r ｾ＠ t
over the average of that year the least? A

400
350
(250 ± c
300
75J [200 i
250
(150 ± 75J
200
150
so, (100 ±
100 so, B
50

2000 2001 2002 2003

). 2000 2. 200 1
3. 2002 4. 2003

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 8

13. A ladder rests against a wall as shown. The ｾ＠ ｾ＠ t I ｾ＠ ｾ＠ qw:r ｾ＠ q;l'f V<li
top and the bottom ends of the ladder are "
marked A a)td B. The base B slips. The
3reR' ｾ＠ 'QCti' Jtq:; cnr ｾ＠ ｾ＠ t 1 3fa'RT
central point C of the ladder falls along ａｾ＠ zrrcn, ｾ＠ ｾ＠ 9 ｾ＠
ｾ｡ｔ＠
1. 936 2. 1148
3. 1872 4. 2574

16. A code consists of at most two identical

letters followed by at most four identical
digits. The code must have at least one letter
and one digit. How many distinct codes ·can
0
1. a parabola be generated using letters A to Z and digits I
2. the arc of a circle to 9?
3. a straight line I. 936 2. 1148
3. 1872 4. 2574
4. a ｨｹｰｾｲ｢ｯｬＮ｡＠

14. 61'1\5lalfU1<"1 ｾ＠ ｾＭ＠ ｾ＠ ｾ＠ (I + ,x)" = a0 +

17. mｾ＠ ｾ＠ 'lffi>IT <m 1ｯｾＮ＠ rrcn -am:r ｾ＠ c%
arx+ a2-i+ .....+anXn, ｾ＠ a0, ar. ..... , On n tR' ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ -aT<iT 6 I 3'affi ｾ＠ 'QCti'

ｾ＠ ｾ＠ tf ll)JJQ)(>l ao + a1 + a2 +.... +
ｾ＠ ｾ＠ arr<tiTt ｾ＠ c:rtrr ｾ＠ ｾ＠ ｾ＠ 3f1'Cm'

a, q::m t? ｾ＠ t. mq;'f;r-m mm m- ｾ＠ cnmr-nrtr

I. 2" 2. n (.m:R") rr<fi q!:;:) J II !
3. n2 4. n
2
+n t. ｾｭＭ

14. Binomial theorem in algebra gives (1 + = xr 2. -mer mm-

2
ao + a,x+ a2x +.....+a,x", where ao, at, ..... , an 3. zym ｾ＠ 'QCti' mtT
are constants depending on n. What is the 4. <r6 <nmr-(ll'q' tR' ｾ＠ WIT
sum ao +a, + a2 + .... +an ?
1. 2n 2. n
2 17. Two solid iron spheres are heated to .100°C
3. n 4. n2 + n
and then allowed to cool. One has the size of
a football; the other has the size of a pea.
15. ｾ＠ q;l aRT w: Which sphere will attain the room
2,5, 10, 17,28,41,-,-,- temperature (constant) first?
I. 58, 77, lOO 1. The bigger sphere
2. 64, 81, 100 2. The smaller sphere
3. 43, 47, 53 3. Both spheres will take the same time
4. 55, 89, 113 4. It will depend on the room temperature

15. Continue the sequence 18.

2,5, 10, 17,28,41,-,-,-
I. 58, 77, 100 70, 72, 74, 76, 78,80,82, 84,86, 88,90,92,94
2. 64, 81, 100
3. 43, 47, 53
4)- 3W ｾＮ＠ ｾ＠ ｾ＠ 1oo f%:m. rrm
4. 55, 89, 113
79 f%.m. tf. -ww ｾ＠ ｾｔ｀ｮ［ｲ＠ ｾ＠ tf 1 CiT -ww
16. Vcli ｾ＠ ｾ＠ ｾ＠ 4)- ｾ＠ ＨｾＩ＠ cnr mor ｾ＠ ¢ ｾ＠ ｾ＠ 6:
3-Ta'R, 'fM ｾ＠ ｾ＠ ｾ＠ "Cl'R' ｾ＠ 1. of<n:m. 2. 1f%.m.
3. 1.6 fco.m. 4. 1.8f<f>.m.

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 9

18. Weights (in kg) of 13 persons arc given 21. The reaction betW!!t:n SbF5 and iwo equivalent s
below: of HF leads to the formation of
70. 72. 74, 76, 78, 80, 82. 84. 86, 88. 90, 92, I H2Sbro + 2F2
94 2 H ｓ｢ｆｾｔ＠ 3F2
3. Sbf, + H2 + 2F2
Two new persons having weights 100 kg and 4. [SbFor [H2F] '
79 kg join the group. The average weight of
the group increases by
22. ｯＭｾｴＮ＠ ｑｴ［ｾ＠
I. 0 kg 2. 1 kg
3 1.6 kg 4. 1.8 kg 1. Ｇ､ｸＲ Ｍ Ｏｃｊｭ､ｾＲＮＬ＠ ｾ＠
2 du crm du .3fTfftu;r
19 ｾ＠ nVC!i' tm ｾ＠ t. nT 3. d,y CitfT ､ｸｾ＠ ｾ＠
n(n+ I )(n+2)(n+3 )(n+4 )(11'1'5)(n+6)
4. dyz ｾｔ＠ dyz ｾ＠
ｾｴＺ＠ •
I. ＳｾＷｯＺＤｩＧ＠ 22. The 8-bond is formed via the overlap of
2. 3 3fit7 ｾ＠ I d/ /and d/. / orbitals
2 dxz and dtt orbitals
3. ＷｾＳ＠
3. dxy and dxyOrbitals
4. ;f m3 ｾＮ＠ ;f 1 ｾ＠ 4 dyz and d\'Z orbitals
19. rfn is a positive integer, then
n(n+ I )(n+2)(n+3 )(n+4)(n+S )(n+6)
23.
ｾ＠
F",Na\02 ｣［ｴｬｔｍｧ Ｒ
Ｇｾ＠ * ｾ＠ ｾ＠ ｾ＠
is divisible b} ｾ＠ (itlT cr4Cii(iJOI ｾ Ｇ＠ ij' ｾ＠ ｾｔＺ＠
I. 0 2. c:JmNa-
"
I. 3 but not 7
2. 3 and 7 2 F- c;m Mg2 •
3. 7 but not 3
3. ｯ Ｒ
Ｍ ｾ＠ Mg2
4. neither 3 nor 7
4. Mg2 'c:Jm o 2-
20. 3ITll111 50 1ft.. 120 ;fr \rei 130 ;fr ci; 'tJCF
23. 1\mong F . Na· , 0 1 and Mg' ions, those
ft)(h'lu"4 ＠ｾ q:;r ･ｾ＠ ｣･ｮｔｾ＠ ｒＩｾ＠
having the highest and the lowest ionic radii
1. 3000 2. 3250
respectivel y are
3. 5550 4. 7800
I. 0 2 and Na·
.,.
20. The area (in tn 2 ) of a triangular park of
2 F and Mg-
2
dimension s 50 m. 120 m and 130 m is 3. 0 and M!(
4. Mg2 'and0"
I. 3000 2. 3250
3. 5550 4. 7800
24. Ｈ｡ＩｾＮ＠ (h) Ch)Q.-\511$1R 8 12 CitiT (c) CfC'fi:J.)fQl(>l
cfi ｾ＠ ｾ＠ ｾ＠ ｾ＠ n-$<'lct?I01 Ｇｦｬｾｊ［ｩｪ＠
31TcTT ﾷｾ＠ I PART I B I
q:;r q ｾｊｏｉｕ＠ f3rn' ｾ＠ Cf;T 3r.i'ffi'Ur
.;)
ｾ＠ t.
ｾｴ＠
(a) (c)> (b) 2. (a )> (b)> (c )
3. (c )-. ( a )> (b) 4. (b) ::<-(a) > (c)
ｾｦＺｲｭｵｴ＠
(if; tit 24. The extent of n-elcctron conjugatio n m
1. H2SbFl + Ｒｆ ｾ＠ macrocycl ic rings of (a) heme. (b) coenzyme
2 H SbF 2 + 3F2 Ｘ Ｑ ｾ＠ and (c) chlorophy ll follows the order
3. Sbf1 + ｈｾ＠ + 2F1 I (a) > (c ) ' (b) 2 (a)> (b) ·(CJ
4. (sbr6J [H2rr 3 (c )>{a )>(b) 4 (b) ""(a)> lc)

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 10

fclf.!i&Fll ｾ＠ ｾ＠ ｾ＠ tR 28. The hapticities 'x'and ' y' of the arcne moieties
25. ｾＨＢＴｬｨｩＧ｣ｲＱ＠ ｾ＠
in the diamag netic comple x [(7l-C6116)Ru(rf -
ｾ＠ ＠ｾ CfiT ｾ＠
ｾ＠ ifiJOf 6 C6H6)] respect ively are
I. Ag' > K' > Na '> Li' I. 6 and 6 2. 4 and 4
2 K'>Na'> Ag.>L i 3. 4and6 4. 6and 2
3. Li'> Na '> K+> Ag'
4. Lt > Na' > Ag+> K'
29. ｾ＠
hv
25. The correct order of the retention of cations on Ni(CO )• + PPh3 ...,.. [Ni(C0 )3(PPh 3)] + CO
a sulfona ted cation exchan ge resin column is
｣ｦＺｲｾＶ＠
I. Ag" > K• > Na+ > Li'
2 K ' > Na• > Ag' > u· I. ｾ｣ｦＺｲｴｒ＠ I
3. Li' > Na ... > K' > Ag+ 2 ｾ＠ Ni(C0)4 cf:r mrwrr tR I
4. Li" > Na+> Ag·> K..
3. ｾ＠ PPh 3 cf:r mr?JIT tR I
KCI ｾ＠ 4. PPh 3 cf:r ｾ＠ ｾ＠ tf{ I
26. ｱＩ＼ｨ［ｵ｣ｦｬｾ＠ mq;; ｾ＠ Ｈ ｾ＠ <iiT
"
ｾ＠ ｾ＠ ｦ｣ｲｰﾷｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ Ｉ＠
29. The rate of the reactio n
+0.4 V ｾ＠ JTfUq; fcmcr ｾ＠ ｾ＠ CfiT ｱｾｕｉｊｏＡ＠ hv
Ni(C0) 4 + PPh3 ...,.. [Ni(C0 )3(PPh3)] +CO
ｾＺ＠ fctttr;r t depend s on
2. Hg11 CfiTI I. concen tration of both the reactants
2 concen tration ofNi(C 0)4 only
4. 0 2 CfiTI
3. concentration of PPh 3 only
4. the steric bulk of PPh 3
26. ln a polarog raphic measur ement, (aqueo us
KCI solutio n used as suppor ting etectrolyte) an
ｾ Ｎ ｃｏ＠ C1m H2 cf:r, Co2(CO)a ｾ＠ ｾ＠
applied potenti al more than + 0.4 V, results 30.
mainly in the formation of ｾＮＶ＠
I. Hg1 2. Hg11
4. 02
I. qtr!'l$cti 31R'f
3 Ch
2 ｾ＠
ｦｱｩｾｬＱ＠ CFe
7 "
27. m ｾ＠ ｾ＠ ｾ＠ #ffi ii'R
Rtcr)
l.
ｾｊｏＡｉｃｱ＠
Fe(IJ) >
*
Fc(III)
ｾ＠
>
CfiT ｾ＠
Fe(TV)
sn;r ｾ＠ I

2 Fe(III) > Fe(II) > Fe(TV) 30. The produc t ofthe reaction of propen e, CO
3. Fe(IV) > Fe(TTI) > Fe(H) and H2 in the presenc e of CD2(C0)8 as a
4. Fc(IV) > Fe(II) > Fe(lll) catalys t is
I . butano ic acid
27. The correct order of the isomer ic shift in 2 butanal
Mossb auer spectra CS'Fe source) of iron 3. 2-butan one
compo unds is 4. methyl propan oate
I. Fe(ll) > Fe(III) > Fe(IV)
2 Fe(Ill) > Fe(II) > Fe(IV)
31.
3. Fe(IV) > Fe(IIl) > Fe(II)
I. Yl <iml 2. ｾ ｮｭｯ＠
4. Fe(IV) > Fe(II) > Fe(Ill)
3. 1 nmo 4. 3/2 nmo
28. ｾ＠ ｾｫｬ｣ﾮ＠ ｾ＠ [(7l-C6H6)Ru(rf-C6H6)] ｾ＠
15
ｾ＠ cf:r ｾ｣ｴｬｦＧｩ＠ 'x' <1m 'y' ｳｮ［ｲｾＺ＠ ｾ＠ 1 31. The Sand L values for N atom respect ively,
are
I. 6<1m6 2. 4c-Tm4
l. Y2 and I 2. Y2 and 0
3. 4 Mm6 4. 6 c-Tm 2 3. I and 0 4. 3/2 and 0

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 11

ＬＮ＠ ｾ＠ ft:rQ- ｦ｡ｾﾭ !. tran.1-(PtCI2(N0 2 )(Nfhl]

32. /ram-[Cr(enh Fll. c=IWr ｛ｔｩｃｉｾ
2 ＬＭｾＨｐｴｃｉ Ｒ ＨＧ｜Ｐ ｬ ＩＨｎｈＮ＾ ｉ＠
mw Ｇｈｉｾｩ＿ｬ＠ 6. ｾｔＺ＠ 3. rram-[PtCJ,(N H;),]
D3d <1m 4. C/S-(PtC12(M>2hll
1. ｄＬ｣Ｑｾ､＠ 2. D4d

4. DJt. 'C'fW D," 35. In the follov. ing, ｲｾ｡ｯＺｴｩｮ＠

., _ NH3
[PtCir]" .._ NO! ｾ＠ A __, R
32. The point group symmetries lor trans-
3
[Cr(cnhF2r and [TiCl6] - . respectively are compound B is
l. 04d and o,d 2 ＰＳｾ＠ and 04d
I. trcms-[PtCI2(NO_)("\H 3 )j
3. 04h and 03h 4. 03h and o,h
2 ci.\-[PtCh(N 02)(NH,)r
3. trans-[PtCI 2 (NI-1,)2]
33. Co4 (CO)t_ ｾ＠ ｾ＠ 4. ci.\-fPtCb(N02)2] -
2

I. ｣ｬｯＮｷＭｾ＠
2 ｮｩ､ｯＭｾ＠ 3<>. ｾ＠ 61'fHT 'HIll ｾ＼ｲｩ＠ ｾ＠ ｾ＠ 6rfH' rRT?Jroi
3. arachno- ｾ＠ it> ｾ＠ ｾ＠ ｾ＠ ｾ＠ 'HA.-ClfllCi

4. ｨｹｰｯＭｾ＠ ｾｦ､Ｇｬ＼ｲｩ＠ ｾ＠ .3I"R''' cf; <rii$?'131<ri qn:nurJit ｾ＠

*t ｾ＠ 6 ｓｦｩＱｾｌ＠
33. Co4(C0), 2 adopts the L 2, 3 c;m 3, 3
I. closo - structure
2 3. 3 ＨＧｦｾｬｔ＠ 2. 3
2 mdo - structure
3. arachno- structure 3. 3, 3 Cim2. 2
4. hvpho- structure 4. 2, 4 c;m 3. 2

34. ｦ｣ｈｾ＼ｲｩＧｃ＠ Ｎ［ＩＨＢｾ＠ '{ Cf> ｾ＠ ｾ＠ cf;

36. The number of histidine amino acid nitrogen
, atoms coordinated to bimetallic active site of
Jlq'tllliCfi f(l(>l)q<ri <liT qc;
ｾ＠

ｴｩｾｉＮｊＱｯｃｦ＾ｻ＠ Ul
*ｾ＠ 'fiA.,-qll oxyhcmocyanin and oxyhemerythrin.
ｾｦ［＠ I (Rh AUSM * Ri(>llllq-, respective!), are
ｱ［ＧｲｾＩ＠ I. ::!, 3 and 3, 3
I. ｔＭｾ＠ CfiT [Rh(PPh)hCI ] 2 3, 3 and 2, 3
2 ｾ＠ ｾ＠ [Rh(PPh 3 hCif· 3. Ｓｾ＠ 3 and 2. 2
4. 2. 4 and 3. 2
3. T- .mq:;fct
c.
<liT [Rh(H)(PPh,) CJf
•
4. ｾ＠ ｾ＠ [Rh(H)(PPh 1h] 37. ｾ＠ cfi ｾＮ＠ 'QCii q4ia«or ｾ＠ ｾ＠ ｾ＠
R ｾ＠ ｾ＠ q:;T qt::all'ill:! I
34 Reductive elimination step in hydrogenation
A. Cfilhtulillo-t"l ｾ＠ ｾ＠ ｾ＠
of aiJ...enes by Wilkinson catalyst results in
(neglecting solvent in coordination sphere of MeHg' R ＧｻｬｱＮＬＭＨＱｾ＼＠ ＼ｦｩｴｾ＠ t
Rh) B. ft Rl01 ｾ＠ Uf$'JITc;r 11'Cf ｾ＠ ｾ＠ cfi
..:>
I. T-shaped [Rh(PPh3 ) 1CI]
2 Trigonal-planar [Rh(PPhJh Cif ｾ＠ Gitrc=rr
..:>
ｾ＠ t:tft f;
3. T-shaped [Rh(H)(PPh ,)ctr c. :Mlc;_ll'rfJrq:; ｾ＠ ｾ＠ mq;fr ｾ＠
4. Trigonal-planar [Rh(H)(PPh3 h] UT ｾ＠ ｾ＠ ｾ＠ ｾ＼ｲｩａｉｃＺ＠ ｾ＠ ｾ＠ I

ｾ＠ ｾ＠ ｾｦ［＠
35. ｾｃｨｲｬｦｩＧ＼Ｑ＠
NH3 I. A c=IWr B 2. ａｾｃ＠
｛ｐｴｃｉｾｦ＠ ｾ ｎｏ｟＠ --+ A __, B
.) . ｂｾｃ＠ 4. A, B CimC

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 12

37. Identify correct statements for mercury as an 0

｀ｎｾ＠
environment pollutant. Me
N'
A. Carbanionic biomethylation converts
it to MeHg• oANI
®weN
BF 4-)t_
[}E)
N+
I
B. Thiol group of cysteine has strong affinity Me H2N'" NH2 BF4- Me
for mercury
II Ill
C. Mercury containing industrial catalyst
release caused Minamata disaster I. I<II<III 2. I<Ill < ll
The correct answer is 3. 11 <1<111 4. II<III<I
I. A and B 2. A and C
3. 8 and C 4. A, 8 and C 40. The increasing order of pKa values of the
circled hydrogens in the following
38. compounds is
0

｀ｎｾ＠
Me
I

N
I. R (;tiTS 2. S CfmR
oA N
[}E)
N+
3. R C1trr R 4. scrm s I BF . I
Me 4 Me

38. The configurations of carbon atoms C3 and II Ill

C4 in 0-ribose, respectively, are I. l<ll<III 2. I< III < II
3. ll<l<III 4. II < III <I
I. R and S 2. S and R
3. R and R 4. S and S
41. ｲＺｴｫＱｾｕｓｉｃ＠ ｾ＠ <f:r ｾ＠ ｾ＠ q;r sn7:r
39. 6
H

0
H N
[1
0
8

II
0 Ill
E>=o
IV
N

II Ill
N
IV

I. I > II > III > IV

2 IV > I > H > Ill
I. I 2. II 3. Irl >II> I> IV
3. Ill 4. IV 4. IV > III > II > I

39. The compound that is antiaromatic is 41. The decreasing order of basicity of the
H following compounds is

0
B
J? 0 II Ill
IJ::'-=0
IV
[>>
H
N

N
&ｈＭｎｾＩ＠ 0 N
I. I 2. II II Ill IV
3. III 4. IV
I. l > Il>III>IV
2 lV>I>II>III
{;j k1 ｾ＠ ft!l C1 ｾ＠
40. if;
crm * ut6 sv 3.
4.
HI > IT> I> IV
Ｈ｜ｬＤｾＩＳＱ｣ｲｴＧｩ＠ ｾ＠ pKa ｾ＠ q;r ｾ＠ q;r sn11 TV> III> II > I

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 13

42. ｦＮｩｾ＠ 44.

ＧｈｉＤｃｦＨ＾ＩｾＺｬＰＱ＠ ｾ＠ ｾ＠ ｾｊｩＧｴ＠ * f'lfcm
'{I'HI4o-t"i ｾ＠ 6
I. OH: RlCS!ckll'l;
.:>
i-Pr: Rl"ictn"i4
.:>
ｾｍ･Ｚ＠
ｦＧＺｾＡｮＢｩｲｃＮ｣Ｑ＠ 4,.,.
.:>

2 OH: 3refl<f; i-Pr: fc:l<i1Cl<1lll

.:>
(it1T Me:
3. .
3.
Rl<i1ctcflll
.:>

OH: Rlt!1ari'l4;
.:>
i-Pr: fa<i1ctn"i'l
.:>
Cim Me:
:rD
,•
0
. 0 l
.
4.

31aft<r
4. OH: fa<i1c:tcfl4
.:>
; i-Pr: :trmrrm Me:
44. The reaction of 1-bromo-2-fluorobenzene
with furan in the presence of one equivalent
42. In the most stable conformation of neomenthol, ofMggives
stereochemical orientation of the three substi-
l. 2.
tuents on the cyclohexane ring are
1. OH: equatorial: i-Pr: equatorial and
Me: equatorial
2 OH: axial; i-Pr: equatorial and Me:
equatorial
3. OH: equatorial; i-Pr: equatorial and 3. 4.
Me: axial
4. OH: equatorial: i-Pr: axial and Me:
equatorial

43 . f.!l<hl1ffiffi<1 ｾ＠ t- ｾ＠ ｾ＠ t- 45.
fcf;t<;r ｾ＠ em ｾ＠ ｾ＠ ｾ＠
Et .,H )J0 Et "'>·''H HO"'>',,H
1 ｂｲｃｈ Ｒ Ｐｍ･ｦｐ ＨｏｅｴＩｾ ｄｍｅ＠ ...
. .ｘ ｾＮＬﾷ｟Ｚｊ＠ .... Ｍ
LiAIH4
ｾ＠ ..- ·,/"-'fs ., 2. NaHIOMF
Me Me
Major product I. 2.
r-0
I.
3.
3R, 6S
3R, 6R

43. The absolute configurations of the chiral centres of

2.
4.
3S,6S
3S, 6R
6 4.
I

Ｇｾ＠
I

3.
starting ketone in the following reaction is

Et....._.•,
H HO"'>·''
H
ｾ ｳ Ｂ＠
Me Me 45. The product for the following sequence of
MaJor product reactions is

I.
3.
3R, 6S
3R. 6R
2.
4.
3S,6S
3S. 6R 6 0 1 BrCH 20MefP(OEt)31DME
2. NaHIDMF
3. H3o+

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 14

I. 2.

3. CHO 4.

6 COOH 2. COOH

ｾ＠ ｾ＠
46.
Ｇﾷ ｾ ﾷ ﾷ ｾ＠
47 . The major product of the following reaction
is

I. 2.

2. COOH

3. 4.
ｾ＠
ﾷ ﾷｾ＠
46. The major product formed in the following
reaction is 48.

1. sec-Buli ｾ＠ Br2 {excess), CHCI 3 , rt

2. C02 ...
1. ｂｲ ｾ ｂｲ＠ 2. Br

ｾ ｲ＠ Br' Q ｾ＠ j
I
I. 2. : : ,. . s

3. Br 4.
ｂ ｲｾ＠ I ｾ＠
0}-sr : : ,. .
Br
s

3. 4.
48. The major product of the following reaction is

Br2 (excess), CHCI 3, rt

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 15

l. B r ' C r J 50. A compound with molecular formula C4H60:

, 'j-ar shows band at 1770 em·' in IR spectnun and
ｾ｟ＮＭｳ＠
peaks at 178, 68. 28, and 2::! ppm in "C NMR
spectrum. The correct structure of the compound
is
ｂｲｾ＠
3. Br 4.

cQ-ar ｾ＠

Br
I -,
s 1.
Ｍｾ＠
,;0 2. Ｐ ｾ
l_j
Ｐ＠
r o
49. ｦｩｬｫＱｾｃ＠ 1TcmT-{1'814filCfl ｾ＠ q;r* 4.
ｾ＠ ｴｾ＠ 3. 0 ｾＰＬ＠
'3('tiT?;
1\-o I
ｾ＠
ｍ･ｾﾷＧ｟ｶ｡ｰＭｲｨｳＮＬ＠
0

51. F 1+ c'i; fa ｬｾ｜ＵＱＰＧ＠ ｾ＠ filklfc:lflll(1 ｾ｣ｬｊＱｃｩ＠ '&Sa;

0
ｾ＠ ;:f ｾ＠ ｾ＠ 3iTll0'1" CfiT ｾ｣ｬｊＴＱＰＧ＠
l. ｾ｣ｩｳＭＱＬＲ＠ t (Dtethyl phthalate"' ｾＩ＠
2 ｾｴｲ｡ｮｳＭＱＬＲ ｾ＠
Diethylpht halate- F1·--... F2• .. CO
3. cis- miT trans-1,2- ｾ＠ (M• 222) (171)
CfiT ｾ＠
1. 141.2
4. ｾＲＬＶＭ＠ 2. 125.4
3. 45.0 4. 210.2
49. The cyclic product(s) of the following
51. The mass of metastable ion produced due to
photochemic al reaction is(are)
decomposition of p 1+ in the following mass

ｍ･ｾﾷ Ｇ ｍ･＠ ｶ｡ｰｾｲ＠

fragmentation sequence is
phase
D•ethy• phthalate Fl. F2. + co
0 (M•, 222) (177)

1. only cis- I ,2-dimethylc yclopentane I. 141.2 .., 125.4

2 on I} trans-1 ,2-dimethylc yclopentane
3. a mixture of crs- and trans-! ,2- 3. 45.0 4. 210.2
dimethylcyc lopentanes
4. only 2,6-dimethy lcyclohcxano l 52. CD1CI ｾ＠ ｾ＠ CiiTft *" 13
C NMR ｾ＠ ｾ＠
ｾＪｲｊｉｔｃｦｩ＠
50. ｾ＠ ｾ＠ ｾ＠ IR ｾ＠
"
C4H602 CfiT 'Q'Cfl'
t
if 1770 cm·1 tR' ｾ＠ ｾｦｲ｣Ｚ＠ t om 13
C NMR I. I :4:6:4:1
ｾ＠ if 178, 68, 28, CitlT 22 ppm tR' ffm:r<;r 2 1:3:3:1
3. I :6:15:20:15:6: I
ｾ＠ tl 4'tf1Tq:; <fi't ｾ＠ ｾ＠ t 4. I :3:6:7:6:3:1

__(p -,.,
I. 2. o-'>=o
.... -..../
=>-. The ratio of the relative intensities of the
carbon signals in the first order uc NMR
.J-O spectrum of CDJCI is
/
l. 1:4:6:4:1
3. ...- 0 4. ｾ ｯ＠ .. ' 2
..,
I :3:3: I
)=:O I .). 1:6:15:20:15:6:1
ｾＮｊ＠ 0 4. I :3:6:7:6:3:1

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 16

53. Qfct!QR:<t> m CfiT ｾ＠ ｾ＠ 61 3. ｾ＠ n:r;r (1m Ｄｾｃｦ＼［ｬ｣ｴ＾＠ fq<t<;ft!Jll

I. fil ｾｆａＢＧ＠ 31R'I' 4. cf;q;; nm Ｄｾ＼ｴ［ｬｦ＾＠ ｦｑ＼ｴ［ｾｊｲｬ＠

2 ｴｬ｡＼ＧｦｾｱＬ＠ ｾ＠
55. Bond lengths of hornonuclear diatomic
3. ihWH'l f.A<t> ｾ＠ molecules can be determined with the help of
4. ｾ［Ｉｦａｃｬ＠ ｾ＠ both
l. rotational and vibrational spectroscopy.
53. The biosynthet ic prl!cursor of abietic acid is 2. rotational and rotational Raman spectrosco py.
I. shikimic acid 3. rotational Raman and electronic spectrosco py.
2 mevalonic acid 4. vibrational and electronic spectrosco py.
3. chorismic acid
4 cinnamic ac1d 56. 'fft ｾ＠ o=qCf<'i'll1 ･［ｾＴｻｊｩＰＱｃｦ＠ 3fC1T c);- ｾ＠
" .. .:> .:J

ｾ＠ ｾ＠ ｾ＠ CfiT ｾ＠ 3m c);-
54. ｾ＠ ftcr crftm ｾ＠ c);- ｾ＠ JT"FN QCCh' ｾ＠
'HiliG'IIcr(i{ ｾ＠ ｾｆ＠ ｾ＠ t. err ｾＭ＠

COOH ｾｭｲｴ＠

Ｈｾ＠ -../COOM e I. ｾ＠ ｐｃＱｭｒｾ＠

ｈＲｎｾ＠ : 2. ｾ＠ Pntrr Q ｾ＠
3. ｾ＠ Qntrr ｒｾ＠
O 'Ph
4. ｾ＠ P, Qntrr R ｾ＠

I. 0-fli'i.._tl?!Cfl .w:1'f C1m ｌＭ｣Ｇｴ＾ｦＮＺｩｬＤｾｇＱ＠

56. If the componen t of the orbital angular
2. L- ｦｬｩＧｾ｜ｊ｣ｴ＾＠ 3n:c;r C1m L- ｣Ｇｴ＾ｦ［ｬ＼ｾｇｉ＠ momentum along the molecular axis of a
"'
3. L-Qf41ft<t> ｾ＠ ntrr L- c't>f;l<'!Qi'llf.M heteronucl ear diatomic molecule is nonzero,
the rotational- vibrational spectrum will show
4. L- Qf41ft<t> 31R'I' ntrr ｌＭｃＺｉＤｻＩｾｇＱ＠
I . P and R branches only.
2. P and Q branches only.
54. The amino acid constituen ts of artificial
3. Q and R branches only.
sweetener given belo'A> are
4. all the P, Q and R branches.
COOH
ｾ＠ L, ｾ＠ c);- CifTCR'l' ｾ＠

ｈＬｎｾ［ｃｏｍ･＠
57. m CfiT 'Q'Cfl' CfiUT

4nfi"'l?!C1 t1 t>.x =L ｾｉ＠ ll.p(min) = (p 2 } 1/z

3fit Rrrr ｾ＠ I CfiUT <fiT :;;;;rr c);- ilTG1" <fiT
O '-Ph
ｾﾢ＼Ｉ［Ｍｦｩｔ＠
I. D-G lutam 1c acid and L-phenylg lycine
2. L-Giutami c acid and L-phenylal anine ｾ＠ ｾ＠ I ｾ＠ ilTG1" WIT
3. L-Aspartic acid and L-phenylal anine I. 2
h /(8mL 2
) 2. h 2 /(8mL•)
3. h 2 /(32mL 2
) 4. h 2 /(2mL2 )
4. L-Aspartic acid and L-tyrosine

55. 'H J'IG'IＧ ｾ＠ ｾ＠ ｃｦｾ＠ l1 e; ｾ＠ q{ill o Icti JiUT3tT ｾ＠ .3mfO=tT 57. For a particle of mass m confined in a box of
' ｾ＠ ｾ＠
length L, assume 6x = L. Assume further that
ｾ＼ｒ＠ 1
6p(min) = (p 2 ) h. Use the uncertainty
6. cf ｾ＠ 6 principle to obtain an estimate of the energy of
I. ｾ＠ ntrr cf;q;; 'fq<t<;l?!ct'J I the particle. The value will be
" h 2 /(8mf2 )
2. ｾ＠ nm ｾ＠ {"1101 ｴ］ｱｾｬ＿Ａ｣Ｇｩ＠ I. h 2 /(8mL2 ) 2
2
3. h /(32mL ) 2
4. h 2 /(2mL2 )

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58. 59. For the cell reaction,
Sn(s) + Sn4+ (aq) .= 2 Sn + (aq),
2

separate electrode reactions could be written

with the respective standard electrode potential
F(V) data at zs·c as

Sn 4 +(aq) + 2c-> Sn 2 +(aq), f: 0 = +0.15 V

Sn 2 +(aq) + 2e-+ Sn(s), £ = -0.14 V
0

ｓｰｾ＠

When RTJF is given as 25.7 mV, logarithm of

Ne, Ar, c;m Kr cl; 'ftfls fcrcRur ｾ＠ em the equilibrium constant (ln K) is obtained as
I. 22.6 2. 226
ｾ＠ 34{)q-(1 ft'r;r c); ｾ＠ ｾ＠ ｾ＠
3. 2.26 4. 2.26 X 10-1
ｾｉ＠
I. Nc-A. Ar-B, Kr-C 60. irf1 ｾ＠ ｾ＠ ｾ＠ tR 61$$)@411 em ｾｉｔｇＭｯｲ＠
2. Ne-B, Ar-C, Kr-A
ffi4)@411 c;_qm ｾ＠ ｾ＠ (S \rCfi ｾ＠ ｾ＠ <fiT
3. Ne-C, Ar-B, ·Kr-A
4. Nc-C, Ar-A, Kr-B ｾｦｩＺｲ＠ ｾＺ＠

58. H H
I I I I
H2+-s - ｓＭ］ｾ＠ s- s -
ｾ＠ 61@,1\?1411 <fiT ｾ＠ t m61$$,91411
(p) ｾ＠
ｾ＠ G*t ｾ＠ em Jhr <H'II41141cfl t ..)

2
I. p ｾＧ＠ 2. p iiil
h ｾｉ＠
1 3
3. p h iiil 4. p

Identify the speed distribution functions of

Ne, Ar, and Kr with the curves in the figure 60. Hydrogen is adsorbed on many metal surfaces
above by dissociatio n (S represents a surface site):
I . Ne-A. Ar-B. Kr-C II H
2. Ne-B, Ar-C, Kr-A I I
3. Ne-C, Ar-B, Kr-A H2+-S-S-=="" s- s-
4. Ne-C, Ar-A, Kr-B

59. ｾ＠ ｾ＠ Sn(s) + Sn4 ... (aq) ｾ＠ 2 Sn 2 +(aq) If the pressure of H2 (p) is small, the fraction of
ｾ＠ zs·c the surface covered by hydrogen is proportion al
ｾ＠ $<'lif?)s ｾＳＡｔ＠
ｾ＠ ｾ＠
'R 3ftrci $<'1Cf?)s ftmcr ｾ＠ ｾ＠ ｾ＠ ｾ＠
ｾ＠

Sn4+(aq) + 2e-+ Sn2 +(aq), £0 = -LQ.lS V 61. Gfc; ｾ＠ ;r l:<ti ｾ＠ ｾ＠ fu m-er ｾ＠

Sn 2 +(aq) + 2e-+ Sn(s), E0 = -0.14 V
ｾＮ＠ ｱｧＭｾ＠
ｾ＠ RT/F , 25.7mV fa<rr t, ffi ｾ＠ ｾ＠

<fiT <>IEjdiOICfi (InK) ｾ＠ ｾ＠ tl

I. 22.6 2. 226
3. 2.26 4. 2.26 X 10-1

5/55 CS 1/1 d-1 AH-2A

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 18

61. For n process in a closed system, temperature 64. ｘＭｾ＠ ｾ｣ｫａｇＱ＠ ｾ＠ ｾ＠ q;)f 'ti<=tt"1k<ACfi
is cqunl to
ｾＮ＠
I. ('Ill)s i)p
2. ＭＨＺｾＩｔ＠ I. ｾ＼ｭｦ＠
2. ｾｯｗＧ＠
3. ＨＺｾＩｲ＠ 4. (iJ/1)
/JS p
3. ｾｯｗＧ＠
4. 31Rhfei>fFt1 oW'

62. F.'ik1rnffil<1 if ｾ＠ ＮＱｾ＠ ｾ＠ f(x,y) <iiT 64. X-ray diffraction does not give any structural
ｾ＠ 3fC1CiiN ｾ＠ information for
I. xdy 2. dx-=-dy 1. metallic solids
y 2. ionic solids
3. ydx- xdy 4. -dx X
--dy
l 3. molecular solids
y y2
4. amorphous solids

62. The exact differential df of a state function 65. ｾａＫ＠ 8 + C-+ ｄｾ＠ ｒｨ＼Ｔｩｾｉｖ＠ <iiT
j(x,y), among the following, is
ｾ＠ Cfi«t ｾＮ＠ ｾ＠ ｾ＠
I. xdy 2. dx- :.dy A+ B ｾ＠ AB
y
1 X AB + C-+ D
3. ydx- :xdy 4. -dx
y
--dy
y2
ｾ＠ ｾ＠ tiG 3{TCf1'lfcfi ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠
63.
ｾ＠
ｾ＠
ｾ＠
mf.rT ｾ＠
<iiT ｾ＠
Lz = -ih : 0 cii ｾ＠ ｾ＠ lrtt ｾ＠ ｾ＠ * ｾＨＢ｣ｦｬ＠ ｱｾ｡ａ｣ｴＰＱ＠
ｾ＠ exp[iA0]1 ｾ＠ ｾ＠ AH ｾ＠ ｾ＠ ｇｦ｣ｬｴＱｾＧＴ＠ ｾ＠ ｾ＠ <Hfsh<QUi ｾ＠
ｾ＠ ｾ＠ '(!"q; ｾ＠ QlWT ＳＱＴｾ｡ｲｮＨ＠ ｾ＠ ｾＮ＠ E0 ｾ＠ ciT ｾ＠ ｾ＠ ｾ＠ <Hfsh<Qvl ｾ＠ Cii'r
ｾｱ［Ｇｲａ｣ｩｭｴｦ＠ ｾＮ＠
;:m:r ｾ＠ l. Eo 2. E0 -AH
3. E0 + AH 4. E0 + 2AH
I.

2. 0, ±1, ±2, ±3, ... 65. A reaction A + B + C -+ D follows the

mechanism
3. 0 ±!.2 +1 ±!2 ...
1 1
- I
1

0--1 3 5 A+ B ｾ＠ AB
4. , 2, 2, -2 , ...
AB + C-+ D

63. The angular momentum operator Lz = -ih : has in which first step remains essentially in
0 equilibrium. If llH is the enthalpy change for
eigenfunctions of the fonn exp[iA0]. The the first reaction and Eo is the activation ･ｮｲｾＺＬｹ＠
condition that a full rotation leaves such an for the second reaction, the activation energy of
eigenfuction unchanged is satisfied for all the the overall reaction will be given by
values of A I. E0 2. E0 - AH
1 2 4
I. O, ±3. ±3. ±1, ±3 .... 3. E0 + AH 4. E0 + 2AH
2. 0, ±1, ±2, ±3, ... ＤｾｃｦｉＰＱ＠ .311v.r ｾ＠
66. '(!"q; ｾ＠ .toft ｾ＠ oi7r
1 3
3. 0• ±-2' ±1·+-
- 2'
... ｾ＠ (A nrn ;f) ｾ＠ tovr 24 ｾ＠ ａｾ＠ 30 ｾ＠ I
1 3 5 3{1'<Q;i ｾ＠ ｾ＠ ｾ＠ q;r ;:m:r f.;mci;
4. 0---
• 2, 2. 2 , ...
ｾＮ＠ ｾ＠ ｾ＠ = 1.6 ev)
1019
f.'i<fiC:(1A (1 J

5155 CSI/14-1AH-2B

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 19

l. 32 eV 2. 42 eV
69. Ｇｑｃｦｩｾ＠
3. 52 eV 4. 62 eV
4{1'fHUt!1lc1'l ｾ＠ ｾｉ＠
66. Wavelength (..:t in run) of the Lyman senes I. 3ffi'-3fRic:r ｾ＠ 3m'
for an one-electron ron is in the range
24 s; A. s; 30 . The ionization energy of the
2. mr- JtR:rc:r ｾ＠ 3m'
3. ｾ＠ ＠ｾ
3m' 3tT'ffi:r (iUT ｾ＠
ion will be closest to (1 J = 1019
1.6
ev) 3fTfU'qq; ::rl"{
I. 32 eV 2. 42 eV 4. ｾＧｬｏｩｃｲＭ 3fh:rc; ｾ＠ 3m'
3. 52 eV 4. 62 eV

67. mt-<n=r * ｾ＠ ｐｖｃｾ＠ fmr (Mn) = 13, (=fliT

69. For a polydispersed macromolecular col1oid,
osmometry gives
(Mw) = 16 VCfi 3CII(HOI ｾ＠ ｾ＠ ｾ＠ ｾｉ＠ 1. weight- average molecular weight
ｾ＠ (Mn) ｾ＠ 3fh:rci ｾ＠ ｾ＠ OllT
2. number- average molecular weight
3. both weight- average and number
(Mw) 3m' ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ I Mn average molecular weights
q;r C1Gr ｾ＠ WIT I 4. viscosity-average molecular weight
I. 39 2. 3
3. 1 4. 87 0.02 M NaOH ｾ＠
70. 10 ml <fiT 0.02 M Q'f!1R:Cfl

61. A sample experiment revealed that PVC ｾ＠ (pKa = 4.75) <i> 10 rnl 'R f1t';rr f'aml
formed in the medium has (Mn) = 13, and
(Mw) = 16, where (Mn) stands for the
ｾ＠
I. 7.0
*" pH ｾ＠ mCflcCIA
2.
tft1fr.
8.4
ｾ＠ ｾ＠

number average molar mass and (Mw) for the 3. 5.6 4. 9.6
weight average molar mass. The variance of
Mn will then be 70. 10 ml of0.02 M NaOH is added to 10 ml of
I. 39 2. 3 0.02 M acetic acid (pKa = 4.75). The pH of
3. I 4 87 the solution will be closest to
1. 7.0 2. 8.4
68. VCfi ｑＮＭＱＵＤａｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ OllT 3. 5.6 4. 9.6
v
(S;o ｾ＠ m.:<:T ｾ＠ <nT ｾ＠ 40 S ｾ＠ 'llfa'
ｾＪｲｚＮｓｦｉｍ＠ JmT ﾷｾ＠ I PART ' C '
ｾｭ＠
I. 40 Lmol- 1 s- 1 11. mkfrn ｾＨｩ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ Cf)T"(C11' ｾ＠ fa1m:r ｾ＠
2. 10-4 Lmol- 1s- 1 ｾｴｮｭｬ＠
3. 107 Lmol- 1s- 1
104 Lmol- 1 s- 1
A. mt-<n=r ｾ＠ ＮＱＴ｡ｾｬｩｃｦ＠ * ｱｾ｡ｬｩＱ＠
4. ｂＮｾ＠ ｾ＠ C\Cij\Cf>{UI ｾ＠ ｦ｡ｾｉｓＱｩ＠
｣Ｎｾ＠ croff ｾｲ＠
68. For an enzyme-substrate reaction, a plot ｄＮｾ＠ *t qtT ｾ＠
1
between .!. and -[ yields a slope of 40 s. If the
v s10 1. A. B OllT C 2. B,C'CI'mD
enzyme concentration is 2.5 JiM, then the 3. A, C CltrrD 4. A, B (1tlT D
catalytic efficiency of the enzyme is
I. 40 Lmol- 1 s- 1
71. Which ofthe following will result in deviation
2. 10-4 Lmol-1 s- 1 from Beer's law:
A. Change in refractive index of medium.
3. 10 7 Lmol- 1 s- 1 B. Dissociation of analyte on dilution.
4. 104 Lmol- 1 s-:

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 20

C. Polychromatic light 75. ｾｲｴＧｬ＠ Fsf>:UkACfi 3rcfftlT # ｾｉｃｗＱｬｊｩｨＨ［ｻｪｦＺｴ＠

D. Path length of cuvette Citrr ｦｧＧｊＱｃａｩＴｬ｡Ａｾ＿Ｎｉｇ＠ ｾ＠ 3ilcwf1Jiit ｾ･ｬ＠
I. A, B and C 2. B, C and D
3. A , C and D 4. A, Band D fm! ｾ＠ asfl C1trr ｰｈｾ＠ 6, Siimf:
1. ｾ＠ Citrr pH f.mt;
72 . ＺｬｴｮｾｗＢｦ＠ .;>
Ｓｩｦ｣ｎﾫ｡＼Ｇｉｾｃ＠ ｾｰｈ＠
4'0i1Uql'Q 3rt"llil ｾＱＧｦｩ＿ｲ＠ (ICP-AES) # 2. ＳｩｦＴＧ＼｡ｉｾｃ＠ (;tiT ｰｈｾ［＠
ｾ＠ ｾＮ＠ ｾｴ［＠ ｾＨ［ｴｩｔ＠ ｰｈｾ＠
l. 3fldir;:r 3. ｾ＠ Citrr pH ｾ［＠
2 crnt;r ｾＳｩｬ＼ｴＤＵ＠ 31 ffi q «a ＼Ｇｉｾ＠ Cfi nm pH f.!rm-
3. ｾ＠ 311<ttll$5 4. Ｓｩ｜ＷＱＴｻｱ＼ＧＡｾｃｦ＠ ｾ＠ pH f.!rm-;
4. ＶＱＤｾＩ｜ｩｃｆｬ＠ ｾｃｩｴｲｰｈ＠

75. Under physiological condition, oxygen is

72. The gas commonly used in generating plasma
binding to deoxybemoglobin and
in Inductively Coupled Plasma-Atomic
deoxymyoglobin, the binding curve and its
Emission Spectroscopy (ICP-AES) is
pH dependence, respectively, are
l. argon
I. Sigmoidal and pH dependent;
2 carbon dioxide
hyperbolic and pH independent
3. nitrous oxide
4. hydrogen
2. Hyperbolic and pH independent;
sigmoidal and pH dependent
3. Sigmoidal and pH independent;
73. ｾ＠ A==l25, r0 = 1.4 x l0-15 m ell ｾ＠
hyperbolic and pH dependent
\TllliTIC'fl<ll ｾ＠ qfhtlG (bam #) t", 4. Hyperbolic and pH dependent;
sigmoidal and pH independent
ｾ＠
l. 1.05 2. 1.54
3. 2.05 4. 2.54 76. ｾａｬｃｩｴｲｂ＠
at 1ft ｾ＠ ｭＭｾ＠ em ｾ＠ ｾＺ＠
73. The geometric cross-section (in barn) of a
nucleus ./\=125, r0 = 1.4 x 10-:15 m ｾａ＠ ｾｂ＠
approximately is
I. 1.05 2. 1.54 I. 3it<Wi'lg)A'ltli'ilf.'M (a) ｃＭｾ＠ ｾ＠
3. 2.05 4. 2.54 3ml'rtr <tiT 'J\'<'1' ｾ＠

II. Cfittiff.'iq:; ｾｩｬＨＺＤｴ＠ (b) ｾ＠

74. ｴｲ｡ｮｳＭ｛ｃｯＱ Ｒ ｾ｝ｂｲ＠ ell fttfcrn
III. tii$C:.)Sfl)A P,.50 (c) C02<tiTH2C03 #
tiJilq'ZIQl tt' ｱｾ｡ａｩｴ＠
l. "QCf; 2. ｾ＠
IV. ｃｦｩｬＧ＼ｆｾｴＺ＠ A (d) ｾ＠ em 3f1CHfiCfi<{Ui
3. cfrir 4. 'CJR"
(e) Jtf<A11\ilit ｾ＠
74. The number of stereoisomers of trans- (f) li1CHfl61it em ｱｾ｡ｩｴ＠
(CoCh(triethylenetetramine)]B r is ｾＳｭｻＧ＠
1. One 2. Two l. I-(f); II-(c); lll-(d); IV-(a)
3. Three 4. Four 2 I- (e) ; II- (c); III- (a); IV- (f)
3. I -(f); 11-(b); III-(c); IV -(a)
4. I -(e); II -(d); lll -(c); IV -(a)

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 21

76 . Match the mctalloproteins in column A with ｾ＠ ｾ＠ tR' ｈｾ＠

78. <fiT ｾ＠ ;1
their function in column B
3ltCf'RCfl{uft ｾ＠ ｾ＠ ｾｴ＠ 6. ｾ＠ ｾ＠
Column A Column B [Mn(CO)sl
I.
I. Oxyhemocyanin (a) hydro!> sis of C- 2. [( 175-CsHs)Mo(COhj-
terminal peptide bond 3. [IrCI(CO)(PPh3h]
5
II. Carbonic (b) methylation 4. [(77 -CsllshReHJ
anhydrase
Ill.Cytochrome P4so (c) conversion of C02 to 78. The compound that undergoes oxidative
H2C03 addition reaction in presence of 112 is
IV.Carboxy- (d) oxidation of alkene I. [Mn(COhr
peptidase A 5
2. [( 17 -C5 l I5)Mo(C0)3]-
(e) oxygen storage 3. [IrCI(CO)(PPh3h]
(f) oxygen transport 4. [('75-C,HshReH)
The correct answer is
I. 1- (f); II- (c); III- (d); rv- (a)
2 1-(c); ll-(c); lll-(a); IV -(f) 79. ｾ＠ ｾ＠ 1
H NMR ｾ＠ ,f - 7.2 ppm. tR'
3. 1-(f);Il-(b);lll-( c);rv-(a)
ｾ＠ ｾｦｩＺｲ＠ t1 [(rl-CGH6)Cr(C0)3] ｾ＠ 1
J-I NMR
4. 1-(e); II -(d); III -(c); IV -(a)
ｾ＠ (ppm) Jl C6 H6 ｾ＠ cfrr ｾ＠
77. Na[{tl-CsH 5)Fe(CO)z] ｾ＠ Br2 ｾ＠ ｾ＠ A 'ii'RillfilCfl ｾ＠ 3tk :mCfiT qiRUJ' Ｈｾ＠ ｾＩ＠ ｾＯＶ＠
ｾ＠ ｾ＠ I LiAIH4 ｾ＠ A cfrr ｾ＠ B ?;cfr ｾｉ＠ 1. 4.5 ; m;m ｾ＠ q;r m-r ｾＭｭｲ＠
" ｂｾｎｍｒＣｬ＠ 2 9.0; ｾ＠ IJ:l-TTCf
ｾｃｊ［ｔＳＵＺＱ＠ 3. 7.2
ｾｉ＠
4. 2.5; ｾ＠ ｾ＠ <1m 'Cf(iflf ｾ＠ Wr
ｾａｂｔＺ＠
ｃｦ［ｔｾ＠
I. (11 5·CsHs)Fe(CO)zBr ｾ＠
(r/- CsHs)Fe(COhH 79. 1
H NMR spectrum of free benzene shows a
2 (rl-CsHs)Fe(C0)2Brl ntrr peak at - 7.2 ppm. The expected chemical
(r,C- CsHs)Fe(CO)zHBr shift (in ppm) of C 6H 6 ligand in 1H NMR
3. Ｈｴｔ Ｍ ｃｳｈＩｆ･Ｈｏｨｂｲｾ＠ spectrum of [( ＱＷ Ｖ ＭｃＶｈＩｲＨｏｾ＠ and the
(r/- CsHs)Fe(COh(H)2 reason for it, if any. is/ are
1. 4.5 ; disruption of ring current
4. ＨｴｦＭｃｳｈＩｆ･ｏｺｂｲｾ＠
2 9.0; inductive effect
(,f- CsHs)Fe(CO)zHBr
3. 7.2
4. 2.5; combination of inductive effect
77. Na[(rf-CsHs)Fe(C0) 2] reacts with Br2 to and disruption of ring current
give A. Reaction of A with ｌｩａｉｾ＠ results in
B. The proton NMR spectrum of B consists
80. [Mn(H20)6f ｾ＠ CJ;T td'f ｾ＠ ｾ＠ 'R
of two singlets of relative intensity 5: I. ｾ＠

Compounds A and B, respectively, are ｾ＠ ｾ＠ t 1 ｾ＠ mmao qiRUJ' ｾ＠

1. (t{C5 H5)Fe(C0)2Br and A1t *t ｾ＠
6
A. filk1(1A 3fCR=m
(r/- CsH5)Fe(C0)2H ｾ＠
B. CRUT f.nn:r ｾ＠ }lfd'l'fiffi ｾ＠
2 (1(CsHs)Fe(C0)2Br2 and
C. f.ik1(1J"I .3-T'Cft=trr 2T2tt <frr ｾ＠
( r/- CsHs)Fe(C0)211Br
3. ( r/-C 5Hs)Fe(C0)2Br and D. ｾｔ＠ ｾｉｏｩｬｯＭＨＧＱｻＰ＠ ｾｕｦ＠
(r/- CsHs)Fe(COMHh ｾ＠ :xcR 6
4. ＨｲＯＭｃｾｈ Ｕ Ｉｆ･Ｈｃｏｺｂｲ＠ and I. .., ａｾｃ＠
A (;tiT 13
( r/- ｃｾｈ Ｕ Ｉｆ･ＨｃＰＲｈｂｲ＠
3. B amc 4. ｃｾＧｔ＠ D

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 22

80. An aqueous solution of [Mn(I:h0)6t 3

complex is pale pink in color. The probable
rensons for it nrc
6
A. presence of A 1& ground state 4
D. disallowed transition by spin selection
rule
C. presence of 2T2c ground state
D. charge transfer transition The reaction between diphenyldichlorositanc
82.
The correct answer is and water in 1:2 molar ratio gives product A
1. A and B 2. A and C
which on heating above I 00 oc yields a cyclic
3. BandC 4. CandO
or polymeric product B. The products A and D
respectively, arc
81. !'hFt'"9i'i'l'H ｾｬＤＱｦｴＴｨｩＵ＠ cfrr ｾ＠ ｾ＠
I :3 mt;rr ｾ＠ ..:>
'R ｾ＠ 3FtlT4 ' A', act I. r11
ｾ＠ /
ou
/
Ph
ｾ Ｎ＠ ｾ＠ ｾ＠ ｊｭｴｾ＠ ｾ＠ JrfJl\1EI4i ｾ＠ Si"- / 51-;;::::--rh
ｲ ｾ＠ ' o Oil
l:R 'B' ｾｭ･ｮ＠ I "BuLi ｾ＠ B ｊｬＧｾ｜ｩＴＱ＠
ｾ＠ ｾ＠ 'C' ｾｉ＠ A , B(ftlTC ｾＮ＠ 2.
ifimT:
I. [PPh4)Cl, Wh2P=CH2]I, Ph 2P("Bu)
2. PPhJ, [Ph3PI)Mc, Ph2PtBu)J
3. PPh3, ｛ｐｨｾｍ･｝ｉＬ＠ Ph3P=CH2
4. ｛ｐｾ｝ｃｉＬ＠ [Ph3P=CH2]I, [Ph]P("Bu)]Li

81. The reaction of phosphorus trichloride with

phenyllithium in 1:3 molar ratio yields
product ' A', which on further treatment with
methyl iodide produces 'B'. The reaction ofB
with "BuLi gives product 'C'. The products A, 83 . iitiDII4i1 C2B 9H 12 -as ｾ＠ ｾ＠ ｾ＠ .3rrmR
..:>
ｾ＠ ｾ＠
B and C, respectively, are 1. ｣ＯｯｳＭｾ＠
I. [PPh4)CI, [Ph2P=CH2]I, Ph2P("Bu) 2 ｮｩ､ｯＭｾ＠
2. PPh3, [Ph3PI]Me, Ph2P("Bu)3
3. PPh3, [Ph3PMe]I, Ph3P=CH2 3. arachno- ｾ＠
4. [PPh4)CI, [Ph3P=CH2]l, [Ph3P("Bu)]Li 4. ｨｹｰｯＭｾ＠

82. ｳｴＤｩＱｐｲｬ＼ＧＡＴＩｦｾＰ＠ <frr \MI' ｾ＠ 1:2 1ffi:rr 83. According to Wade's rule, anion C2B9H12- adopts
act ｾ＠ ｾ＠
1. closo - structure
3r._f1<i ;j' ｾ＠ 3(=q1G A
2 nido - structure
l00°C ｾ＠ 3lfl)q; nTQ' l:R 1TR ｾ＠ l:R '(fcf; 3. arachno - structure
ｾ＠ 3l'1laT ｾ＠ 3(=q1G B ｾ＠ ｾ＠ I A (ftlT 4. hypho- structure
ｂｾｲＺ＠
84. [Cp*2ThHl (ftlT co<frr lmTi1' 1ffi:rr ｾ＠ 'R
ｾ＠ q;y ｾ＠ 3"fti1G ｾ＠
1.
Cp*2Th--0

2 "'cn2--Thcp•l
2.

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 23

ctr ｾ＠ tit 1T<fi m;r ｾ＠ ｾ＠ ｾｉ＠ W ｾ＠

3.
ｾｱ［ｲｻｏｔｭＭ＠
A. [CoCI(N H3) 5J •
2
R ｾ＠ ｾ＠ <1cfirl
4. 3
ｾ＠ mc:r;r ｾ＠ ｾ＠ <itiT [Co(CN)6] -

Ｃｔｾ＠ I ｾ＠
2
B. SN ca Psfi:a1faR.r CfiT ＠ｾ
1 [CoCI(NH3) 5] +

84. The final produc t m the reactio n of [Cp* 2ThH] ｾ＠

with CO in an equimo lar ratio is C. ｓｾＧ Ｑ
｣｡＠ ｦｳｨＺ｡ｬｾ＠ ＼ｬｩｔｾ＠ [Co(CN )0]3- ｾ＠
1.
Cp* 1Th--0 ｾｉ＠
""CH1 --ThC p*2 D. SN ca ｳｨＺ｡Ｑｦｾ＠
1
CfiT M ｾＧａＭ ｾ＠
ｾｉ＠
ｾ＠ 'ft!ISt'\Cfi{OI ｾｦｴ＠
2.
A<imB 2. A <'fmC
ｃｰＪｺｔｨＭＰｾｬ＠
l.
.., A <'fm D
.). ｾｂ＠ 4.

Ｓ Ｉ Ｕ ｝ ｾ＠ is an
3. Ｒ
86. Base hydrol ysis of ｛ｃｯｉＨｎｈ
overall second order reaction, wherea s that of
3
[Co(CN)6] is of first order. The rates
4.
depend in both cases solely on the
concen tration s of the cobalt comple x. This
may be due to
A. presenc e of ionizab le proton in 3
2
[CoCI( NH 3)s] but not in [Co(CN )6] -
85. ｾ＠ p- s1$<t1c::Mc::1 ｾ＠ dpmH (dpmH =
B. SN 1ca mechan ism in the case of
ｳｮ［ｦ･ｩｾ＼ＴｍＩ＠ cr;r :;cniTor ｾ＠ ｾ＠ 2
[CoCI( NH3 )s] • only
1
ｾ＠ ｾ＠ ｾ＠ -;;nnr ｾ＠ CRiffin dpmH ｾ＠ C. SN CB mechan ism in the case of
[Co(CN )6 ]J- only
ｭｾｱ［ＩＭ ｾ＠ ｾ＠ Cflt ＮＴＭｾ＠ ＼ｴ＾ｃＱ＠ｾ t'
D. SN 1c 8 mechan ism in both the comple xes
l. ｾ＠ ｾ＠ ｓｦｬｾｊｫＧｉｎｩ＠ ｾ＠ Correc t explan ation(s ) is/are
2 ｾ＠ SflMc.'IJjcfi'J ｾ＠ I. A and B 2. A and C
3. ｾ＠ ｾｦＴｒｴＱ＠ ｳｴｾＩｊｫｪ｣ｦｩＧ＠ ｾｉ＠ 3. B only 4. A and D

4. 3fTli01 ｾ＠ Sflh'lc.'IJ.lcfi'J ｾｉ＠

87. ｾ＠ (X) ｾ＠ .31J"I)fil41 ｾ＠ ｾ＠ 1Tcfi

85. Hinder ed /3- diketon ates like dpmH (dpmH = ｇｦｩ＼ＩｾｬＤＱＵ＠ CfiT m (Y) a-m ｾ＠ Y ｾ＠
11
8
dipival oylmet hane) arc used for the separat ion NMR ｾｩｦ＿＠ A it 1Tcfi f:tcfi rim thrci; ｾ＠ ｾｉ＠
of lanthanides becaus e comple xes formed with
dpmH can be separat ed by ｾｘ＠ 6'
I. Gel pennea tion chroma tograph )
2 Gas chroma tograph y
3. Gel filtration chroma tograph y ia to
87. A borane (X) is reacted with ammon
4. Ion exchan ge chroma tograph y dride (Y). The
11
8 NMR
give a salt of borohy
spectru m of Y consist s of a triplet and a
ｾ＠ ｾ＠
86. [CoCI(NH 3) 5 )
2
+ cr;r ｾ＠ ｾ＠
ｾ＠ - quintet . The borane X is
ｾ＠ *t ｾ＠ ｾＮ＠ ｾ＠ [Co(CN )6f CfiT I. B 2H6 2. B,H9
3. B4Hs 4. BsH9
ｾ＠ ｾ＠ ctr I M" cf; ft:Rr G\ ｾ＠ ｾ＠ ｾ＠

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 24
88. XefG nm NaN 03 cfi'r W1Tii1 ｾ＠ 1l'T'IT.3it cfrr 91 . [CrCl6] 3- ｾ＠ ｾ＠ ｾ＠ (J..ls) (1t1T ｾ＠ +
ｯｮｦｲｾｴｬ＠ ｊｾ＠
..:) (J..lS+L) i_!fkl® li ｾ＠ ｾ＠ 'RfGl t
I. Xe0F4, NaF Ci'tiT N02F I. 3.87 BM 'C1'tiT 5.20 BM
2 Xe0 2F2, NaF, NOF Ci'tiT F2 2 2.84 BM Citrr 5.20 BM
3. XcOF., NaN02 Cim F2 3. 3.87 BM Citrr 6.34 BM
4. XeF., NaN02 Ci'tiT F20 4. 2.84 BM Citrr 6.34 BM

88. The main produc ts of the reaction of 91. The spin-on ly ＨｾｳＩ＠ and spin plus orbital
equimo lar quantit ies ofXeF6 with NaN0 are (J.Ls+L) magne tic momen ts of [CrCI6 ) 3- are
3
I. XeOF4, NaF and N0 2F I. 3.87 BM and 5.20 BM
2 Xe02F2, NaF, NOF and F2 2 2.84 BM and 5.20 BM
3. XeOF4, NaN02 and F2 3. 3.87 BM and 6.34 BM
4. XeF4, NaN0 2 and F20 4. 2.84 BM and 6.34 BM

89. [MnF6] 3- ｾ＠ '4; thla:fl;;;t ｾ＠ ｾ＠ ft:ttr ｾ＠ 92 . ｾ＠ ..:)

HM(C0 )5 Citrr [( 7,S-C,Hs)M'(C0hh
ｾ＠ ilfkli{;j<q ｾ＠ ('l'trr ｦｾｃｗｈｊ＠ ｾｍｃＧｉａ＠ q_cmT ＱＸＭＤｾｃｦｻｉＰ＠ fitmr CflT qn;r;r ｾ＠ ｾｉ＠
..:1 " •X
ＮＱｾ＠ ｾ＠ ft:r\r ｾ＠ ｾ＠ ｾ Ｎ＠ ｾｲＺ＠ M Cl1IT M' qi)' 3fR' ｾ＠ 1
H NMR # TMS
I. 4.9 BM <1tTT 5 D t" ｾ＠ Ｇ＼ｉｅｩｬｾｃｦ＠ ｾ＠ <liT ｱｾｩｦｑ＠ I
2 ＴＮＹｂｍｾ Ｔ
ｆ＠ 1. M = Mn, -7.5; M' = Cr, 4.10
2 M • Cr, 4.10; M' = Mn, -7.5
3. 3.9 BM t'fm 3 D
3. M "" V, -7.5; M' = Cr, 4.10
4. 4.9 BM ntrr 3 F 4. M = Mn, 10.22; M' =Fe, 2.80

89. The spin-on ly magne tic momen t and the 92. Compl exes HM(C O)s and [(775-csHs) M'(CO )Jh
spectro scopic ground state term symbol of obey-th e 18...electron rule. Identify M ·and M' and
manga nese centre in [MnF6]3- ion respect ively, their 1H NMR chemicaLshifts relative to TMS.
are 1. M=M n,-7 .5 ; M'=C r, 4.10
l. 4.9 BM and 5D 2 M = Cr, 4.10; M ' =Mn, -7.5
2 4.9 BM and 4 F 3. M=V, -7.5; M'=Cr,4. 10
3. 3.9 BM and 3D 4. M = Mn, 10.22; M' =Fe, 2.80
4. 4.9 BM and 3F
93 . I2-Sfil'3Vf-4 ｾｍＱｦｴＺｉｃ＠ SfW1 it m me;
90. <:itf7rcf> [Co(Co(NHJMOHh)JJBr6 *t ftt3.rn:rrR'r .3mfa'IT ｾ＠ ｾ＠
.:>
CR'ffi ｾ＠
ｾＪ＠ ｌｴ＾ｎ｡Ｋｋ･ｳﾷｾ＠ <liRUT
I. ｾｃｯＭｏＧｭｩｦｊｗ ｯＭｎ ｾ＠ 1. ｾ＠ CflT ｾ＠ 3ffCfiR' ｾ＠
2 ｾ ｃｯＭｏ ｮｴｲ＠ ｾ ｃｯＭｎ ｾ＠ 2. ｾ＠ ｱｾ｡ＰＱ＠ q;r tl011<+tCfl ｾ＠ ｾ＠
3. ｾ ｃｯＭｏ ｏＧｭｾｃ ｯＭｎ ｾ＠ snT3Gi ｾ＠
3. CflT ｾ＠ <'lifl (>llq01 ｾ＠
4. ｾｃｯＭｏ＠ O'm ｾ＠ Co-N 3mrrtr ｾ＠
4. snT3Gi ｾ＠ *" ｾ＠ ｾ＠
90. The three dimens ional structu re of compo und 93. 12-Cro wn-4 binds with the alkali metal ions
[Co(Co(NH3)4(0H)z)3)Br6 has in the followi ng order:
1. twelve Co-O and twelve Co-N bonds Li+ >> Na+> K+> Cs+. It is due to the
2 ten Co-O and ten Co-N bonds 1. right size of cation
3. fourteen Co-O and ten Co-N bonds 2. change in entropy being positive
4. twelve Co-O and ten Co-N bonds .3. conform ational flexibil ity of crown ether
4. hydrop hobicit y of crown ether

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 25

4.

s
1.

94. The correct schematic molecular energy

diagram for SF6 molecule is
1.
2.
s SF,

. ｾ＠

:' .2(1 \

E
E

3. 2.

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 26

3. The correct answer is

s SF,
2t, 1. A and B 2. Band C
:-·. 3. C and D 4. A nnd D
/ 2 I t ...

ｳｾ＠
. . . ｾＯ ｾ
====i :'
ﾷ＼Ｚ＠ .. - .
'.,.\
96.

E ', : ;: 'e::::;:: t
HOOC ' ( "COOH 1. Me2C(0Me)2, TsOH (cat)
.\ ｴｾ ＮＺｩﾷＨ＠ 2. BH3, THF
OH
'• -: ｾ｜ Ａｵ｜Ｑ ＱＺＧＮ＾ Ｍ 3.H3o·

·.
Ｐｾ＠ Ｐｾ＠
/
. .--ft_:i'.,.
1. 2.
OH bH
4.

3.
OD
Hd.
4. Ｐｾ＠
HO

96. The major product formed in the following

reaction is
HOOCy - "COOH 1. Me2 C(OMe)2. TsOH (cat)
OH 2. BH 3 , THF
3. H,o·

I. Ｐｾ＠ 2. O D
OH ':-OH

95. ｾ＠ ｾ＠ Sfi'IAG)J.)cfi'l CfiT ｾ＠ ｾ＠ 3. Ｐ ｾ＠ 4.

op
il t ｾ＠ cnT tprCf; ｾ＠ ｾ＠ ft:r'(r ｾ＠ ｾ＠ He{ HO
ｾＶ＠

ａｾ＠ D. a-nt<:r ｾ＠ tm_prr

C. crnTＭｾ＠ D. ifi11 3n'fUacfi 31R' ｾ＠ qCGI$m

2. B ('!"tiT C
9H 0 0
4. A ('!"tiT D
ｐｨ ｾ ｷＭ ｾ＠
l.
MeL P
Me.,..\
95. Gel permeation chromatography can be used to 2.
Ph
separate which of the following
OH 0 O
A. Lanthanides B. Alkaline earths ｐｨ ｾ ｎ ＭＧ＼＠
C . Fatty acids D. Low molecular weight Me L P
3. Me.,.. \ 4.
peptides Ph

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 27
0
97. The maJor . product formed
· in the following
transfonnation is
0 0 I. MeO
J::b>
ｾｎ｟ＯＨ＠ 1 au.,BOTi, i-Pr2 NEt >

ｍ･ｾ＠ Ｐｾ＠
2. PhCHO
3.
OH 0 0 OH 0 0 0
Ｉ｟ｊｾｴｲＨ＠ ｾ＠ . 0
)..__Jl_ l{
Ph' l Ｍｾ＠ 0
Ph
ｦＮｾｲ＠ /---( ｍ･ｾ＠ 99. . prod uc t of the foliowing reaction is
The maJOi
(.
Me Ph 2. Me Ph

3. 4.

98. 0

I. f!.eO
en>
Q""NMe2 O··••NMe2
3. ot::Q 0
3. 4.
NMe2 NMe2
100. fi!Mfc:lfi!r.r ｾ＠ <nT ｾｉ＠

98. The product B in the following reaction

sequence is

s12 (1 equ1v)
0
ｉＣｾ Ｌ［｟ﾭ
hcxnne, rt.
A
excess MezNH ... o
2. NaOH

!. 2.

Ｈ｟ＩﾷＢｲｾｍ･ｺ＠
J. 4. 'iJMa 2
2.

Me
99.
ｈｾ＠

ax
Me \_NH

4.
F!

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 28
100. The major product of the following reaction is
Fl
MeN Me
LOA
H 1. H 3o•, hv PdC!,. 0 2 , I . NaOEI
ｾｄｲ＠ A CUCI, OMF·H,O B 2. H,O
2. NaOH

H l. A; 0 B: 0

M(\ Me ｾ＠ 6l f
cff elf e 2
AH(J B 0
I.
H
2
H
• 'H
cYY
(t '
3 A: 0
Me

6r
e·

4.
ｾＢ＠ ｾ＠
3. H - H
H
4. A; OH B. 0

101. ｆｲｩｫＱｾｒｓｉｃ＠ Ｓｾ＠

0
II
q;r ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾｃｈｏ＠

ｍ･ ｯＭＢＧｹ Ｐ
ＧＩﾷｾＭ｢ｐｨ＠ 102. The products A and Din the following reaction
Meo'' V sequence are
OPh
I
o ::::P\OPh
N--
! 0 ｾ＠
A PdC!,, 0, •
Cuel, OMF-H,O
B 1 NeOEI
2. H,O (O=o
Meo: : t J
I. MeO'''

''68
Mco" 'y ') ...., l. A: 0
.o····V'"· NI
ｾ＠
0
Meo"" 'y ')·"';NH MeO
3. MeO',..l,__)..,,o ' ,,0
4. f'- OPh
PhO 2.
ｈｾ＠
A; B. 0
101. The major product for the following reaction is

MeO : o ﾷＢ Ｇ ｎ Ｇｾ
0
" ｾｐｨ＠ 12 , Phi(0Ac)2 3. A: 0
lYY
ｾ＠
HOP 1 ｃｈ Ｒ ｃｾＬ＠

ｾ＠
rt. B:
MeO''..

4. A: OH B: 0

Meo ::tJ
ｈｎｾ＠
f o' ｾ＠ ｾｃ ｈｏ＠

2. Meo····

103. ｆｲｩｫＱｾｒｓｉＨ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ A ＨＧｾｬｩｔ＠ 8

0
Meo" 'y ') ...,, ｾｉ＠
Meo""r0 1····'' .o····V'"·. NI
3. v
&1'\,•••
Mea···· '''O
, NH
4.
MeO
" ,,0
f'-oPil MeＳｾ＠ Sl ｾ ｎ Ｌ ｂｯ｣＠ Co2(CO}a. ｃｾ＠ Sml B
PhO I + A 2 •
ｾ Ｐ＠ Me N -O' THF, EtOH
3

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 29

I. A: B:
P Pl'h1 *'d EtO,CN =NCO,Et

B 0 0

ｾｎＭｯｈＫ＠ &OH- ｾｎＭＰＮ＠

0 0
2. A: B:

ｾｏｈ＠ 1. A-P, B-Q, C-R 2. A-Q, B-R, C-P

0
3. A-P, B-R, C-Q 4. A-Q, B-P, C-R
3. A. B:
104. The correct combinations of the reactions and
the reagents are

4. A.

ｾｏｈ＠
B: A. Ta.........._N,CH0 . - . Tt..-....NC
H

B. 0 o

0 ｾｎＭｏｈＫ＠ lluOH- ｾｎＭｏｂｵ＠ Q Poa,.a,N

0 0

103. The products A and B in the following

reaction sequt:nce are
I. A-P, B-Q, C-R 2. A-Q, B-R, C-P
3. A-P, B-R, C-Q 4. A-Q, B-P, C-R
Sml2 ...
B
THF, EtOH 105.

ｾｈＬ＠
Q-coct
l. B: ｈ Ｒ ｎｾＢ｣ｯｈ＠ ｾｉＮＺｍ［･ Ｓ ｓＺｩｃｉﾷＮｍ･ｏｈ｟Ｌ＠ A 8
OH 2. Et3 N, heat Pyridine
BockHN
OH
;/
A
0
SiMe3

2. A: a· BocHN

ｾｰｈ＠ A.

3. A: 8:

3 A

0 ｾ＠
B
4. A: e· HN"'y]

ｾｏｈ＠ OY''NH,
0

0
105. The products A and B in the following reaction
sequence are
104. ｾｊｴｔ＠ (Reactions) 3tR' ｾ＠
Ｈｒ･｡ｧｮｴｳＩｾ＠ t ｾｈＬ＠
1 Me,SICl. MeOH
ｲ｜ｾ ｣ｯ ｴ＠
ｈ Ｒ ｎｾｃｏｈ＠ A ｾ＠ -... B
OH 2. Et,N heat Pyndino

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 30
I A
0

'"ft(J• (1 "?.
.- ' ( ' " ( NH
107.
0 .J'oH

. . .a.
t>o•
2 A
0 e 0

"""·(:7 p
Oil
·o·Co
l A
ＢＧＨｾ＠ D
""'y
O
0
NH1
O "NH-c-o (I
0

""'y
4
" 0 0
O
0
Ｇｾ ｎｨｊ＠
0 C•HNl ? uo .... ｾＬ＠ 2.

106. \7lhlft:!Ug("l Ｓｾ＠ q;r ｾ＠ ｾ＠ ｾ＠

0 3.
r :NH
-.../
MeD
2. Br '>=<COOEt
N
R NC H
3. H20. OH.
4. H•
0 J0!7. The major product ofthc following reaction

ｎｃｾ＠
0
\I IS
ｅｴｯｾ･＠
I. NC EtOOC . N- R NC CN
2.
N-R >=<
NC CN
.....
0 0 heat

ｾ＠
II

J. EtOOC
N

wR
e

4. EtOOC
NYB Me wR
ｍ･Ｒｎｾｃ＠
I.
106. The major product of the following reaction is

MeD
0 CNH 2. ｍ｣ Ｒ ｎｾｍ･Ｒ＠
CN

ｍｯＬｎ Ｍｾ
N

ｾｎ＠
I
R
3. H20. OH. 3.
4.H• NC

ｾＰ＠
0

･ｴｯｾ＠ N
EtOO
4.
I. NC
2. N- R
N-R
108.
0 0

ﾷｾ＠ _____ ..
II

ｎｾ＠
1 T&.F. MtCN. 50"c Heal
A B

3. EtOOC N- R 4. EtOOC Me N-R

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 31
O" El 0
h 109. ｦＺｩｍｉ＿ｾｃ＠
PhS

ｾｪ＠ ｾ＠
_.t
r-h ｾ＠ sm1 ;;- Ｓ｣ＭＴｾ＠ ｾ＠
C(p'El ｾ＠
lJ-r:'= 1 EtCOCI. Et 2N

c)-rOMOM ______
A CO,Me a: co,Me OH 2. LOA, THF, -78 °C, TMSCI
.,..
ｅＩ［Ｍｾ＿ＮＬｎ＠
3. 1\
4. 1-130+
/ SPh 0

2 A B
0:" ｣ｯｾﾷ＠
'
5. CH2N2

OCOEt
r sl'll ｾｏｍ＠

ccｾ ;
1' 2. ( ).._., OH
TMS 0 0
ｾ＠

3 A MeOOC 0
ｅｴ＠ B.
P\___;- OMOM ｾｏｍ＠

r SPII
3 ｈｏｃｾ､＠ -4. Mooo cJ-o'
Me

ｾ＠
Me
ｾ＠

N ' El 109. The major product formed in the following

MeOOC
) reaction sequence is
• A Et02C B

1. EtCOCI, Et3N
OH 2. LOA, THF -78 °C TMSCI
108. The products A and Bin the following reaction
sequence are c)-rOMOM 3.6

ｾ］ ｎ Ｇｓｐｉ＠
I TBAF MeCH , SO"C
OCOEt
Nh 9i1Ao
A 0 ｾｏｍ＠ ｾ＠
1.
' ' ｅｴｏａ｟
0 0 2 lYOH
Ｐ ｾ･ｴ＠
CO,Mo
2 TMS O 0

0
N Et
/YOMOM ｊｾｏｍｴａ＠

1 A
PhS '-N

ｾ＠ ｣ＺｾＮ＠
·.11.

B.
;b.
｣ｲｾ＠
ｾＮ＠
Et
3 HOOC
Me
4. MeOOC
ｾ＠
Mt>
0

"et.r..
110. ｦＺｩｍｉ＿ｾｃ＠ ｾ＠ ｾ＠ '# A C1'm D ｾ＠
ｐｉｓｃｂＺ ｾ＠ 6.
2 A:
Ｎｾ＠

N
CO,Mt
a

B·
ｾﾷ＠
ｾ＠
I
ti:tilCiil<l

OH
ｾｬＺ＠
Cl v lh
＠ｾ
12 • PPh, . Br
r SPII PhS) mdazole CN
lw-'
3 A
ｾ＠ MoOOC' 0 El
Be
&0 'II
N
CQzMo
Boc
I
A
Zn. Pd(dppi)CI2 (cat)
Cul(cat)
NC
[l

rSPII Boc- NJ-1 Boc- NJ - - b -c l

ｾ＠
PhS)
ｾ＠
CN
MoOOC
N ,

..
Et
cxO
- ; N Co,Et Boc-NJ - 1 Boc- NJ-- -6--B r
• A EtO,C e· ｃＺｾＮ＠ 2

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 32

CI- Q -NJ-OH
ｈｎ ｾ Ｍ ｏｈ＠ 1. DIBAL·H (1.1 equlv), hexane -78 °C
3. ｾ＠ CN
Mev+{_
ｍ･ｾ＠ 2. CICH2 COOH, dlethyl azodlcarboxylate
PPh3
H Me 3. LIAIH4
Br--p-NJ -OH
ｈｎ ｾ＠ OH
4. ﾷ ｾ＠ NC
H CH H .QH
110. In the following reaction sequence, the structures Mev+->- Me ｍ･ ｾ＠ Me
of A and Bare, respectively, ｍ･ｾ＠ Me' '--1:-f
CI'Ql
1. . H Me 2. R Me

»H
lob
Br

c5 I
Boc
A CN

Zn, Pd(dppf)CI2 (cat)

Cui (cat)
B M
e>CD·.,IMe
H .QH
-:: ｾ＠ Me,
?\_j.__]-Me
Me : . Me .: .
NC 3. H ｾ･＠ 4. H t,e
Boc-NQ-1 Boc-NJ-0-cl
1.
CN 112. f}tk1ft:iffllct ｾＺｩｬ＠ (reactions) ｾ＠ ｾ＠ p

Boc-NQ-1 Bec-NJ-d-Br
;:n;IT (values) <ill' ｾ＠ ｾ＠ ｾ＠
2.
Entry Reaction Entry p
CI-Q-NJ-OH
value
HNo-OH p
3. CN A ArNH 2 + PhCCCI in +2.01
benzene
Br--p-NJ-OH B ArC - + Etl in EtOH Q -0.99
4.
HNo-OH
NC
c ArCC 2Et + aq NaOH R -2.69
in EtCH
s +0.78

111. i}tJ;;1ft:lffllct ｾ＠ ｾ＠ ｾ＠ ｾ＠ *" I. A - P; B - R; C - P

2 A- R; B - Q; C- P
ｾ＠
3. A - R; B - P; C - Q
0 4. A - Q; B - R; C- S
1. DIBAL-H (1.1 equiv), hexane -78 °C
Me><$-
:
;J Me 2. CICH2 COOH, dlethyl azodlcarboxylate 112. The correct combination of the following
Me ' PPh3
H Me 3. LIAIH 4 reactions and their p values is

H CH H ,PH Entry Reaction Entry p

ｍ･ｾ＠ Me ｍ･ｾ＠ Me A ArNH2 + PhCCCI p

value
+2.01
ｍ･ｾ＠ Me/ '--1:-f in benzene
1. H Me 2. R Me . B ArO-+ Eti in Q -0.99
EtCH

M
ti
-
PH
.
H CH c ArCC2Et+ aq
NaCH in EtOH
R -2.69

e>CD··nMe Me> d ) - M e s + 0.78

Me : . Me : .
3. H tte 4. H ｾ･＠ l. A- P; B- R; C-P
2 A-R B-Q· C-P
3. A - R;' B - P;' C-Q
111. In the following reaction sequence, the structure 4. A - Q; B - R; C-S
of the product is

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 33

113. ｾｫｬｦｩＺｉｕＡＱ＠ ｊｦｬｾ＠ 'Qqi ｾ＠ Ｈｾｦ＿ｴａｱ［Ｉ＠ 3. CfiTift;r (1'trr 3-Jf1Cffll0'11$'fii$Cft'l) (5.1.0)

ｾ＠ ｾ Ｎ＠ ｾＮ＠ ｾｫｊｑｲｵＨＱ＠ NMR ｾ＠ ｾＨｒＺｲ＠ ＠ｾ .3f1'Cft;;-2- Jit;r
1
H NMR: o 2.67 (2H. s), 5.60 (2H, s) ppm; 13C 4. CfiTift;r ｻＱｉｔＨｅＩＭＵＺｴＴｳ｣ｲ･Ｎｊｾｩ＠ ｾ＠
NMR: o 170.3, 129.0, I 05.0, 25.4 ppm.
ｾ＠ ＨｾｦｬＺｴｱ［Ｉ＠ ｾ＠ *'" mo:rr 114. The reactive intermediate and the product formed in
the following reaction are

ｾ ｯｲＬ＠
0
I. Free radical and 4-iodomethyloxepan-2-one
2 Free radical and 5-iodooxacan-2-one
3. Carbene and 3-oxabicyclo[5.l.O]octane-2-one
II 4. Carbene and (E)-5-iodopent-3-en-1-yl acetate

3. ｈｏｃｾ＠ '''COOH 115. ｾｫｬｦｩＡＨＱ＠ ｾ＠ SfiR CfiT ｾ＠ ｾ＠ ｾ＠

OH
. . . . . .1-. . . . . . 1. 4-Methoxybenzaldehyde, H+
113. The following reaction gives a product HO' 'v' ' ( ｾ＠
(racemic) which exhibits the following NMR Me 2. DIBAL·H, • 78 to - 40 °C
data:
1
H NMR. o2.67 (2H, s), 5.60 (2H, s) ppm;
OPMB
13
C NMR: 170.3, 129.0. 105.0, 25.4 ppm. o J.."';'ｾ＠ ｾ＠ ｾ＠
OH

The structure of the product (racemic) is

1· HO.........,__
/

Me
2· ｐｍｂｏｾ＠
Me

§'
OMe

ｾ＠
ＳＮｾ＠
X ＴＮ
0
ｾ＠
0

Me Me

115. The major product formed in the following reaction

sequence is
3 . HOOC,! '''COOH
OH
1 4-Methoxybenzaldehyde, H•
ｈｏｾ＠
I 14. ｾｊ］ＰＱｦｩＺｬＡＨ＠ ｾ＠ * ｾ＠ ｾｦｩ［Ｚｲ＠ Me 2. DIBAL-H, • 78 to· 40 °C

m."li'CRff' (11IT ｾ＠ ｾ＠
OPMB OH
Ｑ ｈｯｾ＠
Me
2- ｐｍ｡ｯ ﾷＮＭ ｾﾭ ｜
Me
OMe OMe

2
1. 1f<f(1'
ｾ＠
2-ffivf
1f<f(1'
ｾ＠
ｾ＠
ｾ＠
"

"
ｾ＠
ｾ＠ ＴＭｾＳＱｃｦｩＧｉＰ

5-.3inrn)'311Cfflili>01-2-3ffrr 3
9
a·· ' o
l__.. 1 --./""-...-:? Ｔ Ｎｾ＠
2.
? ''jl ｾＬＮ＠

ｾＱ･＠ Me

S/55 CSI/14-1AH-3

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 34
116. 3fOj ｾ＠ C1oH1202 qi'f' Cfii4f':ict; ｾ＠
ｐｲｩｫｬｾ＼ＧＱ＠ :Flct?(A'l ｾ＠ ｾ＠ *' M H
V---(0 -
X
ｾ
BO,Ph

Ｐ＠ ｾ＠
Soy>h

o:1'-C00Et
lR: 3400 (br), 1600 em·•.
1H NMR:
o
1.85 (3H, d, J • 6 Hz), 3.8 (3H, s), 0 0 0

5.0 (1H, s, ｾＰ＠ far!All'), 6.0 (1H, dq, J = 18, 6 1. X= PhS02H, BF 3·0Et2 andY = CH =CHC00Et, BF ·0Et
2 3 2
Hz), 6.28 ( IH, d, J • 18Hz), 6.75 ( IH, d, J = 8
Hz), 6.8 (1H, s), 6.90 (1H, d, J = 8Hz) ppm; 2 X = 1. PhSH, PTSA; 2. m-CPBA and Y =CH2=CHCOOEt. BF3 0El2
13
C NMR: o 146.5, 144.0, 131.0, 130.5, 123.0,
119.0, 114.0, 108.0, 55.0, 18.0 ppm.
ｾｴＧ＠ 4. X:: 1. PhSH, PTSA; 2. m-CPBA andY = LOA, CH2=CHCOOEI

117. In the following reaction sequence, the reagents X

and Y are, respectively,
ｾ ｍ･＠
HoA.(' ｾ＠
1.
HoA.{ Me
OMe
2. OMe

3.
QCM' 2. X =1. PhSH, PTSA; 2. m·CPBA andY o: ｃｈ Ｒ ｾｃｈｏｅｴ＠ BF3 OEt2
OMe 4.

4. X " 1. PhSH, PTSA; 2. m-CPBA and Y =LOA. CH2=CHCOOEt

116. An organic compoun d having molecular
formula C1oH120 2 exhibits the following
spectral data:
IR: 3400 (br), 1600 em·•.
ｂｲｾ ＧＭＮ＠ _,Br
1
H NMR: 1.85 (3lL d, J =6Hz), 3.8 (3H, o 1. Zn, AcOH
s), 5.0 (lH, s, D20 exchange able), 6.0 (1H,
dq, J= 18, 6Hz), 6.28 (IH, d, J= 18Hz), ｍ･ｾｏ＠ 2.PhSeNa
3. m-CPBA, heat
6.75 ( lH, d,J= 8Hz), 6.8 (lH, s), 6.90 ( lH,
d, J= 8Hz) ppm;
'\_.--.,-;,
13
o
ｾＰ＠
C NMR: 146.5, 144.0, 131.0, 130.5,

ｍ･ｾｏ＠
123.0, 119.0, 114.0, 108.0, 55.0, l8.0ppm .
The structure of the compoun d is 1. 2.

ｾ ｍ･＠

1.
Hoy
OMe
2.
ｈｏ ｾ
OMe
ｍ･＠ 3. Me
ft 0 0 4. Br ｾ＠ ONa

ｾ ｍ･＠ ll8. The major product of the following reaction is

3. OMe 4.
ｂｲｾ ＮＬ＠ Br

117. ｾｫｬｦ｣Ｚｩ＼ＧＱ＠
ntlT y t'.
ｾ＠
Sfimf:
Sfi'1f #l ｾ＠ X Me4o -- " 1. Zn, AcOH

2. PhSeNa
3. m-CPBA, heat

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 ·-

35

ＲＮｾＰ＠
1. LOA, THF 1. M-..gBr. Et20
B
2. ICH2CH2CH2Cl 2.H,o·

Me 0

ＴＮｂｲｾｏｎ｡＠ 1. A: eX:
ｉｾ＠
0

r(YCHO 1. CH3NHCH2COOH, ｅｾｎＮ＠ DMF

2. A: l__)l_OEt B: ｾｏｅｴ＠
ｾｎ＠
ｃｬｾ＠
2. heat Me

｣Ｑｾ
Ｐ＠
I
Ta
3. A: ｾｏｅｴ＠ B: ｾ＠

1. 0?3 I
Ts
2.
-4. A:

120. The major products A and B formed in the

C6.. OEt

3.
dYH d9H Ts
I
4. I
Ts
following reaction sequence are

1. LOA, THF
A B

119. The major product of the following reaction is

ｾ･ｲ｡＠
0
ｾｃｈｏ＠

ｾｎ＠ I
T1
1. ｃｈ
2.1tellt
Ｓ ｎｈｃｾｏ Ｌ＠ Et3N, DMF

1. A: eX:
ｉｾ＠
0

1. C8 I
Ts
2.
2.

3.
A:

A:
ｃｬｾ＠
l__)l_OEt

l_)lOEt
0
B:

B:
｣Ｑｾ
ｾｏｅｴ＠
Me

Ｐ＠
4.
d9H N
I
Ts
-4. A: B: C6.. OEI

121. ｾ＠ ｾＮ＠ 2NO(g) + Cl 2 (g) --+ ｾ＠

ｾ＠ 3fQftiT ｾ＠ 2NOCI, t" fmr ｾ＠ FviliC'Iiifi *
4chHiliC1i*t ｾ＠
ｾ＠ ｾ＠
ｾ＠ 'HJil014kri (;, Qtr (;ｾ＠

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 36

1. r112 2. r -1/2
3. r-s/2 4. r-7/2

121. For a gaseous reaction, 2NO(g) + Cl2 (g) -+

Non-linear T.S.-+ 2NOCI, the pre-exponential
factor in the rate constant is proportional to
1. r112 2. r-1/2 (Ahn P,
3. r-s12 4. r-7/2 The value of k 1 will be
I: koo/[A]t/2 2. koo [A]l/2
122. ｾ＠ A trt ｑｩｪｬｾ｡ｃｦ＠ ｾ＠ ｾ＠ ｾ＠ 3. koo - [A]l/2 4. . [A]t;zlkco

ｾｴ＠ 123. cf;qo:f :A fa (1(0 I ｾ＠ ｾ＠ ft:nr ｾ＠ Ctm ｾ＠

A+A <'1Ttf ｾ＠ ｾ＠ (6 = hv/k )

k.t 1.

k2 2.
A* p
3.
ｾ＠ 4Jif tft ｾ＠ ｾ＠ ｾ＠ ft:nr ｾ＠ ｾ＠ 4.
CfiT a\ Frill<'1iCfl koo t1 ｾ＠ ｾ＠ CfiT a\
123. The low and high temperature limits of
PrillC1iCfl k;' m- ｾ＠ t "aiif A CfiT GT6T [A] 1;z
vibrational partition function are (0 = hv/k )
ｾｴＢ＠ l. e-8/T and ie-8/T
2. e-8/2T and ie-8/ZT
3. e-8/ZT and ie-8/T
4. e-8/2T and ｾ･ＭＸＯｚｔ＠

124. mM 3rnrcft ｾ＠ ｾ＠ ｾ＠ 31CfftiT n = 1 ｾ＠

ｾ＠ ｾ＠ ｉｊｾｃｦｬｴＱ＠ 6 ＼ｾｆ＠ ｾ＠ ｾ＠ ｾ＠
ｾ＠ ｾ＠ ('il.IT· hv = k8 T 1=iT;:f ｾ＠
l. e 2. i
3. 1- e- 2 4. e-2 (e- 1)
1. koo/[A]l/2 2. koo [A]l/2
3. koo- [A)l/2 4. [A]l/2/kco 124. The probability of finding the harmonic
oscillator in the energy level n 1 is (neglect =
122. Species A undergoes a unimolecular reaction zero point energy and assume hv = k8 T)
as follows: l. e 2. i
3. 1- e- 2 4. e-2 (e- 1)

A+A A*+A 125. V<ii CflUT L ｾ＠ * ＱＭｾ＠ ｾ＠ ｾ＠ 111-"Zf ｾ＠

V<ii ｾ＠ ffmcr o(x - L/2), ｾ＠ eJml<:r
QiMoi

p
ｾ＠ 6 I ·Prilhi1<'1A 31CfftiT ｾ＠ fi:nr lA1m ｾ＠
A*
ｾｗｦｲ＠ .;)

l. 0 2. I
For this Teaction, the first order rate constant at 3. L/2 4. 2/L
high pressure is k 00 • Thefrrst orderTate constant
becomes k;'
when pressure of A is [A] 1; 2 . ｾＺ＠ J;: f(x)o(x- a)dx = f(a)]

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 37

125. A particle in a !-dimentional box of length L is 1. 2.

perturbed by a delta function potential,
o(x- L/2), in the middle of the box. The first
order energy correction to the ground state will
be
l. 0 2. 1
3. L/2 4. 2/L
[Hint J:: f(x)o(x- a)dx = f(a)J
126. ｾ＠ s± """ ｦＮ［Ｉｾ｣ｴ＠ m ｾ＠
S± = Sx ± iSy ()"J 128. ｲＡｫＱｾｩＹｃ＠ｆ ＠ｾ m ｾ＠ ｾ＠ 6
x1 dp1 + x2dJ.l 2 =0 (A)
ｾ＠ ｓｸｃｦｴｩｔｹｾ＠
ｾ＠ ｾ＠ ｾｉ＠ CfiR{tC::'l (Sz, S+] t
(B)
2. hS_
4. -hS_
ｾｻ＠ ctrtr nm ｾ＠ trr 1JCfl" ｾｗｦｲ＠ ?iCf Pt-'lfUT
126. The operators S± are defined by t" ft:ttr ｾｉ＠
S± = Sx ± iSy, I. ｭｏｦｔｾｉ＠

where Sx and Sy are components of the spin

2. ｾａ＠ t, ｾ＠ ｂｾ＠ ;ntl-tl

angular momentum operator. The 3. ｾ＠ ｂｾ＠ t. ｾａ＠ wnttt1

commutator [Sz,S+] is 4. cJm mitT mfr ｾ＠ t . .3@ ｾ＠ ..,
2. liS_ fcl i'l <4 Cii'l ｾ＠ 31 ffi ft CfC1 I
4. -hS_
128. Given the following two relations,
X 1 df,l 1 + x 2 df,l 2 = 0 (A)
127. ｾ＠ ｾ＠ ｾ＠ E0 < V CfiT 1JCfl"
Cfd ir<::Ji q;tJT Frlfhlffi f19ct ｾ＠ ｾＪ＠ ｾ＠ and

ｾＢ＠ ｾ＠ n mrr tl ＴＱＧｬｾｩＰ＠ ｾ＠ (B)

S.il?iCfiC11 ｾ＠ ｾ＠ t. ｾ＠ t for a binary liquid mixture at constant

temperature and pressure, the true statement is
1. 2.
that,
I. both the relations arc correct.
2. relation A is correct, but B is not.
3. relation B is correct, but A is not.
4. both the relations are incorrect, except
for very dilute solutions.

129. ｾ＠ ｾ＠ ＮＭ＼ＴＧＢＡｾ＠ cjaq(J"IfOjcti 3fUT cfi'r

3t1'Girt.T ｾ＠
"

3UT <f;tr.:r
..

ｾ＠
.:;,

* ｾ＠ .:J

t
2A err ｲＭｾ＠ ｾ＠ ..,
31101Shf1!Cfi ｾ＠ m3IT ｾ＠
ｭＺＧ＼Ｔｾ＠
127. A quantum particle with fixed initial energy
E0 < V is allowed to strike the. following I. 3fffi!rq; ｾ＠ "()" ｾ＠ ｾ＠ I
four barriers separately. The transmission 2. 3fffi!rq; ｾ＠ "()" "EIC?.T ｾ＠ I
probability is maximum in

S/55 CSI/14-1AH-4A

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 38

3. ｾＢｴｬＧ＠ 3. repulsive tenn is equal to the attractive

tenn
4. 'ffitrq; ｾ＠ ｾ＠ uc:nT ｾ＠ I
4. the system is mdependent of both the
attractive and repulsive tenns
129. If the bond length of a h1eteronuclear
diatomic molecule is greater in the upper
132. ｾ＠ D0 (A) <1m I (A), ａｾ＠ Sfimr: ｾＴＧＱ｜Ｘ＠
vibrational state, the gap between the
successive absorption lines of P-branch ｾ＠ <rm 3fT'll'rni fa1rcr ｾ＠ m m- ｾ＠
I. increases non-linearly
2. decreases non-linearly ｾａＬ＠ H, Hz, H2.. ｾｬｴ［ｲ＠ # ｾ＠ 'QCF t) clt
3. increases linearly ｭｍｾｮｄｃｬ＠ # ｾ＠ ﾷ ｾ＠ t1
4. decreases linearly
I. D0 (H2 ) =D0 (Hi) +/(H) -/(Hz)
130. ｾ＼ｦｩ＠ 1jim' ｾＧ＠ ｾ＠ rqJffo(441 <frr ri_CfJI<a 2. D0 (H2 ) = D0 (Ht)- I(H) +/(Hz)
tl:tr.i Ｚｭｾｯ］ｬｦ＠ tmft t', Cf;l' EPR ｾ＠ ｾ＠
3. D0 (Hi) = D0 (H2 ) + I(H) +!(Hz)
em:- ｾ＠ ｾＮ＠ ｾ＠ ｭｍｾｒｙｃｬ＠ QTOT ｾ＠ ifiT
4. D0 (Hi) = D0 (H2 ) - l(H) -/(Hz)
ｾｭＭ
I. 6m5 = 0, flm 1 =0 132. If D0 (A) and I (A) refer respectively to the
/.. .1m5 = ±1, =0
flm1 dissociation energy ..and ionization 'POtential
3. 6nt 5 = ±1, ami= ±1 of.A (where A is either H, H2, or Ht species),
4. Am5 = 0, Am1 = ±1 the correct relation among the following is
1. D0 (H2 ) = DD(HJ) + I(H) -/(Hz)
130. EPR spectrum of .a free radical containing
nuclei with nonzero nuclear spin is obtained 2. D0 (H2 ) = D0 (Hi) -I('H)+ I(Hz)
if the follo.wing selection rules are observed:
I. Am5 0, Am1 0 = = 3. D0 (Ht) = D0 (H2 ) + I(H) + I(Hz)
2. Am 5 = ±1, llm, = 0 4. D0 (Hi) = D0 (H2 ) - I(H) -/(Hz)
3. Am.s = ±1, Am1 = ±1
4. l1m5 = 0, llm, = ±1 133. C2" ｾ＠ Wfl .f r ｾ＠ lfR1Jft Ｎ ｾ＠ eft
131: ｾ＠ ｃｬｆｒＱｾＦ＠ 1ffi ｾ＠ fc:lv ｾ＠ ｾ＠ tR
t't ｣ｩｳｾｕｬＤＱ＠ ｾ＠ ｾ＠ :if;cr.:r ｾ＠ ｾ＠
ｾ＠ A2 # 3fffi ｾＮ＠ ｾ＠ ｾ＠
ｱＺ＼ｲｩｬｾｴＧ＠ ｾ＠ 'fiT t1li1 ｾ＠ ｾ＠ ｾ＠ mrr ｾ＠ 3Hsis;fl4
t;t ｾＧｲｬｩｒ＠ ｾ＠ t'l
IR

ｾ＠
I. 'llffi4,cft 'Cf4 tR ｾ＠ t1G mfr ｾ＠ t'l C2., E ｾ＠ l1u ｬＱｾ＠
2. ｾ＠ ｾ＠ trr Slkl&>\fl 'Cf4 Hrt'r tmu t'l A, I I I I z,x 2 , v2 ,z
A, I 1 -1 -1 R,,xy
3. Ｇｬｦｩ＼ｨｾ＠ ｾ＠ 3ft\ ｾ＠ ｾ＠ iiTm' ｾ＠ ｾｉ＠ 1 -1 I -1 X,Ry,XZ
..81
4. ｾ＠ ｾ＠ Ｓｾ＠ mt ｜ｉｾｃｦｬｴ＠ tt4l ｾ＠ 82 I -1 -1 I y,R,, vz
ｾ ﾷ ｴＬ＠
1. 7A1 + 581 + 882
13 J. At high pressure, .the fugacity coefficient of a
2 9A 1 + 481 + 782
3. 7A1 + 381 + 78..2
real gas is greater than one, because 4. 9A 1 + 381 + 882
I. -attractiv.e tenn overwe!ghu.he repulsive
tenn 133. The character table of C2 v point group is given
2. repulsive term ovcnveighs the attractive below. In cis-butadiene molecule the
tenn . ¥ibrational medes belonging <to A 2 ·irreducible
-representation -are l'R inactive. The remaining
IR activ.emodes are

S/55 CSII14-1AH-4B

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 39

c,, E Cz (J, a! ｾｱＺＨｩ＠ ｾＢｔ＠ ｾﾥ＠ :;..;;fr ｾ＼Ｚｦ＠ ｾＱｦ＼Ｇ＠ ｾＨＧＺＩ＠ ｾｉ＠ 1.0
A1 I, 1 1 I z,x 2 ,y2 ,z
bar Ｈｾｲ＠ 298 K, trr ｾＱＤ ［ｻＰＱ＠ <t F !irv:r q T ｬｩｴｾ＠
A2 ] ' l -1 -1 R,.,xy
81 I -1 1 -1 j x,Ry,XZ Ｄ｜ｾＮ｡＠ <6T ｾｊｔ＠ em ｾ＠ ｦｾ ［＠ ｾｲ＠
82 I -1 -1 1 y,Rx,yz ＳｩｦｴｳｨＺｲＮｾ＠

1. 7A1 + 581 + 882

2 9A1 + 481 + 782
3. 7A1 + 381 + 782
4. 9At + 381 + 882 ｾ＠ Ｓｻｾ＠ t' ｾ＠ ｾ＠ 26 ｾｪｱＮ＠
ｾＧＺｎ｣ｩ＠ ｾＮ＠ ｾ＠ ｾｩＧ［Ｎｲ＠ .,
61CFa -xir ;q
134. ｾ＠ qX'Y.St ｾ＠ (Sl Z ·3nlf ｾ＠ ｾ＠ ｾ＠ ｱｾ｡［Ｌ ﾷ＠ 2746.06 kJ Jnl)l- 1 ｾ＠ m ｾ＼ｩ＠ tiW1T
.:>
fcrtm ｾ＠ 3m t Otrr qx'Y, xy Cic:f ｾ＠ ｾｩｬ＠
q:oaAa:t ｾ＠ I. 1.55 v 2 1.09 v
I. c.: 2. c.:. i 3. 3 15 v 4 2.06 ...
｣Ｇｾ＠
3. 4 4. c: 136. Fuelt;c:tts provide clean electrical cncrg) to a
varie:ty of applications including automobiles
134. The product cr%Y.SI (SI is the four fold and stationary power sources. Normally
improper axis of rotation around the z axis, hydrt.)gcn combines with oxygen to give
and qXY is the reflection in the .xy plane) is eleetrica I energy and water. Jf we use butane
I. c.: 2 c.:. i instead of hydrogen al 1.0 bar anc ｾ ＹＳ＠ K, th<·
3. c: 4. c: foll r.)wing reaction occurs:
13
C41itoC9) + -20z(B)..,. 4C0 2 (g) + SH2 0(l)
135. ｾ＠ X 4'tAIUJ:flt ｾ＠ <mf ｾ＠ ｾ＠ ｾ＠
Jf the change in the Gibbs frc<> energy of this
ｾＱＧｦｩＩｃ＠ Ｎ＠ｾ ＠ｾ X-X ｾ＠ 160 pm ｾｉ＠ ｾ＠
reaction is 2746.06 kJ mol- 1 • invol\ ;ng 26
ｾ＠ 7ft;it ＠ｾ ｾ＠ ｾ＠ ｾ｣ｮｬ＿ＴｃＱ＠ ｾ＠ electrons , its open circuit voltage is
ｾ＠

3ftt 7ft;it ｾ＠ ｾ＠ ｾ＠ X-X .3mfi=tr ｾ＠ L 1.55 V 2. 1.09 V

ifiT 3rltlT ｾ＠ 1 cm 3 ｾ＠
3. 3.15V 4. 2.06V
CR, 4:0"11UI:flt
..:>
ｾ＠
ｾｉ＠
I. 6.023 X 1027 137. ｾ＠ ｴｮｾｲＺ＠ ｾ＠ ｾｔ＼ｑＧｏ＠ ｾ ｾ＠
2. 3.45 X 1023
3. 6.02 X 10 21 4. 3.8 X 1021 Ｈｾ＠ ＼［ｾｮＱ＠ Cfitlt ｾＩ＠ ｾ Ｎ＠ ｾ＠ r tn

135. A solid consisting of only X atoms has a

ｾ＠ ｾＺｉｔ＠ <6T mr ｾ＠
close-packed structure with X-X distance of
" I. 1 + kdAJo 2.
1
l+kt(Aiu
160 pm. Assuming it to be a closed-packed I Ｋｬｴ Ｚ ＮＱ Ｑｾ＠
structure ofhard spheres with radius equal to 3. 4.
kt!Alu
half of the X-X bond length, the number of
atoms in 1 cm3 would be
I. 6.023 X 10 27 2. 3.45 X 10 23 137. The fraction of groups ｣ｯｮ､ｲ ｾﾷ＠ ...:':i at tin.:,· :
3. 6.02 X 1021 4. 3.8 X 1021 any stepwise condcns3tion p•Jiym<:ri7iiti· ,:
(overall second order) reaction is
1
136. ｾ＠ ｾＮ＠ ｾ＠ cmr.:rr C1'trr ｾ＠ qrtR ｾ＠ I 1 + kt[A] 0 2 i•.caL.q,
ｾ＠ 3. ....!!.. lAlo .,
·'
:;;;;fr an ｾ＠ I :tl1AirliC1 : ｾＤＩ｜ＵＱｃｉ＠ ｾ＠ :iJ<tf!'IJta:t
1+ lct(Aio .:ti4lc.

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 40

140. The number of microstates that are possible,

when two particles are distributed hi four
states such that the resulting wave functions
are antisymmetric with respect to exchange
of the particles, is
2 3D3/2, JD Jn, 3D tn
l. 16 2. 12
3 3 3
3. DJ , D2 . Dt 3. 8 4. 6

141. H2 3fUJ *t ｾ＠ kl C1A .mJ"ftrr t' fc:tv

138. The configuration [Ne]2p 3p has a D 1 1 3 ［ｈｱｾ｜ｩｪ＼ｦＨＱ＠ 3mrrtT 'ffi7T ｾ＠ t' ｾ＠ 3WT
tenn. Its levels are ｾ＠ ｾ＠ ｾ＠ 'HFtfCIICfi ｾ＠
0312 I 30tn
3
I. (1saa, 1saP,1sba,1sbP ＢＧｾＱＤＩ＠ ....
\il-01 3iOJ t'
3 3 3
2 Dsn 0312, 0tn 1 tWJTUj a ntrr b t' q (A IUj<f; ft.:tr.i ｾ＠ ｾｉＩ＠
3.
3031 3D2, 30,
1saa(1) 1sa/J(1)1
3
4. 03 302, 30,1 0o
3
I
I. 11saa(2) 1saP(2)
1saa(1) 1sbfJ(1)j
2
11saa(2) 1sbP(2)
139. ｾ＠ 'ITCf>' ＤｗｾＮｲｴ＠ ｾＮ＠ ｾ＠ l = o c:rm
1saa,1) lsba(l)l
.m =0 ｾＮ＠ t' ｾ＠ tfi"M'Vf N0 e-t1 ntrr 3.
11saa(2) 1sba(2)
N1(4- a)e-t1/Z ｾｲＺ＠ ｾｩｬＢＺｲＨＧＱｒ＠ (£0 ) c;trr
1saa(1) 1sbP(1)1
4.
'C1trn' 3('fff-;1(1 (E1 ) ｾ＠ Ｚ ｾ＠ ｾ＠ ｾ＠ 11saa(1) 1sbfJ(2)
'lffa' ｾ＠ <itaT IJiCifii N2 (3 Ｍ ｾ ｣ｲ＠ )e -tT ｾ＠
141. A Slater determinant corresponding to the
ｾﾣ｡｣］ｲＺｬ＠ ｾ＠ ionic·part of the ground state.valence bond
1. E ;;:: o 2. oｾ＠ E s; E0 wav.e function of H2 molecule is
3. Eｾ＠ E1 4. E.o ｾ＠ E ｾ＠ E1 (1saa,1saP.1sba,lsb'fJ are atomic spin-
oroitals ofbydrogen atoms a and ·b of the
139. 'For some one-electron system with l 0 and = hydrogen molecule)
m = 0, the functions N 0 e-a and
N1 (2- a)e-ufZ refer respectively to the lsaa(1) lsaP(l)l
ground (E0 ) and first excited (£1 ) energy l. l lsaa(2) lsaP(2)
levels. If a variational wave function lls4 a(l) lsbP(l)l
N2 (3 ｾ＠ a)e-u yields ·an average .:energy E, it 2
lsaa(2) 1sbP(2)
will satisfy
I. E;;:: o
3.
2. 0 ｾ＠ E s; E0
E ｾ＠ E1 4. E0 ｾ＠ E s; E1
3.
l lsaa(l)
1saa(2)
lsba(l)'
1sba(2)
lsaa(l) lsbp(t)l
140, ma- mCfl0'1T ｾ＠ ｾ＠ ｾＮｭ＠ ｾ＠ ﾷ ｾ＠ ｾ＠
4.
l ＱＮｾ Ｔ ｡ＨＱＩ＠ .1sbp(2)
fc!rc:rfu.1 fcr;m ｾ＠ f.f; ｾ＠ irt1r q;c;r;f ｾ＠
t- ｾ＠ t- Ｎ ｾ＠ 11' SlffiaAfll(1 m- en t42. ｾ＠ r ｾ＠ co ｾＮ＠ c:rr Ｍ ｾ＠ ｩｦｏｔＭｾｊＧＢｴｬ＠ Ｍ ｾ＠ ·q ;r 11r.f

ｾＪｴｭｲ｣＠
tmiT Ｈｾ＠ ｾＺ＠ ｾ＠ j *t 3mlii>G(11 BJ)
I. 1 2. ｧｾ＠
I. 16 2. 12
3. 8 4. 6

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 41

142. When T -+ oo, value of the single-particle

partition function will be (given: degeneracy
oflevelj = Bil
I. 1 2. Bo

p p

143. 311"i1&41

p
ｾ＠ ｾ＠ ｾ＠ ｾＴ｣ｴｩｦＱ＠ m- fi1r;; ｾ＠
ｾＮ＠ 0.01 M ｾ＠ 0.04 M ｾ＠ ｾ＠ ｾ＠ ｾ＠ M4AIII1 ｾＴＱｇｦ＠
ｾ｣［ｴＴＢｩＬ＠ "A" ·1 1ro ｾ＠ ｾｉ＠ ｾｬｯｧ＠ :o.o• = 0.3 ctt
0.01
qRac%111 q;r ｾ＠ 'QCfi G«f (=fliT ｾ＠

B tR ｾｔ＠ n ｾ＠ fri"'C:ct)i ｾＮ＠ ｾ＠ ｾ＠ ｾ＠ tm.r Cfi& ｾＮ＠ at

1. I 2. 2 I. ｾｔＺ＠ A (=fliT C
3. 3 4. 6
2 ｾｔＺ＠ A (=fliT B
3. ｾｲＺ＠ CC'imA
143. The rate constant for a reaction
4. ｾｔＺ＠ BC'imA
At++ Bn+-+ P
is measured in two different aqueous
145. Among the following figures,
solutions of ionic strengths 0.01 M and 0.04
004
M. If log : = 0.3, the charge n on B is
0.01
closest to
1. I 2. 2
3. 3 4. 6 p

144. ｾ＠ l?'l'lcr-ct ｾ＠ ｾ＠ ,:)

sflcftf;)c;t mmr.;
(CH2 CHCH 2 f ｾ＠ ｾ＠ ｾ＠ tRmUJ tR n
$ti1<H;1111 3fi'Chr ＨＤｾｃｦｓＧｉＱ＠ JmT ｾ＠ ｾ＠ p

ｾ＠ the variations or mass adsorbed with rrcssurc

I. 1/2 2. 1/.fi for a monolayer and a multi ｉ｡ｾ＠ cr arc
3. I 4. 2
represented by
I. A and C respectively
144. According to Htickel theory, the rr electron 2 A and B respective!}
1
charge on the central carbon atom in 3. C and A respectively
propenyl cation (CH 2 CHCH2 )+ is (in units of 4. B and A ｲ･ｾｰ｣ｴｩｶｬｹ＠
electronic charge)
I. 1/2 2. 1/-i2
3. I 4. 2

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