Preriopic PROPERTIES Along a Period (—+) Along a Group (|) Max. Z | const] Max. SUMMARY OF PERIODICITY ZX (effective due to screening) ———___________—> c radi ‘Cainer thn stem son ager an seine, ieniemsi) Fe, Co, Ni have same size, also Zr, HE =D, N> Oe mas <1 Th (LP) Tren pas 200 (Electronegativity) (Electron-affinity) __!.es 200, C1>,S> 0,P>N (Hydration and Hydration Energy) (Size of Hydrated ion) (ect (Polarising Power of cation) __s' 0%>¥~ a : (Acidic nature of oxides) a (Basie nature of oxides) (Reactivity) (Reducing Nature)>, VT TSS 3CR (bond length) - ‘Single Bond Covalent Radius, teen 2 @ Forbomodiatomic molecules d, ,=1,+1,9F24, $0, (6) For heterodiatomie molecules in which cletronegativty remains approximately same, Gee ttt, For heteronuclear diatomic molecule, A~B, where difference between the electronegativity values of atom A and atom B i relatively larger, (GanE tt ty 009 Ay ‘This formula was piven by Stevenson & Sehomaker. Elestronegativiy values are given in Pauling units and radius in picometers, Ag=X,—X, where X, and X, are electronegativiy values of high electronegative clement A and less electronegative element B. Later on modified and more accurate formula was proposed by Porterfield as given below; a=, 1, Pauling’s Scale (935): The ENN. difference between two atoms is determined by the expression, a =0208 Es “Eyu%Ena) X,= EN. ofA Pes Fxg X, = EN.ofB E,, | Bond energies of A- A, B-B, A~B molecules. ‘Scale of measurement (2) Mulliken Scale (1934) : According to this scale, EN. ofan atoms the average sum of E, and EA. ofan atom. LPABA. 2 In Pauling Seale LPAEA. EN = 5G 5 (ULE BA ae taken ineV) yee PSEA > = > => _ = > “> => <= __ 1 23 1 <= x = “ ~ ie we =CL || TT EXERCISE - 1 Single Correct Ty Blectronie Configuration 1. Choose the s-block element from the follwing: SS has eee (a) 18%, 2st, 2p®, 38% 3p, 30°, ds! (by 15%, 2s, 2p6, 38%, 3p, 34°, 4s? {c) Is?, 2s, 2p%, 3°, 3p°, 4s! (d) all of the above 2. Pick ont the isoelectronic species from the following: = 1.°CH, IL. H,0° 1. NH, TV. CHy e fa) Land I (b) Hand IV (c) Land IIT (d) U, 1 and IV 9 (©) Ufthere were 10 periods in the periodic table then how many elements would this period can maximum be @ comprise of Ont x = (@)50 () 72 (32 @s ) e S) —_FFeach orbital can hold a maximum of three electrons, the number of elements in * pd of 3 periodic table (long form) are am Worle’ < 7 [ : (a) 48 (b) 162 (50 (75 way Node “a The Z,g for oN “a 3d election of Ce 4s eketron of Cr er ee - 3d electron ofr? 3gelectron of CX" are in the order respectively iL (2) 4.62.95, 4.95, 8.05 (0) 4.93, 295, 4.6, 805 “a (©) 46,295, 5.3, 12.75 (d) none of these “~T 6 Which of the following element has highest metallic character ~~ Element ip Oa @ P ITev - ® Q av @ R low “ @ s Bev oi Nees iae configuration ofan element is 1s? 2? 2p 3°? 3p! The atomic number and the group oF ‘number of the element “X° which is ust below the above element in the periodic table are respectively. —e (4&6 (0) 24815 (934& 16 (34a a fj, Whichofthe flowing ish erie mnbe ofthe eke whose atomic mmr 5 98 NN @4 o7 (@s (6 et). «F Age Which ofthe lowing eve sme mune of eetronsin its ute shall and pettus she _- (art $b) CaP OF (he late po a GO) Accontng to TUPAC sytem of ming elements, the symbol ofelement of atomic nusber Z = 109 i ~t (@anp () uns (©) uno (dies < 11. The screening effect of d electron > (a) less than p-electrons (b) equal to p-electrons a! (c) much more than p electrons (@ equal to f “yt =a a oa 5 a Tals Shinai orasToN tae ‘heh Se IAUUUUUICACTSCSE CE HOC E @ VULEGUTTY + Tees order of size of ions is Cr aS (©) Is?, 28%, 2p%, 382, 3p%, 4s! (d) alll of the above “i> > 36. Arrange following isoelectronic species in decreasing order of their size “OP NY, Ne, F, Mg, Na* (a)N* > 0% > F->Ne> Na’ > Mg (b) N>> 0% > F-> Nat > Mg” > Ne (0)Ne>N*>O*>P>Nar>Mg? —(d) N-> 0 > F-> Mg®* > Na’ > Ne a> 37. The size of the following species increases in the order: “> (@) Mg < Mg” “i 38. Highest size will be of “i> ()Br wr @r @r = =) 39. Element Hg bas two oxidation states Hg! & Hg. the right order of radii ofthese ions (@) Hg"! > Hg’? (b) He?>He* — (c) He"! =Hg? (a) Hg*2 Hg" a =) (4) Tre correct order of increasing atomic size of element NF, Si&eP. “a3 WY (@)NN, N3- (d)S*, 0% As* @) _ iftve ionic radii of K* and Fare about 1.34 A each, the expected valne of atomic radii of K and F should be 9 = = aN = = 4 Ls] (a) 1.34 and 1.34 A (b) 2.31 and 0.64A (c) 0.64 and 2.31 A (4) 2.31 and 1.34 A re = a E 5.) Metallic radius and covalent radius of K and Na are given below Ww Metallic Radi (P..) Covalent Radii (P,,) K : y Na P 4 x is greater than ‘ @y @)p ©aq @ all 46. In erystal of which of the following ionic compound, would you expect the maximum distance between centre of cation and anion, z (a) CsE () Csi (Lit @ LF\ | = — | TS Ionization Energy 47. The correct order of second ionisation potential of C, N, O and P is @C>N>O>F (K)O>N>F>C ()O>F>N>C {d)F>O>N>C 48. Decreasing ionization potential for K, Ca & Ba is beildiny ba rae pl om (a) Ba> K>Ca (b) Ca > Ba > K (c)K > Ba>Ca (d)K>Ca>Ba (49) The ionization energy will be maximum for the process. (@) Ba > Bat (b) Be > Be* (Cs es (Lis Lit 50. Alkaline earth metals always form dipositive ions due to (2) IE, -IE, > 11 eV (b) IE, -1E, =17 eV (c) IE, IE, <11 eV (4) None of these Si, Amongst the following, the incorrect order is (@)IE, (Al) IE, (Na) (4) IE, (Mg)> IE; (Al) 52, The correct order of decreasing first ionization energy is (@C>B>Be>Li (b)C>Be>B>Li (c)B>C>Be>Li (4) Be> LeB-C 53. Which of the following configuration is expected to have maximum difference in second and third ionization energies (@ (sf Gs)? Gp? (b) (13? 2s? 2p)6 Gs? Gpy* (©) Us? Gs? 2p)*Gs? @(s¥ 2s? 2p)! 54, The screening effect of inner electrons causes (a) decrease in ionization energy (b) Increase in ionization energy (c) No efféct on ionization energy (d) Increase in attraction of nucleus to electron 55. Comment on (IE) of Cu, Ag, Au (a)Cu>Ag>Au (bo) CuCu>Ag —_(d) Can't be predicted 56. _ TheIE, ofan element M(g) is 6000 k mot! and ratio of IE, and IE, is 3 :2. IfAH for conversion, °V (eg) > M"(g) is 10,000 kl mot! Find its IE, (a) 2400 kJ mot! (6) 1600.kJ mot! —_(¢) 10,000 kJ mot (@) 4000 ki mot? 57. Which of the following configuration is associated with biggest jump between second and third IE. (@) 1s%2s%2p? (b) 1s?2stop%3s! —(c) 1822%2p83s? (a) 15*28%2p! The five successive ionization energies of an element are 800, 2427, 3658, 25024 and 32824 kJ mot. The number of valence electrons is @3 os 1 @2 n ‘The graph of first ionization enthalpy versus atomic number of as follows Fi Ne ‘Atonie Number “North Delhi: 72, Mall Road, GTB. Nagar, New Delhi - 110009 + South Delhi: 28-B:7, E sxe path - 110016 + Ph: 01141415514, 09136597244, Tol Free: 180-200-4940 a re eee op paPpPppPPrrrsrPATT TASB BsSbELL LE SSSCE 9 | ETE = which of following is correct (2) Alkali metals are at maxima and noble gases at minima i> (b) Noble gases are at maxima and alkali metal at minima a> (©) Transition element are at maxima —-—_(d) None of these ZS ° The ionization of hydrogen atom would give tise to (2) Hydride ion () Hydronium ion (c) Proton (a) Hydroxy ion BS 6. ko any given element, the second ionization potential will be the first ionization potential (@) less than (b) Higher then (¢) Same (a) depends on element = 63. Value of IE, of Be, B and C are in order (a)Be>B>C (b)B>C>Be (C>Be>B (d)Be>C>B (63) The IE, 1B, and TE, of an element is 6 eV, 13 eV and 80 eV Predict element @Li 64. (2) IE, of M@) is 100 eV (b) FF, of M'(g) is 200 eV (©) IE, of M(g) is 200 eV (@) TE, of M(g) is 300 eV 65, Fist and second IE of Mare 7,646 eV and 15.035 eV, The amount of energy in kJ needed to wp _jeomertall atoms of Mg ito Mg ions present in 12 Mg of Mg vapour willbe(1 eV = 96 5k) mol oe fa) 1.094 kt (b) 2118.6 KI (0) 25416 kd (A) 6.589 kl Which configuration represent the atom having highest second ionization energy? ay i> £ (3 Incorrect statement ia the following B [3 3 3 23 (a) 1825%2p* (b) 1s*2s22p%3s!__(c) 1s?2s%2p6 (4) 1s2292ap53s2 67. In which of the following electronic configuration ionisation energy will be maximum in =A (@)[Ne]3s3p! _(B) [Ne] 3s 3p? (€) [Ne]38°3p? (a) [Ar] 34!” 4s? ap =4 Electron Affinity os 68. The process requires absorption of energy is 3 (QF>F @d>cr () 0% (@HoH 3 <§9- Of the following elements, which possess the highest electron affinity? wv) (@As wo @s (@Se 70. Electron affinities of O,F,S and Cl are in the order. Pv (@)OBr>I>F ()CI>FCI>Br>1 @)Cl> F>Brl Correct order of electron affinities is (a) Cl> Na> Si>Ar (b) Cl> Si>Na> Ar (9 Si> Cl> Ar> Na (a) Ar> Si> Cl> Na A*B™ is formed when (a) (IE), + (EA), <(E), + (EA), (b) (IE), +(EA), <(1E), + (EA), (©) (EB), + BA), <(E), + (EA), (@ (IE) + EA) < (IE), *(EA), EN, of element (a) is E, and IP is E,, Hence BA will be E E+E, @-4, (6) 28, G} @57 Ionization energy of element X(g) is I and electron affinity of X(g) is B, then {a)I=E (bo) I=-E (o)1 (@I=-£2 Which of the following is least stable (a) Lit Be Qo @cr ‘Ag/2 atoms of X (g) are converted into X" (g) by energy K,. Ay/2 atoms of X (g) are converted into X"(g) by energy E,, Hence ionisation potential and electron affinity of X (g) are 26 WEF) Eel OAg hy ae ks, The eletro affinity ofthe members of oxygen family ofthe periodic table, follows the sequence (a)O>S>Se — (B)S>O>Se —()OO>S The outermost electronic configuration of most electronegative element is: (2) ns? np (b) ns? np* (c) ns? np (4) ns? np® In the following which configuration of element has maximum electronegativity. (a) 1s?, 2s? 2p (b) 182, 28? 2p*(c) 13%, 25? 2p*(d) 1s?, 25? 2p®, 3823p? On the Pauling’s electronegativity scale, which element is next to F . @ct wo (Br (@Ne The increasing order of acidic nature of 1,0, BeO, B,O, (@) LiO> BeO < B,O, (6) Li,0 B,O, (@ Li,0> Be0> B,0, Bond distance C-P in (CF,) & Si-F in (SiF,) are respective 1.33A & 1.54 A. C-Si bond is 1.87 A. Calculation the covalent radius of F atom ignoring the electronegativity differences. 064A y) HSE A (05A oa 110009 + South Dethi: 28-217, ‘Near IT, Howz Khas, New AVASSELA QOLSOTIAA. Til Free: 1ROO-210-4940_ eh. nrc copy me fed, ae zg 4 » ei » 4 » { » » ce { { PPA ALL orp prPpPpPPPP?) qT doceven ll u Il in 86. Which of the following clement is having highest electronegatii (a) 1s? 2s? 2p! (b) [Ne] 3s? 3p! (c) [He] 2s? 2p* (@) [Ne] 3s? 3p5 Which one is not correct order of electronegativity. (@F>Cl>Br>1 (b) Si> AL> Mg> Na (0) Cl> S>P> Si (@) None of these Calculate the bond length of C-X bond if C —C bond length is 1.54 A and X-X bond length is 1.2 A and electronegativities of C and X are 2.0 and 3.0 respectively. ophte 785 (@)274A (137A (9) 146A (128A a Two elements A & B are such that B. E. of A-A, B-B & A-B are respectively 81 Keal / mole, i WALA 64 Keal / mole, 76 Keal / mole & if electronegativity of B is 2.4 then the electronegativity of Amy {we be approximately, if x, > x, @281 (1.8 (91.99 (4)3.0 90. Which of the following does not reflect the periodicity of element (@) Bonding behaviour () Electronegativity Sv (c) lonisation potential (d) Neutrow/ Proton ratio Calculate bond length of C-X bond, if C-C bond length is 1.54 A, X-X bond length is 1.00 A and electronegativity values of C and X are 2 and 3 respectively 96. Given oxides CO, BeO, Na,O, N,0,, CLO, frame code using P, N, B, A where \Y psamphoteric oxides N=neutraloxide © B=Basic oxide A= Acidic oxide (@)NPBAA (6) NNABA (©) NPAAB (@) NABBA @) Bond distance (C-H) in CH, is x and that of (SiH) in SiH, is y. C-Si bond is Z A. Calculate covalent radii of H atom ignoring the electronegativty difference 3 3 =) 3 3 (a) 1.18 (b) 1.27 (c) 1.36 (4) 0.88, SS G2) Covatent radius oF oxygen is 0.74 5 and its electronegaivty 35. Whats ffective nuclear she ps “3 Se experienced by oxygen ot” a te 2 (@) 520 9) 420 (0)0.655 (3.8 0 _ @)Na,0 (&) MgO (ALO, (@ uo 3 @) Anhydrous AICI, is covalent compound but in aqueous sotution, AICI, become ionic. 3 A,H of AICI, = 4665 kJ / mol AyyiH Of AP* = 5195 KI / mol 2 A,yg Hof Cl’ = -381 ki/mol > What is value of Hydration energy of AICI, (2) 6338 KJ mol (6) +6338 KI mot (¢) 1673 KI mot! (4) - 1673 KI mol! Se Re , (a) HF > HCl> HBr > HI (b) HF > H,0>NH, > (©) H,PO, >H,SO, > HCIO, (O)H,P0,>H,PO, > HPO, > > ) + xty= ee Ceepener Saree Clare wyCAVE | ISS Correct order of bond strength of halogens is (@)F,>Cl,> Br, >1, (by (©) Cl,>Br,>1,>F, (d) Cl, > Br, 99. If P,Q, R, S are clements of 3rd period of p block in modern periodic table, among these one element is metal and rest are non-metals and their order of electronegativity is given as PCI>Br>I (o)CI>F>Br>l CO » » , , | TT f I W 12, Ww 14 tw Which of the following are correct (a) IE,(Mg) Atomic size (Lit) (4) IP of Na —> A’ (g) AH may be negative (b) For A(g) + © — A* (g) AH may be negative (c) For A (g)+¢ —> A® (g) AH must be positive (d) For A? (g) +e” —> A? (g) AH must be negative Which of the following is false (a) Cr?*(g) ion has greater magnetic moment compared to Co*(g). he magnitude of ionization potential of iron anion (monoanion) would be equal to electron ain enthalpy of iron. (©) lanthanide contraction is cause of lower LP. of Pb than Sn. (d) If successive ionization energy are 332, 738, 849, 4080, 4958 (in kJ/mol). Then this element can be of 15th group. Select the correct order (s). (@) IE, of F>1E, of Cl (b) EAof O>EAof S (6) Ionic radius of CI” > Ionic radius of K* (d) None of these yar A «= North Delhi: 72, Mall Road, GTB. Nagar, New Delhi - 110009 + South Defhi: 28-B/7, Jia Sarai, Near TT, Hauz Khas, New 4 “wewwcchemacademty.in ‘Delhi - 110016 « Ph.: 011-41415514, 09136597244, Toll Free: 1800-200-4940 Web:CHEMACADEMY ff 14 Il Periodic Properties 15, The correct statement is *v (a) The second ionization energy of Se is greater than that of second ionization energy of As (6) The first ionization energy of C* ion is greater than that of first ionization energy of N** ion (©) The third ionization energy of F is greater than that of third ionization energy of O (@) Halogens have highest IE in respective period 16, Which of the following represent correct order (a) Be* 1E,(Al) (©) Order of IE, : Cu Cu>Ga 20. Which of the following group represent isoelectronic species? (a) HS, K’, Ar, Cl (b) OH HONE F Jeane! i baat (c) CH,, NHL, OH, HF (d) PA, SiH, HS", Ar yoy? (22) Which of the following statement is incorrect Si/ (a) Bnergy is released when electron is added to an isolated gaseous atom (b) The oxides and hydroxides of alkali metals are strong base (©) Vander Waal’s radius of chlorine is less than that of covalent radius (d) The reactivity of non-metallic elements in periodic table increases from top to bottom, 22, Consider the following reactions %Y @0(@) +e > O(g) AH, (i) F@)+¢ + F@) AH, (ii) Cl(g) +e" Cg) AH, (iv) 01g) + + 07(g) AH, ‘Then according to given information, the correct statement is/are (@) AH, is more negative than AH, and AHL, (b) AH, is less negative than AH, (©) AH, AH, AH, are negative whereas AH, is positive (4) AH, and AH, are negative whereas AH, and AH, are positive - 110009 + South Dethi: 28-B/7, Jia Sarai, Near IT, Hauz Khas, New + 011-41415514, 09136597244, Toll Free: 1800-200.4940 Jeb, PIPIIIADAL LSS, iz 2022 i? D » err prppPpPPPSL26. 27. 28. 29. VVvssyd eo. » co a | REI The sum of IE, and IE,, IE, and IB, for elements P and Q are give + IE, P 882 Q 285 6.11 then according to given information, correct statement is/are (a) P® is more stable than Q” (b) P?* is less stable than Q** (c) P** is more stable than Q** (@) P¥* is less stable than Q"* Consider order 0? < F< Na" < Mg” Then correct statement is/are (@) Increasing order of Zeff (b) Increasing order of size (©) Increasing order of IE (4) Increasing order of EA The value of four quantum number (a, 4m, s) forany electron of element X are 4, 3, 2, correct statement regarding element X is (a) Element X may befong to lanthanide series (b) It may belong to actinide series 1/2, then (©) It may belong 2nd transition series __(d) It may belong 3rd transition series Choose the correct order of the following: (2) N-H>SbH>AsH> PH dipole moment (b) Mg®*(aq) > S12 (aq) > Ba (aq) Hydrated radius order (©) Mg™(aq) > Sr? (aq)> Ba (aq) Tonic mobility order (@) NaP> MgO > $10 : Lattice energy order Which among the following factors is most important in making fluorine, the strongest oxidising halogen: (a) Bond dissociation energy (6) Lonisation Enthalpy (©) Hydration enthalpy (4) Electronegativity ‘The incorrect order of radii is : (a) NLi>Na (d) Fe* > Fe¥* > Fe* Which of the following ionisation energy order is/are correct. (a) Be*> BY (b) +> B® (N* <0* (@F Cl + e~ by the energy released from the proc ESS Cl-+e—> Ch for 6,02 * 10% atoms (1.P. for Cl= 1250 kJ mot" and B.A. = 350 ki foes ° Calculate the lattice energy of NaCl crystal from the following data by the use of Born ea: 2 y the use of Born-Haber cycle, soeeee energy of Na = 26 kcal/g, atom, dissociation energy of Cl, = 54 kcal/mole, aaa ‘energy for Na(g) = 117 keal/ mol, electron affinity for Ci(g) = 84 kcal/g ator i , Wat ene Kg) /g. atom, heat of formation of Caloulate the electron affinity of iodine with the help of the following data (given in Keal/mole), i at ; (AH qui*~ 68.8, (AH sap 25.9, 5 (Bu, +44 gins), =25.5, (IP)yy = 118.4, (U)yg)=— 165.4 imp 2 p> eees2972234123 PRRARBRRSS * North Delhi: 72, Mall Roed, GTB. Nagar, New Delhi - 110009 « South Delhi: 28-BV7. Ji Dati, 1016 «PhzO1-AASSU4 O13659ia4 Bree ge NEE, Haz Khas, Nowe in(13) eee he Pee SEL UUUUUDDLEUAAAARAAN I @Q® s (EEGGLERm) mo cas The lattice enthalpy of solid NaCl is 772 kImo and enthalpy of solution is 2 kImol*. If the hydration enthalpy of Na‘ & Cl ions are in the ratio of 3:2.5, what is the magnitude of enthalpy of hydration (in kJ) of chloride ion? From the following information A>(g) > A® (g) + 3e AH, = 1400 ki/mole A(g) —> A”? (aq) + 2e AH, = 700 ki/mole AH g¢ [A*(g)] =— 350 kJ Amol (IE, +E.) for A(g) = 950 ki/mol Find (a) IE, of A (IE, of A (©) AH;gofA (4) Aye of A (2) oy For ionic compound A®* 2B~ & 2C’ D> abt @ —A\S)+B,(Q@—AB, 6) AH,=-500 Find the lattice energy of AB, (b) Find AH, for according D, (g) + C(s) —+ C, D(s) Given on sublimation of above metal (A,) it dissociates into individual atom. Given : Sublimation energy of A, is 1600; Sublimation energy of Cis 100 Dissociation energy of B, is 200 3 Dissociation energy of D, is 90 A@— At) ; AH=50 ANG) A*(@) ; AH=150 B-(g) > Big) ; AH=260 B-(g) > B* (2) > AH=250 D(g)—> D-(g) . AH=-50 D-(g) —> D* (g) . AH = 100 C@—Cc® ; AH=-150 CD (s) — 2" (g) + D* (g) 5 AH = 1000 All the values are in ki/mol Calculate E.N. of flourine if (Fp),oyan = 0-72 A- Calculate the screening constant of Ca . (atomic number 20) ‘The maximum number of electron that can have principal quantum number n= 3 and spin quantum number, ™, = 2 What is maximum mumber of electrons that may be present in all atomic orbital with principal quantum number 3 and azumuthal quantum number 2 1 ifankston as pin vas ( 03) ‘then what will be maximum number of elements in 6th period? HET = 0, 1, «+1 ve iteges) and one eetrn bs 3 spin values, then munbe of valet clectrons ind shell ofZn are gr 15% Mall Road, GTB, Nagar, New Delhi - 110009oc -IV Previous Year Questions 1T-JAM Previous Year 1, Among the following, th Jectronie pair is (b) 0,” (superoxide anion) and NO’ (a) NO and CO (@ NO" and CO (€) 0,- (superoxide anion) and NO" > Among thu, nitrogen, carbon and oxygen which element has the highest first ionization potential? (lithium (b) nitrogen (0) carbon (a) oxygen Identify the correct option: In the Periodic Table, on moving from left to right among « period, (a) the atomic size of the element increases (0) the first ionization potential of the element decreases (©) the oxide of the element becomes less basic (@) the oxide of the element becomes more basic 4. The decreasing order of the first ionization energy of the following elements is (@)He>H>Be>B (b)Be>B>H>He (@) H>He>Be>B (® B> Be>He>H Q “The degree of hysration is expected to be maximum for (oe (HyNat (Be (ak © _ The decreasing order of the first ionization energy of the following elements is (a) Xe> Be>As>Al (b) Xe> As > Al> Be (-)Xe>As> Be>Al (@ Xe> Be > Al> As Net & Gate Previous year Questions 7. The size of the d orbitals in Si, P, S and Cl follows the order (a)Cl>S>P>si ()Cl> P>S>Si (c)P>S>Si>Cl (d)Si>P>S>Cl 8. The eleetronegativity differences is the highest for the pair pr rrPPPe PPP RP Is sssbessesbd @lic (®) K,F (c) Na, Cl (@) Li F Which of the following pairs has the highest difference in their first ionization energy (a) Xe, Cs (b) Kr, Rb (ALK Maj Ne, Na ay 8 ‘Among the molten alkali metals, the example ofan immiscible pair (n all proportions) is > rare (@KandNa ——_(t)KandCs ligics | @RemiG | ~ . l (The comet ore of decreasing eeoneatity ofthe allowing toms eae « G@)As>AI>Ca>S (D)S>A8>Al>Ca ()AI>Ca>8>As (@S>Ca>AS>Al OW g ° e 12. The correct order of the size of S, S*, S* and $‘* species is (@)S>S*>s¥>s* ()S*>st>st>s ()S*>S>s*>s* (@S*>S*>s>s% 13. The series with correct order of decreasing ionic size is (a) K*> CaP > S> Cr (0) > Cr >K*> Ca (Kt >Cr> Catt > s> (@Cr>Kt>s*> catET IVP-JEE Previous Year Questions Single Choice 14. The correct ordes of second ionization potential of carbon, nitrogen, oxygen and fluorine is ()C>N>O>F (b)O>N>F>C (O>F>N>C (@)F>O>N>C 15, The element with the highest first ionization potential is _ (abboron (6) carbon (©) nitrogen (@) oxygen (ig The hydration energy of Mg”* is larger than that of 5 (ayar (fo) Na (0) Be (4) Mg? 17, The first ionization potential in electron volts of nitrogen and oxygen atoms are respectively given by (a) 14.6, 13.6 (6) 136,146 (913.6, 13.6 (A) 146,146 18. Atomic radii of fluorine and neon in Angstrom units are respectively given by (0.72, 1.60 (b) 1.60, 1.60 (0) 0.72, 0.72 (a) None of these 19. ‘The electronegativty of the following elements increases in the order (@)C,N, $i, P (O)N, Si, C, P ()SiP,.C.N @P.SLNC 20, The first ionization potential of Ne, Mg, Al and Si are in the order W/ (a) NaAl Mg> Al> Si (6) Na Si (@)Na> Mg>Al ()NaNa> Li (b)Be>Mg>Ca (c)B>C>N (d) Ge> Si>C Identify the least stable ion amongst the following (a)Li (b) Be OB @ec ‘One or more than one correct option 30. dy 31 w Sodium sulphate is soluble in water whereas barius sulphate is sparingly soluble because (a) the hydration energy of sodium sulphate is more than its lattice energy (b) the lattice energy of barium sulphate is more than its hydration energy (c) the lattice energy has no role to play in solubility (q) the hydration energy of sodium sulphate is less than its lattice energy Tonic radii of (a) Ti#? Ct fd Pt > PSEEN SOSQUULUU UL CE ET ANSWER KEY EXERCIS le 2d 3.b 4d 5c 6b Le 8b 9.b 10.4 Ma 12.6 a Ie 1S.d l6.¢ Ine 18a Xe 20.4 2b 2b B.a 24.b 25.¢ 26.d 7.4 28.d 29.4 30.¢ 3L.b 32d 33.0 34.d 35.¢ 36.a 37.8 38.¢ 39.4 40. 4Lb Qa 43.6 44.6 43.4 46. 41.0 48.6 49.b 50.¢ She 52.6 53.¢ 54a 55.b 56.0 57.¢ 58.4 59.b 60.6 61.b 62.4 6.8 64.4 65.0 66.6 61.e 68.¢ 69.¢ 70. Ta ae B.d 1. 15.8 76. Tha 78.b 79.6 80. Ble 82. 3.5 84.b 85.0 86.6 87.4 88.4 89.6 90.4 91a 92.b 93.8 94.4 95.6 96.8 97.b 98.4 99.(A)a(B)a 100. a 10l.a EXERCISE - Il ( Lae 2.a,bd 3.a¢ 4.04 Sab 6abd Tab 8. bed 9. a64 10. bd Habe acd — 1.ed 14.6 Is.abc 16.a¢ 17.b¢ 18.ab 19.be 20.64 A.ed 2.abe 23.ad D4acd Sabed 26.ab 2ac 2B.ae 29. bye 30.a,0,4 EXERCISE - III 1.5.919A 2.1.21 3. (a) 4.64 (b) 3.28 4, 1825 ki/mol, 2737.5 ki/mol 5. EN(A)> (B) 6.3.03, 7. 3.8752 8.3.2 9. 1.686 « 10? atoms 10. -185 K cal/mol 11, 73.2 K cal/mol 12. 350 13, (a) 350 kJ/mol (b) 600 ki/mol (c) 450 kI/mol (d) -250 ki/mol 14. (a) -780(b) -420 15.4.1 16.17.15 17.9 18.10 19.48 20.15 EXERCISE - IV Le 2.b 3.0 4a Sa 6.0 1d 8.b 9d 10.¢ lb 126 13.b l4.c 15.¢ 16.b Tha 18.4 19.¢ 20.4 2d 22.6 23.4 24.b 25.d 26.6 27.b 28.b 29.b 30. ab 31d