JOURNAL OF BASIC CHEMICAL PRACTICUM VIII

" FACTORS THAT INFLUENCE THE RATE OF REACTION"

BY :
SITI AROFATUL AMRINA
(1913071019)

CLASS IIA
S1 SCIENCE EDUCATION
DEPARTMENT OF PHYSICS AND SCIENCE THEACING
FACULTY OF MATHEMATICS AND NATURAL SCIENCES

UNIVERSITAS PENDIDIKAN GANESHA

SINGARAJA
2020
 EXPERIMENT VIII
FACTORS THAT INFLUENCE THE RATE OF REACTION

I. Purpose
Students have the knowledge and skills in conducting experiments on
theeffect of concentration, touch surface area, temperature and catalysts on
reaction rates.
II. Basic Theory
Chemical reactions can take place at a fast or slow rate. Fast or slow rate
of chemical reactions is influenced by several factors, including the
concentration of reactants, touch surface area, temperature and catalyst.In
general, the greater the concentration and the surface area of the reacting
substance, the greater the likelihood of collisions occurring, so that the rate of
reaction will also increase. Likewise with temperature. Increasing the
temperature of the system will increase the fraction of molecules that have
more energy than the activation energy so that the reaction rate will increase.
In addition to the above factors, the reaction rate can also be increased
byadding catalysts. Based on the catalyst phase with the reaction system, the
catalyst can be distinguished from homogeneous catalysts and heterogeneous
catalysts.

III. Tools and Materials

Tools
- 50 mL and 100 mL glass - Tube “Y”
- 100 mL and 250 mL volumetric flask - Stative and clamping
- Stopwatch - Balance
- Balloon - Tripod
- Test tube and rack - Burner
- Test tube clamp - Gas flow pipe
- 400 mL beaker - Drop pipette
Ingredients
- Zinc granules / powder - KMnO4 0,01M
- HCl 0,5 M, 1M, 1,8M, 3M, 6M - H2SO4 2M
- Na2S2O3 1M - H2CO4 0,05M
- CaCO3 powder and granules - H2O2 3%
- MnO2 powder - FeCl3saturated
- Soap Solution
IV. Work Procedures
4.1 Effect of Concentration on Reaction Rate
4.1.1 The reaction between zinc and hydrochloric acid
1. Put 2 grams of zinc into the balloon, then attach the balloon to a
flask that has been filled with 50 mL of 1M HCl solution.
2. Activate the stopwatch just as the zinc is dropped in the HCl
solution and stop the stopwatch just when the balloon can stand.
Record the time required.
3. Do the same for 1.8 M, 3 M and 6 M HCl solutions.
4.1.2 The reaction between sodium thiosulfate and hydrochloric acid
1. Provide four 100 mL volumetric flask, successively mark A, B,
C and D.
2. Enter 10 mL of 1 M thiosulfate solution into each of the flasks
above
3. To the pumpkins B, C and D add 5mL, 7.5mL, and 12.5mL of
water respectively and shake the flasks for perfect mixing.
4. To pumpkin A, add 10mL of 2 M HCl solution and shake the
flask. Run the stopwatch just when the HCl solution is poured
and stop the stopwatch just when turbidity occurs.
5. Do the same for pumpkin B, C and D.

4.2 Touch Surface Area

1. Weigh the two types of limestone, CaCO3 which weighs the same
(±0.5 gram) one in the form of powder the other chunks.
2. Provide two "Y" tubes. Fill the first tube with 3mL of 0.5 M HCl on
one leg of the "Y" tube and powder on CaCO3 on the other leg. Fill
the second "Y" tube with 3mL of 0.5 M HCl on one leg and CaCO3
chunks on the other leg.
3. Arrange the tools as shown, in the following way:
a. Fill a 400mL beaker with tap water until it is almost full.
b. Mark the test tube with a marker or rubber at a distance of ± 3 cm
from the bottom of the test tube.
c. Fill the test tube with tap water until it is full, then put it in the
beaker in an upside down condition so that the mouth of the tube is
submerged in water contained in the beaker. Try the test tube does
not contain air bubbles.
d. Pinch the test tube so it is upright and doesn't fall.
 Picture 6. Series of Determinants of the Influence of Surface
Area on the Reaction Rate
4. The first "Y" tube stopper with a flowing pipe plug, Insert the other
end of the runner tube into the mouth of the test tube contained in the
chemical jar.
5. Turn the "Y" tube so that the HCl solution flows from one foot to the
foot containing CaCO3.
6. Record the time needed since the reaction occurs until the volume of
gas stored in the test tube is right on the markers (markers / rubber).
7. Do the same for the second "Y" tube.
8. Compare the reaction rates of the two experiments above.

4.3 System Temperature

1. Provide 2 clean test tubes and each filled with 2 mL H2C2O4 0.05 M
and 1 mL H2SO4 1 M.
2. Add 5 drops of 0.01 M KMnO4 to the first tube. Record the time from
the addition of KMnO4 until the color no longer appears.
3. Soak the second test tube in hot water (± 50ºC) for 1 minute, then add
5 drops of 0.01 M KMnO4. Record the time from the addition of
KMnO4 until the color is no longer visible.
4. Compare reaction rates in the two experiments above.

4.4 Catalyst
1. Provide 3 test tubes and each filled with 2 mL 3% H2O2 and 1 mL
soap solution. Shake and observe the gas bubbles that occur.
2. Save the first tube for comparison. Add a small spoonful of MnO2
powder to the second tube. Add 5 drops of saturated FeCl3 solution to
the third tube.
3. Observe the changes that occur. What conclusions can be obtained
from this experiment?
V. Observation Result
Obsevation :
1.a. The reaction between Zn and HCl
HCl concentration Time
1,0 M
1,8 M
3,0 M
6,0 M

Conclusion: .............................................................................................
.............................................................................................

1.b. The reaction between Na2S2O3 and HCl

Pumpkin Time
A
B
C
D

Conclusion: .............................................................................................
.............................................................................................

2.a. Results :
.................................................................................................................
.................................................................................................................
.................................................................................................................

2.b. Results :
.................................................................................................................
.................................................................................................................
.................................................................................................................

Conclusion:
.................................................................................................................
.................................................................................................................
.................................................................................................................
 3. Observation Result : Effect of temperature
Tube Themperature Time
1
2

Conclusion:
...................................................................................................................
...................................................................................................................

.4.Observation Result : Effect of catalyst

Tube Observation
1
2
3

Conclusion:
...................................................................................................................
...................................................................................................................

VI. Questions and Discussion

1. Write the reaction equation for each experiment!
2. What changes can be observed from the above experiments to mark the
speed or speed of a reaction!
3. In experiments on the reaction rate between limestone and HCl, how is the
relationship between increasing time and reaction rate? Explain!

VII. Conclusion
.............................................................................................................................
.............................................................................................................................
.............................................................................................................................
.............................................................................................................................
.............................................................................................................................
.............................................................................................................................

VIII. References
Drs. I Wayan Subagia, MAppSc., Ph.D. and Dra. Suheimi Sya’ban, M.Pd.
2014. Penentuan Rumus Suatu Hidrat. Jurnal Praktikum Kimia Dasar 1.
 Singaraja, February 12, 2019
Supporting lecturer, Do it,

(Dr. I NyomanSuardana, M.Si) (Siti Arofatul Amrina)

NIP. 19661123993031001 NIM. 1913071019