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IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO.

3, MARCH 2010 813

Energy Harvesting From Piezoelectric Materials


Fully Integrated in Footwear
J. G. Rocha, L. M. Gonçalves, P. F. Rocha, M. P. Silva, and S. Lanceros-Méndez

Abstract—In the last few years, there has been an increasing TABLE I
demand for low-power and portable-energy sources due to the A PPROXIMATED E NERGY C ONSUMPTION FOR 1 h OF
O PERATION OF S OME P ORTABLE D EVICES
development and mass consumption of portable electronic devices.
Furthermore, the portable-energy sources must be associated with
environmental issues and imposed regulations. These demands
support research in the areas of portable-energy generation meth-
ods. In this scope, piezoelectric materials become a strong can-
didate for energy generation and storage in future applications.
This paper describes the use of piezoelectric polymers in order to
harvest energy from people walking and the fabrication of a shoe
capable of generating and accumulating the energy. In this scope,
electroactive β-polyvinylidene fluoride used as energy harvesting
element was introduced into a bicolor sole prepared by injection,
together with the electronics needed to increase energy transfer
and storage efficiency. An electrostatic generator was also included
in order to increase energy harvesting.
Index Terms—Microgenerator, piezoelectric generator, shoe
energy generator.

I. I NTRODUCTION

A S LOW-POWER and wearable electronic devices are


more and more present in our everyday life, there is a
growing need for the delivery of power to different points of
the human body.
Table I shows the approximate energy consumption for 1 h
of operation of some portable devices that can be considered as
possible applications of the energy generated by our system.
Another interesting application is a posture monitoring sys- Fig. 1. Location of the sensing modules in a suit [1].
tem of the human body presented by Silva et al. [1]. The posture
monitoring system is composed of five sensing modules, i.e.,
The delivery of power to different points of the human body
two located on upper members, two on lower members, and
can be performed by batteries and wires, which incentivizes the
one on the spine, as shown in Fig. 1. The detection algorithm
development of more efficient, light, and long-lasting batteries.
uses the gravitational force to detect inclination and the earth
It can also stimulate the research in the field of energy
magnetic field to measure the rotation of the body about the axis
generation, in order to produce energy close to the point in
perpendicular to the gravity field. The total energy consumption
which it will be used. In this case, energy storage might not
of the suit is near 20 J per operating hour.
be necessary at all.
As power requirements of most modern electronic portable
Manuscript received July 31, 2008; revised July 16, 2009. First published devices are decreasing, it becomes possible to use the energy
August 7, 2009; current version published February 10, 2010. This work was
supported in part by the Portuguese Foundation for Science and Technology
harvesting from human body activity, in order to power these
(FCT) under Grants POCI/CTM/59425/2004 and PTDC/CTM/69362/2006 and devices. Table II compares the main characteristics of several
in part by the company Atlanta-Steps. portable power sources [2], [3].
J. G. Rocha and L. M. Gonçalves are with the Department of Industrial
Electronics, University of Minho, Azurem Campus, 4800-058 Guimarães,
Portugal (e-mail: gerardo@dei.uminho.pt; lgoncalves@dei.uminho.pt).
P. F. Rocha, M. P. Silva, and S. Lanceros-Méndez are with the Department II. M OTIVATION
of Physics, University of Minho, Gualtar Campus, 4710-057 Braga, Portugal
(e-mail: rochapfa@gmail.com; marco.uminho@gmail.com; lanceros@fisica. As shown in Table II, vibration-based devices compare
uminho.pt). well with other potential energy-scavenging sources, includ-
Color versions of one or more of the figures in this paper are available online
at http://ieeexplore.ieee.org. ing batteries, fuel cells, and solar, temperature, and pressure
Digital Object Identifier 10.1109/TIE.2009.2028360 devices.

0278-0046/$26.00 © 2010 IEEE


814 IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO. 3, MARCH 2010

TABLE II
C OMPARISON B ETWEEN P ORTABLE -E NERGY AND P OWER S OURCES [3]

where K is a constant that depends on the number of turns of


the coil, their length, area, and shape, and the magnetic field
intensity. A similar relationship exists between the mechanical
force on the coil and the current through it

F = Ki. (2)

Notice that the factor K in (1) and (2) needs to be identi-


cal for energy conservation. Compact systems for low-power
applications based on small magnets have been demonstrated,
Fig. 2. Schematic diagram of a vibration scavenger [8]. including capacitive energy storage components [9], [10].

Researchers have successfully built and tested vibration-


based generators using three types of electromechanical trans- B. Electrostatic Generators
ducers: electromagnetic [4], electrostatic [5], and piezoelectric An electrostatic generator consists of a capacitor whose value
[6], [7]. All of them are based on the same principle: To convert changes as a function of the displacement. The electrical current
mechanical energy into electrical energy, one should be able is given by [8]
to realize a movement between the mechanical parts of the
generator (e.g., the rotor and the stator of a macroscopic gener- dC(z) dV
I = Vo + C(z) (3)
ator). Vibrations consist, however, of a traveling wave in or on dt dt
a solid material, and it is often not possible to find a relative where V and Vo represent the voltages across the charged
movement within the reach of a small generator. Therefore, capacitor and its initial value, respectively. The first term at
one has to couple the vibration movement to the generator the right side of (3) represents the electromechanical coupling,
by means of the inertia of a seismic mass. Fig. 2 shows a while the second term describes the electrical behavior of
seismic mass connected to an energy generator. The mass is the capacitor. Notice that the electromechanical coupling is
also connected to the outside world by means of a suspension/ enhanced when the capacitor is biased with a voltage Vo .
damping system. This polarization of the capacitor can either be reached by
preloading the capacitor [11], by using electrets [12], or by
A. Electromagnetic Generators using piezoelectric elements, which is the main innovation of
this paper and will be analyzed in the following sections.
In electromagnetic generators, an electromotive force (emf)
is induced across a coil if the magnetic flux coupled to the
inductor changes as a function of time. The relationship be- C. Piezoelectric Generators
tween this emf and the displacement of the mass depends on There are two types of piezoelectric signals that can be used
the design of the system. An expression that relates the emf for technological applications: the direct piezoelectric effect
with the displacement (z) can be written as [8] that describes the ability of a given material to transform
mechanical strain into electrical signals and the converse effect,
dz which is the ability to convert an applied electrical solicita-
emf = K (1)
dt tion into mechanical energy. The direct piezoelectric effect is
ROCHA et al.: ENERGY HARVESTING FROM PIEZOELECTRIC MATERIALS FULLY INTEGRATED IN FOOTWEAR 815

TABLE III energy will be demonstrated through the construction and test
E NERGY S TORAGE D ENSITY C OMPARISON
of a sole prototype. This paper shows an integrated way to
include the piezoelectric material into a sole, its geometry and
harvesting of the energy. In the next sections, the different
steps: development and preparation of the electroactive mater-
ial, positioning of the material into the sole of the shoe, readout
electronics design, and preliminary test results of the system
will be presented.
more suitable for sensor applications, whereas the converse
piezoelectric effect is most of the times required for actuator A. Polymer Preparation
applications [13]. Therefore, it can be stated that a material The piezoelectric films used for the energy generation are
is called piezoelectric when it shows the ability to transform constituted by a polymeric material coated in both sides by a
electrical into mechanical energy and, conversely, mechanical conducting material, which form the electrodes. The polymeric
into electrical energy. material is based on the polyvinylidene fluoride (PVDF) poly-
Mathematically, the piezoelectric charge (strain) coefficients mer in its electroactive (β) phase. It can be processed in the
predict, for small stress (or strain) levels, the surface charge form of a film by extrusion and injection or from the solution,
density originated by external stress. In the charge mode and usually in the nonelectroactive α phase. In order to obtain the
under conditions approaching a short circuit, the generated electroactive β phase, the α phase films must be submitted to
charge density is given by mechanical stretching at temperatures below 100 ◦ C and with
Q a stretching ratio (ratio between the final and the initial lengths
D= = d3n Fn , n = 1, 2, 3 (4) of the sample) from 4 to 7. After getting the electroactive β
A
phase, the material must be activated by poling. This is done
where D is the surface charge density developed, Q is the by subjecting the film to an electric field with amplitude larger
charge developed, A is the conductive electrode area, d3n is than 60 MV/m along the thickness direction [20], [21].
the appropriate piezoelectric coefficient for the axis of applied The main advantages of using polymeric films instead of
stress or strain, and Xn is the stress applied in the relevant piezoceramics or single crystals are that polymer films are
direction. The mechanical axis n of the applied stress (or flexible and can be fabricated in the desired shapes and sizes
strain), by convention, is 1 for length (or stretch) direction, 2 for through simple processing processes. Furthermore, electroac-
width (or transverse) direction, and 3 for thickness direction. tive polymers are very cheap in comparison with their ceramic
In the voltage mode, the emf is given by and single crystal counterparts, making them more suitable for
mass production systems and devices.
emf = g3n Fn t, n = 1, 2, 3 (5) For this paper, high-performance films, prepared by a method
patented by us have been used [20], [21]. Unoriented films
where g3n is the appropriate voltage piezoelectric coefficient exclusively in the β phase were obtained from the crystalliza-
for the axis of applied stress and t is the film thickness [14]. tion of PVDF from a solution with N,N-Dimethyl Formamide
Table III compares the three generator principles on the basis or Dimethyl Acetamide at temperatures below 70 ◦ C. The
of two energy densities [2], [3]. Practical values represent what electromechanical properties of the film were improved by a
is currently achievable with standard materials and processes, treatment that consists of pressing, stretching, and poling at a
while aggressive values represent what is theoretically possi- high temperature [20]. A final step of stretching at a temperature
ble. In addition to energy density, three further considerations around 80 ◦ C results in oriented films, which further increases
affect transducer technology selection: Electrostatic transducers the material performance. The final film thickness ranged from
are more readily implemented in standard micromachining ∼20 to 60 μm.
processes, electrostatic transducers require a separate voltage
source (such as a battery) to begin the conversion cycle, and
B. Electrode Deposition
electromagnetic transducers typically output ac voltages well
below 1 V in magnitude. Once the material is prepared, electrodes are deposited
Based on the data presented in Table III and on the con- on both sides either by magnetron sputtering or by thermal
straints of the application, we decided to focus our work on evaporation. Silver and aluminum has been used as electrode
both piezoelectric and electrostatic generators. materials for the present tests.
The thermal deposition system consists in a vacuum chamber
where the pressure reaches 10−6 mbar. An evaporation boat
III. S YSTEM D ESCRIPTION
containing the material to be evaporated is placed in its interior.
The idea to use footwear to produce energy has been pursued The boat is heated by means of an electric current ranging
for a long time. Several patents based either on electrical, between 100 and 200 A. At the top of the chamber, the
mechanical, or piezoelectric systems [15]–[19] have been reg- β-PVDF film, where the deposition is performed, and two mass
istered. In the following sections, the basics on piezoelectric sensors are placed. In order to deposit the electrode on the thin
polymers will be discussed, and their suitability for harvesting β-PVDF polymer, the electrical power applied to the boat must
816 IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO. 3, MARCH 2010

Fig. 5. Voltage change for a single impact applied to the sample.


Fig. 3. First prototype of the energy generator. Two piezoelectric polymer
films above the sole.

Fig. 6. Connection of the circuit board to the piezoelectric material.


Fig. 4. Experimental setup for material testing.
After the placement of the piezoelectric films into the soles,
increase slowly. When the temperature of evaporation of the preliminary tests are performed by simple jumps. Fig. 5 shows
silver is reached, the mass sensors will indicate a variation of the voltage change when a single jump is applied to a 28-μm-
the mass attached to them—proportional to the film thickness. thick PVDF sample.
At this point, the electrical power must be kept constant. When
the mass sensors indicate that the electrode thickness is equal
to 30 nm, the power supply is switched off, and the deposition E. Electronic Circuit
of the electrode is complete. The second electrode is deposited In order to maximize the energy transfer to a charge or to
by turning upside down the β-PVDF film and repeating the a battery, in the case of energy storage, a rectifying circuit
previous procedure. is necessary in order to obtain a single polarity voltage. This
circuit consists of a rectifier bridge based on four Schottky
C. Positioning of the Piezoelectric Material barrier diodes. These diodes have a forward bias voltage
drop near 0.33 V, which is an advantage for this applica-
As piezoelectricity is a dynamic process, the material should tion, as it means that, for potential values larger than 0.66 V
be positioned in places were larger and more variable pressure (two diodes), it is possible to use the full wave configura-
is exerted during walking. Those places are shown in Fig. 3, tion. With p-n junction diodes, this value would be approxi-
together with the first prototype. In this prototype, single layers mately 1.4 V.
of electroactive material were placed on the top of the sole. The circuit board of the full wave rectifier is then connected
to the piezoelectric element placed in the sole, giving origin to
the first prototype 3 (Fig. 6). The whole system is implemented
D. Performance Tests
into a shoe (Fig. 7), and further tests are performed in real
As a dynamic process, the material reacts to pressure varia- walking situations (Fig. 8).
tions, and the generated voltage changes when the pressure on Fig. 8 shows the values of the rectified signal, for a single-
it increases or decreases. Fig. 4 shows the experimental setup step situation.
developed for testing the material performance: A shaker ap- Once the system was tested and verified, the circuit board
plies force to the piezoelectric material at different frequencies was minimized in order to be fully integrated within a real shoe.
and forces. The voltage is recorded on the digital oscilloscope, Fig. 9 shows a photograph of the final circuit. As can be seen,
and the energy is stored in a battery. its dimensions are less than a 1-cent Euro coin.
ROCHA et al.: ENERGY HARVESTING FROM PIEZOELECTRIC MATERIALS FULLY INTEGRATED IN FOOTWEAR 817

Fig. 10. Electrostatic generator placed below the sole for test purposes.

Fig. 7. Sole and electronic circuit placed in the shoe.

Fig. 11. Schematic diagram of the connections between the piezoelectric film
and the electrostatic generators.

Fig. 8. Voltage versus time after rectification for a single impact applied to
the generator.

Fig. 12. Cross section of a thin-film lithium battery.

electrostatic generator exceeds that of the battery, the charge


of the first is transferred to the second.
Fig. 11 shows the schematic diagram of the electrical con-
nections between the piezoelectric element, the electrostatic
Fig. 9. Circuit implemented in the final prototype shown on a 1-cent Euro generator, and the load.
coin.

F. Addition of an Electrostatic Generator G. Energy Storage


In order to increase the power generation, an electrostatic A thin-film rechargeable lithium battery can be used to
generator was also coupled to the sole. It consists basically in store the energy generated. All-solid-state lithium batteries,
two metallic plates separated by a flexible dielectric material fabricated entirely of thin-film components, achieve capacities
(foam), which changes its thickness every time a pressure is over 35 μA · h/cm2 , with current densities above 200 μA/cm2 ,
applied, i.e., when the person puts his/her foot on the floor. in less than 10 μm of thickness. A layered structure, as shown
Fig. 10 shows a photograph of the test setup. The steady-state in Fig. 12, is being prepared to implement the proposed battery.
capacitance of this electrostatic generator is 20 pF. When the On top of a polymeric flexible substrate where the metal current
person steps with a foot on the floor, the capacitance increases collector was previously prepared (a platinum layer provides
about two times, which means that the voltage decreases to external cathode connection), a LiCoO2 cathode is deposited,
one-half. At this time, the piezoelectric voltage is higher than followed by a Li3 PO4 (LiPON) electrolyte, both by reactive
the one at the electrostatic generator terminals; therefore, its sputtering. The Li cathode is then deposited by thermal evap-
capacitance will be charged. When the person raises the foot, oration. The anode current collector is deposited on top of the
the capacitance of the electrostatic generator decreases, and the battery, providing the external connection to the anode. The
voltage increases. In this case, the load is an energy storage final step is the deposition and patterning of a parylene or Si3 N4
device (battery of 3 V); therefore, when the voltage of the protective coating.
818 IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 57, NO. 3, MARCH 2010

Fig. 15. Voltage generated by a person walking with and without the electro-
static generator.

Fig. 13. Performance test. A handspike system was used in order to apply
constant pressure impulses to the sole.

Fig. 16. Energy generated in 1 h by a person applying four steps per second,
when the generator is coupled to a resistive load.
Fig. 14. Voltage generated by a person walking.
Fig. 15 shows the whole system (piezoelectric + electro-
IV. E XPERIMENTAL R ESULTS
static) performance. It is possible to see that the output peek
After testing the foils and the readout electronics, the system voltage value is greater in the case that uses the electrostatic
was introduced in a bicolor sole of a shoe prepared by injection generator. Moreover, its time response is slower, which means
molding (Fig. 13). It is important to notice that, during this that the associated piezoelectric–electrostatic generator sup-
process, temperatures higher than 160 ◦ C are reached at certain plies energy to the load during a long time interval.
points of the sole. This process did not affect the performance Fig 16 shows the average energy generated in 1 h, by a
of the electroactive setup. running person (four steps per second), when the generator is
The power generated by the PVDF foil within the shoes coupled to a resistive load.
ranges from tens to hundreds of milliwatts, depending on the When we compare the results in Fig. 16 with the data of
area, the placement, the geometry, and the numbers of foils. It is Table I, the conclusion is obvious: The amount of energy gener-
particularly important that the system allows stretching and not ated is less than that needed by the described applications. This
just pressing of the foil, as the longitudinal electromechanical means that this work is far from being concluded. Instead, some
coupling of PVDF (k31) is more efficient that the k33 mode improvements must be done, by increasing the thickness of the
[14]. In this way, the PVDF foils are more efficient in the piezoelectric polymer film, by placing four or six generators
electromechanical conversion when they are introduced within in each sole, and by using films with increased properties with
the sole in the form of a bimorph. A bimorph converts the foot respect to piezoelectricity and elasticity.
pressure toward the bottom into a combination of pressing and
stretching of the PVDF films, making use, in this way, of the
V. C ONCLUSION
k33 and k31 electromechanical conversion.
Important for the generation of energy is also the number of From the several methods available to integrate energy-
polymer layers in each piezoelectric element. Fig. 14 shows the generating elements harvesting human energy, piezoelectric
voltage generated by a person walking. materials associated with electrostatic generators seem to be
The voltage generated in a system with two superimposed one of the most promising elements. In particular, electroactive
layers of piezoelectric material was also tested. The generated polymers are particularly interesting due to their low cost, flex-
voltage was approximately double that of the one generated by ibility, and easy integration into elements such as clothes and
the single-layer system. shoes. In this paper, electroactive polymers based on β-PVDF
ROCHA et al.: ENERGY HARVESTING FROM PIEZOELECTRIC MATERIALS FULLY INTEGRATED IN FOOTWEAR 819

have been used in order to fabricate an energy-harvesting J. G. Rocha received the B.Sc., M.Sc., and Ph.D.
system fully integrated into the sole of a shoe. Conventional degrees in industrial electronics engineering from the
University of Minho, Guimarães, Portugal, in 1995,
methods were used in order to fabricate the sole, with no 1999, and 2004, respectively.
modification of the industrial production process. Through Since 2004, he has been an Assistant Professor
the simple configuration and electronics, energy harvesting is in the Department of Industrial Electronics, Uni-
versity of Minho, where he is involved in research
possible. In order to get energy values suitable for the func- on sensors and sensor interfaces. He was a Visiting
tioning of electronic appliances, improvements in the material, Researcher at Delft University of Technology, Delft,
in order to improve electromechanical conversion, and in the The Netherlands, in 2001–2002.
readout electronics, in order to optimize the energy transfer,
and the precise determination of the geometry and number of
the piezoelectric generators should be performed. L. M. Gonçalves received the B.S. degree and the
M.Sc. and Ph.D. degrees in electronics engineering
from the University of Minho, Guimarães, Portugal,
R EFERENCES in 1993, 1999, and 2008, respectively.
[1] H. R. Silva, J. A. Afonso, P. C. Morim, P. M. Oliveira, J. H. Correia, From 1993 to 2002, he conducted research on
and L. A. Rocha, “Wireless hydrotherapy smart-suit network for posture embedded systems and electronics at Idite-Minho,
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[2] S. Roundy, P. K. Wright, and J. Rabaey, Energy Scavenging for Wire- between universities and industry. Since 2002, he
less Sensor Networks With Special Focus on Vibrations. Norwell, MA: has been teaching in the Department of Industrial
Kluwer, 2003. Electronics, University of Minho, where he became
[3] S. Roundy, E. S. Leland, J. Baker, E. Carleton, E. Reilly, E. Lai, B. Otis, an Assistant Professor in 2008. There, he started a
J. M. Rabaey, and P. K. Wright, “Improving power output for vibration- new laboratory for thermoelectric thin-film deposition, characterization, and
based energy scavengers,” Pervasive Comput., vol. 4, no. 1, pp. 28–36, patterning, in collaboration with the Department of Physics. He is involved in
Jan.–Mar. 2005. research on thermoelectric materials for on-chip cooling and energy harvesting.
[4] M. El-hami, P. Glynne-Jones, M. White, M. Hill, S. Beeby, E. James, His professional interests are thermoelectrics, microfabrication technology, and
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[5] M. Miyazaki, H. Tanaka, G. Ono, T. Nagano, N. Ohkubo,
T. Kawahara, and K. Yano, “Electric-energy generation using variable- P. F. Rocha received the B.E. degree in industrial
capacitive resonator for power-free LSI,” in Proc. ISLPED, 2003, electronics engineering and the M.Sc. degree from
pp. 193–198. the University of Minho, Guimarães, Portugal, in
[6] C. Keawboonchuay and T. G. Engel, “Maximum power generation in a 2006 and 2007, respectively.
piezoelectric pulse generator,” IEEE Trans. Plasma Sci., vol. 31, no. 1, Since 2006, he has been a Researcher in the De-
pp. 123–128, Feb. 2003. partment of Physics, University of Minho, Braga,
[7] J. Yang, Z. Chen, and Y. Hu, “An exact analysis of a rectangular Portugal, where he is involved in research on sensors
plate piezoelectric generator,” IEEE Trans. Ultrason., Ferroelectr., Freq. and actuators.
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[8] M. S. M. Soliman, E. F. El-Saadany, and R. R. Mansour, “Electromagnetic
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Electron., vol. 4, Jul. 9–13, 2006, pp. 2747–2753.
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Ind. Electron., vol. 49, no. 3, pp. 640–648, Jun. 2002. M. P. Silva received the M.S. degree in materials sci-
[10] J. B. Wang, W. Y. Wang, G. W. Jewell, and D. Howe, “Design of a ence and engineering from the University of Minho,
miniature permanent-magnet generator and energy storage system,” IEEE Guimarães, Portugal, in 2007.
Trans. Ind. Electron., vol. 52, no. 5, pp. 1383–1390, Oct. 2005. Following graduation, he was with the Institute
[11] P. D. Mitcheson, T. C. Green, E. M. Yeatman, and A. S. Holmes, of Physical Engineering, Brno University of Tech-
“Architectures for vibration-driven micropower generators,” J. Micro- nology, Brno, Czech Republic, for six months. Cur-
electromech. Syst., vol. 13, no. 3, pp. 429–440, Jun. 2004. rently, he is working on electroactive materials as
[12] T. Sterken, P. Fiorini, K. Baert, R. Puers, and G. Borghs, “An a member of the Center of Physics, Department
electret-based electrostatic micro-generator,” in Proc. Transducers, of Physics, University of Minho. He is involved in
2003, pp. 1291–1294. investigations on new processing techniques for elec-
[13] J. Fraden, Handbook for Modern Sensors. New York: AIP, 1997. troactive polymers and polymer-based composites
[14] Piezo Film Sensors Technical Manual, Meas. Specialties, Inc., for sensor and actuator applications.
Norristown, PA, 1999.
[15] N. Lakic, “Inflatable boot liner with electrical generator and heater,”
U.S. Patent 4 845 338, Jul. 4, 1989.
[16] J. M. Donelan, A. D. Kuo, J. A. Hoffer, Q. Li, and D. Weber, “Meth- S. Lanceros-Méndez received the B.Sc. degree in
ods and apparatus for harvesting biomechanical energy,” WO200701678, physics from the University of the Basque Country,
Feb. 15, 2007. Leioa, Spain, in 1991, and the Ph.D. degree from the
[17] Y. Osawa, “Portable walking generator,” JP2004 096 980, Mar. 25, 2004. Institute of Physics, Julius-Maximilians-Universität,
[18] F. Bradbury, “Footwear incorporating piezoelectric energy harvesting Würzburg, Germany, in 1996.
systems,” WO200 6014 622, Sep. 2, 2006. He was a Research Scholar at Montana State
[19] E. R. Pelrine and D. R. Kornbluh, “Biologically powered electroactive University, Bozeman, from 1996 to 1998. Since
polymer generators,” WO0165615, Jul. 9, 2001. September 1998, he has been with the Department of
[20] V. Sencadas, R. Gregorio Filho, and S. Lanceros-Mendez, “Processing Physics, University of Minho, Braga, Portugal, as an
and characterization of a novel nonporous poly(vinilidene fluoride) films Associate Professor, where he is involved in experi-
in the β phase,” J. Non-Cryst. Solids, vol. 352, no. 21/22, pp. 2226–2229, mental investigations in the area of condensed matter
Jul. 2006. physics and its applications. He was a Visiting Researcher at the A.F. Ioffe
[21] S. Lanceros-Mendez, V. Sencadas, and R. Gregorio Filho, “A new elec- Physico-Technical Institute, St. Petersburg, Russia, in 1995, the University of
troactive beta PVDF and method for preparing it,” Patent PT103 318, Porto, Porto, Portugal, in 1996, The Pennsylvania State University, University
Jul. 19, 2006. Park, in 2007, and the University of Potsdam, Potsdam, Germany, in 2008.

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