11/18/2019 CN104529753A - Production process of boron citrate - Google Patents

 Patents

Production process of boron citrate

Abstract
CN104529753A
The invention discloses a production process of boron citrate. With copper carbonate or
China
copper oxide as a raw material, the raw material reacts with edible citric acid to prepare
boron citrate, and the boron citrate is further prepared by centrifugal dewatering and drying.
The production process of boron citrate, disclosed by the invention, is simple, and the Download PDF Find Prior Art Similar
prepared boron citrate is high in purity and can be formed to powder.
Other languages: Chinese
Classi cations Inventor: 姚建飞, 朱碧君, 姚佼

C07C51/412 Preparation of salts of carboxylic acids by conversion of the acids, their

Worldwide applications
salts, esters or anhydrides with the same carboxylic acid part
2014 CN
View 1 more classi cations

Application CN 201410800822 events

2014-12-22 Application led by 南通市飞宇精细化学品

有限公司

2014-12-22 Priority to CN201410800822.8A

2015-04-22 Publication of CN104529753A

2016-05-18 Application granted

2016-05-18 Publication of CN104529753B

Info: Patent citations (3), Legal events, Similar documents,

Priority and Related Applications

External links: Espacenet, Global Dossier, Discuss

Claims (4) Hide Dependent

translated from Chinese

A boron citric acid production process, using boron oxide as raw materials and the consumption of citric acid prepared by the reaction of boron citrate, after
centrifugal dewatering, drying is made of boron citrate, characterized in that: includes the following steps:. A a acid dehydrated at 220 ~ 260 ° C is made of boron
oxide;. b food grade citric acid dissolved in water to a concentration of 40 to 50% aqueous citric acid, and heated to above 60 ° C; c lemon step b. acid was slowly
added to the aqueous solution of step a boron oxide was subjected to the reaction and boron citrate; D boron citrate prepared in step c was poured into a stirred
mixer 25 ~ 35min, then placed in a centrifugal dewatering machine for spin-drying. ;. e the boron citrate dehydrated into a 85 ~ 95 ° C drying oven 90 ~ 100min, to
obtain boron citrate.

One boron according to claim 1, the citric acid production process, characterized in that: said step c PH value of the reaction solution was controlled to be
4 to 8.

One boron according to claim 1, the citric acid production process, characterized in that: said step e drying temperature is preferably 90 ° C.

One boron according to claim 1, the citric acid production process, characterized in that: after said step c through step further reaction was concentrated,
cooled and crystallized.

Description translated from Chinese

Boron one kind of citric acid production process

FIELD

[0001] The present invention relates to the eld of food pharmaceutical raw materials, particularly boron, to a citric acid production process.

Background technique

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11/18/2019 CN104529753A - Production process of boron citrate - Google Patents
[0002] Currently, there is not yet a method described in the production of boron citrate details, but there is no disclosure of the patent, boron citrate mainly
used in pharmaceutical or food additive raw material, and the general production methods can not obtain a powder citric acid boron.

SUMMARY

[0003] Object of the invention: object of the present invention is to solve the de ciencies of the prior art, there is provided a boron citric acid production
process, to obtain a powdery boron citrate can be prepared.

[0004] The present invention employs technical solutions: A boron citric acid production process, the reaction of boron oxide with boron prepared with the
consumption of citric acid and citric acid as starting material, after centrifugal dewatering, drying is made of boron citrate, comprises the steps of :

. A dehydrating boric acid, boron oxide formed at 220 ~ 260 ° C;

. B food grade citric acid dissolved in water to a concentration of 40 to 50% aqueous citric acid, and heated to above 60 ° C;

. C In step b, aqueous citric acid was added slowly boron oxide obtained in step a boron generated in the citric acid and the reaction;

. D Citric acid prepared in step c was poured into a mixer with stirring boron 25 ~ 35min, then placed in a centrifugal dewatering machine for spin-drying;

The e. Place boron citrate dehydrated into 85 ~ 95 ° C in the drying oven 90 ~ 100min, to obtain boron citrate.

[0005] The reaction solution of the step (c) controlling the PH value of 4 to 8.

[0006] The step e, drying temperature is preferably 90 ° C.

The [0007] After the reaction in step b through step further concentrated, cooled and crystallized.

[0008] The bene cial effects: one boron citrate disclosed in the present invention production process, the oxidation reaction with boron as raw materials
and the consumption of citric acid to prepare boron citrate, boron prepared after drying can be citric acid, the overall process is simple.

Detailed ways

[0009] The following embodiments in conjunction with speci c embodiments of the present invention is further described:

Example 1:

Boron one kind of citric acid production process includes the following steps:

. A boric acid at 220 ° C dehydrated boron oxide formed;

. B food grade citric acid dissolved in water to a concentration of 40% aqueous citric acid solution, and heated to above 60 ° C;

. C In step b, aqueous citric acid was added slowly boron oxide obtained in step a boron citrate generated in the reaction, the reaction solution was
controlled PH value of 4;

. D boron citrate prepared in step c was concentrated, cooled and poured into a blender crystallized stirred 25min, and then into the centrifugal dewatering
machine for spin-drying; E boron citrate into dehydrated to 85 ° C. the drying oven 90min, to give boron citrate.

[0010] Example 2:

Boron one kind of citric acid production process includes the following steps:

. A boric acid at 240 ° C dehydrated boron oxide formed;

. B food grade citric acid dissolved in water to a concentration of 45% aqueous citric acid solution, and heated to above 60 ° C;

. C In step b, aqueous citric acid was added slowly boron oxide obtained in step a boron citrate generated in the reaction, the reaction solution was
controlled PH value of 7;

After stirring for 30min poured into a mixer d boron citrate prepared in step c was concentrated, cooled and crystallized, and then into the centrifugal
dewatering machine for spin-drying.;

e. Place boron citrate 95min dehydrated and dried into an oven of 90 ° C to obtain boron citrate.

[0011] Example 3

Boron one kind of citric acid production process includes the following steps:

. A boric acid at 260 ° C dehydrated boron oxide formed;

. B food grade citric acid dissolved in water to a concentration of 50% citric acid aqueous solution, and heated to above 60 ° C;

. C In step b, aqueous citric acid was added slowly boron oxide obtained in step a boron citrate generated in the reaction, the reaction solution was
controlled PH value of 8;

After stirring for 35min poured into a mixer d boron citrate prepared in step c was concentrated, cooled and crystallized, and then into the centrifugal
dewatering machine for spin-drying.;

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11/18/2019 CN104529753A - Production process of boron citrate - Google Patents
e. Place boron citrate dehydrated into an oven dried 95 ° C lOOmin, to give boron citrate.

[0012] Example 3 above were obtained product quality indicators:

The boron content of 36 to 37.8%

23 to 26% loss on drying

Cadmium (cd counted in) <7ppm arsenic (As) <2ppm Heavy Metals (as Pb) <Ippm particle size of 20 to 80 mesh.

Patent Citations (3)

Publication number Priority date Publication date Assignee Title

WO1992012714A2 * 1991-01-23 1992-08-06 Food supplement

US20090204187A1 * 2008-02-12 2009-08-13 Mankovitz Roy J Soil-based compositions and methods for removal of toxins
from mammals

CN102964369A * 2012-10-24 2013-03-13 中国科学院青岛生物能源与过 Polymeric borate salt, and preparation method and
程研究所 application thereof

Family To Family Citations

* Cited by examiner, † Cited by third party

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Priority And Related Applications

Priority Applications (1)

Application Priority date Filing date Title

CN201410800822.8A 2014-12-22 2014-12-22 Boron one kind of citric acid production process

Applications Claiming Priority (1)

Application Filing date Title

CN201410800822.8A 2014-12-22 Boron one kind of citric acid production process

Legal Events

Date Code Title Description

2015-05-20 C10 Entry into substantive examination

2016-05-18 C14 Grant of patent or utility model

2018-10-09 CP03 Change of name, title or address

Concepts

machine-extracted Download Filter table

Name Image Sections Count Query match

BORON CITRATE abstract,title 6 0

boron citrate abstract,title 6 0

methods abstract,title 3 0

production abstract,title 3 0

raw materials abstract 2 0

Citric acid abstract 1 0

Copper oxide abstract 1 0

citric acid abstract 1 0

citric acid abstract 1 0

O O

HO OH OH

O OH

citric acid abstract 1 0

copper carbonate abstract 1 0

copper oxide abstract 1 0

copper oxide abstract 1 0

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11/18/2019 CN104529753A - Production process of boron citrate - Google Patents

O Cu

copper;carbonate Cu+2 abstract 1 0

- -
O O

drying abstract 1 0

powders abstract 1 0

Show all concepts from the description section

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