Science League- Chemistry I Exam March 2010 Choose the answer that best completes the statements or questions below and fill in the appropriate response on the form. If you change an answer be sure to completely erase your first choice. You may use the given periodic table and formula sheet as well as a calculator. On the formula sheets is a table of the activity series of the elements. Please PRINT your name, school, area, and which test you are taking onto the scan-tron, 1. A volatile compound with a mass of 0.8822 grams is placed in an evacuated 0.250 L flask. The flask is heated to ‘evaporate the compound. At 99°C, the pressure in the flask is 1.25 atm. What is the molar mass of the compound? a, 86.2 g/mol b. 116 g/mol ©. 229 g/mol 4. 257 g/mol 2. 16.00 g of nitrogen gas is introduced into an evacuated 2.00 L flask at 28°C, what is the pressure inside the flask? a, 0.246 atm b. 1.83 atm ©. 2.65 atm d. 15.8.atm 3. One way in which real gases differ from ideal gases is that the molecules of a real gas a, move in curved paths. ©, occupy no volume, b. have no mass. dare attracted to each other. 4, Use VSEPR theory to predict the shape of the chlorate ion, CIOs. a. trigonal-planar —b. octahedral ¢. trigonal-pyramidal d. bent 5. A binary compound consists of an element with a low ionization potential and a second element with a high electron affinity is likely to have a. covalent bonds b. metallic bonds c, ionic bonds d. coordinate covalent bonds 6. When 0.132 g of magnesium metal was placed in hydrochlorie acid, the following reaction occurred: Mg(s) + 2 HCI(aq) -> MaCl(aq) + H(g) The hydrogen gas produced was collected over water at 20.0°C and a total pressure of 765 mm Hg. The vapor pressure of water at 20.0°C is 17.5 mm Hg, How many cm° of hydrogen was collected? (Assume 100% yield) 2907 266. 133d. 3230, 13,400 \ 7. What are the hybrid orbitals surrounding the central atom in the SOs" ion? asp bsp cpp esp esd ES NJSL Chem I Exam March 2010 28. How many possible resonance structures exist for sulfur tr a. 3 be 4 a 5 d 6 9. What are the bond angles in a phosphat a 90° b. 109.5° e. 120° d. 90° and 120° 10, Based on interparticle attractions only, what would be the descending order of melting temperatures for the following substances? (highest to lowest) 1, SiO,(sand)2.CasHp 3. Po 4, NaCl a1>2>3>4 b,.4>3>2>1 ¢,2>3>4>1 d.1>4>3>2 €.3>2>4>1 11._The volumes, temperatures, and pressures of two gases are given in the data table below. Gas, Volume, Liters ‘Temperature, K Pressure, atm A 2 250 3.0 B 2 500 6.0 What is the ratio of the molecules of gas A the molecules of gas B. ale ina a A di e ail 12. Which expression would give the volume of a certain mass of a known gas at an absolute temperature of T and a pressure of P? m represents mass and M represents molar mass. a. V=mRT MP ov =" oP MRT b.V=MRT mP e. V=mRIP M ©. V=mRT Fe 13. In the following unbalanced reaction, which atom is reduced? H,0 + Cl, + SO, + HCI+H,S0, a. hydrogen b. oxygen c. chlorine 4. sulfur eS rc NJSL Chem I Exam March 201014, Ifa pure substance begins at point A on the phase diagram below and the pressure on the substance is reduced until point B is reached, what process occurs? a. fasion b. vaporization . condensation _—d._ sublimation 15. How many structural isomers exist for CsHi2? al ib) oe) a4 16. fonic compounds are brittle because the strong attractive forces ‘a, allow the layers to shift easily. b. cause the compound to vaporize easily. c. keep the surface dull d. hold the layers in relatively fixed positions. 17. Which of the following statements is NOT true, according to the kinetic theory? a. There is no attraction between particles of a gas. b. Only particles of matter in the gaseous state are in constant motion. ‘c. The particles of a gas collide with each other and with other objects. d. All of the statements are true. 18. What is thought to cause the London dispersion force? a. attraction between ions c. sharing of electron pairs b. motion of electrons 4. differences in electronegativity 19. Which relationship could be used to calculate the volume of 15.0 grams of argon gas at 1.12 atm of pressure and 25°C? a, V= 15.0 x 0.0821 X 25° d, V= 15.0 X 0.0821 X 208 40X 1.12 80.0X 1.12 b. V=150X 831X298 e, V=15.X.0.0821 X 298 40.0 X1.12 40 X 1.12 X 760 ©, V=15.0X 0.0821 X 208 40X 1.12 rsa ner mn RSS Sn NJSL Chem I Exam March 2010 é"20. When the external pressure is 505 kPa, what is the vapor pressure of water at its boiling point? i a. OkPa b, 101.3 kPa c, 505 kPa d. 1010kPa 21, How many sigma(o) and how many pi(r) bonds are there in CH;CCH.? a. 86, 00 d. 20,6m b. 80,20 &. 46,46 c. 60,2 22. In which species does sulfur have the same oxidation number as chlorine in the perchlorate anion? a HS . SO,? b, $05? ©. Se on 23. What type of intermolecular forces are present in liquid acetone? ° I! c ex cH3 HS I. London Dispersion Forces Il, Dipole-dipole interaction II Hydrogen bonding IV. Covalent a. Lonly b. only c, Hlonly —d, Land only e, Ill and IV only 24, Which of the following isotopes has the same number of neutrons as phosphorus-312 a 2p b Bs e 45; 4. 25; 25. What type of bonds must be broken in order to melt a network solid? a. breaking Van der Waals bonds ©. breaking hydrogen bonds . breaking ionic bonds d. breaking covalent bonds oe en ee eg NJSL Chem I Exam March 2010March 2010 Chemistry I Answer Key LEA cane ie PAE ia! TAN Eee Do ae Senne camel aXe =D) ASSES: a} “4D 4B Shae Ow [Saal oe) CHEMISTRY 1 For Honor’s, Enriched or College Prep. Not for AP or Second year: January Test has the following topics: scientific method, measurement, factor label conversions, properties, density, graphing, mixtures, compounds, formulas, mole, weight percent, chemical reactions, using the metal and non-metal activity series for writing chemical reactions, Stoichiometry, atomic structure and history, but not electronic configuration. February Test. Quantum Theory, Electronic structure, orbital notation, dot notation, periodic behavior, plus January topes. March Test. Chemical bonding, molecular structure, simple isomers, intermolecular attractions, redox but not balancing redox equations, kinetic theory, solids, liquids, gases, gas laws, gas Stoichiometry, plus January and February topics. April Test. solutions, reaction rates, chemical equilibrium, entropy, reaction spontancity, Keq, acids, bases, salts, net ionic equations, heat, heat in phase changes, thermo chemistry, AH, Hess's law, plus January, February, and March topics. ‘TESTING DATES FOR THE NEW JERSEY SCIENCE LEAGUE Thursday January 14, 2010, Thursday Feb 11,2010; ‘Thursday March 11,2010; Thursday April, 2010 * The testing date for the April wll be decided by each local area during the January exam. The date of the April exam should bea date that all schools in the area can attend, The April exam must be completed by “April 30", No area may take the April exam during the first weck of April Testing Dates for 2011 ‘Thursday January 13,2011, Thursday Feb 11,2011; *eThursday March 17, 2011; *Thursday April ld, 2011 The April2011 exam can be changed based upon the Schools spring break. **Changed due to HSPA testing. New Jersey Science League PO Box 65 Stewarsvile, NI OBB86-0065 phone # 908-213-8923 fax # 908-213-8924 email njscil@enter.net Web address www.enter.net/~njscil