th-Techstrect Carvato Analytics Mr Lewis Poole KdNE754610240.NBSLMEVELZPTIFBMDONWLNAF.2-2018-01-30 12:30:04 Sofort Download 8 UDC 660: : 669.3 : 621.64: 620.103 £620.194,22 : 620.197 DEUTSCHE NORM ‘Corrosion of metals Probability of corrosion of metallic materials when subject to corrosion from the outside Buried and underwater pipelines and structural components September 1985 Korrosion der Metalle; Korrosionswahrscheinlichkeit metalischer Werkstoffe bel SuSerer Korrosionsbelastung: Rohrleitungen und Bauteile in Baden und Wassern In keeping with current practice in standards published by the International Organization for Standardization (ISO), 2 comma has been used throughout as the decimal marker. 2.2 Cohesion : 23. Structural components Materials Corr Estimating the probability of corrosion ‘of materials in contact with soil... .. 5.1. Unalloyed and lowaalloy ferrous materials 5.1.1. Free corrosion in the absence of extensive concentration cells . Free corrosion in the presence of extensive concentration cells . “Assessment of the effect of anodic and cathodic regions in the absence of impressed current cathodes Anodic corrosion due to cell formation in the presence of impressed current cathodes. 5.2 High-alloy stainless steels 5.3. Hotdip galvanized steels 5.4 Copper and copper alloys 6 Estimating the probability of corrosion of materials in contact with water 6.1. Unalloyed and low-alloy ferrous materials 6.1.1. Free corrosion under water 6.1.2 Corrosion at the water/air interface Contents 613 6.2 High-alloy stainless steels . 6.3 Hotdip galvanized steels 6.4 Copper and copper alloys 7. Stress corrosion eracking : Unalloyed and lowalioy ferrous materials 7.2 Austenitic Cr-Ni steels 7.3 Hotdip galvanized steels 74 Copper and copper alloys 8 Convsion proweton mesures : Unalioyed and lowalloy ferrous materials. 74 at ata B12 813 8.14 82° High- 821 8.22 i Cell formation in the presence of impressed current cathodes Measures against free corrosion in the presence or in the absence of ‘concentration cells Measures against call formation in the presence of impressed current cathodes Meatures against stray currents Measures against stress corrosion cracking loy and stainless steels Measures against pitting and crevice corrosion Measures against stress corrosion eracking 8.3 Hot-dip galvanized steels - 8.4 Copper and copper alloys 84.1 842 843 Measures against free corrosion. Measures against stray currents Measures against stress corrosion erseking Continued on pages 2 to 12 DIN 50920 arto Cngh. (rive group 9 Sales No, 0109)th-Techstrect Carivato Analytics Mr Lewis Poole KdNE754610240.NBSLMEVELZPTIFBMDONWLNAF.2-2018-01-30 12:30:04 Sofort Download 8 Page 2 DIN 50929 Part 3 1 Scope and field of application ‘The specifications given in this standard are intended ‘to serve as a basis for estimating the probability of corrosion of metallic pipelines, vessels and structural ‘components whose external surfaces are in contact with soil or surface water. The probability of corrosion of these items is governed: not only by the properties of the materials and the ‘corrosive agents but also by their design, their size and by external electrochemical effects. Since these param: ‘eters cannot always be described with adequate accuracy, tthe likely corrosion behaviour can only be estimated. Such estimates, besides providing information on the ‘ype and extent of corrosion to be expected, also serve a8 a basis for deciding which protective measures may or must be taken. The present standard is based on the information given in DIN 50929 Part 1 2 Concepts In this standard concepts as defined in DIN 50900 Parts 1 103, DIN 50929 Part 1 and DIN 30676 shall apply. In addition, the following concepts shall apply. 2.1 Elutriable matter Elutriable matter is the clay and sit fraction of a soil composed of particles smaller in size than 0,06 mm, ‘which is separated by elutriation from a given container at a specified flow rate until the overflow water is completely clear. 22 Cohesion For the purposes of this standard, cohesion is a fun« of the proportion of clay to silt, -e. to the content of elutriable matter. The cohesion characterizes the degree 10 which a soil is aerated. 2.3: Structural components For the purposes of this standard, structural components are buried structures, such as sheet piling, mast bases, driven piles and similar structures, 3. Materials “The materials dealt with in the present standard are those specified in DIN 50929 Part 1. If other materials are used, ‘an expertise is required as to whether and to what extent the specifications of the above standard are applicable. 4 Corrosive agents ‘The assessment of corrosive agents shall be made on the basis of investigations of the parameters given in tables 1 ‘and 6 and the ratings specified therein. These ratings shall be used in various ways for the various types of corrosion and materials specified. 5 Estimating the probability of corrosion of materials in contact with soit 5.1. Unalloyed and low.alloy ferrous materials While unalloyed and low-alloy ferrous materials in contact with soil may undergo uniform surface removal 2s a result of corrosion, wide or deep pitting is the rule. LLocatizea corrosion phenomena are generally 10 be ascribed to the formation of corrosion cells or to the action of impressed current cathodes. The soils are classified in soil categories as a function of their corro- sivity. Sea and lake beds cannot be assessed on the basis of the information given below. 5.1.1. Free corrosion in the absence of extensive concentration cells Free corrosion in the absence of concentration cells, in articular aeration calls, is hardly ever encountered, Samples used for field corrosion tests carried out in homogeneous soil to assess soil aggressiveness can reliably similate the conditions of homogeneous free corrosion ‘The removal rates are around 0,01 to 0,1 mm per year ‘and usually decrease with time as coatings are formed, ‘Such conditions are, to a limited extent, also applicable to small-size structures if anv risk due to impressed ‘current cathodes is excluded and the soil is homogeneous. This also includes pipelines the elements of which are not frictionally connected in the axial direction and pipelines provided with high-resistance sheathing exhibit- ing smal defects. To estimate the probability of corrosion, ratings Zy to Z;q given in table 1 shall be used. These ratings are ‘obtained from soil analyses for Z; to Zg, and from information on the local factors for Zg to Zz. A total rating, Bo, shall be calculated from equation (1). This ‘otal rating shall be used in accordance with table 2 to estimate the probability of free corrosion at the sampling point concerned and to classify the soil, but does not allow for any extensive concentration cells that may be present in heterogeneous soils. By=Z,+Z,+Z,+lZytDytletZ,+Zq+Zy (1) ‘There is always an increased probability of corrosion in heavily contaminated soils (soils contaminated by fuel ash, slag, pieces of coal, coke, refuse, rubble, waste water) due to concentration cells and where cells are formed in the presence of impressed current cathodes {see subclouse 5.1.4)DIN 50929Part 3. Page 3 Table 1. Information relating to the assessment of soil No. Parameters investigated/measured Unit [Measurement ranges] Rating a4 2) Assessment ofa soil sample ii Type of soi z a '@) cohesion: proportion of elutriable Percentage <10 i matter by mass >10 to 30 2 $30 to 60 i $50 to 80 a >80 i 1 “Sse i contamination due to fuel ash, slag, z pieces of coal, coke, refuse, rubble, a waste water i ‘Soil resistivity Qem Zs e | |. >50000 +4 & | |>20.000 to 50 000] 42 f 2 5.000 to 20 000] ° i 5 2000 to 5.000) 2 1000 to 2.000 “4 g |< 1000 6 5 Water content Percentage | Z 5 : 3 By inaae <2 0 2 >20 a s DH value 2 : | >9 +2 3 4 | >55 109 ° = 4 055 I : <4 3 é Buffer capacity mmol/kg Zs 5 Acidity up to pH 4,3, | 0 Q {alkalinity Ks.) " & 33 3 s| = —~---______-___ }---=-- 3 Alkalinity up to pH 7.0 a s (acidity Kp 70) 2 8 4 5 +6 3 3 g 10 a Sulfide (S2—) content mgikg % é c <5 ° : 5 to 10 3 a >10 6 i Neutral salt e(Ct= and 2 c(S042-) mmol kg Z, 5 {aqueous extract) contents | a a é 7 | 3% 10 4 § >10 t 30 2 i $30 to 100 3 . >100 4 i ‘Sulfate (S04?) content ‘mmol Teg Zs i 9 | (hydrochloric acid extract) ee "| 2 200 5 4 >5 1010, 2 >10 3 Sofort Download 8