Professional Documents
Culture Documents
Surname
Forename(s)
Candidate signature
A-level
CHEMISTRY
Paper 1 Inorganic and Physical Chemistry
Table 1
Enthalpy change
/ kJ mol−1
*02* IB/M/Jun17/7405/1
Do not write
3 outside the
box
0 1 . 4 Identify a reagent that could be used to indicate the presence of iodide ions in
an aqueous solution and describe the observation made.
[2 marks]
Reagent
Observation
Turn over ►
*03* IB/M/Jun17/7405/1
Do not write
4 outside the
box
0 2 . 1 The acid dissociation constant, Ka, for ethanoic acid is given by the expression
[CH3COO − ] [H+ ]
Ka =
[CH3 COOH]
A buffer solution with a pH of 3.87 was prepared using ethanoic acid and
sodium ethanoate. In the buffer solution, the concentration of ethanoate ions
was 0.136 mol dm−3
*04* IB/M/Jun17/7405/1
Do not write
5 outside the
box
A 7.00 × 10−3 mol sample of sodium hydroxide was added to 500 cm3 of this
buffer solution.
Calculate the pH of the buffer solution after the sodium hydroxide was added.
Give your answer to two decimal places.
[6 marks]
pH of buffer solution
Turn over ►
*05* IB/M/Jun17/7405/1
Do not write
6 outside the
box
[H2O]
A Kw =
[H+ ][OH− ]
B +
Kw = [H ][H2O]
C + −
Kw = [H ][OH ]
[H+ ][OH− ]
D Kw =
[H2O]
pH of water
*06* IB/M/Jun17/7405/1
Do not write
7 outside the
box
pH of solution
Explanation
Turn over ►
*07* IB/M/Jun17/7405/1
Do not write
8 outside the
box
Table 2
m/z 46 47 48 49
Equation
m/z value
Mass kg
*08* IB/M/Jun17/7405/1
Do not write
9 outside the
box
m
t= d
2E
In this equation d is the length of the flight tube, m is the mass, in kg, of an ion
and E is the kinetic energy of the ions.
Time of flight s
Turn over ►
*09* IB/M/Jun17/7405/1
Do not write
10 outside the
box
Table 3
Use the equation and the data in Table 3 to calculate the Gibbs free-energy
change for this reaction at 989 °C
Give your answer to the appropriate number of significant figures.
Explanation
*10* IB/M/Jun17/7405/1
Do not write
11 outside the
box
Turn over ►
*11* IB/M/Jun17/7405/1
Do not write
12 outside the
box
0 6 . 2 Describe a test you could carry out in a test tube to distinguish between sodium
oxide and the product of the reaction in Question 6.1
[3 marks]
0 6 . 3 State the type of crystal structure shown in silicon dioxide and in sulfur trioxide.
[2 marks]
Silicon dioxide
Sulfur trioxide
0 6 . 4 Explain why silicon dioxide has a higher melting point than sulfur trioxide.
[4 marks]
*12* IB/M/Jun17/7405/1
Do not write
13 outside the
box
0 6 . 5 Write an equation for the reaction of sulfur trioxide with potassium hydroxide
solution.
[1 mark]
13
Turn over ►
*13* IB/M/Jun17/7405/1
Do not write
14 outside the
box
0 7 . 1 State the type of bonding between the oxygen and hydrogen in this compound.
[1 mark]
0 7 . 2 State why the chloride ions in this compound are not considered to be ligands.
[1 mark]
Write an ionic equation for the reaction that occurs when solution A is
converted into solution B and state the colour of solution B.
[2 marks]
Equation
Colour
Identify reagent D and write an ionic equation for the reaction that occurs when
the yellow-green solution is formed from solution A.
[2 marks]
Identity of reagent D
Equation
*14* IB/M/Jun17/7405/1
Do not write
15 outside the
box
Turn over ►
*15* IB/M/Jun17/7405/1
Do not write
16 outside the
box
Reagent
Reagent
*16* IB/M/Jun17/7405/1
Do not write
17 outside the
box
Figure 1 Figure 2
Deduce the optimum conditions for the industrial conversion of methane and
steam into the gaseous products.
Turn over ►
*17* IB/M/Jun17/7405/1
Do not write
18 outside the
box
*18* IB/M/Jun17/7405/1
Do not write
19 outside the
box
20.1 mol of carbon monoxide and 24.2 mol of hydrogen were placed in a
sealed container. An equilibrium was established at 600 K. The equilibrium
mixture contained 2.16 mol of methanol.
Turn over ►
*19* IB/M/Jun17/7405/1
Do not write
20 outside the
box
At equilibrium, the mixture contained 2.76 mol of carbon monoxide, 4.51 mol of
hydrogen and 0.360 mol of methanol. The total pressure was 630 kPa
Calculate a value for the equilibrium constant, Kp, for this reaction at 600 K and
state its units.
[6 marks]
Value of Kp Units
14
*20* IB/M/Jun17/7405/1
Do not write
21 outside the
box
Electrode half-equation Eο / V
Nitrogen in NO3−
Nitrogen in NO
1 0 . 3 Write the conventional representation of the cell that has an EMF of +0.43 V
[2 marks]
Turn over ►
*21* IB/M/Jun17/7405/1
Do not write
22 outside the
box
1 0 . 4 Use data from Table 4 to identify an acid that will oxidise copper.
Calculate the EMF of the cell that has the same overall reaction.
[4 marks]
*22* IB/M/Jun17/7405/1
Do not write
23 outside the
box
In the first titration 25.0 cm3 of the solution were added to an excess of sulfuric
acid in a conical flask. The flask and contents were heated to 60 oC and then
titrated with a 0.0200 mol dm−3 solution of potassium manganate(VII). When
26.50 cm3 of potassium manganate(VII) had been added the solution changed
colour.
In the second titration 25.0 cm3 of the solution were titrated with a
0.100 mol dm−3 solution of sodium hydroxide using phenolphthalein as an
indicator. The indicator changed colour after the addition of 10.45 cm3 of
sodium hydroxide solution.
Turn over ►
*23* IB/M/Jun17/7405/1
Do not write
24 outside the
box
*24* IB/M/Jun17/7405/1
Do not write
25 outside the
box
Suggest why the value of the enthalpy change for this reaction is close to zero.
[2 marks]
1 1 . 3 Draw the displayed formula of the iron complex produced in the reaction in
Question 11.2
Bond angle
Type of isomerism
1 1 . 4 Ethanedioate ions are poisonous because they react with iron ions in the body.
Ethanedioate ions are present in foods such as broccoli and spinach.
Suggest one reason why people who eat these foods do not suffer from
poisoning.
[1 mark]
END OF QUESTIONS
14
Turn over ►
*25* IB/M/Jun17/7405/1
Do not write
26 outside the
box
*26* IB/M/Jun17/7405/1
Do not write
27 outside the
box
*27* IB/M/Jun17/7405/1
Do not write
28 outside the
box
Copyright Information
For confidentiality purposes, from the November 2015 examination series, acknowledgements of third party copyright material will be published in a
separate booklet rather than including them on the examination paper or support materials. This booklet is published after each examination series and is
available for free download from www.aqa.org.uk after the live examination series.
Permission to reproduce all copyright material has been applied for. In some cases, efforts to contact copyright-holders may have been unsuccessful and
AQA will be happy to rectify any omissions of acknowledgements. If you have any queries please contact the Copyright Team, AQA, Stag Hill House,
Guildford, GU2 7XJ.
*28* IB/M/Jun17/7405/1