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The 2016 Management and Innovation Technology International Conference (MITiCON-2016)

Fabrication of Ozone Generator for Indoor


Air Quality
Wannana Panuwatsuk Pumate Duanden
Environmental Engineering Branch, Computer Engineering Branch,
Faculty of Engineering, Faculty of Engineering,
Ramkhamhaeng University Ramkhamhaeng University
Bangkok 10240 Thailand. Bangkok 10240 Thailand.
Email: wpanuwat@hotmail.com Email: pumate192@hotmail.com

Abstract⎯Ozone generator was fabricated in the size Ozone can be generated by using corona discharge and
of 40x12.5x12.5 cm3. It composed of 6 ozone tubes, a UV irradiation. Corona discharge is selected in this paper
computer fan, electronic board with variable resistors due to practical and safe method for various scales of
and adjustable buttons of 7 ozone production levels. The application. Generally, commercial ozone generator is
generator was operated in a chamber of 96.5x47x47 cm3 made to produce ozone at high concentration which is
representing a model room met air ventilation standard. usually over the standard value at least 10-100 times. The
At level 1 of operation, ozone concentration in the user only turns the generator on and off at certain time
chamber was to be 0.1 ppm which is obeyed the when ozone odor has become strong. This paper presents
standard OSHA recommendation for 8 hrs of working. the ozone generator capably operated at various ozone
The generator was also tested in a normal room with the concentrations especially in indoor air which amount of
size of 4x4x2 m3. Due to low flow of computer fan, the ozone produced met the standard of indoor air quality (0.1
generator was performed to obtain ozone concentration ppm).
of 0.1 ppm as following: turning on at level 7 for 3 hrs 2. MATERIALS AND METHODS
and further on at level 3 until 8 hrs.
A corona discharge system, the feed gas passed between
Keywords⎯ozone generator; ozone level two closely spaced electrodes under an applied voltage
potential of ~ 10 kV. A barrier discharge occurs when the
1. INTRODUCTION feed gas becomes partially ionized, resulting in a violet
glow. Efficiency of ozone production depends on the
Ozone is composed of three atoms of oxygen (O3). It is the strength of micro-discharges. [5] In this paper, the generator
oxidizing agent which is the most attention due to its strong consisted of ozone tubes (500 mg/h of ozone production),
behavior and rapid decomposition. The removal of air blower, and electronic board containing variable
ammonia and methylamine under laboratory conditions was resistors (at least 1,000 kΩ) with adjustable buttons. The
found to be five times after 1-hr exposure (applying 2 times device was performed in a chamber of 0.213 m3 and a room
the stoichiometric ozone quantity). [1] Ozone applied to of 32 m3 volume with air ventilation following
incoming air in piggery building at concentration of 0.03 ANSI/ASHAR Standard 62.1-2004. (25oC, 30-60%
ppm reduced 21 % of inhalable particles and 30 % of humidity and air flow rate > 0.568 m3/min/person) The
airborne bacteria but increased 26% of respirable particles. ozone level in a room can be determined by the equation of
[2] Ozone was also used to reduce more than 90% of
airborne microbes such as Staphylococcus salivarius and = − 
Staphylococcus epidermis by using O3 at concentration of
0.6 ppm for 10 min and 4 min, respectively. [3] For bacteria
where, V is the volume of room, C is the ozone
found in soil and water, Pseudomonas fluorescens and
concentration, t is time and λ is the decay rate of ozone due
Escherichia coli, were able to be reduced 50 % by applying
to ozone deposition and ventilation system, G is the
O3 at concentration of 0.1 ppm for 20 min. [4] Therefore,
generation rate of ozone. [6]
ozone is commercially used as a disinfectant for air and
An ozone produced was determined by using iodometric
water. However, inhaling ozone, even in small amounts,
method. Ozone gas was bubbled into 100 ml of 2%
may cause throat irritation, coughing, chest pain and
potassium iodide at flow rate of 2 l/min. The solution was
shortness of breath. The Occupational Safety and Health
then titrated with 0.01 N sodium thiosulfate solution using
Administration (OSHA) recommends an average
1% starch as indicator. Concentration of ozone in ppm
concentration of ozone at 0.1 ppm or less for 8 hrs in indoor
modified from International Ozone Association [7] equals:
environments. (ANSI/ASHARE Standard 62.1-2004)

978-1-5060-4105-3/16/$31.00©2016 IEEE

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The 2016 Management and Innovation Technology International Conference (MITiCON-2016)

0.24 x volume of thiosulfate in ml x 1,000 x 298 divided by


the inlet volume of gas passed in l, 12.187, and 48.

3. RESULTS AND DISCUSSION KI solution

The size of ozone generator was to be 40x12.5x12.5 cm3. 6


ozone tubes and electronic board with variable resistors Suction pump
were fabricated in the generator. Adjustable buttons were (2 l/ min)
set up into 7 levels of ozone production. At first, air from
air pump was introduced into the generator which is turned
on at certain level of ozone production. Gas flowing out at
Model room
Table 1. Amount of ozone produced from ozone generator
with pumping air in and bubbling gas out

Level of ozone Amount of ozone produced


production mg/h ppm
Fig.2. Gas inside a model room was drawn and determined
1 0.05 0.20
by iodometric method
2 0.10 0.41
3 0.17 0.71 Table 2 demonstrated the average ozone concentration
4 0.91 3.87 at various levels of ozone production. Level 1 was found to
5 1.97 8.35 be the restriction of ozone concentration for 8 hrs of
6 2.90 12.3 staying. In order to obtain a practical ozone generator, it
7 8.47 36.0 was also operated in a normal room with the size of 4x4x2
m3 for 10 hrs at certain level of ozone production, as shown
flow rate of 2 l/min (breathing rate) was bubbled into 2 sets in Fig. 3. This room was controlled to meet the air
of potassium iodide solution in order to determine the ventilation standard. Gas inside the room was drawn to
efficiency of ozone production. The result of ozone
concentration at each level was shown in Table 1. It was Table 2. Amount of ozone produced from refabricated
found that higher amount of ozone produced was done by generator in a room model
turning on the higher level. This is consistent with using
higher voltage to obtain higher ozone concentration of Level of ozone Amount of ozone produced
ozone generator with dielectric barrier discharge. [8] The production mg/h ppm
minimum level of ozone production was to be 0.20 ppm 1 0.02 0.10
which is more than the requirement of standard air quality 2 0.06 0.26
(0.1 ppm). To meet the OSHA value, a computer fan with 3 0.11 0.46
low flow was introduced into the generator in order to let
4 0.18 076
the air flow in and out for a practical use. The refabricated
5 0.19 0.82
generator was tested in a chamber with a size of
6 0.25 1.07
96.5x47x47 cm3 (0.213 m3) representing a model room with
indoor air quality by controlling the air ventilation at 0.568 7 0.47 1.99
m3/min/person, temperature and humidity at 25oC and 50%.
The device was operated in the chamber at various levels of
ozone production for 8 hrs. Gas inside the chamber was Refabricated ozone generator
bubbling out at interval of 3rd hr, 5th hr, and 7th hr to
determine the ozone concentration, as shown in Fig. 1.&2.
Suction pump
Refabricated ozone generator

Flow of gas KI solution


Inside a model room
Fig.3. The refabricated generator operated in a normal room
Fig.1. The refabricated ozone generator was operated in a and suction gas determined by iodometric method
model room.

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The 2016 Management and Innovation Technology International Conference (MITiCON-2016)

determine an ozone concentration at interval of 3rd hr, 5th hr, obtain ozone concentration of 0.10 ppm for 8 hrs, the
7th hr, and 9th hr, respectively. The results were shown in operation should be turning on at level 7 for 3 hrs and
Table 3. Due to low flow of computer fan and large space further on at level 3 for 5 hrs.
of normal room, level 1 2 and 3 were not able to reach 0.1
ppm of ozone concentration within 5 hrs of operation. 5. REFERENCES
Therefore, it was conducted to operate at level 7 first. For 2
and 3 hrs of operation, ozone concentrations were found to [1] J.L. Ullman, S. Mukhtar, R.E. Lacey, and J.B. Carey, “A
be 0.02 ppm and 0.10 ppm, respectively. Then, another review of literature concerning odors, ammonia, and dust
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production and time 3rd hr 5th hr 7th hr 9th hr “Bactericidal effect of high airborne ozone concentrations on
of operation Escherichia coli and Staphylococcus aureus,” Ozone Sci.&
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2 for 10 hrs 0 0 0.10 0.10
[4] L. Fan, J. Song, P.D. Hildebrand and C.F. Forney,
3 for 10 hrs 0.02 0.05 0.08 0.15 “Interaction of ozone and negative air ions to control micro-
7 for 2 hrs+2 for 8 hrs 0.02 0.05 0.10 0.10 organisms,” J. Appl. Microbiol, vol. 93, pp. 144-148, 2002.
7 for 3 hrs+2 for 7 hrs 0.05 0.08 0.10 0.10
[5] A. Khurana, “ Ozone treatment for prevention of microbial
7 for 2 hrs+3 for 8 hrs 0.05 0.08 0.10 0.10
growth in air conditioning systems,” Master of
7 for 3 hrs+3 for 7 hrs 0.10 0.10 0.10 0.13 Engineering’s thesis, University of Florida, U.S.A, pp.17,
2003.
concentration of 0.10 ppm was held for 8 hrs by operating
[6] S.R. Ardkapan, A. Afshari and N.C. Bergsoe, “Performance
at level 3 following 3 hrs of level 7. In addition, the
and effectiveness of portable air cleaners in an office room:
generator used electric power less than 150 watts/10 hrs. It
an experimental study,” J. Civ Eng Archit, vol 9, pp. 757-
is closed to the power consumption of 191.5 g/kw/hr for
766, 2015.
ozone generator using DBD at 50 Hz. [9]
[7] International Ozone Association, Quality Assurance
4. CONCLUSION Committee, Revised Standardized Procedure 001/96,
“Iodometric method for the determination of ozone in a
process gas,” Retrieved July 31, 2015, from http://www.
The generator was set up in the size of 40x12.5x12.5 cm3
otsil.net/articles/IODIMETRY20%METHOD%20OZONE%
and composed of 6 ozone tubes, electronic board with
20MEASUREMENT.pdf
variable resistors, and adjustable buttons of 7 ozone
production levels. By using air pump to let air flow in the [8] L.Vaduganathan, B.A. Poonamallie, and M. Nagalingam,
generator, air flowing out was drawn for ozone “Effect of temperature and flow rates of ozone generator on
determination. The maximum and minimum ozone the DBD by varying various electrical parameters,” Am. J.
concentrations were to be 36.0 and 0.20 ppm. To be a Appl. Sci, vol. 9, no. 9, pp. 1496-1502, 2012.
practical generator, computer fan was inserted into the [9] G. Huang, T. Wang, I. Timoshkin, S. MacGregor, M. Given,
generator. The refabricated generator was tested in a model and M. Wilson, Investigation of ozone generation using
room of 96.5x47x47 cm3 size which met the air ventilation dielectric barrier discharges at 50 Hz., 2.6 kHz. and 20kHz,
standard. The gas inside the room was bubbled out at In: Proceedings of the XIX International Conference on Gas
interval of time for each level of ozone production. The Discharges and Their Applications. High Voltage
level 1 was shown to be operated to get limit concentration Engineering, Beijing, pp. 650-653, 2012.
of ozone for indoor air quality (0.10 ppm). The refabricated
generator was also performed in a normal room (4x4x2 m3
size) meeting the standard of air ventilation. In order to

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