A 12

ln γ 1 =
x 1 A12
(
( 1+
x 2 A21
)2
)
T(ªC) = 75 A 12 A 21
x 1 A 12 x2 A
T(K) = 348.15

γ1 =e
( ( 1+
x 2 A 21
)2
) γ2 =e
(
( 1+
x1 A

Parámetros de Van Laar: Cálculo del coeficiente de actividad:

T x1 x2 A 12= A 21 =
A 12= 0.7564 348.15 0.001 0.999 0.7564 0.4508
348.15 0.1 0.9 0.7564 0.4508
A 21 = 0.4508 348.15 0.2 0.8 0.7564 0.4508
348.15 0.3 0.7 0.7564 0.4508
348.15 0.4 0.6 0.7564 0.4508
348.15 0.5 0.5 0.7564 0.4508
348.15 0.6 0.4 0.7564 0.4508
348.15 0.7 0.3 0.7564 0.4508
348.15 0.8 0.2 0.7564 0.4508
348.15 0.9 0.1 0.7564 0.4508
348.15 0.999 0.001 0.7564 0.4508

CALCULO DE LAS PRESIONES DE VAPOR:

n-propyl alcohol benceno

VP_A= -8.05594 VP_A= -6.98273 A 12=
VP_B= 0.0425183 VP_B= 1.33213
VP_C= -7.51296 VP_C= -2.62863 A 21 =
VP_D= 6.89004 VP_D= -3.33394
Pc= 51.7 Pc= 48.9
Tc= 536.8 Tc= 562.2
T= 348.15 T= 348.15
x= 0.35143443 x= 0.380736393

DIAGONAL
 0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

n-propyl alcohol(1)-benceno(2)

1
0.9
0.8
0.7
Y1

0.6
VAN LAAR
0.5
0.4 DIAGONAL
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 A 21
ln γ 2 =
x 2 A 21
(
( 1+
x 1 A12
)2
)
A 21
x 2 A 21

γ2 =e
( ( 1+
x 1 A 12
)2
)

γ 1= γ 2= Pvp1 Pvp2 P y1 y2
2.1251991383 1.00000127 0.41111217 0.861861947 0.86187487 0.00101371 0.99898629
1.7114805067 1.011193511 0.41111217 0.861861947 0.85471933 0.08232064 0.91767936
1.4555745924 1.04015313 0.41111217 0.861861947 0.83685561 0.14301259 0.85698741
1.2916826749 1.0820735 0.41111217 0.861861947 0.81212652 0.19616148 0.80383852
1.1835521314 1.1339097 0.41111217 0.861861947 0.78099325 0.24920711 0.75079289
1.1112413857 1.19360931 0.41111217 0.861861947 0.74278565 0.30752133 0.69247867
1.0630651219 1.25971171 0.41111217 0.861861947 0.69650244 0.37648598 0.62351402
1.0318054095 1.33112708 0.41111217 0.861861947 0.64110577 0.46315514 0.53684486
1.0128004347 1.40700873 0.41111217 0.861861947 0.57562912 0.57867063 0.42132937
1.0029219398 1.4866762 0.41111217 0.861861947 0.49921304 0.7433341 0.2566659
1.0000002689 1.56872409 0.41111217 0.861861947 0.41205319 0.99671881 0.00328119

T x1exp x2exp P y1exp y2exp

A 12= 0.7564 348.15 0.0376 0.9624 0.90447235 0.0763 0.9237
348.15 0.042 0.958 0.93727498 0.1435 0.8565
A 21 = 0.4508 348.15 0.0984 0.9016 0.94167533 0.149 0.851
348.15 0.2048 0.7952 0.95287622 0.2085 0.7915
348.15 0.2344 0.7656 0.94780915 0.2145 0.7855
348.15 0.3092 0.6908 0.94447555 0.242 0.758
348.15 0.4172 0.5828 0.93060778 0.2797 0.7203
348.15 0.539 0.461 0.88540416 0.3185 0.6815
348.15 0.634 0.366 0.84606768 0.3494 0.6506
348.15 0.744 0.256 0.77379523 0.4225 0.5775
 348.15 0.8395 0.1605 0.67498733 0.5265 0.4735
348.15 0.919 0.081 0.55028402 0.6808 0.3192
348.15 0.9495 0.0505 0.5088407 0.7695 0.2305

n-propyl alcohol - benceno (2)

1.2

0.8
Xvs P
P

0.6 Y vs P
Xexp
vs P
0.4 Yexp vs
P
0.2

-1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
y1+y2
1
1
1
1
1
1
1
1
1
1
1

y1+y2
1
1
1
1
1
1
1
1
1
1
1
1
1
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

A 12
ln γ 1 =
x 1 A12
(
( 1+
x 2 A21
)2
)
A 12 A 21
x 1 A 12 x2 A
P (bar) = 1

γ1 =e
( ( 1+
x 2 A 21 )
)2
γ2 =e
(
( 1+
x1 A

Parámetros de Van Laar: Cálculo del coeficiente de actividad:

Presion T x1 x2
A 12= 0.4262 1 337.28919811 0.001 0.999
1 319.06087378 0.1 0.9
A 21 = 0.4394 1 315.78861416 0.2 0.8
1 316.72617751 0.3 0.7
1 317.798954 0.4 0.6
1 318.89576444 0.5 0.5
1 320.08586279 0.6 0.4
1 321.31201156 0.7 0.3
1 322.62896764 0.8 0.2
1 324.06351782 0.9 0.1
1 325.63308599 0.999 0.001

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6

VP_A VP_B VP_C VP_D Pc Tc x

-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.334472774
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3704402648
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3768969729
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3750470057
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3729302407
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3707660528
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3684177925
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3659983986
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3633998271
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3605692229
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.357472206
oseph Christian Cruz Huanca

A 21
ln γ 2 =
x 2 A 21
(
( 1+
x 1 A12
)2
)
A 21
x 2 A 21

γ2 =e
( ( 1+
x 1 A 12
)2
)

A 12= A 21 = γ 1= γ 2= Pvp1 Pvp2 y1

0.4262 0.4394 1.5301619555 1.0000004134 1.2935408355 0.9990652929 0.001979327
0.4262 0.4394 1.4152490808 1.0041675757 0.6794396654 0.9990652929 0.0961576362
0.4262 0.4394 1.3179473171 1.0168772057 0.7132160943 0.9990652929 0.1879962476
0.4262 0.4394 1.2369562461 1.0386122857 0.7372430262 0.9990652929 0.2735812098
0.4262 0.4394 1.1702143547 1.0701107791 0.7655267257 0.9990652929 0.3583321453
0.4262 0.4394 1.1160821301 1.1124059832 0.7953361709 0.9990652929 0.4438302439
0.4262 0.4394 1.0732789072 1.1668832517 0.8287245806 0.9990652929 0.5336715674
0.4262 0.4394 1.0408353245 1.2353571095 0.8642871545 0.9990652929 0.6297064207
0.4262 0.4394 1.0180590646 1.3201749243 0.9038304916 0.9990652929 0.7361222598
0.4262 0.4394 1.0045123074 1.4243556995 0.9485337825 0.9990652929 0.8575324726
0.4262 0.4394 1.000000453 1.5503713415 0.9994450747 0.9990652929 0.9984460819

METIL ACETATO (1) - METANOL (2) METIL ACETATO (1) - METANOL

1 340
0.9
335
0.8
0.7 330
0.6 325
T
y

VAN
0.5 LAAR
0.4 320
0.3 315
0.2
310
0.1
0 305
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 -0.8 0.2
x X-Y

VP_A VP_B VP_C VP_D Pc Tc

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
 DIAGONAL:
0 1
0.2 1.2
0.4 1.4
0.6 1.6
0.8 1.8
1 2

y2 y1+y2
0.9980666403 1.0000459672
0.9029060759 0.9990637121
0.8127413787 1.0007376263
0.7263490412 0.999930251
0.6414663234 0.9997984687
0.5556831047 0.9995133486
0.4663170231 0.9999885905
0.3702607237 0.9999671444
0.2637881895 0.9999104493
0.1423024344 0.9998349071
0.0015489222 0.9999950041

METIL ACETATO (1) - METANOL (2)

340

335

330

325 X vs
T
320

315

310

305
0.2 1.2
X-Y

x
 0.342003125
0.3775636485
0.3839472997
0.3821182647
0.3800254506
0.3778857502
0.3755640601
0.3731720414
0.3706028723
0.3678042961
0.3647423215
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

[
ln γ 1 =−ln ( x 1 + Λ12 x 2 ) +x 2
Λ12
−
Λ21
x 1 + Λ12 x 2 Λ 21 x 1 +x 2 ]
Volúmenes:

v 1=

v 2=
79.84

40.73
ln γ 2 =−ln ( x 2 + Λ21 x1 )−x 1
[ Λ12
−
Λ 21
x 1 + Λ12 x 2 Λ21 x 1 +x 2 ]
Parámetros de Wilson:
v2 λ 12
λ12 = -31.19 Λ 12 =
v1
exp −
RT ( )
λ21 = 813.18

Isoterma a la temperatura de: R T (K) x1 x2

1.987 333.15 0.001 0.999
T ( ºC )= 60 1.987 333.15 0.1 0.9
1.987 333.15 0.2 0.8
T ( K )= 333.15 1.987 333.15 0.3 0.7
1.987 333.15 0.4 0.6
La contante sera: 1.987 333.15 0.5 0.5
1.987 333.15 0.6 0.4
R= 1.987 1.987 333.15 0.7 0.3
1.987 333.15 0.8 0.2
1.987 333.15 0.9 0.1
1.987 333.15 0.999 0.001

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6
T= 333.15 T= 333.15
x= 0.3426400947 x= 0.3500780336
oseph Christian Cruz Huanca

Λ12
−
Λ21
x 1 + Λ12 x 2 Λ 21 x 1 +x 2 ] [
γ 1 =exp −ln ( x 1 + Λ 12 x 2 ) + x 2
[ Λ12
x 1 + Λ 12 x 2
−
Λ 21
Λ21 x 1 + x 2 ]]
Λ12
−
Λ 21
x 1 + Λ12 x 2 Λ21 x 1 +x 2 ] [
γ 2 =exp −ln ( x 2 + Λ 21 x 1 ) −x 1
[ Λ 12
−
Λ21
x1 + Λ12 x2 Λ21 x 1 + x2 ]]
λ 12
(
p −
RT ) Λ 21 =
v1
v2
exp −
λ 21
RT ( )
v 1= v 2= λ12 = λ21 = Λ12= Λ21= γ 1=
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 2.8567143434
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 2.2956641456
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.906163501
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.6299745532
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.4295410903
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.2822109231
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.1738971103
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.095743458
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.0423238581
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.0106956337
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.0000010992

Metil Acetato (1) - Metanól(2)

0.8
Y1

0.6 WILSON
DIAGONAL
0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 0.8

Y1
0.6 WILSON
DIAGONAL
0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

Λ12
1 + Λ 12 x 2
−
Λ 21
Λ21 x 1 + x 2 ]]
Λ 12
−
Λ21
x1 + Λ12 x2 Λ21 x 1 + x2 ]]

γ 2= Pvp1 Pvp2 P y1 y2 y1+y2

1.0000012047 1.1259658997 0.8465407651 0.8489118061 0.0037890425 0.9962109575 1
1.01155895 1.1259658997 0.8465407651 1.0291772532 0.2511559148 0.7488440852 1
1.0451788234 1.1259658997 0.8465407651 1.1370842049 0.3775050418 0.6224949582 1
1.1010581848 1.1259658997 0.8465407651 1.203052176 0.4576598923 0.5423401077 1
1.1815825888 1.1259658997 0.8465407651 1.2440005052 0.5175607287 0.4824392713 1
1.2914994371 1.1259658997 0.8465407651 1.2685163487 0.5690607682 0.4309392318 1
1.4385933611 1.1259658997 0.8465407651 1.2801920394 0.6194858624 0.3805141376 1
1.6350315231 1.1259658997 0.8465407651 1.2788750889 0.6753113306 0.3246886694 1
1.8998036952 1.1259658997 0.8465407651 1.2605491513 0.7448316439 0.2551683561 1
2.2631521808 1.1259658997 0.8465407651 1.2157929945 0.8424196728 0.1575803272 1
2.7687936963 1.1259658997 0.8465407651 1.1271850669 0.9979205751 0.0020794249 1

Metil Acetato (1) - Metanól (2)

1.4
1.2
1
WILSON
P

0.8 X1 vs
DIAGONAL P
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
 1.2
1
WILSON

P
0.8 X1 vs
DIAGONAL P
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
X1 vs
P
X1 vs
P
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

[ Λ12 Λ21
]
Presión(bar)= 1

ln γ 1 =−ln ( x 1 + Λ12 x 2 ) +x 2 −
x 1 + Λ12 x 2 Λ 21 x 1 +x 2
Volúmenes:

v 1=

v 2=
79.84

40.73
ln γ 2 =−ln ( x 2 + Λ21 x1 )−x 1
[Λ12
−
Λ 21
x 1 + Λ12 x 2 Λ21 x 1 +x 2 ]
Parámetros de Wilson:
v2 λ
λ12 =

λ21 =
-31.19 Λ 12 =
v1
exp − 12
RT ( )
813.18

Asumimos la temperatura de: R Presion T (K) x1 x2

1.987 1 337.24582153 0.001 0.999
T ( ºC )= 60 1.987 1 332.3990594 0.1 0.9
1.987 1 329.75445403 0.2 0.8
T ( K )= 333.15 1.987 1 328.21572792 0.3 0.7
1.987 1 327.27995915 0.4 0.6
La contante sera: 1.987 1 326.71340851 0.5 0.5
1.987 1 326.41769355 0.6 0.4
R= 1.987 1.987 1 326.38537349 0.7 0.3
1.987 1 326.7027166 0.8 0.2
1.987 1 327.58810695 0.9 0.1
1.987 1 329.68317979 0.999 0.001

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6

VP_A VP_B VP_C VP_D Pc Tc x

-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3345583632
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3441218244
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.349340067
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3523762275
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3542226536
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3553405515
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3559240459
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3559878187
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3553616484
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3536146272
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3494807029
an Cruz Huanca

−
Λ21
Λ 21 x 1 +x 2 ] [
γ 1 =exp −ln ( x 1 + Λ 12 x 2 ) + x 2
[ Λ12
x 1 + Λ 12 x 2
−
Λ 21
Λ21 x 1 + x 2 ]]
−
Λ 21
2 Λ21 x 1 +x 2
] [
γ 2 =exp −ln ( x 2 + Λ 21 x 1 ) −x 1
[ Λ 12
x1 + Λ12 x2
−
Λ21
Λ21 x 1 + x2 ]]
v1 λ
Λ 21 =
v2
exp − 21
RT ( )
v 1= v 2= λ12 = λ21 = Λ12= Λ21= γ 1= γ 2=
79.84 40.73 -31.19 813.18 0.5344511557 0.5824877213 2.8338224776 1.0000012008
79.84 40.73 -31.19 813.18 0.5348139983 0.5722716403 2.2987256064 1.0115673059
79.84 40.73 -31.19 813.18 0.5350165859 0.5666487568 1.9162933079 1.0453571511
79.84 40.73 -31.19 813.18 0.5351359969 0.563361367 1.6407194832 1.1017565189
79.84 40.73 -31.19 813.18 0.5352091784 0.5613564717 1.438740225 1.1833814176
79.84 40.73 -31.19 813.18 0.5352536939 0.5601405401 1.2892508206 1.2953248633
79.84 40.73 -31.19 813.18 0.535276992 0.55950525 1.1787525918 1.4458995476
79.84 40.73 -31.19 813.18 0.5352795409 0.5594357902 1.0986415724 1.6480117877
79.84 40.73 -31.19 813.18 0.5352545355 0.560117578 1.0436527669 1.921370835
79.84 40.73 -31.19 813.18 0.5351850325 0.5620171568 1.0110136872 2.2955365896
79.84 40.73 -31.19 813.18 0.5350220919 0.5664967407 1.0000011217 2.8039227362

METIL ACETATO (1) - METANOL (2) METIL AC

1 340

0.8
335
0.6 WILSON
Y

DIAGONA
330
0.4 L

0.2 325

0 320
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 -0.8
X
 1 340

0.8
335
0.6 WILSON

T
DIAGONA
330
0.4 L

0.2 325

0 320
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 -0.8
X

VP_A VP_B VP_C VP_D Pc Tc x

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3420877457
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3515429977
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3567021966
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3597040033
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3615295374
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3626347864
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3632116786
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3632747298
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3626556445
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3609283907
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3568412411
 DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

Pvp1 Pvp2 y1 y2 y1+y2

1.2916889798 0.9973558573 0.0036604173 0.9963596978 1.0000201151
1.0974864749 0.82107093 0.2522820262 0.7475116578 0.999793684
1.0016770738 0.736410097 0.3839014146 0.6158492488 0.9997506634
0.949049944 0.6906057774 0.4671374201 0.532615592 0.9997530121
0.918130454 0.6639359825 0.5283804864 0.4714137025 0.9997941889
0.8998017592 0.6482128852 0.5800350782 0.4198231334 0.9998582116
0.8903507817 0.6401309738 0.6297019749 0.3702260342 0.9999280091
0.8893226274 0.6392528129 0.6839327668 0.3160488513 0.9999816181
0.8994586695 0.6479191902 0.7509780233 0.2489786071 0.9999566304
0.9282228234 0.672621236 0.8446013814 0.1544026658 0.9990040472
0.9991895772 0.7342336743 0.9981915073 0.0020587345 1.0002502418

METIL ACETATO (1) - METANOL (2)

340

335
X vs
330 T

325

320
-0.8 0.2 1.2
X-Y
 340

335
X vs
330 T

325

320
-0.8 0.2 1.2
X-Y
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

2
G21 2
τ 12 G
γ 1 =exp(( x 2 ) ( τ 21 . ( )+
x 1 + x 2 G21 ( x 2 + x1

2
G12 2
τ 21 G
γ 2 =exp(( x 1 ) ( τ 12 . ( )+
Volúmenes: x 2 + x 1 G12 ( x1+ x2
v 1= 79.84
Λ 12 Λ 21
v 2= 40.73
τ 12 =
R.T
τ 21 =
R.T
G12=exp ( ¿α 12 . τ 12)
g g
Parámetros del NRTL: Λ 12 = g ¿ 22 Λ 21 = g ¿ 11

Λ12= 381.46

Λ21= 346.54

α 12= 0.2965 Cálculo del coeficiente de actividad:

Asumimos la temperatura de:

T (K) x1 x2 v 1= v 2=
T ( ºC )= 60 333.15 0.001 0.999 79.84 40.73
333.15 0.1 0.9 79.84 40.73
T ( K )= 333.15 333.15 0.2 0.8 79.84 40.73
333.15 0.3 0.7 79.84 40.73
La constante será: 333.15 0.4 0.6 79.84 40.73
333.15 0.5 0.5 79.84 40.73
R= 1.987 333.15 0.6 0.4 79.84 40.73
333.15 0.7 0.3 79.84 40.73
333.15 0.8 0.2 79.84 40.73
333.15 0.9 0.1 79.84 40.73
333.15 0.999 0.001 79.84 40.73

CALCULO DE LAS PRESIONES DE VAPOR:

0.8
Y1

0.6
METIL ACETATO METANOL 1
VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982 0.8
VP_C= -5.12994 VP_C= -3.1085

Y1
0.6
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9 0.4
Tc= 506.8 Tc= 512.6
T= 333.15 T= 333.15 0.2
x= 0.3426400947 x= 0.3500780336
0
0 0.1
 ian Cruz Huanca

2
τ 12 G12
)+ 2
))
G21 ( x 2 + x1 G12 )

2
τ 21 G 21
)+ 2
))
G12 ( x 1 + x 2 G21 )
=exp ( ¿α 12 . τ 12) G21=exp ( ¿ α12 . τ 21 )

Λ12 = Λ 21= α 12= τ 12 = τ 21 = G12= G 21= γ 1=

381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 2.7379334383
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 2.2620123378
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.905965907
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.6399017127
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.4399125235
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.289691195
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.1780508894
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.0973623378
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.0425706063
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.0105948209
381.46 346.54 0.2965 0.576250506 0.523498795 0.8429410308 0.8562290193 1.0000010673

Metil Acetato (1) - Metanól (2) Metil Acet

1 1.4
1.2
0.8
1
Y1

0.6 NRTL
P

DIAGONA 0.8
 Metil Acetato (1) - Metanól (2) Metil Acet

1 1.4
1.2
0.8
1
Y1

0.6 NRTL

P
DIAGONA 0.8
L 0.6
0.4
0.4
0.2
0.2
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.2 0.4
X1
 Diagonal
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

γ 2= Pvp1 Pvp2 P y1 y2 y1+y2

1.0000010208 1.1259658997 0.8465407651 0.8487779073 0.0036320687 0.9963679313 1
1.010191581 1.1259658997 0.8465407651 1.0243463942 0.2486413553 0.7513586447 1
1.0411754712 1.1259658997 0.8465407651 1.1343285074 0.3783829117 0.6216170883 1
1.0946778654 1.1259658997 0.8465407651 1.2026246286 0.460610908 0.539389092 1
1.1740841059 1.1259658997 0.8465407651 1.2448629944 0.5209544849 0.4790455151 1
1.284852486 1.1259658997 0.8465407651 1.2699141566 0.5717505782 0.4282494218 1
1.4352344607 1.1259658997 0.8465407651 1.2818608691 0.6208685333 0.3791314667 1
1.6374503925 1.1259658997 0.8465407651 1.2807653528 0.6753108979 0.3246891021 1
1.9095833281 1.1259658997 0.8465407651 1.2624271869 0.7438996643 0.2561003357 1
2.2786498637 1.1259658997 0.8465407651 1.217002776 0.8414983074 0.1585016926 1
2.7797245169 1.1259658997 0.8465407651 1.1271942844 0.9979123829 0.0020876171 1

Metil Acetato (1) - Metanól (2)

4
2
1
8 X1 vs
 Metil Acetato (1) - Metanól (2)

4
2
1
8 X1 vs
P
6
4
2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
 FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

2
G21 2
τ1
γ 1 =exp(( x 2 ) ( τ 21 . ( )+
x 1 + x 2 G 21 ( x 2+
Presion(bar)= 1
2
G 12 2
τ2
γ 2 =exp(( x 1 ) ( τ 12 . ( )+
Volúmenes: x 2 +x 1 G 12 ( x 1+
v 1= 79.84
Λ 12 Λ 21
v 2= 40.73
τ 12 =
R.T
τ 21 =
R.T
G12=exp (−α 12 .τ 12 )
g g
Parámetros del NRTL: Λ 12 = g ¿ 22 Λ 21 = g ¿ 11

Λ12= 381.46

Λ21= 346.54

α 12= 0.2965
Cálculo del coeficiente de actividad:
Asumimos la temperatura de:
R Presion T (K) x1
T ( ºC )= 60 1.987 1 337.24962527 0.001
1.987 1 332.53166335 0.1
T ( K )= 333.15 1.987 1 329.8105016 0.2
1.987 1 328.23140939 0.3
La constante será: 1.987 1 327.28081496 0.4
1.987 1 326.71127082 0.5
R= 1.987 1.987 1 326.41192873 0.6
1.987 1 326.37134621 0.7
1.987 1 326.68538449 0.8
1.987 1 327.60925949 0.9
1.987 1 329.6756592 0.999

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6

VP_A VP_B VP_C VP_D Pc Tc x

-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3345508578
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3438601749
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3492294759
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3523452853
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.354220965
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3553447695
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3559354208
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3560154968
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3553958475
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3535728897
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3494955422
oseph Christian Cruz Huanca

G21 2
τ 12 G 12
)+ 2
))
x 1 + x 2 G 21 ( x 2 + x1 G 12 )
G 12 2
τ 21 G 21
)+ 2
))
x 2 +x 1 G 12 ( x 1 + x 2 G 21 )
G12=exp (−α 12 .τ 12 ) G21=exp (−α 12 .τ 21 )

x2 Λ12 = Λ 21 = α 12 = τ 12 = τ 21 = G12=
0.999 381.46 346.54 0.2965 0.5692455726 0.5171351144 0.8446936073
0.9 381.46 346.54 0.2965 0.5773220334 0.5244722316 0.8426732643
0.8 381.46 346.54 0.2965 0.5820853343 0.5287994855 0.8414839811
0.7 381.46 346.54 0.2965 0.5848856952 0.5313434929 0.8407855811
0.6 381.46 346.54 0.2965 0.5865845087 0.532886792 0.8403621855
0.5 381.46 346.54 0.2965 0.5876070807 0.5338157545 0.8401074326
0.4 381.46 346.54 0.2965 0.5881459566 0.5343053002 0.8399732137
0.3 381.46 346.54 0.2965 0.5882190894 0.5343717381 0.839955
0.2 381.46 346.54 0.2965 0.5876536423 0.5338580538 0.8400958345
0.1 381.46 346.54 0.2965 0.5859964287 0.5323525465 0.8405087287
0.001 381.46 346.54 0.2965 0.5823234161 0.5290157726 0.8414245818
 VP_A VP_B VP_C VP_D Pc Tc
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
 Diagonal
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

G 21= γ 1= γ 2= Pvp1 Pvp2 y1 y2

0.8578461041 2.7072780484 1.0000010089 1.291851288 0.9975056622 0.0034974006 0.9965091619
0.8559819268 2.2626586655 1.0102094748 1.1024737958 0.8255213577 0.2494521888 0.7505545475
0.8548843798 1.9137679854 1.0415692675 1.0036365865 0.7381253502 0.3841455136 0.6150469443
0.8542397852 1.6472775182 1.0960360903 0.949575013 0.69106024 0.4692640712 0.5301988745
0.8538489846 1.445162561 1.1771533283 0.9181583624 0.6639599729 0.5307552362 0.4689496151
0.8536138351 1.2928942948 1.290594626 0.8997331552 0.6481541563 0.5816299316 0.4182521355
0.8534899418 1.1797274929 1.4449192768 0.8901673241 0.6399742649 0.6300929193 0.3698844608
0.8534731292 1.0980543607 1.652680606 0.8888766894 0.6388719956 0.6832244474 0.316755407
0.8536031294 1.0427343063 1.9319474117 0.8989027243 0.6474433332 0.749853367 0.2501652944
0.8539842482 1.0105823756 2.3079973664 0.9289188124 0.673220905 0.8448740822 0.1553792076
0.8548295586 1.000001057 2.8077564853 0.9989273907 0.7340043407 0.9979295181 0.0020609054

Metil Acetato (1) - Metanól (2)

0.9

0.8

0.7

0.6
Y1

NRTL
DIAGONA
 Metil Acetato (1) - Metanól (2)

0.9

0.8

0.7

0.6

Y1
NRTL
0.5 DIAGONA
x L
0.3420803253 0.4
0.3512843087
0.3565928568 0.3
0.3596734113 0.2
0.3615278678
0.3626389566 0.1
0.3632229248
0
0.3633020948 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.3626894567
X1
0.3608871255
0.3568559126
 y1+y2
1.0000065626
1.0000067362
0.9991924579
0.9994629457
0.9997048513
0.999882067
0.9999773801
0.9999798544
1.0000186613
1.0002532898
0.9999904235

Metil Acetato (1) - Metanól (2)

340

338

336

334

332
NRTL
T

X1 vs
DIAGONA
 Metil Acetato (1) - Metanól (2)

340

338

336

334

332
NRTL T
X1 vs
DIAGONA 330 T
L
328

326

324

322

320
1 0 0.2 0.4 0.6 0.8 1 1.2
X-Y
X1 vs
X1 vs
T
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Presion Total 1

DATOS EXPERIMENTALES:
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340 Presion T x1
0.03 0.333 335.15 1 345.79955166 0.001
0.0505 0.445 332.55 1 321.90168544 0.1
0.107 0.49 330.35 1 324.01678724 0.2
0.124 0.5 330.1 1 325.03754578 0.3
0.248 0.522 329.4 1 325.42651595 0.4
0.401 0.5365 328.95 1 325.51646079 0.5
0.505 0.5483 328.85 1 325.5160035 0.6
0.55 0.552 328.8 1 325.7511579 0.7
0.603 0.561 328.85 1 326.71862317 0.8
0.727 0.595 329.15 1 329.51356577 0.9
1 1 337.85 1 337.1684589 0.999

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Φ1 z θ1 r1 τ 21 τ 12
ln γ 1 =ln
( )
+ q1 ln
x1 2 Φ1 ( ) ( )
+ Φ2 l 1− l 2 −q1 ln ( θ1 +θ2 τ 21 ) +θ2 q1
r2
−
(
θ 1 +θ 2 τ 21 θ2 +θ1 τ 12 )
Φ2 z θ2 r2 τ 12 τ 21
ln γ 2 =ln
( )
+ q2 ln
x2 2 Φ2 ( ) ( )
+Φ1 l 2 − l 1 −q 2 ln ( θ 2 +θ1 τ 12 ) +θ 1 q2
r1
−
(
θ2 +θ 1 τ 12 θ 1 +θ2 τ 21 )
z Φi =
ri x i qi x i
( )
τ 12 =exp
−a12
T
θi =
li= ( r i−q i ) −( ri −1 ) NC NC

=exp (
T )
−a
2 ∑ r j xj ∑ qjx j τ 21 21
j j

r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
a12 = -29.64

z= 10

l1 l2 Φ1 Φ2 θ1 θ2 τ 12
 l1 l2 Φ1 Φ2 θ1 θ2 τ 12
-0.43 0.22 0.0004296746 0.9995703254 0.0005073423 0.9994926577 1.0894951206
-0.43 0.22 0.0455414013 0.9544585987 0.0533383066 0.9466616934 1.0964501259
-0.43 0.22 0.0969491525 0.9030508475 0.1125098348 0.8874901652 1.0957912903
-0.43 0.22 0.1554347826 0.8445652174 0.1785268414 0.8214731586 1.0954765404
-0.43 0.22 0.2225680934 0.7774319066 0.2526501767 0.7473498233 1.095357145
-0.43 0.22 0.3004201681 0.6995798319 0.3364705882 0.6635294118 1.0953295787
-0.43 0.22 0.3917808219 0.6082191781 0.4320241692 0.5679758308 1.0953297188
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.0952577236
-0.43 0.22 0.6320441989 0.3679558011 0.6697892272 0.3302107728 1.0949626628
-0.43 0.22 0.7944444444 0.2055555556 0.8202676864 0.1797323136 1.0941204223
-0.43 0.22 0.9976744186 0.0023255814 0.998029887 0.001970113 1.0918882956

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO

VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4

VP_A VP_B VP_C VP_D Pc Tc x

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3254007966
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3720216827
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3678954599
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3659041245
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3651453064
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3649698385
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3649707306
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3645119822
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3626246134
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3571721308
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3422386678
oseph Christian Cruz Huanca

x2 ln γ 1 = ln γ 2 = γ 1= γ 2= Pvp1 Pvp2
0.999 4.3196057214 1.780036E-05 75.158988869 1.0000178005 1.3851092664 0.8967860255
0.9 2.4435700928 0.0930254377 11.514073766 1.0974896526 0.5268285804 0.3986324863
0.8 1.5833902672 0.2384013964 4.8714433415 1.2692185503 0.5775894383 0.4307496854
0.7 1.0762278513 0.4045511978 2.9335927058 1.4986297608 0.6035206269 0.4469715773
0.6 0.7312673443 0.5887472832 2.0777121163 1.8017299437 0.6136559388 0.4532798066
0.5 0.482072057 0.7917074339 1.6194264721 2.2071617937 0.6160198482 0.4547485683
0.4 0.2984708225 1.0154812115 1.3477962114 2.7606915544 0.6160078104 0.4547410913
0.3 0.1648889463 1.2629884463 1.17926215 3.5359727782 0.6222241379 0.4585989497
0.2 0.0729300219 1.5381735781 1.075655262 4.6560785366 0.6483561666 0.4747462045
0.1 0.0183800449 1.8463784743 1.0185499975 6.3368289284 0.7290760004 0.523951315
0.001 1.8806835E-06 2.1916472343 1.0000018807 8.9499436333 0.9943131006 0.6796839267

METANOL (1) - TETRACLORURO DE CARBONO

τ 21 τ 12
q1
( −
θ 1 +θ 2 τ 21 θ2 +θ1 τ 12 ) 0.9
1

0.8
τ 12 τ 21
q2
( −
θ2 +θ 1 τ 12 θ 1 +θ2 τ 21 ) 0.7
Y1

0.6
0.5
( )
τ 12 =exp
−a12
T 0.4
0.3
=exp (
T )
−a21
τ 21
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1

τ 21
 τ 21
0.0383170316
0.0300762284
0.0307721015
0.0311103572
0.0312396653
0.0312695986
0.0312694464
0.0313477619
0.0316708347
0.032611964
0.0352475108

VP_A VP_B VP_C VP_D Pc Tc

-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
 DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

y1 y2 y1+y2
0.1041034119 0.8959051868 1.0000085987
0.6065943136 0.393745526 1.0003398397
0.5627388446 0.437372393 1.0001112376
0.5311451126 0.4688914355 1.0000365482
0.5100001518 0.4900126802 1.000012832
0.4987994247 0.5018518329 1.0006512576
0.4981517958 0.5021599561 1.0003117519
0.5136357622 0.4864780207 1.0001137829
0.5579261778 0.4420911227 1.0000173005
0.6683403226 0.332018985 1.0003593076
0.9933206556 0.0060831328 0.9994037884

ACLORURO DE CARBONO (2) METANOL (1) - TETRACLORURO DE CA

355
350
345
340
UNIQUAC 335
T

DAT. EXP.
330
DIAGONAL
325
320
315
310
305
0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
1 X-Y
 x
0.3785054787
0.4214563525
0.4176549474
0.4158203706
0.4151212869
0.4149596319
0.4149604538
0.4145378183
0.4127990238
0.4077757624
0.3940178668
1) - TETRACLORURO DE CARBONO (2)

X1 vs T
(CALC.)
Y1 vs T
(CALC.)
X1 vs T (EXP.)

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X-Y
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Temperatura 328

DATOS EXPERIMENTALES:

x y P(bar) x1 x2 ln γ 1 =
0.005587 0.0514 0.43427 0.001 0.999 4.5725313449
0.0234 0.3692 0.75861 0.1 0.9 2.4468261488
0.0343 0.3926 0.79019 0.2 0.8 1.5933470296
0.0525 0.4326 0.85891 0.3 0.7 1.085663334
0.1734 0.5084 0.96216 0.4 0.6 0.7391892209
0.545 0.5535 0.99515 0.5 0.5 0.4883010862
0.8699 0.6724 0.91647 0.6 0.4 0.3029933105
0.7 0.3 0.1677705567
0.8 0.2 0.0743618658
0.9 0.1 0.0187625786
0.999 0.001 1.915401E-06

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Φ1 z θ1 r1 τ 21 τ 12
ln γ 1 =ln
( )+ q1 ln
x1 2 Φ1 ( ) ( )
+Φ2 l1− l 2 −q1 ln ( θ1 +θ2 τ 21 ) +θ2 q1
r2
−
(
θ 1 +θ 2 τ 21 θ2 +θ1 τ 12 )
Φ2 z θ2 r2 τ 12 τ 21
ln γ 2 =ln
( )+ q2 ln
x2 2 Φ2 ( ) ( )
+Φ1 l2 − l1 −q 2 ln ( θ 2 +θ1 τ 12 ) +θ 1 q2
r1 (−
θ2 +θ 1 τ 12 θ 1 +θ2 τ 21 )
z Φi =
ri x i qi x i
τ 12 =exp ( )
−a12
T
θi =
li= ( r i−q i ) −( ri −1 ) NC NC

=exp (
T )
−a
2 ∑ r j xj ∑ qjx j τ 21 21
j j

r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
 a12 = -29.64

z= 10

l1 l2 Φ1 Φ2 θ1 θ2 τ 12 τ 21
-0.43 0.22 0.0004296746 0.9995703254 0.0005073423 0.9994926577 1.0846089553 0.0321008763
-0.43 0.22 0.0455414013 0.9544585987 0.0533383066 0.9466616934 1.0846089553 0.0321008763
-0.43 0.22 0.0969491525 0.9030508475 0.1125098348 0.8874901652 1.0846089553 0.0321008763
-0.43 0.22 0.1554347826 0.8445652174 0.1785268414 0.8214731586 1.0846089553 0.0321008763
-0.43 0.22 0.2225680934 0.7774319066 0.2526501767 0.7473498233 1.0846089553 0.0321008763
-0.43 0.22 0.3004201681 0.6995798319 0.3364705882 0.6635294118 1.0846089553 0.0321008763
-0.43 0.22 0.3917808219 0.6082191781 0.4320241692 0.5679758308 1.0846089553 0.0321008763
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.0846089553 0.0321008763
-0.43 0.22 0.6320441989 0.3679558011 0.6697892272 0.3302107728 1.0846089553 0.0321008763
-0.43 0.22 0.7944444444 0.2055555556 0.8202676864 0.1797323136 1.0846089553 0.0321008763
-0.43 0.22 0.9976744186 0.0023255814 0.998029887 0.001970113 1.0846089553 0.0321008763

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO

VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4
T= 328 T= 328
x= 0.3601248537 x= 0.410496046
ian Cruz Huanca

ln γ 2 = γ 1= γ 2= Pvp1 Pvp2 P y1
2.137181E-05 96.788805785 1.000021372 0.6843791697 0.4968262616 0.5625802855 0.1177436257
0.0907566511 11.551625336 1.0950025052 0.6843791697 0.4968262616 1.2801925767 0.6175392594
0.2364218696 4.920189419 1.2667085833 0.6843791697 0.4968262616 1.1769223019 0.5722170689
0.4034534821 2.9614035671 1.4969855939 0.6843791697 0.4968262616 1.1286361038 0.5387182568
0.5887330254 2.0942368625 1.8017042552 0.6843791697 0.4968262616 1.1103812279 0.516309912
0.7931454186 1.6295454098 2.2103379415 0.6843791697 0.4968262616 1.1066904355 0.5038567692
1.0190191437 1.3539054074 2.770475992 0.6843791697 0.4968262616 1.1065288872 0.5024277284
1.269714829 1.1826652249 3.5598372554 0.6843791697 0.4968262616 1.097160202 0.5164004402
1.5496991151 1.0771965356 4.7100527855 0.6843791697 0.4968262616 1.05778428 0.5575510127
1.8648657505 1.0189397018 6.4550692381 0.6843791697 0.4968262616 0.9483117882 0.6618150319
2.219314484 1.0000019154 9.2010212563 0.6843791697 0.4968262616 0.6882674091 0.993358237

τ 12
21
−
θ2 +θ1 τ 12 )
METANOL (1) - TETRACLORURO DE CARBONO
τ 21
−
12 θ 1 +θ2 τ 21
) 1
0.9
0.8
0.7
Y1

0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 DIAGONAL:
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
y2 y1+y2 1 1
0.8822563743 1
0.3824607406 1
0.4277829311 1
0.4612817432 1
0.483690088 1
0.4961432308 1
0.4975722716 1
0.4835995598 1
0.4424489873 1
0.3381849681 1
0.006641763 1

CLORURO DE CARBONO (2) METANOL (1) - TETRACLORURO DE CAR

1.4

1.2

0.8
P

UNIQUAC
DAT.EXP.
DIAGONAL 0.6

0.4

0.2

0
.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 X-Y
 DAT.EXP.
DIAGONAL 0.6

0.4

0.2

0
.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 X-Y
ACLORURO DE CARBONO (2)

X1 vs P
(CALC.)
Y1 vs P(CALC)
X1 vs P (EXP)
Y1 vs P (EXP)

0.6 0.7 0.8 0.9 1

 Y1 vs P(CALC)
X1 vs P (EXP)
Y1 vs P (EXP)

0.6 0.7 0.8 0.9 1

FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

DATOS EXPERIMENTALES
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340
0.03 0.333 335.15
0.0505 0.445 332.55
0.107 0.49 330.35 T x1 x2
0.124 0.5 330.1 348.31603344 0.001 0.999
0.248 0.522 329.4 328.34284212 0.1 0.9
0.401 0.5365 328.95 327.97820586 0.2 0.8
0.505 0.5483 328.85 328.24411346 0.3 0.7
0.55 0.552 328.8 328.3297906 0.4 0.6
0.603 0.561 328.85 328.31441267 0.5 0.5
0.727 0.595 329.15 328.35782382 0.6 0.4
1 1 337.85 328.69796792 0.7 0.3
329.71575869 0.8 0.2
332.08315044 0.9 0.1
337.22097764 0.999 0.001

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Grupos funcionales:
Me tan ol=CH 3 OH . .. . . .. . . .. . . .. . .. . . .. . . .. Un∗subgrupoCH 3 OH
Tetracloruro . . de .. Carbono=CCl4 .. . .. . . Un∗subgrupoCCl 4
Sub-Grupo k Rk Qk v k 1 ( me tan ol ) v k 2 (tertracloruro )
CH 3 OH 1 1.4311 1.432 1 0
CCl4 2 3.39 2.91 0 1

R1= 1.4311 Q1= 1.432 v 11 = 1 v 12=

R2= 3.39 Q2= 2.91 v 21 = 0 v 22 =

Parámetros de interaccion Binaria:

Sub-Grupo CH 3OH CCl4

Grup. funcional 6 24
CH 3OH 6 0 -67.8
 CH 3OH
CCl4 24 860.1 0

a11 = 0 a12 = -67.8

a21 = 860.1 a22 = 0

NSG NSG ri xi
Φi =
Parte combinatorial:
r i= ∑ v ki . R k qi = ∑ v ki . Q k NC
∑ r jxj
k k j

r1= 1.4311 q1= 1.432

r2= 3.39 q2= 2.91

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO

VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4
T= 343.6 T= 343.6
x= 0.3296917675 x= 0.3824586628

VP_A VP_B VP_C VP_D Pc Tc x

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3204915462
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.359456024
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3601673705
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3596486277
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3594814854
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3595114852
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3594267971
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3587632307
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.356777685
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3521592851
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.3421362122
eph Christian Cruz Huanca

γ 1= γ 2= Pvp1 Pvp2 y1 y2 y1+y2

20.271300669 1.0000072887 1.520398107 0.9693269446 0.0308204472 0.9683646757 0.9991851229
7.5052937049 1.058225204 0.6942968815 0.5028703104 0.5210902014 0.4789350331 1.0000252346
3.8664656844 1.1866319017 0.6837527455 0.4964440097 0.5287413054 0.4712770394 1.0000183449
2.5125824502 1.3674838929 0.6914285989 0.5011238365 0.521181409 0.4796951424 1.0008765513
1.858673253 1.6066440307 0.6939171356 0.5026391566 0.5159060879 0.4845373203 1.0004434082
1.4944980733 1.9189478557 0.6934699238 0.5023669084 0.5181947325 0.4820079508 1.0002026833
1.2754320788 2.3275230408 0.6947330024 0.5031357535 0.5316508545 0.4684240236 1.0000748781
1.1397205691 2.8660156414 0.7046966244 0.5091924102 0.5622100664 0.4378060237 1.0000160901
1.0575953634 3.5830337777 0.7352278312 0.5276621983 0.6220588362 0.3781262959 1.0001851321
1.0136791902 4.5502135073 0.8105491372 0.5726839565 0.7394731137 0.2605834274 1.0000565411
1.0000013311 5.8639327576 0.9963778762 0.6808657379 0.9953828233 0.0039925509 0.9993753742

METANOL (1) - TETRACLORURO DE CARBONO(2)

1
0.9
0.8
0.7
0.6 UNIFAC
y1

0 0.5 DAT. EXP.

1 DIAGONAL
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
 0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1

(
z
ri xi
θi =
qi x i li  (ri  qi )  (ri  1) ln γ C
i = ln(
Φi
)+
z θ Φ NC
q i ln( i )+l ¿ i ) ∑ x j l
C NC 2 xi 2 Φi xi j
∑ r jxj ∑ qjx j
j
Φ1 = Φ2 = θ1 = θ2 = l1=
0.0004223975 0.9995776025 0.0004923463 0.9995076537 -0.4356
0.044804343 0.955195657 0.0518427341 0.9481572659 -0.4356
0.0954633082 0.9045366918 0.1095471236 0.8904528764 -0.4356
0.1532046547 0.8467953453 0.1741668694 0.8258331306 -0.4356
0.219625236 0.780374764 0.2470243229 0.7529756771 -0.4356
0.2968409699 0.7031590301 0.3298019346 0.6701980654 -0.4356
0.3877163989 0.6122836011 0.4246737841 0.5753262159 -0.4356
0.4962279011 0.5037720989 0.5344993068 0.4655006932 -0.4356
0.6280610901 0.3719389099 0.6631164621 0.3368835379 -0.4356
0.7916397765 0.2083602235 0.8157994683 0.1842005317 -0.4356
0.9976344308 0.0023655692 0.9979699723 0.0020300277 -0.4356

VP_A VP_B VP_C VP_D Pc Tc x

-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.3739826861
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4098798668
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4105352159
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4100573087
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4099033239
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4099309621
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4098529407
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4092416105
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4074123676
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4031575298
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.3939234766
 DIAGONAL:
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

O(2) METANOL (1) - TETRACLORURO DE CARBONO (2)

355

350

345

340 X1 vs T (CALC)
UNIFAC
Y1 vs T (CALC)
T

DAT. EXP. 335 X1 vs T (EXP)

DIAGONAL
330 Y1 vs T (EXP)

325

320

315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
 320

315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y

[
v mi X .Q
Θ mi= NSG mi m
(
θi
)+l ¿
Φi NC
)∑ x j l j ¿
X mi = NSG
∑ v ni ∑ X ni . Qn ( )
−a
Ψ mn =EXP mn
Ln Γ ki=Q k 1−Ln
(∑ Θ
m
mi Ψ mk

Φi xi j n n T

l2= ln γ C
1= ln γ C
2= Ψ 11 = Ψ 12 = Ψ 21 = Ψ 22 = Ln Γ 11=
0.01 -0.204277755 -1.3145327E-07 1 1.214886693 0.084643307 1 0
0.01 -0.178267174 -0.0014081638 1 1.2293572622 0.072837959 1 0
0.01 -0.152102161 -0.0060587698 1 1.2296395194 0.0726261415 1 0
0.01 -0.126253854 -0.0147194679 1 1.2294336177 0.072780593 1 0
0.01 -0.101007992 -0.0283748716 1 1.2293673532 0.0728303748 1 0
0.01 -0.076758575 -0.0483030335 1 1.229379244 0.072821439 1 0
0.01 -0.05405332 -0.0761848949 1 1.22934568 0.072846665 1 0
0.01 -0.033661692 -0.1142635028 1 1.2290830309 0.0730443919 1 0
0.01 -0.016678554 -0.1655792439 1 1.2283006929 0.0736367888 1 0
0.01 -0.004684877 -0.2343216312 1 1.226501409 0.0750189918 1 0
0.01 -5.30312E-07 -0.325296052 1 1.2226921498 0.0780384933 1 0
X 11 = 1 Θ 11= 1
X 12 = 0 Θ 12 = 0
Θ 21 =
 X 21 = 0 Θ 21
21
= 0
X 22 = 1 Θ 22 = 1

[ ( ∑ )]
Θmi Ψ km ∑ x j v nj x m .Q m
ki=Q k 1−Ln ∑ Θmi Ψ mk −∑
( m ) m
n
Θni Ψ nm Xm=
∑∑
n
j

j
x j v nj
Θ m=
∑ x n Qn
n
[
Ln Γ k =Qk 1−Ln
(∑ Θ Ψ )−∑
m
m mk
m

Ln Γ 12 = Ln Γ 21= Ln Γ 22= X 1= X 2= Θ1 = Θ2 = Ln Γ 1=
3.2283330882 2.0972541033 0 0.001 0.999 0.0004923463 0.9995076537 3.2134838805
3.4227102414 2.0971513275 0 0.1 0.9 0.0518427341 0.9481572659 2.1938757729
3.4264764643 2.0970996647 0 0.2 0.8 0.1095471236 0.8904528764 1.5044429909
3.4237291643 2.0971375278 0 0.3 0.7 0.1741668694 0.8258331306 1.0475649428
3.422844904 2.0971495112 0 0.4 0.6 0.2470243229 0.7529756771 0.7208709207
3.4230035837 2.0971473681 0 0.5 0.5 0.3298019346 0.6701980654 0.4785489882
3.4225556767 2.0971534093 0 0.6 0.4 0.4246737841 0.5753262159 0.2973383265
3.4190501925 2.0971998102 0 0.7 0.3 0.5344993068 0.4655006932 0.1644448092
3.4086036866 2.0973288032 0 0.8 0.2 0.6631164621 0.3368835379 0.0726763598
3.3845499923 2.0975724493 0 0.9 0.1 0.8157994683 0.1842005317 0.0182713513
3.3334968387 2.097837621 0 0.999 0.001 0.9979699723 0.0020300277 1.86139E-06
 [ ( ∑ )]
Θm Ψ km
Γ k =Qk 1−Ln
(∑ Θm Ψ mk )−∑
m m Θn Ψ nm
R
Lnγ i =∑ v kj ( LnΓ k −LnΓ kj ) C
Lnγ i=Lnγ i +Lnγi
R
n k
R R
Ln Γ 2= Ln γ 1 = Ln γ 2 = Ln γ 1= Ln γ 2= γ 1= γ 2=
7.4201255E-06 3.2134838805 7.4201255E-06 3.0092061256 7.2886723E-06 20.271300669 1.0000072887
0.0580013328 2.1938757729 0.0580013328 2.0156085989 0.056593169 7.5052937049 1.058225204
0.1771777292 1.5044429909 0.1771777292 1.3523408299 0.1711189594 3.8664656844 1.1866319017
0.3276919446 1.0475649428 0.3276919446 0.9213110888 0.3129724767 2.5125824502 1.3674838929
0.5025224222 0.7208709207 0.5025224222 0.6198629283 0.4741475505 1.858673253 1.6066440307
0.7000800775 0.4785489882 0.7000800775 0.4017904135 0.651777044 1.4944980733 1.9189478557
0.9209895244 0.2973383265 0.9209895244 0.2432850065 0.8448046295 1.2754320788 2.3275230408
1.1671862898 0.1644448092 1.1671862898 0.1307831175 1.052922787 1.1397205691 2.8660156414
1.4417891094 0.0726763598 1.4417891094 0.055997806 1.2762098655 1.0575953634 3.5830337777
1.7494957877 0.0182713513 1.7494957877 0.0135864746 1.5151741565 1.0136791902 4.5502135073
2.0941165495 1.86139E-06 2.0941165495 1.331079E-06 1.7688204975 1.0000013311 5.8639327576
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Temperatura 328

DATOS EXPERIMENTALES:

x y P(bar) T x1 x2 γ 1=
0.005587 0.0514 0.43427 328 0.001 0.999 24.641225603
0.0234 0.3692 0.75861 328 0.1 0.9 7.5123833067
0.0343 0.3926 0.79019 328 0.2 0.8 3.8664032859
0.0525 0.4326 0.85891 328 0.3 0.7 2.512614806
0.1734 0.5084 0.96216 328 0.4 0.6 1.8585591292
0.545 0.5535 0.99515 328 0.5 0.5 1.494384994
0.8699 0.6724 0.91647 328 0.6 0.4 1.2753350702
328 0.7 0.3 1.1396014851
328 0.8 0.2 1.0574506357
328 0.9 0.1 1.013582496
328 0.999 0.001 1.0000013063

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Grupos funcionales:

Me tan ol=CH 3 OH . .. . . .. . . .. . . .. . .. . . .. . . .. Un∗subgrupoCH 3 OH

Tetracloruro. . de .. Carbono=CCl4 .. . .. . . Un∗subgrupoCCl 4
Sub-Grupo k Rk Qk v k 1 ( me tan ol ) v k 2 (tertracloruro)
CH 3 OH 1 1.4311 1.432 1 0
CCl4 2 3.39 2.91 0 1

R1= 1.4311 Q1= 1.432 v 11 = 1 v 12= 0

R2= 3.39 Q2= 2.91 v 21 = 0 v 22 = 1

Parámetros de interaccion Binaria:

Sub-Grupo CH 3OH CCl4

Grup. funcional 6 24
CH 3OH 6 0 -67.8
 CH 3OH
CCl4 24 860.1 0

a11 = 0 a12 = -67.8

a21 = 860.1 a22 = 0

NSG NSG ri xi qi x i
Φi = θi =
Parte combinatorial:
r i= ∑ v ki . R k qi = ∑ v ki . Q k NC NC
∑ qjx j
k k
∑ r jxj
j j

r1= 1.4311 q1= 1.432

r2= 3.39 q2= 2.91

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL (1
METANOL TETRACLORURO DE CARBONO
VP_A= -8.54796 VP_A= -7.07139 1
VP_B= 0.76982 VP_B= 1.71497 0.9
VP_C= -3.1085 VP_C= -2.8993
0.8
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6 0.7
Y1

Tc= 512.6 Tc= 556.4 0.6

T= 328 T= 328
x= 0.3601248537 x= 0.410496046 0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0
ian Cruz Huanca DIAGONAL:
0
0.2
0.4
0.6
0.8
1

γ 2= Pvp1 Pvp2 P y1 y2 y1+y2

1.0000086374 0.6843791697 0.4968262616 0.5131976639 0.0328605189 0.9671394811 1
1.0583355119 0.6843791697 0.4968262616 0.9873598534 0.5207137634 0.4792862366 1
1.1866154424 0.6843791697 0.4968262616 1.0008505455 0.5287674334 0.4712325666 1
1.3677700084 0.6843791697 0.4968262616 0.9915552125 0.5202679225 0.4797320775 1
1.6071640192 0.6843791697 0.4968262616 0.9878724364 0.5150297172 0.4849702828 1
1.919565029 0.6843791697 0.4968262616 0.9882081394 0.5174648542 0.4825351458 1
2.3283444806 0.6843791697 0.4968262616 0.9864007275 0.5309076111 0.4690923889 1
2.8677531072 0.6843791697 0.4968262616 0.9733761794 0.5608763336 0.4391236664 1
3.5870952288 0.6843791697 0.4968262616 0.935390373 0.6189477326 0.3810522674 1
4.5566975114 0.6843791697 0.4968262616 0.8506959714 0.7338782519 0.2661217481 1
5.8599162156 0.6843791697 0.4968262616 0.6866070439 0.9957597868 0.0042402132 1

R1 R2 Q1 Q2 v 11 = v 12= v 21 =
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
 1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0

(
z
qi x i li  (ri  qi )  (ri  1) ln γ C
i = ln(
Φi
)+
z θ Φ NC
q i ln( i )+l ¿ i ) ∑ x j l j ¿
θi = NC 2 xi 2 Φi xi j
∑ qjx j
j Φ1 = Φ2 = θ1 = θ2 = l1= l2 =
0.0004223975 0.9995776025 0.0004923463 0.9995076537 -0.4356 0.01
0.044804343 0.955195657 0.0518427341 0.9481572659 -0.4356 0.01
0.0954633082 0.9045366918 0.1095471236 0.8904528764 -0.4356 0.01
0.1532046547 0.8467953453 0.1741668694 0.8258331306 -0.4356 0.01
0.219625236 0.780374764 0.2470243229 0.7529756771 -0.4356 0.01
0.2968409699 0.7031590301 0.3298019346 0.6701980654 -0.4356 0.01
0.3877163989 0.6122836011 0.4246737841 0.5753262159 -0.4356 0.01
0.4962279011 0.5037720989 0.5344993068 0.4655006932 -0.4356 0.01
0.6280610901 0.3719389099 0.6631164621 0.3368835379 -0.4356 0.01
0.7916397765 0.2083602235 0.8157994683 0.1842005317 -0.4356 0.01
0.9976344308 0.0023655692 0.9979699723 0.0020300277 -0.4356 0.01

METANOL (1) - TETRACLORURO DE CARBONO (2) METANOL (1)

1 1.2
0.9
1
0.8
0.7
0.8
Y1

0.6 UNIFAC
P

DAT. EXP. 0.6

0.5
DIAGONAL
0.4
0.4
0.3
0.2
0.2
0.1
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3
X1
 0
0.2
0.4
0.6
0.8
1

v 22 = r1 r2 q1 q2 X 11 = X 12 = X 21 =
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
 1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0

[
Θmi Ψ

(∑
v mi X .Q
Θ mi= NSG mi m ∑ Θmi Ψ mk −∑
Φi NC
)∑ x j l j ¿
X mi = NSG
∑ v ni ∑ X ni . Qn Ψ mn =EXP ( )
−amn
Ln Γ ki=Q k 1−Ln
( m ) m Θn
xi j n n T n

ln γ C
1= ln γ C
2= Ψ 11 = Ψ 12= Ψ 21 = Ψ 22 = Ln Γ 11= Ln Γ 12=
-0.204277755 -1.3145327E-07 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.178267174 -0.0014081638 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.152102161 -0.0060587698 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.126253854 -0.0147194679 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.101007992 -0.0283748716 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.076758575 -0.0483030335 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.05405332 -0.0761848949 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.033661692 -0.1142635028 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.016678554 -0.1655792439 1 1.2296226296 0.0726387976 1 0 3.4262511262
-0.004684877 -0.2343216312 1 1.2296226296 0.0726387976 1 0 3.4262511262
-5.30312E-07 -0.325296052 1 1.2296226296 0.0726387976 1 0 3.4262511262

METANOL (1) - TETRACLORURO DE CARBONO (2)

1.2

0.8 X1 vs P (CALC.)
P

Y1 vs P (CALC.)
0.6 X1 vs P (EXP.)
Y1 vs P (EXP.)
0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
X 22 = Θ 11= Θ 12 = Θ 21 = Θ 22 = a11 = a12 = a21 =
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
 1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1

( ∑ )]
Θmi Ψ km ∑ x j v nj x m .Q m
[ ( ∑ )]
Θm Ψ km
∑ Θmi Ψ mk −∑
( ) Xm=
j Θ m= Ln Γ k =Qk 1−Ln
(∑ Θm Ψ mk )−∑
m m
n
Θni Ψ nm ∑ ∑ x j v nj ∑ x n Qn m m
n
Θn Ψ nm
n j n

Ln Γ 21= Ln Γ 22= X 1= X 2= Θ1 = Θ2 = Ln Γ 1= Ln Γ 2=
2.0971028063 0 0.001 0.999 0.0004923463 0.9995076537 3.4086986327 8.7688366E-06
2.0971028063 0 0.1 0.9 0.0518427341 0.9481572659 2.1948199405 0.058105566
2.0971028063 0 0.2 0.8 0.1095471236 0.8904528764 1.5044268524 0.1771638585
2.0971028063 0 0.3 0.7 0.1741668694 0.8258331306 1.0475778202 0.3279011504
2.0971028063 0 0.4 0.6 0.2470243229 0.7529756771 0.7208095182 0.5028460187
2.0971028063 0 0.5 0.5 0.3298019346 0.6701980654 0.4784733216 0.7004016465
2.0971028063 0 0.6 0.4 0.4246737841 0.5753262159 0.2972622641 0.9213423866
2.0971028063 0 0.7 0.3 0.5344993068 0.4655006932 0.1643403185 1.1677923365
2.0971028063 0 0.8 0.2 0.6631164621 0.3368835379 0.0725395044 1.4429219904
2.0971028063 0 0.9 0.1 0.8157994683 0.1842005317 0.0181759574 1.7509197624
2.0971028063 0 0.999 0.001 0.9979699723 0.0020300277 1.836576E-06 2.0934313578
a22 =
0
0
0
0
0
0
0
0
0
 0
0

( ∑ )]
Θm Ψ km
∑ Θm Ψ mk )−∑ R
Lnγ i =∑ v kj ( LnΓ k −LnΓ kj ) C R
m
n
Θn Ψ nm
k
Lnγ i=Lnγ i +Lnγi
R R
Ln γ 1 = Ln γ 2 = Ln γ 1= Ln γ 2= γ 1= γ 2=
3.4086986327 8.7688366E-06 3.2044208778 8.637383E-06 24.641225603 1.0000086374
2.1948199405 0.058105566 2.0165527665 0.0566974022 7.5123833067 1.0583355119
1.5044268524 0.1771638585 1.3523246914 0.1711050888 3.8664032859 1.1866154424
1.0475778202 0.3279011504 0.9213239663 0.3131816825 2.512614806 1.3677700084
0.7208095182 0.5028460187 0.6198015258 0.474471147 1.8585591292 1.6071640192
0.4784733216 0.7004016465 0.4017147469 0.652098613 1.494384994 1.919565029
0.2972622641 0.9213423866 0.2432089442 0.8451574917 1.2753350702 2.3283444806
0.1643403185 1.1677923365 0.1306786268 1.0535288337 1.1396014851 2.8677531072
0.0725395044 1.4429219904 0.0558609506 1.2773427465 1.0574506357 3.5870952288
0.0181759574 1.7509197624 0.0134910807 1.5165981312 1.013582496 4.5566975114
1.836576E-06 2.0934313578 1.306265E-06 1.7681353058 1.0000013063 5.8599162156