31. 32. 33. 34, 35. For waction Aig = Big) + Cy value of A,G was -16560 J at 1000K when partial pressures cf A, B & Cwere2 atm, 1 aim & 1 atm respectively. The total pressure at cequilioriam is Given: [R= 8 J mor! K+, Inx = 23 log X, log 2 = 0.3] (1) 2atm (2) 4atm (3) 5 atm (4) 10 atm The reaction Alg) + 2B(g) —> 2C(g) + Dla) isan elementary reaction. Inan experiment initial concentration of A.and B are 0.6M and 0.8 M respectively. When [C] = 0.4 M the rate of reaction relative to intial rate L ay 2) oy &l- 9 1 & ig M6 If 200 ral of 0.1 M Na,SO, is mixed with 100 ml of 0.2 M NayPO, solution. Melasity of Na* in the finel solution, if final solution has density 1.2 gil, (2) 0.196 M (2) 0.33 M (3) 05M (4) None of these ‘0.001 mdal solution of a complex [MAg] in water hasthe freezing point of -.0.0054°C. ‘Assuming 100% ionization of the complex salt and K; for HO = 1.86 km-1, write the correct representation for the complex (1) Mag) 2) (MA,IA (3) IMARA, (4) [MAJAs ‘A groph was plotted between the molar conductance of various electrolytes (HCL, KCL and CH,COOH) and root of their concentrations in mole per litre. Molar Conductasce Which of the following is conect match ? (2) 1(CHACOOH); IL (KCN); HI (CH (2) I HCI); II (KC); IH (CH,COOH) (3) 1(CH,COOH); IL (HCD; I (KC (4) I YSCI); II (CHyCOOH); 1M (HC)36. 37. 38. 39, 4. A mixture of 82 gm of O, gas and 8 gm Dy gas ie allowed to effuce through an exifice, the relative rate of effusion | "2 ] at the stait of effusion is (Yon ) (yy 2v2 (2) 4V2 (3) V2 as V2 What isthe degree of dissociation of weak acid HA (C= 0.1 M ) in presence of strong acid HB (C = (.1 M ). Given : K, (weak acid) = 10° (1) 10-5 (2) 10 (3) 104 (4) 108 Which of the following statements is CORRECT ? (1) A metal can show only stoichiometric defects (2), Schottiy defect reduces the density of a solid due to significant increase in volume. (3) Impurity defect always increases the density. (4), Solids having Fcenties have metal excess defect due to missing anions Which of the following statements is inconeet (1), Kelectron capture and beta-emission, both decrease the n/p ratio. (2) The amount of gas adsorbed on a dven adsorbent becomes constant at high pressure because the decreasein entropy Is no longer compensated by the decrease in enthalpy, (3) Ifarsenious sulphide sols subjected to electrophoresis the colloid particles will move towards anode (4), When freshly precipitated Fe(OH), is shaken with aqueous solution of FeCl then (on electrophoresis of colloidal solution the colloids particles moves towards cathode A.g28 (Cyn = 5 R) behaving ideally was allowed to expand reversibly and adiabatically 2 from 1 litre to 32 litre, It's initial temperature was 527° C Molar Enthaply change (AH,,) for the porcess is (1) -1500 R (2) -2100 R (3) 21008 (4) None Which of the following group of hydrated metal halide (MX,) en heating do not suffer hydrolysis (1) Be, Mg (2) Mg, Ca (3) Ca, Sr (4) Be, Ba Which of the follouing statement is INCORRECT : (1), ZnClp used in Deacon process of making Cl from HCL (2) MnO, used as a catalyst to decompose KCIO, to give Op (3) Fe was used formerly in the Haber process for making NH, (4) Pt formetiy used for $O,%$0y in the contact process Which of the following statement is CORRECT. (1) Misch metal is used in Mg based alloy to produce bullet (2) In actinide highest sable oxidation state is +5 shown by Usp (3) Th, Pa first tuo actinides are artificial elements (4) Lanthanide does net form carbide44. 47. 49, 50. 51. Select the CORRECT IUPAC name from the following (1), [(ColH,NCH,CH,NH,),},(S0,)3 > Tri othane-1, 2- ciammine)cobsktll) sulphate (2) K{OsClyN] > Potassium peniachloridonitridocsmato(lV) (8) Feg[Fe(CN)gly > Toni) Hexecyanido ferateltl) 0 (4) Kg(Fe(CN)s0,] > Potassium Pentacyanidosuperoxidoferratel)) Which of the following group of compound is green () CugFACNge (ii) NCly (ii). CuCO,Ca(OH}, {ivi C04 (1) ii, i, iw 2) i, ii, i (3) ii, ii, iv (4) ii Which of the following statement is INCORRECT : (1) Basic unit of Tecto (9D) silicate is SiO, (2), Soro (Pyro) silicate has one shared oxygen/comer atom, (3) The number of comer/O-atom shared pertetrahedton in Phyllo (2D) silicate is 2 (4) Sig0g> and $0, are isostructural In periodic table alscreening effect) on last elactron of A is equals to 2° (2) ef last election of B. Here A and B ate respectively (1) LiendB (2) He and Li (3) LiendHe (4) Oand F 513K Boe Kg + Yaa As) feces) 573K /60-70 Bar Xi + Wolo) By (1: 20 ratio) Xig + 2¥ yg) SBA Cy (5% Inabove reaction A, B and C are respectively (1) XeF, XeF, XeFe (2) XeFs, XeFy, KeFs (3). XeFe, XeF, XeFy (AKeF 2, XeFg, XeF Which of the following order is CORRECT (1), Pry < AsHy < SbH, < NH —> Boiling point (2) HF > HCl > HBr > Hl + Acidic stenath (3) CaF, > BaFy > BeF -> Melting point (4) Cly > Fy > Bry > ly > Bond enerey The process of producing ‘syngas from coal is called (1) Bosch process (2) Water gas shift reaction (8) Coal gasification (4) Heber process The distillation technique most suited for separating glycerol from spent-Iyein the soap industry is (1), Distillation under reduced pressure (2) Simple distillation (3) Fracticnal distilation (4) Steam distillation52. 53. 54. 55. 56. 57. The absolute configuration of CH, cl} HO—+—H COM (1) (2R, 3R) (2) @R, 38) (3) (2S, 3R) (4) (25, 38) Which of the follouing will give a tribrome produet when treated with Br, / HO? OH OH NO, (1) 2) H OH @) 4 a coon Which of the following is an ANTACID (1) Phenelzine (2) Renitidine (8) Peniciin (4) Aspirin 00H @NH.A py Gi) Br: NaOH P wil give (1) Hinsberg test (2) Dye test (3), Catbyl amine reaction (4) All of these Product (Q) in following reaction is: OOH < + SOCL— (P) 4S%9(Q) COOH (1) Malonic acid (3) Nardil you MeMgn 6 eq) Major product of above reaction is : yo oO (3) Ae? (2) Barbituric acid (4) Succinic acid eyo OH oN @58. 59. ° OHA N2Hy + Hy02 J» ¢) > ‘Select correct statement among the following for above reaction sequence (1) ‘D's B, y- unstaturated alcohol (2) ‘C's, B- unsiaturaied cerbongl compound (8) ‘C's. a carbonyl compound with DU (degree of unsatution) = 3 (4) 'D’is carbonyl compound with DU {degree of unsaturation) = 4 gk \ | Reagent used for above conversion is: (1) Pc (2) Zn-HgHcl (3) NyHyKOH (4) NHYH,O, Select the comet statement among following (1) Alanine is an acidic amino acid (2) Ketohexose (fructose) does not change the colour of Bry water (3) Uracil is N-Base of DNA (4), D-Glucose and D-fructose fom different osazone with excess of HjN-NH-Ph