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Abstract
Two commercial cold work tool steels, AISI D2 and O1, were heat treated in order to obtain the same hardness 700 HV (60 HRc) and were
subsequently tested in three different modes of wear, namely in adhesion, three-body and two-body abrasion, by using pin-on-disk, dry
sand/rubber wheel apparatus and pin abrasion on SiC, respectively. Even though AISI O1 and D2 steel are heat treated to the same hardness,
they perform differently under the three modes of wear examined. The results show that the steel microstructures play the most important role
in determining the wear properties. For relatively low sliding speeds AISI O1 steel performs up to 12 times better than AISI D2 steel in
adhesive wear. For higher sliding speeds, however, this order is reversed due to oxidation taking place on the surface of the AISI D2 steel.
The wear rate of both tool steels in three-body and two-body abrasion wear is proportional to the applied load. In three-body abrasive wear,
AISI D2 exhibits a normalised wear rate about two times lower than the AISI O1 tool steel, and this is due to the presence of the plate-like
hard carbides in its microstructure. Both tool steels perform 3–8 times better in three-body abrasive wear conditions than in two-body
abrasive wear.
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paper up to 2000 gr. The specimens were held against 400 a second type corresponding to Fe7C3, Fig. 2(d). The
and 1000 gr SiC paper, under a range of applied loads from (Fe,Cr)7C3 type carbides are the primary carbides as
3.0 to 16.9 N. The abrasion paper was rotated at 150 rpm confirmed by EDS microanalysis. The Fe7C3 carbides
leading to a sliding velocity of 0.86 m/s. For each applied have formed during tempering and are the small ones in
load the test was stopped after 300 revolutions. The Fig. 2(c).
specimen was cleaned with acetone and weighed in order
to estimate the wear rate. Then the abrasion paper was 3.2. Pin-on-disk
changed and the same specimen was tested again with the
same conditions until a steady state wear rate was reached. The wear rates of the heat treated AISI O1 tool steel
The total sliding distance covered for each specimen was against the Al2O3 ball are presented in Fig. 3(a). Both load
1067.5 m. After testing the specimen surfaces were and sliding speed affect the wear rate, which attains values
examined with an optical and electron microscope in between 0.5!10K11 and 5.0!10K11 m3/m. An increase in
order to identify the wear mechanisms involved. the applied speed up to 0.55 m/s leads to higher wear rates
and after this value the wear rate remains almost constant.
The performance of heat treated AISI D2 tool steel in
3. Results and discussion adhesion wear is very different from that of AISI O1 tool
steel. The wear rates deduced from the pin-on-disk tests are
3.1. Microstructure presented in Fig. 3(b) and fall between 0.5!10K11 and
6.0!10K11 m3/m. Increasing the sliding speed leads to a
The microstructure of the heat treated AISI O1 tool steel pronounced decrease in the wear rate up to a minimum for
is presented in Fig. 2(a). It consists of tempered martensite the sliding speed of 0.6 m/s and then the wear rate increases
with small carbides, presumably Fe3C. These carbides are again due to intense oxidation phenomena. The wear rate
formed from the martensitic matrix during tempering and increased with increasing applied load in the range between
they are evenly distributed within it. The microstructure is 9.8 and 29.4 N. For the applied load of 39.2 N, the wear rate
confirmed by X-ray analysis, Fig. 2(b). followed a different trend, at least in the velocity range
AISI D2 tool steel presents a different microstructure below 0.6 m/s.
than that of AISI O1. Fig. 2(c) represents its microstructure The wear tracks of AISI O1 tool steel, for relatively low
after the heat treatment process. Large primary carbides sliding speeds, show grooves from plastic deformation,
with length from 5 to 20 mm are surrounded by a tempered Fig. 4(a). Large cavities are also present which have been
martensitic matrix containing small carbides. The XRD of formed from the removal of metallic debris. The examin-
the extracted carbides from the heat treated steel shows ation of the wear debris in the optical microscope reveals
apart from the above mentioned (Fe,Cr)7C3 type carbides, mostly metallic pieces with visible grooves from
Fig. 2. (a and c) SEM micrographs of the heat treated AISI O1 and D2 tool steel, respectively. (b and d) XRD of the heat treated AISI O1 tool steel and AISI D2
extracted carbides (radiation Cu Ka).
482 L. Bourithis et al. / Tribology International 39 (2006) 479–489
Fig. 3. (a) Wear rates of the heat treated AISI O1 tool steel measured from the pin-on-disk test. (b) Wear rates of the heat treated AISI D2 tool steel measured
from the pin-on-disk test.
the alumina ball. For higher sliding speeds the pin on disk formed on steels under mild wear conditions where low
tracks are partially oxidized, Fig. 4(b), but the oxide layer temperatures are reached [11–15].
seems to be very thin and semitransparent in the optical From the above discussion it may be concluded that the
microscope. Examination of the wear debris revealed again dominant wear mechanism throughout the entire range of
large metallic flakes with grooved surfaces, Fig. 4(c). experimental conditions applied is plastic deformation–
Further analysis of the wear debris with XRD showed that delamination [16–18]. An oxidation mechanism [11–15]
apart from tempered martensite, an oxide of the Fe2O3 type may also be active, mainly at the higher sliding speed range,
exists, Fig. 4(d). This kind of oxide is usually the first one but it is not the dominant wear mechanism.
Fig. 4. Optical micrographs of pin-on-disk wear tracks of AISI O1 tool steel for applied load 29.4 N and sliding speed (a) 0.30 m/s, (b) 0.75 m/s. (c and d)
Optical micrograph of wear debris, and XRD of wear debris for conditions as in (b) (radiation Cu Ka).
L. Bourithis et al. / Tribology International 39 (2006) 479–489 483
Fig. 5. Optical micrographs of pin-on-disk wear tracks of AISI D2 tool steel for applied load 29.4 N and sliding speed (a) 0.15 m/s, (b) 0.30 m/s, (c) 0.55 m/s
and (d) 0.75 m/s.
The wear tracks of AISI D2 tool steel for the applied load and continuous, and covers almost the entire track, Fig. 5(c).
of 29.4 N throughout the entire sliding speed range are Finally for the highest sliding speed of 0.75 m/s, the entire
presented in Fig. 5. For a sliding speed of 0.15 m/s the wear wear track is covered by a thick oxide layer, Fig. 5(d).
track shows grooves of plastic deformation and some The wear debris from the pin-on-disk experiments were
cavities, Fig. 5(a). As the sliding speed is increased to examined in the optical microscope, Fig. 6. For low applied
0.30 m/s an oxide layer starts to develop but it is very thin sliding speeds, i.e. 0.15–0.30 m/s, the wear debris consisted
and discontinuous, Fig. 5(b). Grooves from plastic defor- of large metallic flakes and a fine dark powder, Fig. 6(a). For
mation are also present in the wear track. For an even higher higher sliding speeds the size of the metallic flakes
sliding speed, 0.55 m/s, the oxide layer becomes thicker decreased and the wear debris consisted primarily of
Fig. 6. Optical micrographs of pin-on-disk wear debris of AISI D2 tool steel for applied load 29.4 N and sliding speed (a) 0.15 m/s and (b) 0.75 m/s.
484 L. Bourithis et al. / Tribology International 39 (2006) 479–489
Fig. 8. Coefficients of friction against Al2O3 ball of the (a) AISI O1 tool steel and (b) AISI D2 tool steel.
L. Bourithis et al. / Tribology International 39 (2006) 479–489 485
Fig. 10. (a and c) SEM micrographs of the wear scars of AISI O1 and D2 specimens, respectively, after the dry sand rubber wheel test for applied load 29.4 N.
(b and d) The same for applied load 98.0 N.
486 L. Bourithis et al. / Tribology International 39 (2006) 479–489
the effect of high stresses, the carbides are broken and 3.4. Pin abrasion tests
removed from the matrix leaving cavities. This wear
mechanism revealed here for the AISI D2 tool steel is The volume loss of the AISI O1 versus the sliding
very similar to the wear mechanism that other investigators distance covered in the case of the two abrasive papers,
observed for metal matrix composites in three-body 1000 and 400 gr, respectively, are presented in Fig. 11(a)
abrasion wear [27,28]. and (b). For every applied load the volume loss of material
For comparing the performance of the tool steels is proportional to the sliding distance covered on the
examined in low stress three-body abrasion wear, the abrasive media. This is consistent with the linear law of
normalised wear rate, k 0 , was calculated. This is defined Archard’s theory [21,29]. Accordingly, a constant wear rate
from Archard’s linear law [21,29] according to Eq. (1) for every applied load may be calculated and is presented in
Fig. 12(a) and (b). Similar conclusions can be made for the
k V AISI D2 tool steel in Fig. 11(c) and (d), where the volume
VZ FS or Z k0F (1)
3H S loss of the steel with respect to sliding distance is reported.
The constant wear rates calculated are presented also in
where: V is the volume loss of material in m3, H is the Fig. 12(a) and (b). For both tool steels the wear rate
hardness of the material in Pa, F is the applied load in N, S is increases linearly with the applied load for the conditions
the sliding distance covered in m and k is the abrasive examined in this work. The normalised wear rates for both
coefficient. The ratio V/S is defined as ‘wear rate’ and is tool steels calculated with the least square linear fit method
Fig. 11. Volume loss versus sliding distance of heat treated AISI O1 and D2 tool steel worn against SiC abrasion paper. (a and c) 1000 gr and (b and d) 400 gr.
L. Bourithis et al. / Tribology International 39 (2006) 479–489 487
Fig. 12. Wear rate versus applied load graphs of the heat treated AISI O1 and D2 tool steels against SiC abrasion paper (a) 1000 gr and (b) 400 gr.
are summarised in Table 4. It is clear that the normalised clearly seen there is no crack formation or fracture of the
wear rate is more than two times higher for the 400 gr than carbides under all the applied conditions. Cross-sections of
for the 1000 gr abrasion paper and this is valid for both tool the abraded surfaces confirmed the absence of cracks in the
steels. This may be explained considering the true stresses subsurface regions. The abraded surfaces show continuous
which are developed between the SiC particles of the grooves, which traverse both the martensitic matrix and the
abrasion paper and the abraded metal. As the grit size primary carbides. As in the case of three-body abrasive
number becomes smaller, the abrasive particles become wear, the relative hardness of the abrasive media, SiC, can
larger so that the number of SiC particles per cm2 of area is be compared with the material under study, Table 3. The
smaller and the stresses that are developed for the same hardness ratios between the abrasive material and the
applied load are higher. Wang et al.[30] have discovered abraded microconstituents (matrix and carbides), are greater
that the number of particle contacts in two-body abrasive than 1.7 [24–26], which means that SiC particles would find
wear with abrasive paper is inversely proportional to the no difficulty in cutting both the carbides and the metallic
square of the mean size of abrasive particles. Early studies matrix. These findings are in contrast with the work of
have found that the grit size affects drastically the wear rate Cheng et al. [39] who stated that crack nucleation, carbide
when it is larger than 180 gr [31–36], as it is in our case. fracture and exfoliation are the primary factors affecting the
Another point to mention is the severity of two-body wear resistance of AISI D2 tool steel in two-body abrasive
abrasive wear in comparison with three-body abrasive wear. wear. This difference may be attributed to the fact that in the
The results from this work showed that the normalised wear present work AISI D2 tool steel was tempered in order to
rate is 3–8 times greater in the two-body than in three-body develop good fracture toughness and this prevented the
abrasive wear. Rabinowicz et al. [29] have pointed out that nucleation of cracks. In addition, the SiC particle size was
during three-body abrasive wear the particles are abrading smaller in our case leading to lower stresses, and as it has
the surface for approximately 10% of the abrasion time and
been discussed earlier, to smaller penetration depths,
this contributes to a lower wear rate compared with two-
making difficult the cracking and the pullout of the carbides
body abrasive wear.
[40].
The abraded surfaces of AISI O1 tool steel for 1000 and
Comparing the tool steels examined, Table 4, the AISI
400 gr SiC papers are presented in Fig. 13(a) and (b),
D2 steel performs more than two times better than the AISI
respectively. Under the same applied load the grooves on
O1 steel even though they are heat treated to the same
the surface abraded with 400 gr abrasive paper are deeper
hardness. The superior performance of AISI D2 steel is due
than that abraded with 1000 gr. This is in agreement with
to the blocky carbides in its microstructure, which enhance
the statement in a previous paragraph that smaller grit size
the wear resistance.
numbers lead to higher stresses developed between abrasive
particles and abraded material. Generally speaking, only
grooves from plastic deformation are observed on the Table 4
abraded surfaces, cracks or metallic ribbons ready to detach Normalised wear rates (m3/Nm) of AISI O1 and D2 tool steels from the pin
abrasion tests
were not detected under these wear conditions. The wear
mechanism for all the conditions is a mixture of ploughing AISI O1 AISI D2
and cutting [37,38]. Fig. 13(c) and (d) presents SEM 1000 gr SiC 400 gr SiC 1000 gr SiC 400 gr SiC
micrographs of the abraded surfaces of AISI D2 tool for the
5.04!10 K13
13.40!10 K13
2.95!10 K13
8.02!10K13
same conditions as in the case of AISI O1 tool steel. As it is
488 L. Bourithis et al. / Tribology International 39 (2006) 479–489
Fig. 13. (a and c) SEM micrographs of the worn surface of the AISI O1 and D2 tool steel specimens, respectively, after two-body abrasion wear with SiC paper
1000 gr (c and d) The same for 400 gr (applied load 11.3 N).
[15] Quinn TFJ, Sullivan JL, Rowson DM. Origins and development of [29] Rabinowicz E, Dunn LA, Russell PG. A study of abrasive wear under
oxidational wear at low ambient temperatures. Wear 1984;94:175–91. three-body conditions. Wear 1961;4:345–55.
[16] Suh NP. The delamination theory of wear. Wear 1973;25:111–24. [30] Wang AG, Hutchings IM. The number of particle contacts in two-
[17] Suh NP. An overview of the delamination theory of wear. Wear 1977; body abrasive wear of metals by coated abrasive papers. Wear 1989;
44:1–16. 129:23–35.
[18] Jahanmir S, Suh NP. Surface topography and integrity effects on [31] Rabinowicz E, Mutis A. Effect of abrasive particle size on wear. Wear
sliding wear. Wear 1977;44:87–99. 1965;8:381–90.
[19] Lim SC, Ashby MF. Wear-mechanism maps. Acta Metall 1987;35(1): [32] Nathan GK, Jones WJD. The empirical relationship between abrasive
1–24. wear and the applied conditions. Wear 1966;9:300–9.
[20] Lim SC, Ashby MF, Brunton JH. Wear-rate transitions and their [33] Larsen-Badse J. Influence of grit diameter and specimen size on wear
relationship to wear mechanisms. Acta Metall 1987;35(6):1343–8. during sliding abrasion. Wear 1968;12:35–53.
[21] Archard JF. Contact and rubbing of flat surfaces. J Appl Phys 1953; [34] Larsen-Badse J. Some effects of specimen size on abrasive wear.
24(8):981–8.
Wear 1972;19:27–35.
[22] Ma X, Liu R, Li DY. Abrasion wear behavior of D2 tool steel with
[35] Moore MA. A review to two-body abrasive wear. Wear 1974;27:
respect to load and sliding speed under dry sand/rubber wheel
1–17.
abrasion condition. Wear 2000;241:79–85.
[36] Sin H, Saka N, Suh NP. Abrasive wear mechanisms and the grit size
[23] Gore GJ, Gates JD. Effect of hardness on three very different forms of
effect. Wear 1979;55:163–90.
wear. Wear 1997;203–204:544–63.
[37] Kayaba T, Hokkirigawa K, Kato K. Analysis of the abrasive wear
[24] Khruschov MM. Principles of abrasive wear. Wear 1974;28:69–88.
[25] Richardson RCD. The wear of metals by hard abrasives. Wear 1967; mechanism by successive observations of wear processes in a
10:291–309. scanning electron microscope. Wear 1986;110:419–30.
[26] Richardson RCD. The wear of metals by relatively soft abrasives. [38] Hokkirigawa K, Kato K. An experimental and theoretical investi-
Wear 1968;11:245–75. gation of ploughing, cutting and wedge formation during abrasive
[27] Deuis RL, Subramanian C, Yellup JM. Three-body abrasive wear of wear. Tribol Int 1988;21(1):51–7.
composite coatings in dry and wet environments. Wear 1998;214:112–30. [39] Cheng LC, Wu TB, Hu CT. The role of microstructural features in
[28] Pagounis E, Lindroos VK. Processing and properties of particulate abrasive wear of a D-2 tool steel. J Mater Sci 1988;23:1610–4.
reinforced steel matrix composites. Mater Sci Eng A 1998;246: [40] Deuis RL, Subramanina C, Yellup JM. Abrasive wear of aluminium
221–34. composites-a review. Wear 1996;201:132–44.