MATEIAL BALANCE

Stream 1

No. Component Molecular weight Mole Fraction Mass Mass Fraction

1 Propane 44.100 0.800 35.280 0.748
2 Butane 58.120 0.180 10.462 0.222
3 Pentane 72.150 0.020 1.443 0.031
47.185

ENERGY BALANCE
For Stream 1
Liquid phase
Stream temperature, T = 325.15 K and consider datum at 298.15 K
Stream 1
F1 = 13100
kg/hr feed
Molecular Mass Flowrate, Molar Flowrate,
No. Component weight(kg/kmol) (kg/hr) (mole/hr) Cp,(KJ/mol-K)
1 Propane 44.100 9,794.89 222106.371882086 0.10584
2 Butane 58.120 2,904.49 49973.9332415692 0.13367
3 Pentane 72.150 400.624 5552.6541926542 0.167
∑ 840,106.277

For Stream 2
Liquid phase
Stream temperature, T = 320.15 K and consider datum at 298.15 K
Stream 2
D1=10585.86
kg/hr distillate
Mass Flowrate, Molar Flowrate,
Molecular (kg/hr) (mole/hr)
No. Component weight(kg/kmol) Cp,(KJ/mol-K)
1 Propane 44.100 10,443.48 236813.560090703 0.10584
2 Butane 58.120 125.124 2152.8561596697 0.13367
3 Pentane 72.150 17.259 239.20997921 0.167
∑ 558,625.486
For Stream 3
Stream temperature, T = 377.15 K and consider datum at 298.15 K
Stream 2
B1 = 2514.14 kg/hr
bottom product

Mass Flowrate, Molar Flowrate,

Molecular (kg/hr) (mole/hr)
No. Component weight(kg/kmol) Cp,(KJ/mol-K)
1 Butane 58.120 2,209.39 38014.3152099105 0.13367
2 Pentane 72.150 304.748 4223.8115038115 0.167
∑ 457,153.253

TOTAL ∆Hnet(KJ/hr)

STREAM ∆H(KJ/hr)
1(in) 840,106.28
2(out) 558,625.49
3(out) 457,153.25
∑∆Hnet ∆Hout-∆Hin
∑∆Hnet 175,672.46
 Stream 2 Stream 3
F1 = 13100 D1=10585.86 kg/hr
kg/hr feed distillate
Mole Mole
Mass Flowrate, Fraction Mass Mass Fraction Mass Flowrate, Fraction Mass
(kg/hr)
9,794.891 0.990 43.659 0.987 (kg/hr)
10,443.478 0.000 0.000
2,904.485 0.009 0.523 0.012 125.124 0.900 52.308
400.624 0.001 0.072 0.002 17.259 0.100 7.215
44.254 59.523

∆T ∆H, KJ/hr
27 634708.9368
27 180360.42272
27 25036.917755

∆T ∆H, KJ/hr
22 551415.6384
22 6330.990223
22 878.85746362
∆T ∆H, KJ/hr
79 401428.50761
79 55724.74517
 Stream 3
B1 = 2514.14 kg/hr
bottom product
Mass Fraction Mass Flowrate,
0.000 (kg/hr) 0.000
0.879 2,209.392
0.121 304.748
Stream temperature, T = 325.15 K and consider datum at 298.15 K
Stream 1
F1 = 13100
kg/hr feed
Molecular Mass Molar
weight(kg/ Flowrate, Flowrate,
No. Component kmol) (kg/hr) (mole/hr) Cp,(KJ/mol- ∆T ∆H, KJ/hr
1 Propane 44.100 9,794.89 222106.372 0.10584 27 634708.937
2 Butane 58.120 2,904.49 49973.9332 0.13367 27 180360.423
3 Pentane 72.150 400.624 5552.65419 0.167 27 25036.9178
∑ 840,106.277
 MIXER
Stream 3 Recycle
D1=10585.86
kg/hr distillate
Mass
Molecular Flowrate,
Compone weight(kg/km Mole Mass Mole Mass
(kg/hr)
NO. nts ol) Fraction Mass Fraction Fraction Mass Fraction
1 Propane 44.100 0.990 43.659 0.987 10,443.478 1.000 44.100 1.000
2 Butane 58.120 0.009 0.523 0.012 125.124 0.000 0.000 0.000
3 Pentane 72.150 0.001 0.072 0.002 17.259 0.000 0.000 0.000
44.254 44.100

Reactor
Stream 4 Stream 5
F=15110.74
kg/hr
Mass
Molecular Flowrate,
Compone weight(kg/km Mole Mass Mole Mass
(kg/hr)
NO. nts ol) Fraction Mass Fraction Fraction Mass Fraction
1 Propane 44.100 0.991 43.703 0.988 14,922.552 0.991 43.703 0.988
2 Butane 58.120 0.007 0.407 0.009 138.917 0.007 0.407 0.009
3 Pentane 72.150 0.002 0.144 0.003 49.272 0.002 0.144 0.003
4 Propene 42.08 0.000 0.000 0.000 0.000
5 Butene 56.11 0.000 0 0.000 0.000
6 Hydrogen 2 0 0 0.000 0.000
44.254 44.254
Recycle Stream 4
R=4524.8868 F=15110.74
kg/hr kg/hr
Mass Mass
Flowrate, Flowrate,
Mole Mass
(kg/hr) (kg/hr)
Fraction Mass Fraction
10,000.000 0.991 43.703 0.988 14,922.598
0.000 0.007 0.407 0.009 138.972
0.000 0.002 0.144 0.003 49.169
10,000.000 44.254

tream 5
F=123299.61
kg/hr
Mass
Flowrate,
(kg/hr)
121,764.043
1,133.523
402.044
0.000
0.000
0.000