: AP Chemistry

d:od: Date:
Date: Dr. Mandes
Dr. Mandes

following
ollowing questions
questions represent
represent potential
potential types
types ofof quiz
quiz questions.Please
questions. Pleaseanswer
answereach
eachquestion
questioncompletely
completelyand
and
roughly. The solutions will be posted on-line on Monday.
ughly. The solutions will be posted on-line on Monday.

Please do #18 in chapter 12 of your text.

ease do #18 in chapter 12 of your text.
a. This increases the [H2], which will increase the rate, but has no effect on k
This increases the [H2], which will increase the rate, but has no effect on k
b. Due to Arrhenius 1 equation,
Pada
Due to Arrhenius equation, reaksitemperature
changing
changing A  B, diketahui
temperature changes thekonsentrasi
value of k. senyawa A pada detik 51.1 adalah
changes the value of k.
0.675M. Hasil analisis menunjukan konsentrasi senyawa A padaenergy
detik 61.5
c. Catalyst function by lowering the activation energy, so due to Arrhenius equation, changing the activation energy
Catalyst function by lowering the activation energy, so due to Arrhenius equation, changing the activation
changes the value of k.
changes the value of k. adalah 0.605 M, tentukan kecepata reaksi pada selang waktu tersebut
2 Suatu reaksi berlangsung dengan persamaan reaksi:
Consider the reaction: P + 6 H → 4 PH . A rate study of this reaction was conducted at 298 K. The
Consider the reaction: P4 4+ 6 H2 →2 4 PH3. 3 A rate study of this reaction was conducted at 298 K. The
data that were obtained are shown in the table.
data that were obtainedBerikut
are showniniin data hasil eksperimen penentuan kecepatan reaksi
the table.

[P ], mol/L [H ], mol/L Initial Rate, mol/(L . s)

[P4],4mol/L [H2],2 mol/L Initial Rate, mol/(L . s)
0.0110 0.0075 3.20 x 10-4
0.0110 0.0075 3.20 x 10-4
0.0110 0.0150 6.40 x 10-4
0.0110 0.0150 6.40 x 10-4
0.0220 0.0150 6.39 x 10-4
0.0220 0.0150 6.39 x 10-4
a. What is the order with Tentukanlah:
respect to: P4 __0___.
What is the order with respect to:
a. Orde Preaksi
4 __0___.
terhdap H2
H2 __1___.
b. Orde reaksi
H 2 terhadap P4
__1___.
b. Write the rate law for this reaction. rate = k[H2]
c. Persamaan
Write the rate law for this reaction. rate = k[H kecepatan
2] reaksi
c. Determine the value and d. unitsNilai
of theKrate constant, k. plug and chug using the rate law & da tafrom e
xp’t1and
ingDetermine the kvalue
for k, we get s-1 of the rate constant, k. plug and chug using the rate law & da
and units
= 0.0427 taf r
ome xp’t1and
3
g for k, we get k = 0.0427 s-1

Consider the reaction: SO2 + O3 → SO3 + O2. A rate study of this reaction was conducted at 298 K. The
Consider
data thatthe reaction:
were SOare
obtained 2 + O3 →in the
shown SOtable.
3 + O2. A rate study of this reaction was conducted at 298 K. The
data that were obtained are shown in the table.
dari reaksi diatas, tentukanlah
Initial Rate, mol/(L . s)
[SO2a.
[SO2], Senyawa
[O3intermediet
mol/L [O3], mol/L
], mol/L ], mol/L Initial Rate, mol/(L . s)
b.0.25
Tahap reaksi mana yang menentukan
0.40 0.118 kecepatan reaksi
0.118
4 0.25 0.40
0.118
0.25 0.20
Pada 0.25reaksi diatas hubungan antara
0.20 HI vs Waktu adalah linier, tentukan orde
0.118
0.75 0.20 1.062
reaksi
0.75diatas 0.20 1.062
a. What is the order with respect to: SO2 ___2__.
What is the order with respect to: SO2 ___2__.
O3 ___0__.
O3 ___0__. 2
b. Write the rate law for this reaction. rate = k[SO22] [O03]0
Write the rate law for this reaction. rate = k[SO2] [O3]
c. Determine the value and units of the rate constant, k. plug and chug using the rate law & da tafrom e
xp’t1and
. -1.of-1the rate constant, k. plug and chug using the rate law & da
taf r
ome xp’t1
ingDetermine the kvalue
for k, we get andmol
= 2.36 units
L s and
g for k, we get k = 2.36 mol.L-1. s-1

Consider the following mechanism. A2 + B2 → R + C (slow)

onsider the following mechanism. A2 + B2 → R + C (slow)
A2 + R → C (fast)
A2 + R → C (fast)
a. Write the overall balanced chemical equation. 2 A2 + B2 → 2C
Write the overall balanced chemical equation. 2 A2 + B2 → 2C
b. Identify any intermediates within the mechanism. R
Identify any intermediates within the mechanism. R
c. What is the order with respect to each reactant? A2 1st; B2 1st
What is the order with respect to each reactant? A2 1st; B2 1st