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Sugar is the generic name for sweet, soluble carbohydrates, many of which
are used in food. There are various types of sugar derived from different
sources. Sugar is used in prepared foods (e.g., cookies and cakes) and it is
added to some foods and beverages (e.g., coffee and tea). In the body,
sucrose is hydrolysed into the simple sugars fructose and glucose. Some
other chemical substances, such as glycerol may also have a sweet taste,
but are not classified as sugars. Diet food substitutes for sugar, include
aspartame and sucralose, a chlorinated derivative of sucrose.
Sugars are found in the tissues of most plants and are present in sugarcane
and sugar beet in sufficient concentrations for efficient commercial
extraction. The world production of sugar in 2011 was about 168 million
tonnes. The average person consumes about 24 kilograms (53 lb) of sugar
each year (33.1 kg in developed countries), equivalent to over 260 food
calories per person, per day. Since the latter part of the twentieth century, it
has been questioned whether a diet high in sugars, especially refined
sugars, is good for human health. Over-consumption of sugar has been
implicated in the occurrence of obesity, diabetes, cardiovascular disease,
dementia, and tooth decay. Numerous studies have been undertaken to try
to clarify the position, but with varying results, mainly because of the
difficulty of finding populations for use as controls that do not consume or
are largely free of any sugar consumption.
Chemistry
Scientifically, sugar loosely refers to a number of carbohydrates.
Carbohydrates are most abundant biomolecules on earth. Each year
photosynthesis converts more than 100 billion metric tons of CO2 and H2O
into cellulose and other plant products.
Funtions:
dietary staple (sugar and starch) ,their oxidation is central
energy yielding pathway.
Insoluble carbohydrates polymer act as structure and
protective elements in cell wall of bacteria , plants and in connective
tissues of animals.
lubricant in skeletal joint.
Carbohydrates are polyhydroxy aldehydes or ketones or substance that
yield such compounds on hydrolysis.The names of typical sugars end with
-ose, as in "glucose" and "fructose". Sometimes such words may also refer
to any types of carbohydrates soluble in water. The acyclic mono- and
disaccharides contain either aldehyde groups or ketone groups. These
carbon-oxygen double bonds (C=O) are the reactive centers. All saccharides
with more than one ring in their structure result from two or more
monosaccharides joined by glycosidic bonds with the resultant loss of a
molecule of water (H2O) per bond.
Types:
D-Glucose D-Fructose
Many pentoses and hexoses can form ring structures. In these closed-chain
forms, the aldehyde or ketone group remains non-free, so many of the
reactions typical of these groups cannot occur.
Fructose, galactose, and glucose are all simple sugars hexoses. They have
five hydroxyl groups (−OH) and a carbonyl group (C=O) and are cyclic when
dissolved in water. They each exist as several isomers with dextro- and
laevo-rotatory forms that cause polarized light to diverge to the right or the
left. Assigned by (+) and (-) sign respectively.
In general, galactose does not occur in the free state. It is less sweet than
glucose. It is a component of the antigens found on the surface of red blood
cells that determine blood groups.
Glucose, dextrose or grape sugar, occurs naturally in fruits and plant juices
and is the primary product of photosynthesis. Most ingested carbohydrates
are converted into glucose during digestion and it is the form of sugar that
is transported around the bodies of animals in the bloodstream. Glucose
syrup is a liquid form of glucose that is widely used in the manufacture of
foodstuffs. It can be manufactured from starch by enzymatic hydrolysis..
Glucose in solution exists mostly in the ring form at equilibrium, with less
than 0.1% of the molecules in the open-chain form
trisaccharide-raffinose
Lactose, maltose, and sucrose are all compound sugars, disaccharides, with
the general formula C12H22O11. They are formed by the combination of two
monosaccharide molecules with the exclusion of a molecule of water.
Lactose is the naturally occurring sugar found in milk called as milk sugar. A
molecule of lactose is formed by the combination of a molecule of galactose
with a molecule of glucose. It is broken down when consumed into its
constituent parts by the enzyme lactase during digestion. Children have this
enzyme but some adults no longer form it and they are unable to digest
lactose.
Sugar producing crops- There are two major sugar crops: sugar beets and
sugar cane. However, sugar and syrups are also produced from the sap of
certain species of maple trees like sugar maple (Acer saccharum), from
sweet sorghum (Sorghum saccharatum) when cultivated explicitly for
making syrup and from sugar palm (Arenga saccharifera), palmyra palm
(Borassus flabellifer), toddy palm (Caryota urens), date palm (Phoenix
dactylifera).
List of sugar crops that are major sources of various types of sugar:
Sources of Sucrose
Sources of Fructose
Sources of Galactose
Sources of Mannose
Sources of Maltose
Cultivation-The crop needs a hot and humid climate with high rainfall (200-
225 cm per annum), an average temperature of 26 degree C, a dry sunny
and frost free ripening period. The crop grows on a wide variety of soils,
ranging from sandy soils to heavy loams but clay loams with good drainage
are ideally suited for this crop.
Soaking of seed setts in water for 36-48 h before harvesting result in better
germination. Trenches or furrows are covered with soil after planting and
sprouting begins in about two weeks. On an avegage the crop requires
nitrogen120-250 kg/ha, P2O5 75 kg/ha and K2O 75-135 kg/ha. Frequent
-irrigation in early phase of crop is important. Constant weeding is essential
since sugarcane cannot withstand competition from weeds.
The crop is ready for harvesting after 10-15 months of planting. Harvesting
is usually done by hand by chopping the stem at base with a cane knife but
cutting machines are also used for mechanical harvesting. Withering of
lower leaves is the indication of ripening of crops. Harvested canes is
brought to factories immeadiately for extraction of juice as rapid
deterioration starts as cane loses 1-2% water daily in first week of harvest.
Processing of sugarcane
In sugar mills, canes are first carried to crushers where they are torn into
small pieces and then passed through heavy, grooved steel rollers to squeez
out the juice. Several successive expressions are required to ensure
complete extraction of juice. To facilitate complete recovery, water or thin
juice is sprayed on the blanket of bagasse. The final bagasse left out after
extraction of juice contains unextracted sugar, woody fibre and 45-55% of
water. This is used to manufacture paper or as a fuel.
The plant is a biennial with swollen, rounded or tapering roots and dark red
or yellow-green leaves arising in cluster from a shortened stem. Flowers,
which are produced in the second year of growth, are usually borne in
axillary clusters. They are small, bracteate, bisexual, actinomorphic and
perigynous. The fruit is one seeded utricle.
The crop is propagated by seeds which are sown in rows in early spring, in
carefully prepared seed beds. Seed germinate in about 10 days. Plants are
thinned so that they remain 20-25 cm apart. Thorough weeding and deep
cultivation are necessary. The crop is ready for harvest in 90 days. Mature
beets are pulled from ground and tops are removed to prevent any sugar
utilization.
In beet roots sugar is stored in the enlarged tap root and hypocotyl in the
form of sucrose. Sugar contents of roots vary from 5 to over 20%. The roots
are first thoroughly washed and then cut into thin slices. The sugar is
extracted by diffusion in a series of tanks containing hot water. It is possible
to extract up to 97% of sugar by this process.
Analysis of sugar beet pulp gave (dry basis): cellulose, 22.9; hemicellulose,
49.3; lignin, 1.2; protein, 8.2; fat, 1.0; carbohydrates and pectin, 13.6; and
ash, 3.8%. The pulp being high in hemicellulose and cellulose and low in
lignin, is well suited to enzymatic degradation.
Sugar products-
4. Birch syrup – around 42-54% fructose, 45% glucose, plus a small amount
of sucrose. Savory mineral tasting syrup made from the sap of birch trees
(Betula) and produced in much the same way as maple syrup.
5. Coconut sugar (coco sgar) – 70-79% sucrose and 3-9% glucose and
fructose. Produced from sap of cut flower buds.
6. Corn syrup (glucose syrup) – made from maize starch, made of varying
quantities of maltose and higher oligosaccharides.
7. High fructose corn syrup – roughly 50% glucose and 50% fructose. Made
from corn starch that has been processed by glucose isomerase to convert
some of its glucose into fructose.
8. High maltose corn syrup – mainly maltose, not as sweet as high fructose
corn syrup. It is used as sweetener and preservative.
9. Date sugar- made from dried dates. It does not melt like like granulated
sugar. Healthier alternative of brown sugar.
11. Jaggery – made from date, cane juice, or palm sap, contains 50%
sucrose, up to 20% invert sugars, and a maximum of 20% moisture, with
remainder made of other insoluble matter, such as wood ash, proteins, and
bagasse fibres. Traditional non- centrifugal cane sugar, without separation
of the molasses and crystals.
12. Maple syrup – around 90% sucrose. Made from the xylem sap of sugar
maple, or black maple trees.
13. Palm sugar- produced by tapping the sap from the infloresence of the
tree and boiling it down to produce a syrup, which is then sold as is, or
allowed to crystallize into various shapes and size.
14. Xylose- first sugar isolated from wood. Derived from hemicellulose. It is
classified as a monosaccharide of the aldopentose type.
1. Brown sugars are consists of a minimum 88% sucrose and invert sugar. It
is either an unrefined or partially refined soft sugar consisting of sugar
crystals with some residual molasses content (natural brown sugar) or it is
produced by the addition of molasses to refined white sugar (commercial
brown sugar).
Commercial brown sugar contains from 4.5% molasses (light brown sugar)
to 6.5% molasses (dark brown sugar) based on total volume. Based on total
weight, regular commercial brown sugar contains up to 10% molasses.They
are used in baked goods, confectionery, and toffees.
3. Invert sugars and syrup are mixture of glucose and fructose; obtained by
splitting the diasaccharide sucrose. C12H22O11 (sucrose, Specific rotation =
+66.5o) + H2O (water, no rotation) =C6H12O6 (glucose, Specific rotation =
+52.7o) + C6H12O6 (fructose, Specific rotation = -92o), net : +66.5o converts to
-19.65o (half of the sum of the specefic rotation of fructose and glucose.
Used in breads, cakes, and beverages for adjusting sweetness, aiding
moisture retention and avoiding crystallization of sugars.
10. Sugarloaf was the usual cone-form in which refined sugar was produced
and sold until the late 19th century. This shape is still in use in Germany (for
preparation of Feuerzangenbowle), in Iran and Morocco.
11. Syrups and treacles are dissolved invert sugars heated to develop the
characteristic flavors. (Treacles have added molasses). Treacle is any
uncrystallised syrup made during the refining of sugar They are used in a
range of baked goods and confectionery including toffees and licorice.
Vitamins
Thiamine (B1) 0.008 mg (1%)
Riboflavin (B2) 0.007 mg (1%)
Niacin (B3) 0.082 mg (1%)
Vitamin B6 0.026 mg (2%)
Folate (B9) 1 μg (0%)
Minerals
Calcium 85 mg (9%)
Iron 1.91 mg (15%)
Magnesium 29 mg (8%)
Phosphorus 22 mg (3%)
Potassium 133 mg (3%)
Sodium 39 mg (3%)
Zinc 0.18 mg (2%)
Other constituents
Water 1.77 g
Units
μg = micrograms • mg = milligrams
IU = International units
μg = micrograms • mg = milligrams
IU = International units
Health effect
Studies examining the health impact of sugars are inconclusive. The United
Nations meta-analyses and WHO studies showed contrasting impacts of
sugar in refined and unrefined forms. Other studies indicated variable
results between health effects, particularly on obesity, and whether the
research was funded by the sugar industry or those by independent
sponsors. The 'empty calories' argument is that a diet high in added sugar
will reduce consumption of foods that contain essential nutrients. Various
effects are: