GROUP 4: BRACERO, Jestoni L.

LIBREA, Jerom Alry

FUENTES, Verenice Dianne
REVILLA, John Mark
RESULTS:
POTENTIOMETRIC TITRATION OF AN HCl-H3PO4 MIXTURE
FIRST TRIAL
Volume Observed 1st derivative 1st derivative 2nd derivative 2nd derivative
added (mL) pH volume (dpH/dVol) volume change
0 0.65
0.5 0.84 0.25 0.38
1 0.91 0.75 0.14 0.5 -0.48
1.5 1.18 1.25 0.54 1 0.8
2 1 1.75 -0.36 1.5 -1.8
2.5 1.05 2.25 0.1 2 0.92
3 1.18 2.75 0.26 2.5 0.32
3.5 1.2 3.25 0.04 3 -0.44
4 1.34 3.75 0.28 3.5 0.48
4.5 1.19 4.25 -0.3 4 -1.16
5 1.28 4.75 0.18 4.5 0.96
5.5 1.33 5.25 0.1 5 -0.16
6 1.32 5.75 -0.02 5.5 -0.24
6.5 1.34 6.25 0.04 6 0.12
7 1.37 6.75 0.06 6.5 0.04
7.5 1.4 7.25 0.06 7 -8.88178E-16
8 1.42 7.75 0.04 7.5 -0.04
8.5 1.46 8.25 0.08 8 0.08
9 1.5 8.75 0.08 8.5 0
9.5 1.53 9.25 0.06 9 -0.04
10 1.55 9.75 0.04 9.5 -0.04
10.5 1.6 10.25 0.1 10 0.12
11 1.65 10.75 0.1 10.5 -8.88178E-16
11.5 1.72 11.25 0.14 11 0.08
12 1.77 11.75 0.1 11.5 -0.08
12.5 1.84 12.25 0.14 12 0.08
13 1.93 12.75 0.18 12.5 0.08
13.5 2.02 13.25 0.18 13 8.88178E-16
14 2.15 13.75 0.26 13.5 0.16
14.5 2.29 14.25 0.28 14 0.04
15 2.55 14.75 0.52 14.5 0.48
15.5 2.81 15.25 0.52 15 1.77636E-15
16 4.22 15.75 2.82 15.5 4.6
16.5 5.47 16.25 2.5 16 -0.64
17 5.87 16.75 0.8 16.5 -3.4
17.5 6.17 17.25 0.6 17 -0.4
18 6.36 17.75 0.38 17.5 -0.44
18.5 6.51 18.25 0.3 18 -0.16
19 6.67 18.75 0.32 18.5 0.04
19.5 6.82 19.25 0.3 19 -0.04
20 6.98 19.75 0.32 19.5 0.04
20.5 7.11 20.25 0.26 20 -0.12
21 7.25 20.75 0.28 20.5 0.04
21.5 7.44 21.25 0.38 21 0.2
22 7.7 21.75 0.52 21.5 0.28
22.5 8.08 22.25 0.76 22 0.48
23 9.57 22.75 2.98 22.5 4.44
23.5 10.67 23.25 2.2 23 -1.56
 SECOND TRIALS

Volume Observed 1st derivative 1st derivative 2nd 2nd derivative

added (mL) pH volume (dpH/dVol) derivative change
0 1.33
0.5 1.35 0.5 0.04
1 1.36 0.75 0.02 0.625 -0.08
1.5 1.33 1.25 -0.06 1 -0.16
2 1.32 1.75 -0.02 1.5 0.08
2.5 1.34 2.25 0.04 2 0.12
3 1.35 2.75 0.02 2.5 -0.04
3.5 1.36 3.25 0.02 3 0
4 1.38 3.75 0.04 3.5 0.04
4.5 1.39 4.25 0.02 4 -0.04
5 1.42 4.75 0.06 4.5 0.08
5.5 1.44 5.25 0.04 5 -0.04
6 1.47 5.75 0.06 5.5 0.04
6.5 1.5 6.25 0.06 6 0
7 1.53 6.75 0.06 6.5 0
7.5 1.58 7.25 0.1 7 0.08
8 1.62 7.75 0.08 7.5 -0.04
8.5 1.68 8.25 0.12 8 0.08
9 1.72 8.75 0.08 8.5 -0.08
9.5 1.76 9.25 0.08 9 0
10 1.78 9.75 0.04 9.5 -0.08
10.5 1.84 10.25 0.12 10 0.16
11 1.87 10.75 0.06 10.5 -0.12
11.5 1.93 11.25 0.12 11 0.12
12 1.99 11.75 0.12 11.5 8.88178E-16
12.5 2.05 12.25 0.12 12 -8.88178E-16
13 2.13 12.75 0.16 12.5 0.08
13.5 2.22 13.25 0.18 13 0.04
14 2.35 13.75 0.26 13.5 0.16
14.5 2.46 14.25 0.22 14 -0.08
15 2.67 14.75 0.42 14.5 0.4
15.5 3.04 15.25 0.74 15 0.64
16 3.72 15.75 1.36 15.5 1.24
16.5 5.37 16.25 3.3 16 3.88
17 5.78 16.75 0.82 16.5 -4.96
17.5 6.03 17.25 0.5 17 -0.64
18 6.17 17.75 0.28 17.5 -0.44
18.5 6.3 18.25 0.26 18 -0.04
19 6.41 18.75 0.22 18.5 -0.08
19.5 6.57 19.25 0.32 19 0.2
20 6.69 19.75 0.24 19.5 -0.16
20.5 6.84 20.25 0.3 20 0.12
21 6.93 20.75 0.18 20.5 -0.24
21.5 7.07 21.25 0.28 21 0.2
22 7.2 21.75 0.26 21.5 -0.04
22.5 7.4 22.25 0.4 22 0.28
23 7.62 22.75 0.44 22.5 0.08
23.5 8.04 23.25 0.84 23 0.8
24 9.08 23.75 2.08 23.5 2.48
24.5 9.79 24.25 1.42 24 -1.32
25 10.15 24.75 0.72 24.5 -1.4
 THIRD TRIAL

Volume Observed 1st derivative 1st derivative 2nd 2nd derivative

added (mL) pH volume (dpH/dVol) derivative change
0 1.33
0.5 1.35 0.5 0.04
1 1.36 0.75 0.02 0.625 -0.08
1.5 1.33 1.25 -0.06 1 -0.16
2 1.32 1.75 -0.02 1.5 0.08
2.5 1.34 2.25 0.04 2 0.12
3 1.35 2.75 0.02 2.5 -0.04
3.5 1.36 3.25 0.02 3 0
4 1.38 3.75 0.04 3.5 0.04
4.5 1.39 4.25 0.02 4 -0.04
5 1.42 4.75 0.06 4.5 0.08
5.5 1.44 5.25 0.04 5 -0.04
6 1.47 5.75 0.06 5.5 0.04
6.5 1.5 6.25 0.06 6 0
7 1.53 6.75 0.06 6.5 0
7.5 1.58 7.25 0.1 7 0.08
8 1.62 7.75 0.08 7.5 -0.04
8.5 1.68 8.25 0.12 8 0.08
9 1.72 8.75 0.08 8.5 -0.08
9.5 1.76 9.25 0.08 9 0
10 1.78 9.75 0.04 9.5 -0.08
10.5 1.84 10.25 0.12 10 0.16
11 1.87 10.75 0.06 10.5 -0.12
11.5 1.93 11.25 0.12 11 0.12
12 1.99 11.75 0.12 11.5 8.88178E-16
12.5 2.05 12.25 0.12 12 -8.88178E-16
13 2.13 12.75 0.16 12.5 0.08
13.5 2.22 13.25 0.18 13 0.04
14 2.35 13.75 0.26 13.5 0.16
14.5 2.46 14.25 0.22 14 -0.08
15 2.67 14.75 0.42 14.5 0.4
15.5 3.04 15.25 0.74 15 0.64
16 3.72 15.75 1.36 15.5 1.24
16.5 5.37 16.25 3.3 16 3.88
17 5.78 16.75 0.82 16.5 -4.96
17.5 6.03 17.25 0.5 17 -0.64
18 6.17 17.75 0.28 17.5 -0.44
18.5 6.3 18.25 0.26 18 -0.04
19 6.41 18.75 0.22 18.5 -0.08
19.5 6.57 19.25 0.32 19 0.2
20 6.69 19.75 0.24 19.5 -0.16
20.5 6.84 20.25 0.3 20 0.12
21 6.93 20.75 0.18 20.5 -0.24
21.5 7.07 21.25 0.28 21 0.2
22 7.2 21.75 0.26 21.5 -0.04
22.5 7.4 22.25 0.4 22 0.28
23 7.62 22.75 0.44 22.5 0.08
23.5 8.04 23.25 0.84 23 0.8
24 9.08 23.75 2.08 23.5 2.48
24.5 9.79 24.25 1.42 24 -1.32
25 10.15 24.75 0.72 24.5 -1.4
 First Trial Graphs

Potentiometric Curve
12

10

8
pH

0
0 5 10 15 20 25
Volume of NaOH, mL

First Derivative Curve

3.5
3
1sr derivative (dpH/dVol)

2.5
2
1.5
1
0.5
0
0 5 10 15 20 25
-0.5
-1
Volume NaOH (mL)

Second Derivative Curve

5
4
3
2
2nd derivative

1
0
-1 0 5 10 15 20 25

-2
-3
-4
Volume of NaOH (mL)
 Second Trial Graphs

Potentiometric Curve
12

10

8
pH

0
0 5 10 15 20 25 30
Volume of NaOH, mL

First Derivative Curve

5

4
1st derivative(dpH/pVol)

0
0 5 10 15 20 25
-1
Volume of NaOH, mL

Second Derivative Curve

8
6
4
2nd derivative

2
0
0 5 10 15 20 25
-2
-4
-6
-8
Volume of NaOH, mL
 Third Trial Graphs

Potentiometric Curve
12

10

8
pH

0
0 5 10 15 20 25 30
Volume of NaOH, mL

First Derivative Curve

3.5
3
1st derivative (dpH/dVol)

2.5
2
1.5
1
0.5
0
0 5 10 15 20 25 30
-0.5
Volume of NaOH. mL

Second Derivative Curve

5
4
3
2
2nd derivative

1
0
-1 0 5 10 15 20 25 30
-2
-3
-4
-5
-6
Volume of NaOH, mL