Adva PI Sol PDF

1 AITS-FT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
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ANSWERS, HINTS & SOLUTIONS

FULL TEST –IV
(Paper-1)
Q.
ALL INDIA TEST SERIES
PHYSICS CHEMISTRY MATHEMATICS

No.
1. C A B
2. C B C
3. C B B
4. D C B
5. B A B
6. A C D
7. D B D
8. B B D
9. A, B, C, D A, B A, C, D
10. A, C A, B A, B, C, D
11. A, C, D A, D A, B
12. A, C A, B, C A, B, D
13. C A B
14. C D B
15. A A C
16. A B B
17. B A C
18. A A A
(A)  (q),(B)  (p, q, s, t), A → (p, q) B → (p, (A)  (p), (B)  (p, r)
1. (C)  (p, q, s, t), (D)  (r, s) q) C → (q) D → (r, t) (C)  (r), (D)  (p, r)
(A)  (q, r), (B)  (s), A → (p, q, s, t) (A)  (q), (B)  (p)
(C) (p, s, t), (D)  (p, q, r, t) B → (p, r, s) (C)  (t), (D)  (r)
2.
C → (q, s)
D → (q, s, t)
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AITS-FT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
2
Physics PART – I
dx  x
1. Particle vel =  x0 2n cos 2  nt  
dt   

max particle vel = x02n putting cos term = 1 wave vel =  n
T
for x02n = 4n
x 
  0
2
1 1 1
2. mv 2  mg sin 60  mv 20  mg  1 sin30
2 3 2
 v0 = 2 m/s
1
4. = = 100
LCeq
 T = 1/50 sec
5. sin C = 2/1
2
2  
1  cos C =  2 
 1 
2

ˆ ˆ 2   2 
1   n.p
 1 
2 2
 4   2  2 3 3 3
1          5 2 = 5
 25   1 1
1
6. En = 3.4 eV En 
n2
 E1  13.6 eV
n=2
nh 2h h
Angular momentum =    2.11 1034 Js
2  2 
2 2 2 2 2 2 v
7. v =  (A  x ) = 3 a   = = 1 rad/sec
3a
x = 2a sin(t + ), v = 2a cos (t + )
At t = 0, x = a & v = +ve
1
= sin 
2
  6
  = n + (1)n 6 = 
5  6
v at  = /6 = + ve and v at  = 5/6 = ve
So,  = /6
x = 2a sin (t + ) = 2a[sin t cos + cost sin]
x = a ( 3 sin t + cos t)
8. For a polytropic process

R
U  1 1
 
Q R R  1
 1
  1 1 x 1 x
For polyatomic gas,  = 4/3
U 1
 
Q 1
1
3 1  x 
This is max at x = 3/2
9. Use the concept of capacitor.
10. Area in (vL-t)graph = LI

1
 2(if  0) =  10  2
2
 if = 5A
13 -15. For long time capacitor gets full charged and charge on each capacitor must be same.
Q Q
  20
2 3
Q = 24 C
 1 1 10 
     50 rad/s
 LC 2  2  10 6 2 
Q(t) = 24 sin t C
Q(t) = (24 sin t) C
 n
500t =  1  n
2
n n 
t=   1
500 1000
Q20 24  103  24  10 6
Emax =  = 144  106 Joule = 0.144 mJ
2C 2  2  106
16. Q = QAB + QBC + QCA

10U0
Q = 5U0 + 3U0 + ln 2.5
3
17. W AB = QAB  UAB = 5U0  (3U0) = 2U0
18. Process AB U = constant

P RT
 and U  t
 M
 P = const
Process BC isochoric
Process CA  isothermal
4
SECTION - B
1 2 2 2
2. I=  6m  36a2  m4a + 2ma = 24a m for p, q, s & t
12
 v 
 v
p  v  0 ˆj , 24ma  = mv02a k̂ + 2mv0a k̂   = 0 k̂
2
9 6a
  
2  v0
q  v  0 , 24ma = 2mv02a k̂ + 2mv0a k̂   = k̂
4a

 v  
s  v  0   ˆj  , 24ma  = mv02a k̂ + 2mv0a( k̂ )   = 0
2
3
 4v 0 ˆ 
tv   j  , 24ma2  = 4mv0a k̂ + 2mv0a( k̂ )   = v 0 k̂
9 12a
  2 2 2   6v
r  v  0 , (18 ma + ma +2m4a )  = 4mv0a k̂ + 2mv0a k̂   = 0 k̂
25a
Chemistry PART – II
SECTION - A
1. Due to non availability of d-orbitals, boron is unable to expand its octet. Therefore it cannot
extend its covalency more than 4.
3. BaCO3 + 2HCl  BaCl2 + H2O + CO2

ZnS + 2HCl  ZnCl2 + H2S

4. 2Ag2CO3 4 Ag + 2CO2 + O2
552 gm Ag2CO3  432 g of Ag
432
 2.76 g Ag2CO3   2.76  2.16g
552
5. NO in iron complex has +1 oxidation number.

Thus, a  5   0   1  1  2   0
 a  1
6. It is called Zinc blend
7. From left to right in a period acidic character increases due to increase in electronegativity.
H
|
8. C3H7 — C — NH2
|
CH3
9. Roult’s law for ideal solutions can be represented in the above two given ways.
11. Hund’s rule.
12. Addition of Br2 in CCl4 is anti addition.
13. In the original compound

Z atoms  form CCP
X atoms  present in tetrahedral void.
 rX 50 
 rZ  200  0.25 
 
Y atoms  present in octahedral void
6
 rY 100 
 rZ  200  0.5 
 
Assuming, all voids are occupied, formula of the original compound = X8Y4Z4.
On removing atoms along one body diagonal,
We lose  2Z atoms, 2X atoms, 1Y atom (body centre)
 The new formula becomes X6 Y3Z3.75
Simplest formula  X8Y4Z5
14. On removing atoms along another body diagonal, we lose

 2Z atoms
2X atoms
 The new formula becomes = X4Y3Z3.5
Simplest formula = X8Y6Z7
16. pH = pKa + log

Base 
Salt 
0.01 500
[Base] =  0.01
500
Let ‘a’ milli moles of (NH4)2SO4
a2
[NH4+] = ;  [Salt] = [NH4 ]
+
500
 0.01 
pH = 9.26 + log  
 2a / 500 
 0.01 500 
8.26 = 9.26 + log  
 2a 
a = 25
Moles of (NH4)2SO4 added = 0.025
17. Solution (I)  CH3 COONa  HCl 

 CH3 COOH  NaCl
1 1 0 0
0 0 1 1
No.of moles 1
  CH3 COOH   1
Volume of solution 1
K
H   C   C a  K a .C  K a
C
1 1
i.e. pH1 =  log K a  pK a
2 2
Solution (II)  CH3 COONa  CH3 COOH

1 1
It is buffer.
 CH3 COONa 
 pH2 = pKa + log  
 CH3 COOH 
1
pH2 = pKa + log
1
pH2 = pKa
pH1 1
 
pH2 2
HA  BOH  


 BA  H2O
18. t0 a 12  0.1 0 0
t  eq (a  1.2) 0 1.2 1.2
Meq of HA = Meq of BOH at end point
A = 26.6 × 0.1 = 2.66
 Meq of HA left = 2.66 – 1.2
Now, pH = pKa + log

Salt
 Acidleft
1.2
5 = – log Ka + log
 2.66  1.2 
Ka = 8.219×10–6
8
Mathematics PART – III
SECTION – A
1. We can assume that OP and OR are x–axis and y–axis respectively. y

2
Let OP = a, then ar(sq. OPQR) = a N
 a a  R Q
coordinates of M and N are  a,  and  , a  respectively
 2 2 
M
a
a 2 x
1 2  3a O P
 ar  OMN 
2 a 8
a
2
8 k
 
3 6
 k = 16
2. Equation of the two circles be (x – r)2 + (y – r)2 = r2 i.e.

x2 + y2 – 2rx – 2ry + r2 = 0 where r = r1 and r2. Condition of orthogonality gives
2r1r2  2r1r2  r12  r22
 4r1r2  r12  r22
Circle passes through (a, b)
 a2 + b2 – 2ra – 2rb + r2 = 0 i.e. r2 – 2r(a + b) + a2 + b2 = 0
r1 + r2 = 2(a + b) and r1r2 = a2 + b2
 4(a2 + b2) = 4(a + b)2 – 2(a2 + b2) i.e. a2 – 4ab + b2 = 0
3. f(x) is a decreasing function and for major axis to be x–axis

f(k2 + 2k + 5) > f(k + 11)
 k2 + 2k + 5 < k + 11
 k  (–3, 2)
4. f(x) = 2 sin2  + 4 cos (x + ) sin x sin  + cos (2x + 2)

= 2 sin2  + cos (2x + 2) + 2 cos (x + ) cos (x – ) – 2 cos2 (x + )
= 2 sin2  + 2 cos2 (x + ) – 1 + 2 cos2 x – 2 sin2  – 2 cos2 (x + )
= cos 2x
 
 f 2  x   f 2   x   cos2 2x  sin2 2x  1
4 
a0 xn1 a1xn a2 xn1 a x2

5. Consider the function f  x      .....  n 1  an x
n 1 n n 1 2
Then f(0) = 0 and f(1) = 0
Hence f(x) = 0 has at least one solution in (0, 1)
6. fog  x   e x  1
2t 2
 I  ex  1dx  t 2
dt (where ex  1  t )
1
= 2t – 2 tan–1 t + C = 2 e x  1  2 tan1  
e x  1  C  2fog  x   2 tan1  fog  x    C
 A + B = 2 + (–2) = 0
2 2 2
 n x  tan1 x  dx  xn x 12  1 2 x
7. Area = 
1
 1 dx  x tan
1
x1   1 x
1
2
dx
5 1 
= n 2  n 5  2 tan1 2   1
2 2 4
8. Let x + y = v
n
9. I  f   4  15 
n
Let g   4  15  , then 0 < g < 1
3
If  n
C0 4n  nC1 4n1 15  n C2 4n215  nC3 4n 3  15   .....
3
g n
C0 4n  nC1 4n1 15  nC2 4n215  nC3 4n3  15   .....
 I  f  g  2  n C0 4n  n C2 4n215  .....  = even integer
 0<f+g<2
f+g=1
n
 1 – f = g thus I is an odd integer 1 – f = g =  4  15 
(I + f)( 1– f) = (I + f) g = 1
1 2 3
10. (A) P(E1) = 1 – P(R R R) = 1     
3 4 5
2 1 2 1
(B) P(E2) = 3P(B R R) = 3    
3 4 5 5
P R R R 
(C) P(E2) = P(R R R/R R R  B B B) =
P R R R   P B B B 
2 3 4 8 0.1 1
But P  B B B       P(E3 )  
3 4 5 20 0.1  0.4 5
2 3
(D) P(E 4 )  1  P B B B   1  
5 5
11. |z – i Re (z)| = |z – lm (z)|

Let z = x + iy, then |x + iy – ix| = |x + iy – y|
i.e. x2 + (y – x)2 = (x – y)2 + y2
i.e. x2 = y2
i.e. y = x
         
12.    1  a1  a2     a2  a3     a3  a4  2a2   a3  a4  o
    
i.e.    1 a1  1      2  a2       1 a3       a 4  o
   
Since a1, a2 , a3 , a 4 are linearly independent
  = 1 = 0, 1 –  +  – 2 = 0,  +  + 1 = 0,  +  = 0
i.e.  = 1,  = 2,  +  + 1 = 0,  +  = 0
2 1 1
i.e.  = 1,    ,    ,  
3 3 3
4
i
13. 1  2 e 3
 13  32
10
 13 12 22  32 12 22

 2 12  122
14. Since i is real

  is purely imaginary

 i
15.   e 2  i

 2 
 1  i      2  1  i
  
16. Equation of the second plane is –x + 2y – 3z + 5 = 0

2(–1) + 3, 2 + (–4)(–3) > 0
 origin lies in obtuse angle (2  1 + 3(–2) – 4  3 + 7)(–1 + 2(–2) – 3  3 + 5)
= (2 – 6 – 12 + 7)(–1 – 4 –9 + 5) > 0
 P lies in obtuse angle
17. 12+21–33<0
 Origin lies in acute angle
Also (2 + 2(–1) – 3(2) + 5)(2  2 – 1 + 3  2 + 1) = (–1)(10) < 0
 P lies in obtuse angle
18. 1–4–9<0
 Origin lies in acute angle
Further (1 + 4 – 6 + 2)(1 – 4 + 6 + 7) > 0
 The point P lies in acute angle
SECTION – B
sinB b2  c 2  a2 b
1. (A) Since cos A  , we have 
2sinC 2bc 2c
or b2 + c2 – a2 = b2 or c2 = a2
Hence c = a and so the ABC is isosceles
(B) cos A (sin B – sin C) + (sin 2B – sin 2C) = 0
or cos A (sin B – sin C) + 2 sin (B – C) cos (B + C) = 0
or cos A (sin B – sin C) – 2 cos A sin (B – C) = 0
 either cos A = 0  A = 90º
or (sin B – sin C) – 2(sin B cos C – cos B sin C) = 0
 a2  b2  c 2 c 2  a2  b2 
  b  C   2 b  c 
 2ab 2ca 
or a(b – c) – 2(b2 – c2) = 0
 (b – c)[a – 2(b + c)] = 0
 b – c = 0 or b = c
 Isosceles
(C) Combine first and thiral and put the value of cos B
2 1 c 2  a2  b2 a2  b2
  b  
ac b 2ca abc
or 4b + c + a – b = 2a + 2b2
2 2 2 2 2
 b2 + c2 + a2
 A = 90º
sin  A  B  k 2  sin2 A  sin2 B 

(D)  by sine formula
sin  A  B  k 2  sin2 A  sin2 B 
sin  A  B  sin  A  B  sin  A  B 
or 
sinC sin2 A  sin2 B
 1 sinC 
or sin  A  B    2 2 
0
 sinC sin A  sin B 
 Either sin (A – B) = 0
 A = B i.e.  is isosceles
2 2 2 2 2 2
or sin A + sin B = sin C or a + b = c
  is right angled
2 2
2. (A) x – (3k – 1)x + 2k – 3k – 2  0
 [x – (k – 2)][x – (2k + 1)]  0
k–2 –1 +1 2k+1 –1 +1 f(1)  0

f(–1)  0
Hence 2k + 1  1 and k – 2  –1
i.e. k  0 and k  1
 k  [0, 1]
  +m=1
(B) 1  a  2 a (AM  GM)
1 b  2 b
1 c  2 c
1 d  2 d
 (1 + a)(1 + b)(1 + c)(1 + d)  16 abcd  16
 Minimum value = 16
2

(C) 5 x 2  5 x
2
 x2  
x
2
x  2x  2
 0
x
 x  12  1
 0
x
 x  (0, )
3
(D) f(x) = x + 3x + 1 and g(x) is inverse of f(x)
f(1) = 5
 g(5) = 1
1 1
 g'  f  x    

f' x   3x  3 
2
1
 g'  f 1  
33
1
 g'  5  
6

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1 AITS-FT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

ANSWERS, HINTS & SOLUTIONS

PHYSICS CHEMISTRY MATHEMATICS

8. For a polytropic process

9. Use the concept of capacitor.

10. Area in (vL-t)graph = LI

16. Q = QAB + QBC + QCA

17. W AB = QAB  UAB = 5U0  (3U0) = 2U0

18. Process AB U = constant

3. BaCO3 + 2HCl  BaCl2 + H2O + CO2

5. NO in iron complex has +1 oxidation number.

6. It is called Zinc blend

11. Hund’s rule.

12. Addition of Br2 in CCl4 is anti addition.

13. In the original compound

14. On removing atoms along another body diagonal, we lose

16. pH = pKa + log

17. Solution (I)  CH3 COONa  HCl 

Solution (II)  CH3 COONa  CH3 COOH

HA  BOH  

Now, pH = pKa + log

Mathematics PART – III

1. We can assume that OP and OR are x–axis and y–axis respectively. y

2. Equation of the two circles be (x – r)2 + (y – r)2 = r2 i.e.

3. f(x) is a decreasing function and for major axis to be x–axis

4. f(x) = 2 sin2  + 4 cos (x + ) sin x sin  + cos (2x + 2)

a0 xn1 a1xn a2 xn1 a x2

11. |z – i Re (z)| = |z – lm (z)|

 13 12 22  32 12 22

14. Since i is real

16. Equation of the second plane is –x + 2y – 3z + 5 = 0

sin  A  B  k 2  sin2 A  sin2 B 

k–2 –1 +1 2k+1 –1 +1 f(1)  0

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