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TITLE OF EXPERIMENT :
Equilibrium Constants
B. DATE OF EXPERIMENT :
Wednesday, 27th March 2019, 07.00 WIB
C. PURPOSE OF EXPERIMENT :
To find out the equilibrium constant of a reaction and note that the
equilibrium constant does not depend on initial concentration
D. BASIC THEORIES
1. Chemical Equilibrium
Many reactions do not last until they are finished but approach an
equilibrium state, where both unused products and reactants are present in
a relatively certain number of quantities. Once the equilibrium is reached,
no further composition changes will occur. The equilibrium state is
described quantitatively through equilibrium constant reactions which
depend on the temperature at which the reaction takes place (Oxtoby &
Nachtrieb, 2001).
Chemical equilibrium includes changes in physics such as fusion
and evaporation and chemical changes, including electrochemistry. This
discussion is about thermodynamics, especially in terms of the role of
enthalpy and entropy. We will see that the same view of equilibrium and
the direction of change in spontaneity is derived from chemical terms of
substances (Kartodadiprojo, 1994).
In general, chemical reactions are equilibrium reactions where the
change in free energy is zero, ∆G = 0. Equivalent microscopic equilibrium
reactions (in closed systems) at certain pressures and temperatures.
Chemical equilibrium is a dynamic process where each molecule
continuously reacts, and the composition of all molecules in the reaction
mixture does not change. Chemical equilibrium is a reversible reaction,
meaning the reaction can take place from the reagent to form the product
and from the product to the reagent (alternating reaction).Chemical
equilibrium includes changes in physics as in fusionand evaporation and
chemical changes, including electrochemistry. This discussionis about
thermodynamics, especially in terms of the role of enthalpy andentropy.
We will see that the same view of equilibriumand the direction of change
in spontaneity is derived from the chemical terms of substances
(Kartodadiprojo, 1994).
One of the tools used to obtain equilibrium data between the
liquids phase and the gas phase is Glass Othmer Still. The things that
influence the equilibrium system are: Pressure (P), Temperature (T),
concentration of component A in the liquid phase (x) and concentration of
component A in the vapor phase (y). (Sari, 2012).
According to Le Chatelier, an equilibrium system will retain its
position if there are changes that result in a shift in equilibrium reactions.
There are several factors that affect chemical equilibrium.
Asconcentration change. Changes in concentration can affect positionthe
state of equilibrium, or rather the relative amount of reactants and
products.Changes in pressure and volume may have the same effectto the
gas system in equilibrium. Only temperature changes canchange the
equilibrium constant value. Catalysts can accelerate
achievementequilibrium by accelerating the rate of forward and rate of
reactionreverse reaction. But the catalyst cannot change the equilibrium
position orequilibrium constant (Chang, 2003).
Equilibrium constant (K) is the product of the product the reaction
coefficient is divided by the reactant product to be raised the reaction
coefficient. The equilibrium constant has a fixed value at a certain
temperature. If the reactants and products are expressed with
concentration, then the equilibrium constant is written with the symbol
Kc. For example for the reaction:
aA(g) + bB(g) ⇌ cC(g) + dD(g)
So the value Kc is
[𝐶]𝑐 [𝐷]𝑑
𝐾𝑐 =
[𝐴]𝑎 [𝐵]𝑏
If the equilibrium constant (Kc) is small (Kc <1), it means that in
the equilibrium state, the product concentration is small, so the
equilibrium constant is also small, it shows the back and forth reaction is
not going well. If the large equilibrium constant (Kc) (Kc> 1) means in
equilibrium the concentration of the reactants is small, so the price of the
large equilibrium constants shows that the reaction proceeds back and
forth. (Keenan, 1990).
2. Acid-Base Titration
Acid-base titration are often called “aside-alkalimetri”, while for
other measurement titration is often used ometrics replace-imetri. The
word metri comes from Greek, which means the science of the art namely
with or from (with or off). The suffix I comes from the latin word and P
from the Greek word. So acidimetry can be interpreted as meaning the
amount of acid or measurement with acid (measurement in the amount of
base or salt) (Harjadi, 1990).
Acid-base titration can provide a sharp enough end point and for
this reason observations are used with indicators of pH numbers at the
equivalen point 4-10. Like wise the end point of the titration will be sharp
at acidic or weak base titration, if the titration is a strong base or acid with
a ratio of acid dissociation constant greater than 104 the pH if the volume
of titration changes. In an acid-base reaction proton are transferred from
one molecule to another. In water proton usually solvated as H3O. acid-
base reaction are reversible. Temperature affects acid-base titration, pH
and color changes in indicators depending indirectly on temperature
(Khopkar, 1999).
In both types of titration above, similar indicator are use, namely
phenoftalane (PP) and methyl orange (MO). This is done because if you
use another indicator, for example TB, ME or another, then the pH route
is very far from equivalen (Harjadi, 1990).
3. Hydrolysis of Ethyl Acetate Ester
Ester (ethyl acetate) in acidic solutions are studied for various
temperature. For each temperature, the reaction progress will be tracked
by the measurement pH after a certain time step, which in turn will
provide the recation rate.
The hydrolysis ester reaction was chosen for this experiment for
practical reasons. First, it occurs at a rather law level, so changes can be
observes in minutes. Second, it requires acid as a catalyst. The number of
products so that it can be followed as a function of time by extracting a
small amount of the solution reacts at a certain time interval. Thinning
this water by aliquots will almost stop the reaction and allow for analysis
without haste. Third, the product itself is acidic, so its concentration can
be easily and precisely determined by titration.
Esters are thick oxoacid chemicals a hydroxyl and a component,
such as alcohol. Acid catalyse hydrolysis of ethyl acetate forming acetic
acid and ethanol (Sears & Zemansky, 1995).
E. TOOLS AND MATERIALS
a. Tools
1. Burette 1 pcs
2. Staive and clamp 1 set
3. Erlenmeyer 250 mL 3 pcs
4. Erlenmeyes 100 mL 4 pcs
5. Beaker glass 100 mL 1 pcs
6. Measure glass 10 mL 1 pcs
7. Plastic warp sufficiently
b. Substances
1. NaOH solid sufficiently
2. Phenolptalien indicator sufficiently
3. Absolute ethanol 10 mL
4. HCl 2N 15 mL
5. HCl 0,1N 20 mL
6. Acetate acid 10 mL
F. LANES WORK
1. Blanko solution
5 mL HCl 2N
1. Poured into Erlenmeyer
2. Add 2 drops of PP Indicator
3. Filtrated with NaOH 2N
4. Reapeated 3x
Result
2. Experiment 2
5 mL HCl 5 mL HCl 5 mL HCl 5 mL HCl
0,1N + 1 mL 0,1N + 2 mL 0,1N + 3 mL 0,1N + 4 mL
ethanol + 4 ethanol + 3 ethanol + 2 ethanol + 1
mL acetic acid mL acetic acid mL acetic acid mL acetic acid
Utama.
Holman, J., & Stone, P. (1995). Chemistry. Chellenham: Thomas Nelson & Son.
Keenan. (1990). General Collage Chemistry. New York: Harpen and Row
Pletisker.
4CH.
Oxtoby, G., & Nachtrieb. (2001). Kimia Modern (Keempat). Jakarta: Erlangga.
Industry UPN.
Erlenmeyer 1
𝑝𝑋𝑉 1,049 𝑥 4
Mol CH3COOH = = = 0,07 mol
𝐵𝑀 60
𝑝𝑋𝑉 0,789 𝑥 1
Mol C2H5OH = = = 0,017 mol
𝐵𝑀 46
0,0086 𝑋 0,0086
= 0,0614 𝑋 0,0084
7,396 𝑋 10−5
= 5,157 𝑋 10−4
= 0,143
Erlenmeyer 2
𝑝𝑋𝑉 1,049 𝑥 3
Mol CH3COOH = = = 0,052 mol
𝐵𝑀 60
𝑝𝑋𝑉 0,789 𝑥 2
Mol C2H5OH = = = 0,034 mol
𝐵𝑀 46
0,0104 𝑋 0,0104
= 0,0416 𝑋 0.0236
0.000108
= 0.0236
= 0.110
Erlenmeyer 3
𝑔𝑟
𝜌𝑥𝑣 1,049 ⁄𝑚𝐿 ×2 𝑚𝐿
Mol CH3COOH = = 𝑔𝑟 = 0,034 𝑚𝑜𝑙
𝐵𝑀 60 ⁄𝑚𝑜𝑙
𝑔𝑟
𝜌𝑥𝑣 0,789 ⁄𝑚𝐿 ×3 𝑚𝐿
Mol C2H5OH = = 𝑔𝑟 = 0,051 𝑚𝑜𝑙
𝐵𝑀 46 ⁄𝑚𝑜𝑙
0,009×0,009
= 0,025×0,042
0,000081
= = 0,077
0,00105
Erlenmeyer 4
𝑝𝑋𝑉 1,049 𝑥 1
Mol CH3COOH = = = 0,017 mol
𝐵𝑀 60
𝑝𝑋𝑉 0,789 𝑥 4
Mol C2H5OH = = = 0,068 mol
𝐵𝑀 46
0,0084 𝑋 0,0084
= 0,0086 𝑋 0,0596
0,00007056
=
0,00051256
= 0,138
A. DOCUMENTATION