Professional Documents
Culture Documents
1, May 2019
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ISSN 2243-7053
The Official Refereed Journal of the Network of CALABARZON
Educational Institutions
NOCEI Journal, Vol. 3, No. 1, May 2019
INTRODUCTION
Cement is a fine mineral powder manufactured with very precise
processes. Mixed with water, this powder transforms into a paste that
binds and hardens when submerged in water [1].
The scenario in San Isidro National High School was concrete proof
of the difficulties brought by the insufficiency of funds to purchase high-
quality cement due to the existence of the non-concrete passageways
from the entrance of the school to the classrooms. In addition, in spite of
its demand, the manufacturing of cement results in a lot of degrading
problems in the environment. According to Zero-Emission Resource
Organization [2], the production of cement was actually one of the
greatest industrial sources of CO2 in the world.
Republic Act 9003 mentioned by Sapuay [3], otherwise known as the
Ecological Solid Waste Management Act 2000 was signed into the law
by the Philippine Government in 2001. The law encourages the
elimination of environmental waste and hazards in human-related acts
with the infusion of alternative ways to innovate developmental
technologies and strategies to support continuous progress without
compromising the safety of the environment. Similarly, a number of
studies and continuous research was undertaken to minimize the
environmental hazards brought about by the cement manufacturing and
to find an alternative and environmental-friendly component for high-
quality cement production. Williams [4] found that carabao manure is a
nitrogen-rich material with sodium, sulfur, potassium, phosphorous
which is comparatively similar to the components of cement being used
in constructions with calcium, sodium, sulfur trioxide, potassium oxide,
and calcium oxide. Anchoring on the findings of Williams [4], carabao
manure is perceived to offer significant components for a
groundbreaking innovation on alternative yet environmental cement.
This study which generally focused on analyzing the components of
carabao manure ash as alternative cement sought to develop a booklet
entitled “Waste to Ways: A Guide to Carabao Manure Ash Cement
Production” which features the comprehensive process making of
carabao manure ash as alternative cement.
Research Design
The researcher used the feasibility study method of research intended
to set reliable information regarding the chemical composition and
properties of carabao manure ash as cement.
Research Locale
This feasibility study was conducted in the Municipality of General
Luna, Quezon Province, Region IV-A CALABARZON. Among the 18
rural areas and 1 urban area in General Luna, the site of Brgy. Bacong
Ilaya was the main locale of the study because of the big number of
carabaos in the locality.
Research Population and Sample
The researcher used a purposive sampling technique in choosing the
carabao subjects. With the provision from the municipal agricultural
head, the researcher with the help of the carabao owner retrieved sample
manures from the 20 carabaos chosen from Brgy. Bacong Ilaya, General
Luna, Quezon. Moreover, the researcher rest assured that there was no
carabao was harmed during the collection of carabao manure.
Research Instrument
This study used the Department of Science and Technology –
Industrial Technology Developmental Institute (DOST-ITDI) forms and
test reports. Data on chemical testing were delivered using ITDI -
052018-ICS-0091 report format while information on the
physical/mechanical tests was gathered using ITDI – 062018-PPT-0264
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ISSN 2243-7053
The Official Refereed Journal of the Network of CALABARZON
Educational Institutions
NOCEI Journal, Vol. 3, No. 1, May 2019
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ISSN 2243-7053
The Official Refereed Journal of the Network of CALABARZON
Educational Institutions
NOCEI Journal, Vol. 3, No. 1, May 2019
used the analysis of data from the DOST-ITDI test reports for the
developed carabao manure ash and its concrete block following the
researchers’ procedure and formulated ratio and interpreted from the
ASTM standards of chemical composition, physical/mechanical test in
terms of flexural and compressive strength.
Oxide, and Sulfur Trioxide. The data showed the difference between the
ASTM standards and actual chemical test results from the DOST-ITD.
Based on the data, the sample Carabao Manure Ash passed the level of
Loss on Ignition, Magnesium Oxide, and Sodium Oxide. Furthermore,
the ash exceeded the maximum standard level of Silicon Dioxide,
Aluminum Oxide, Ferric Oxide, and Potassium Oxide. Yet, the carabao
manure ash failed to reach the minimum level of Calcium Oxide and
Sulfur Trioxide. This implies that though all the chemical elements
required for a standard cement are present in the developed carabao
manure ash, the developed carabao manure ash still needs further
development to reach the ASTM standard values. Excess and deficit of
chemical components in cement are not acceptable because it may bring
unwanted effects on the concrete to be developed.
The data further showed that there was a significant deficit of 49.80
percent Calcium Oxide which failed to reach the minimum 60 percent
limit in the amount of Calcium Oxide on the tested sample. According
to Babylon [5], Calcium Oxide is an important ingredient of cement and
its proportion is to be carefully maintained. He added that if the Calcium
Oxide is in deficiency, the strength of cement decreases and it causes the
cement to set quickly. In addition, lime can be added together with
powdered shells or gypsum to compensate for the deficiency. Lime and
shells are natural sources of calcium oxide which can enhance the
chemical composition of the carabao manure ash.
Similarly, there was also a 0.81 % deficiency of Sulfur Trioxide in
the sample carabao manure ash. A very small amount of sulfur is useful
in making sound cement. If it is in excess, it causes the cement to become
unsound. Gypsum, lime, and chalks are a good source of sulfur trioxide
[6]. Thus, its addition will not only increase the amount of calcium oxide
in the carabao manure ash but also the amount of sulfur trioxide. Thus,
its addition will not only increase the amount of calcium oxide in the
carabao manure ash but also the amount of sulfur trioxide.
However, data also showed that there was excess in Silicon Dioxide
Aluminum Oxide, Ferric Oxide, and Potassium Oxide. Silicon Dioxide
is an ingredient of cement which gives or imparts strength to the cement
due to the formation of dicalcium and tricalcium silicates. ASTM
requires 17 – 25 percent only, yet the sample revealed an excess of 18.3
percent. If silica is present in excess quantity, the strength of cement
increases but at the same time, and the setting time is prolonged [5]. If
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The Official Refereed Journal of the Network of CALABARZON
Educational Institutions
NOCEI Journal, Vol. 3, No. 1, May 2019
Flexural
4.01
529
152
148
0.3
0.6
Passed
Strength
Since the ASTM standard for flexural stress is 0.3 to 0.6 MPa, the
tested samples passed the standard for flexural acceptability. This
implies that the feasibility of carabao manure ash as an alternative
cement in terms of flexural strength attained the ASTM standard. Yet it
has to meet the further compressive testing required to pass the required
value for cement production.
The result of this study is similar to the work of Thej Kumar [12] who
used Cow Dung Ash as supplementary cementing material in
strengthening cement mortar and concrete. His study focuses only on the
consistency limits, compressive and flexural strength of cement which
resulted in 0.6 MPa average flexural strength. Unlike with the present
study, the researcher determined if pure carabao manure ash with bark
extract of Pili Tree can be an alternative cement. The present study
focused on the two (2) required tests on cement namely chemical test and
physical/mechanical test where the flexural strength of the sample
concreted reached an average of 0.542 MPa which is near to the 0.6 MPa
of Cow Dung Ash as supplementary cementing material.
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Educational Institutions
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The Official Refereed Journal of the Network of CALABARZON
Educational Institutions
NOCEI Journal, Vol. 3, No. 1, May 2019
reduced with the use of Calcium Chloride in the form of powdered rock
salt in order to meet the ASTM standards. The carabao manure ash also
failed to reach the minimum level of Calcium Oxide and Sulfur Trioxide
as required by the ASTM. Thus, the addition of lime or powdered shell
can be used to meet the standard value.
The carabao manure ash cement passed the ASTM flexural strength
test but failed to reach the ASTM compressive strength standards. To
increase the concrete’s compressive strength, the addition of lime,
gypsum or powdered shells which are a good source of both calcium
oxide and sulfur trioxide can be considered.
A carabao manure ash cement procedural method was developed
through a booklet entitled "Waste to Ways: A Guide to Carabao Manure
Ash Cement Production” even if it failed to meet the purpose of the study
to develop a carabao manure ash as an alternative to commercial cement
for the benefit of the people of General Luna, Quezon.
Based on all the procedure undertaken, data gathered and revealed
findings, the following are recommended:
For Farmers to use the booklet in coordination with the Non-
Government Organizations and Local Government Unit for further
action and research regarding the Feasibility of carabao manure as a
potential alternative cement.
For Science Teachers and Principal to orient the students on the
importance of carabao manure ash as an alternative cement using the
booklet on procedural method and may conduct further studies on
carabao manure as innovative and alternative cement material.
For students to use the study to innovate ideas and conduct inquiry
investigations using carabao manure and other alternative materials for
cement production to compensate with the excess and deficiencies of the
results of the study and meet the ASTM standards.
For Agricultural Community to consider the use of non-hazardous
materials and chemicals for the construction of their homes and
passageways.
For Head of DPWH- Engineering Office to use the result of the study
to invest time and research on alternative cement-like carabao manure in
developing projects aside from commercial cement.
And for future researchers to use the present study as a guide and
reference on their conduct of extended studies on the cement from animal
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ISSN 2243-7053
The Official Refereed Journal of the Network of CALABARZON
Educational Institutions
NOCEI Journal, Vol. 3, No. 1, May 2019
REFERENCES
[1] Ameen, N. (2014). GeekInterview. A venture from Exforsys.com.
Retrieved from www. Greekinterview.com/question_details/89195
[2] Zero Emission Resource Organization (2015). Why CCS? Industrial
Emissions ZeroCO2. Retrieved from www. zeroCO2.no/introduction
[3] Sapuay, G. (2018). Ecological Solid Waste Management Act of 2000
(RA 9003): A Major Step to Better Solid Waste Management in the
Philippines. Unpublished Thesis.
[4] Williams (2014). Fact Sheet: Food for the Soil. Retrieved from
http://www.abc.net.au/gardening/stories/s3980103.htm
[5] Babylon, F. (2013). Chemical Testing in Cement Based on ASTM
Standards. Retrieved from http://www.uobabylon.edu.iq/eprints
publication
[6] Zayed (2018). Effect Of Sulfur Trioxide Content On Concrete Structures
Using Florida Materials. Published Thesis. The National Academies of
Sciences, Engineering, and Medicine. 500 Fifth Street, NW |
Washington, DC 20001 | Τ: 202.334.2000. Copyright © 2018 National
Academy of Sciences. Retrieved from https://trid.trb.org/view/755078
[7] Enger (2015). Reduction of Silicon Dioxide by Means of CarbonI in
Electric Furnace. Published Master’s Thesis. Retrieved from
https://patents.google.com/patent/US3887359
[8] Constructor (2018). The chief chemical constituents of Portland cement.
Retrieved from https://theconstructor.org/building/composition-of-
portland-cement/5725.
[9] Balomenos (2011). Carbothermic Reduction of Alumina: A Review of
Developed Processes and Novel Concepts. Published Master’s Thesis.
European Metallurgical Conference (EMC-2011) European
Metallurgical Conference (EMC-2011), Volume: Volume 3, pp.729-743
[10] Nokhrina (2015). Reducing Ferric Oxide by means of coal and carbon.
Published Thesis. Retrieved from https//www.quora.com
[11] ACS (2018) Reduction of Alkalies in Portland Cement. Use of Calcium
Chloride. Published Master’s Thesis. DOI: 10.1021/ie50482a034
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