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) “Study demonstrates
desalination with nano porous graphene membrane”
Among the significant recent advancements in the design and development of new
membrane systems is the use of graphenes.
Graphenes have offered a novel class of mechanically robust, ultrathin, high-flux, high
selectivity, and fouling resistant separation membranes that provide opportunities to
advance water desalination technologies.
Membrane-based desalination techniques, mainly reverse osmosis (RO), are currently
considered as more environmentally friendly and energy-efficient than that of thermal
desalination methods such as multistage flash and multiple-effect distillation. However,
these technologies suffer from low desalination capacity and high capital costs.
This has urged the need for developing novel membranes which can reduce the energy
consumption of the RO process by showing high water permeability coupled with high salt
rejection capacity [4]
Recently, nanostructures such as zeolites, metal organic frameworks, ceramics and carbon
based materials have attracted considerable attention as alternative membrane materials to
replace polymeric membranes [4]
Graphene nanosheets display ideal chemical and physical properties in the desalination
process. Despite its negligible thickness, membranes made of graphene exhibit adequate
mechanical strength, capability of functioning under higher pressures that is superior to
conventional polymeric RO membranes currently in circulation [11,17].
Graphene can be defined as one-atom-thick 2D sheets, consisting of sp2 bonded carbon
atoms arranged in a hexagonal, honeycomb lattice.
The most critical characteristic of graphene is its extremely versatile and tunable carbon
backbone, leading to facile functionalization, and incorporation in a variety of applications
[21].
GO membranes can be fabricated from GO nanosheets by different methods including
vacuum filtration, layer-by-layer (LbL) deposition, drop casting, and spin coating [92].
[4] T. Humplik, J. Lee, S.C. O'Hern, B.A. Fellman, M.A. Baig, S.F. Hassan, M.A. Atieh, F. RAhman, T.
Laoui, R. Karnik, E.N. Wang, Nanostructured materials for water desalination, Nanotechnology 22
(2011) 292001.
[11] Q. Lu, R. Huang, Nonlinear mechanics of single-atomic layer graphene sheets, Int. J. Appl.
Mech. 1 (2009) 443–467.
[17] D. Cohen-Tanugi, J.C. Grossman, Water Desalination across Nanoporous Graphene, Nano Lett.
12 (2012) 3602–3608.
[92] B. Mi, Graphene Oxide Membranes for Ionic and Molecular Sieving, Science 343 (2014) 740–
742.
(MARCANO ET AL- 2010 )“Improved Synthesis of Graphene Oxide”
Currently, Hummers’ method is the most common method used for preparing graphene
oxide. We have found that excluding the NaNO3 increasing the amount of KMnO , and
performing the reaction in a 9:1 mixture of H2SO4 and H3PO4 improves the efficiency of the
oxidation process. This improved method provides a greater amount of hydrophilic oxidized
graphene material as compared to Hummers’ method or Hummers’ method with additional
KMnO4
14. Higginbotham, A. L.; Lomeda, J. R.; Morgan, A. B.; Tour, J. M. Graphite Oxide Flame-Retardant
Polymer Nanocomposites. Appl. Mater. Interfaces 2009, 1, 2256–2261.
15. Hummers, W. S.; Offeman, R. E. Preparation of Graphitic Oxide. J. Am. Chem. Soc. 1958,
80,1339.
16. Lerf, A.; He, H.; Forster, M.; Klinowski, J. Structure of Graphite Oxide Revisited. J. Phys. Chem.
B 1998, 102, 4477– 4482.
17. Dreyer, D. R.; Park, S.; Bielawski, C. W.; Ruoff, R. The Chemistry of Graphene Oxide. Chem. Soc.
Rev. 2010, 39,228–240.
(R.K.Joshietal-2015) “Graphene oxide: the new membrane material”
A membrane is considered as a barrier with an ability to allow the passage of certain species
while blocks other depending on characteristics of the membrane and species to be filtered.
Membrane technology is a rapidly growing research area with several real time applications
such as desalination and water purification.
Membranes have been classified in to two types and they are polymeric membranes and
inorganic membranes
Graphene, in general, does not allow anything to pass through. Graphene oxide (GO) is
continuously demonstrating its excellent membrane characteristics and offer huge potential
for real applications.
(Hanaa M. Hegab, Linda Zou -2015) “Graphene oxide-assisted Membranes: Fabrication and
potential Applications in desalination and water purification”
Desalination is one of the most important and promising methods for fresh water
augmentation [3].
The membrane based desalination processes can be categorised according to membrane
pore size and rejection mechanism: membrane distillation (MD), electrodialysis (ED),
microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) [4].
Graphene is a layer of strongly packed pure carbon atoms that are joined together in a
hexagonal honeycomb matrix. More comprehensively, it is a carbon allotrope arranged in
flat sp2bonded atoms with a very small molecule bond length (0.142 nm). Graphite is a
three-dimensional material formed by the arrangement of graphene layers on top of each
other, with tiny (0.335 nm) interplanar gaps [11].
[3] S.J. Kim, S.H. Ko, K.H. Kang, J. Han, Direct seawater desalination by ion concentration
polarization., Nat. Nanotechnol. 5 (2010) 297–301. doi:10.1038/nnano.2010.34.
[4] R.W. Baker, Membrane Technology and Applications, John Wiley & Sons, Ltd, West Sussex,
England, 2004.
[11] D. Cohen-Tanugi, J.C. Grossman, Water desalination across nanoporous graphene., Nano
(Yi You , V. Sahajwalla ,M. Yoshimura ,R. K. Joshi-2015) “Graphene and Graphene Oxide for
Desalination”
However, the graphene oxide membrane with precise control of pore size can be practical
solutions for filtration due the cost effective fabrication .