*Given T drybulb = 80°F and T
*Calculate the potential energy
*A gas mixture contains
0.0083 g mol of water vapor
per g mol of dry CH4. % RS
(46.4%) % saturation (46%)
temp to which mixture must be
heated (315 K)
*A gas at 200˚F and 30 in Hg
abs. Percentage humidity
(2.79%) RH (11.6%) dew
point (112 F)
*Air saturated with water
vapor at 80°F and 745.0 mm
Hg abs. % water originally in
air removed (63%)
*Toluene is evaporated into
dry air. 40 C, 101.3 kPa, 50%
RS. Pressure (1150 mmHg)
*A furnace used to provide
heat to anneal steel. Orsat
(84.9 N2, 15.1 CO2) New orsat
assuming 5% carbon (0.4 O2,
84.6 N2, 14.2 CO2)
*A synthetic gas generated
from coal has the following
composition: CO2, 7.2%; CO,
24.3%; H2, 14.1%; CH4, 3.5%;
N2, 50.9%. Vol air/vol syn gas
(1.25) If 38% excess air were
used for combustion (6.41) flue
gas analysis (0.23 CO2, 0.14
H2O, 0.63 N2) (0.14 CO2,
0.08 H2O, 0.74 N2, 0.04 O2)
*In a sulfuric acid plant, In the
plant SO2 along with 10%
excess air. Flow rate of product
stream (4.02x10^6 m3/hr)
flow rate of recycle
(0.43x10^6 m3/hr)
*Moist hydrogen containing 4
mole percent water. Orsat
(5.95% O2, 94.05% N2)
*A constant-volume vessel
contains dry air at 66˚F and
21.2 psia. Did all water
evaporate? (Yes) Vessel volume
(90.8 ft^3) Humidity (0.097)
*Assume that Raoult's Law
holds for the following
mixture. Dew point pressure at
150 F (333 mmHg) Dew point
temperature at 85 psia (435 K)
Bubble point temperature at 70
psig (429 K) Bubble point
pressure at 150 F (425 mmHg)
*A natural gas has the
following analysis at 400 kPa.
Temperature to prevent
condensation (300 K)
Composition of liquid (1.04)
*A silica gel drier removes
1000 kg of water per hour.
Volume of wet air/hour (6.04 ×
10^4m3/hr)
*A contact sulfuric acid plant
produces 98.0 % sulfuric acid.
Tons/day of 95.9 % H2SO4
(2060 lb) Tons/day of 97.3 %
H2SO4 (6470 lb) Tons/day of
98 % H2SO4 (2240 lb)
* Based on the process drawn
in the diagram, Waste is 100
kg. kg recycle/kg feed (0.33)
*Many chemicals generate
emissions of volatile. The
recycle stream contains 80%
CO and 20% reactant. Recycle
(6460 kmol) ratio of moles of
the recycle stream to moles of
the product stream (3.5) Ratio
of recycle to product (1.58)
*Plants in Europe sometimes
use the mineral pyrites. SO2
0.7 %, O2 2.9 % and N2 96.4
%. Feed (1130 kg) kg air/ kg
pyrites (3.1)
*Ammonium dihydrogen
phosphate. Approximate final
temperature (21.4 C)
*A heat capacity equation for
acetylene is given by Cp = 9.89
+ 0.8273 × 10^-2T - 0.3783 ×
10^-5T^2 + 0.7457 × 10-9T^3.
in °R (Cp = 5.284 + 0.1175 ×
10^-2 T°R – 0.3783 × 10–5
T°R^2 Btu/(lb mol) (°R)) in K
(Cp = 6.01 + 1.86 × 10-2 TK –
1.45 × 10-5 TK^2 + 1.34 ×
10-9 TK^3)
*A shock tunnel uses hydrogen
as its driving gas. Final
temperature (300 K) Final
pressure (0.48)
*A stainless steel mixing tank.
One thousand lb of 20%
H2SO4 solution at 210 F is
initially in the tank. Final
temperature (249 F) Weight
(1213 lb) Composition (0.46)
*Perchloric acid can be
prepared as shown. 17,400 lb
HClO4, recycle is 6125 lb
Ba(ClO4)2. Overall %
conversion of Ba(ClO4)2
(100%) HClO4 leaving the
separator/lb feed (0.64)
H2SO4 entering the reactor
(10700lb) Per pass conversion
of Ba(ClO4)2 (0.8)
*Polymeric membranes are
proposed to be used from
1.5% to 0.01%. Recycle (364
m3/hr) Waste (14.9 m3/hr)
* TiCl4 can be formed by
reacting. 78 % TiO2 and 22 %
inerts. TiO2 ore fed (100 kg)
45 wt % HCl (3.8 kg) Ratio of
recycle stream to fresh TiO2
(0.26)
*Your assistant reports CO2
11.8%; CO 5.0 %. Would you
compliment? (no. discrepancy
is too large)
*A stream of hot water at 150
°F flowing at a rate of 50
gal/min. Rate of water (377
lb/min) Rate of steam (32
lb/min)
*A 100-hp engine is used to
pump ground water into an
irrigation channel. Rate (2.544
× 10^5 Btu/hr) (7.457 ×
10^4 J/s) (745.7 kW)
*An ideal gas at 50˚C and 1 atm
is heated to 500˚C at constant
pressure. Enthalpy (0) Internal
energy (0)
*An automobile weighing 2500
lb is traveling at 55 miles per
hour. Heat (-325 BTU)
*An ideal gas in a tank at 500˚C
and 100 kPa. Work (14 800 J)
*Calculate the heat of reaction
at standard conditions for 1
mol of HCl(g). (–28.6 kJ/g
mol)
*A laundry can purchase soap
containing 30.0 wt % water at
a price of $ 7.00. Maximum
price of 5% water ($9.52)
*An old way of producing
hydrogen gas. How many
grams of sulfuric acid solution
(98%) must act on an excess of
zinc to produce 12.0 m^3/hr of
hydrogen (5.37 × 104 g)
*Five pounds of bismuth 5%
free sulfur recovered. Limiting
reactant (S). Percent excess
reactant (14.9) Percent
conversion sulfur (70)
* The synthesis of ammonia
proceeds. 4202 lb of nitrogen
and 1046 lb of hydrogen.
Limiting reactant (N2) %
excess reactant (16.2%)
%conversion (60%)
of 1 kg of water located(980 J)
*Determine Q, W, ∆U and ∆H
for the isothermal expansion
of 1.31 mol of an ideal gas. ∆H
(0) ∆U (0) Q (745 J)
*Carbon monoxide and 100%
excess water. Heat loss from
the reactor is 120.2 kJ per kg
mole of CO. Entering
temperature (446 K)
*Carbon monoxide is reacts
with 100% excess water. The
reactants enter the reactor at
500K and 1.0 atm. Outlet gas
temperature (1112 K)
*Find the standard (25°C and 1
atm) heat of reaction for
C3H6(g) + 9/2 O2(g). (-
2058.46 kJ/g)
*In a paper mill two steam
chests are to be operated in
parallel. Pressure in system
after equilibrium (129 psia)
*A gas analyzes 60% methane
and 40% ethylene by volume.
Pressure inside the cylinder
assuming ideal gas (30,400
kPa) Using compressibility
factor (26,000 kPa)
*A solvent storage tank, 15.0
m high contains liquid styrene
sp. gr. 0.909. Gage pressure
(134 kpa) new pressure if tank
is full (96.9 kpa)
*A steel container has a
volume of 200 m3. It is filled
with nitrogen at 22˚C and
atmospheric pressure.
Fraction of N2 leaving (0.6)
*Calculate the vapor pressure
of benzene at 50˚C using the
Antoine Equation. Normal
boiling point (353.3 K)
*In a waste treatment plant,
hazardous chemicals are
oxidized. The inlet gas flow
rate is 3.32 m^3/min. Final
temperature (321 K)
*Lead is used in a number of
manufacturing industries.
Lead vapor at 1850 C. Product
is solid lead at 280 C. Enthalpy
change (–195,400 kJ/gmol)
*Methane at 100°C is burned
with 100% excess air which is
at 25°C. Adiabatic flame
temperature (1484 K)
*n-Butane is a common fuel
used. cooled from 10 atm and
260°F. Enthalpy change (-
2400 BTU) If cooled
isobarically to satd liq (-1730
BTU)
*Chlorine gas containing 2.4
percent O2 is flowing through
an earthenware pipe. Volume
of initial gas (138 m3)
*If sufficient water is placed in
a vessel containing a dry gas at
15˚C and 100.5 kPa. Absolute
pressure (102.2 kPa)
*20 ft3 of nitrogen at 300 psig.
Partial pressure O2 (286 psia)
Partial pressure N2 (396 psia)
*Seven pounds of N2 at 120˚F
are stored in a cylinder. P of
N2 assumed ideal (141 atm) P
of N2 using VDW (139 atm)
Using compressibility factor
(148 atm) Using RK (144
atm)
*Suppose 1.00 g mol of CO2 at
a temperature of 220K is
placed in a Dewar vessel.
Volume of vessel (2.38 x 10-3
m3/g mol)
*The corrosion of aluminum in
water. 2Al(s) + 6H2O(l) →
2A1(0H)3(s) + 3H2(g). Heat of
formation (– 1276 kJ/mol)
*The vapor pressure of
benzene can be calculated
from the Antoine equation ln
(p*) = 15.9008 –2788.51 –
52.36 + T. Heat of vaporization
(31.95 kJ/mol)
*Two gram moles of carbon
dioxide are heated from 400°C
to 1100°C. Enthalpy (75980 J)
*Use the SI data for water.
453.1 K and 1000 kPa.
Enthalpy change (7520 kJ)
Quality (0.51)
*Use the steam tables in
American Engineering. 15 lb of
wet steam at 120 psia. Quality
(0.56)
*A gas saturated with water
vapor in a tank has a volume of
1.00L at 17.5˚C. Volume of dry
gas (0.97 L) Grams of water
vapor (0.015 g)
*Dry air at 25˚C is saturated
with toluene under a total
pressure of 760 mmHg abs. Is
air adequate (No, molar ratio
air/toluene reqd is 42.9,
given ratio is 25.93)
wetbulb = 73°F. RH (75%)
Dewpoint (70 F) specific
enthalpy (36.7 BTU/lb)
specific volume (13.95
ft^3/lb) Humidity (0.0158
1bH2O/1b air)
*Breakfast cereal is being
dried. Cereal must have a
water content of no more than
14.0 percent. Inlet flowrate of
moist air (1.96x10^4
m^3/hr)
*Air enters a drier at 200°F
with a dew point of 80°F.
Humidity (0.022 1b H2O/1b
BDA) T wetbulb (102°F) RH
(4.3%) Adiabatically cooled to
110°F. Humidity (0.044 1b
H2O/1b BDA) Dew point
(100.7°F) Constant humidity
to 180°F. Adiabatic satn temp
(111°F) Dew point (100.7°F)
RH (13%) Energy (18.8
Btu/1b BDA)
*A crystallizer contains 6420
lb of aqueous solution of
anhydrous sodium sulfate.
Weight of ML (3300 lb)
*Gypsum is produced. CaCO3
96.89 %; MgCO3 1.41 %;
inerts 1.70 %. CaSO4 produced
(6600 kg) Sulfuric acid reqd
(4920 kg) CO2 generated
(2165 kg)
*A triple effect evaporator is
designed, 25 wt % to 3 wt %,
produce 14,670 lb/hr of NaCl.
Feed rate (56900 lb/hr)
Water removed in each
evaporator (v1= 13,800 v2=
14,700 v3= 13,800 lb/hr)