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Ric 04 Pinnacle Aa SMPL Prep PDF
Ric 04 Pinnacle Aa SMPL Prep PDF
Riccardo Magarini
Budapest 2016, October 17th
• Fast
◦ 3 – 5” per determination
• Low analytical costs
• Easy to use
• Single element technique
M* M+ + e_ Ionization
Mo M* Excitation
MA Mo + Ao Atomization
Solution Solid Vaporization
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PerkinElmer PinAAcle platform
• EDL lamps
Intuitive Stacked
Syngistix + flame/furnace design
Windows 7
Cutting-edge
fiber optics
Removable Burner
Assembly
Eight-lamps
mount
TubeView color
furnace camera
Graphite Small
Furnace flame/furnace AA
AS 900 furnace Innovative new footprint
auto-sampler mixing chamber
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The PinAAcle™ 500 Flame AA Spectrometer
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Optical System with Fiber Optics
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Unique !
PinAAcle: Unique innovAAtive fiber optics design!
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PinAAcle: Unique innovAAtive fiber optics design!
Light from
lamp Conventional “slit”
shapes the beam.
Lost light intensity
Light from Fiber optics reshaped
lamp captured from circular to “slit”
by fiber optics shape, transmitting ALL
light.
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Customized Solid-State Detector
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Electrodeless Discharge Lamps
HCL EDL
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Lower cost of ownership; Better DLs.
Flame Gas Flow Optimization
User Benefits:
Element specific
Optimized results
Ease of use
Reproducible
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Unique !
Burner Head Optimization – Burner Alignment (Pin900)
User Benefits:
Easy to use – can
be recalled when
stored
Optimized results
Convenience
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PinAAcle 900, Stacked Atomizers
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Graphite Furnace - Atomic Absorption (GF-AAS)
0.06
• Low DLs (g/L) for many elements
AA-BG
Ab so rb an ce
• Slower than flame (45 - 90 seconds) 0.04 BG
Chromium, 10 µL of 1 µg/L
Clean
Atomization
Temp
Pyrolysis
Dry
Dry 1 2
Time
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.
Patented Transversely Heated Graphite Atomizer
Atomization Temperatures
HGA /THGA furnaces
HGA °C THGA °C
As 2300 2000
Al 2500 2300
B 2650 2500
Ba 2550 2300
Cu 2300 2000
Cr 2500 2300
Fe 2400 2100
Ni 2500 2300
Pb 1800 1600
Si 2650 2350
Sn 2300 2200
Ti 2650 2500
Temperature profiles for HGA and THGA tubes V 2650 2400
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.
GF technology improvements: temperature distribution
HGA THGA
Massman-style atomizer Transverse-heated atomizer
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.
Bkgd. Correction: Continuum vs Zeeman
(Se in fish tissue)
background
discrimination
- No energy loss
◦ SSD detector Detector
Modulation Magnet SSD
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Zeeman bkgd. correction
19
.
Longitudinal Zeeman bkgd. correction
20
.
Stabilized Temperature Platform Furnace
Parameter /Feature Benefit Proof Statements
Platform atomization
Integrated platforms Isothermal atomization Gas-phase temperature
THGA (with & without Ease of use (no changing measurements (CARS)
endcaps) platforms) Reduced or eliminated chemical
Integrated platform HGA Reproducible & reliable data interferences
tubes All elements from platform Characteristic mass (m0) stability
Uniform pyrolytic graphite Longer tube lifetimes (corrosive Lifetime studies
coatings samples) Scientific publications
Rapid, controlled furnace heating Reliable day-to-day performance Temperature measurements
Independent of line voltage, tube Refractory element performance
parameters (i.e., resistance) with different voltages
True Temperature Control (TTC)
Integrated Absorbance More robust measurements Peak area vs peak height studies
(peak area) measurements Reliable day-to-day performance
Independent of matrix changes
Zeeman-effect Background No user selection required Interference studies
Correction Wavelength independent method Scientific publications
Better detection limits
1600 oC
1400 oC
0
Time (sec) 5.00
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.
TubeView Furnace Camera
• Color TubeView
Furnace Camera
• Probe Depth
Alignment
• Drying and Pyrolysis
monitoring
User Benefits:
Precision
Method development
Reproducible results
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Accessories
• S10 Auto-sampler
• Flow Injection-MHS AA
• Flow Injection Flame AA
• FIAS-Furnace Coupling
• AutoPrep 50
• FAST Flame Sample Automation
Platform
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CV /Hydride generation
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.
Flow Injection Mercury Systems - FIMS
• Dedicated Hg analyzer
• Determines Hg via CV-AA
• Stand alone system
• Fully automated
• Easy to operate
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.
Hg determination with pre-concentration by Amalgamation
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FIMS-100.
FIAS-Furnace Coupling
• Features
◦ Separation of matrix
and analytes
◦ Controlled atomization
◦ Fully automated
◦ Easy to use
◦ Integrated software
Benefits
Reliable analysis of
difficult elements in
very complex and
difficult samples
Improved detection
limits
More reliable analysis
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.
SMS 100, dedicated Hg analyzer in solids and liquids
• Soils
• Sediments
• Geologicals
• Coal
• Foundry scrap • Blood
• Plastics • Paints
• Sewage/ Sludge • Animal Tissues
• Marine Tissues
• Tobacco
• Vegetation
• Cement
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Direct Hg determination in solids /liquids samples without any sample prep
Matrix Independent Analysis
• Calibrate once for
many sample types.
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Calibration using a variety of Certified reference Materials (CRM)
FAST Flame 2 with SC2 Autosampler (2-trays)
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FAST Flame 2 – Schematic Diagram
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FAST Flame Sample Automation Platform
FAST Flame 1
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Titan MPS™ Sample Preparation System
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The right vessel for the right application
DataViewer
Placeholder,
Need Excel example as well
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Titan and Safety
• Hardware interlocks
◦ Lid, power supply, inverters, magnetrons, oven body
• Software interlocks
◦ Lid, DTC, DPC, vessel venting
• Vessel burst resistance
◦ Elastic, gas containment manifold
• CE/NRTL/FCC certification
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Hot Plates (Open Digestion)
The Good:
• Cheap
• Easy methods
• Large sample volumes
The Bad:
• Not suitable for Mercury
• Corrosion, short lifetime
• Poor Temperature Control
• Contamination of Sample
• Safety
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Sample Preparation Block
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DigiTUBE
Class A
Refluxing
Graduated
Level of conc
cylinder
acid
Labeling
41
.
Typical Application For Touch Screen Controller
• Touch Screen Controller
◦ Ideal for complex digestions at multiple temperatures
◦ Ideal for method development
◦ Typical Samples
- Animal feeds, pet foods, human foods
- Biological samples
- Plastics
42
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Thank you for your attention.
? Any questions ?
Riccardo Magarini
Sr. Specialist Atomic Spectroscopy
riccardo.magarini@perkinelmer.com
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