CHEENA PUBLIC SCHOOL

(AFFILIATED TO C.B.S.E NEW DELHI AFF.NO. (2132593)

MOOSA NAGAR ROAD, GHATAMPUR, KANPUR NAGAR.

ANNUAL EXAMINATION 2022-23

CLASS :: XI (CHEMISTRY)

General Instructions ::
1) There are 35 questions in this question paper with internal choice.
2) SECTION A consists of 18 multiple-choice questions carrying 1 mark each.
3) SECTION B consists of 7 very short answer questions carrying 2 marks each.
4) SECTION C consists of 5 short answer questions carrying 3 marks each.
5) SECTION D consists of 2 case- based questions carrying 4 marks each.
6) SECTION E consists of 3 long answer questions carrying 5 marks each.
——————————————————————————————————————————————————————————————————
1) An atom of an element has the electronic configuration 2,8,2. To which group does it belong?
(a) 4th group. (b) 6th group. (c) 3rd group. (d) 2nd group.

2) Element X forms a chloride with the formula XCI2, which is a solid with high melting point. X would most
likely be in the same group of the periodic table as:
(a) Si. (b) Mg. (c) Al. (d) Na.

3) Pick out the chemically most reactive elements from the given triads.
Li, Na, K F, CI, Br.
(a) Li and F. (b) Li and Br. (c) K and F. (d) K and Br.

4) The number of types of bonds between two carbon atoms in calcium carbide is
(a) Two sigma, two pi. (b) One sigma, two pi. (c) One sigma, one pi. (d) Two sigma, one pi.

5) The structure of IF7 is :

(a) Pentagonal bipyramid. (b) Square pyramid. (c) Trigonal bipyramid. (d) Octahedral.

6) Which of the following is a linear molecule?

(a) ClO2. (b) CO2. (c) NO2. (d) SO2.

7) Third law of thermodynamics provides a method to evaluate which property?

(a) Absolute Energy. (b) Absolute Enthalpy. (c) Absolute Entropy. (d) Absolute Free Energy.

8) In a reversible process the system absorbs 600 kJ heat and performs 250 kJ work on the surroundings.
What is the increase in the internal energy of the system?
(a) 850 kJ. (b) 600 kJ. (c) 350 kJ. (d) 250 kJ.

9) In a reversible chemical reaction at equilibrium, if the concentration of any one of the reactants is
doubled, then the equilibrium constant will
(a) Also be Doubled. (b) Be Halved. (c) Remain the Same. (d) Become One-Fourth.

10) The solubility of Ca3(PO4)2 in water is y mol/L. Its solubility product is.
(a) 6y2. (b) 36 y4. (c) 64 y5. (d) 108 y5.
11) The displacement of electrons in a multiple bond in the presence of attacking reagent is called
(a) Inductive effect. (b) Electromeric effect. (c) Resonance. (d) Hyper conjugation.

12) Which of the following behaves both as a nucleophile and as an electrophile?

(a) CH3 C ≡ N. (b) СнзОН. (c) CH2 = CH CH3. (d) CH3NH2

13) Which of the following compounds will exhibit geometrical isomerism?

(a) 1 - Phenyl - 2 - butene. (b) 3 - Phenyl - 1 - butene. (c) 2 - Phenyl - 1 butene.
(d) 1,1 - Diphenyl - propene.

14) Pure methane can be prepared by

(a) Soda lime decarboxylation. (b) Kolbes electrolytic method. (c) Wurtz reaction.
(d) Reduction with H2.

15) Isopropyl bromide on Wurtz reaction gives

(a) Hexane. (b) Propane. (c) 2, 3 - Dimethylbutane. (d) Neohexane.

SECTION - (B).
* ASSERTION REASON TYPE (16-18) :: In these questions, a statement of assertion followed by a
statement of reason is given. Choose the correct answer out of the following choices ::
(a) If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(b) If both Assertion and Reason are true but Reason ·is not the correct explanation of Assertion.
(c) If Assertion is true but Reason is false. (d) If Reason is true but Assertion is false. (e) Both False.
16) Assertion :: Smaller the size of an atom greater is the electronegativity.
Reason :: Electronegativity refers to the tendency of atom so share electrons with other atom.
17) Assertion :: Lone pair-lone pair repulsive interactions are greater than lone pair-bond pair and bond pair-bond
pair interactions.
Reason :: The space occupied by lone pair electrons is more as compared to bond pair electrons.
18) Assertion :: Decrease in free energy causes spontaneous reaction.
Reason :: Spontaneous reactions are invariable exothermic reactions.

SECTION - (C).

19) How would you justify the presence of 18 elements in the 5th period of the Periodic Table?
Or
Considering the atomic number and position in the periodic table, arrange the following elements in the
increasing order of metallic character : Si, Be, Mg, Na, P ?
20) Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar ?

21) For the reaction,

2 Cl(g) → Cl2(g), what are the signs of ∆H and ∆S ?

22) The equilibrium constant expression for a gas reaction is,

Write the balanced chemical equation corresponding to this expression ?

23) Identify the functional groups in the following compounds ?

24) Explain why the following systems are not aromatic?

25) In the alkane H3C–CH2–C(CH3)2–CH2–CH(CH3)2, identify 1°,2°,3° carbon atoms and give the number of H atoms
bonded to each one of these ?

SECTION - (D).
26) Use the periodic table to answer the following questions.

(a) Identify an element with five electrons in the outer subshell.

(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.

27) Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms in C2H4 and
C2H2 molecules. Also calculate no. Of covalent bond in it ?

28) Derive the Express of “Gibbs Helmholtz Equation” ?

29) A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium the partial pressure of HI(g) is
0.04 atm. What is Kp for the given equilibrium ?
2HI (g) <————> H2 (g) + I2 (g).

30) Give the IUPAC names of the following compounds :

 SECTION - (E)

31) Compare the relative stability of the following species and indicate their magnetic properties;
O2 , O2+, O2− (superoxide), O22− (peroxide). (As per M.O.T) ?

32) Draw all Possible Resonating Structures in “Phenol” ?

OR

Draw all Possible Resonating Structures in “Nitro Benzene” ?

33) Explain “Khrasch Effect” ? Write the steps involved in the mechanism of this reaction ?

OR

(i) Define Wurtz reaction ? Why it is not applicable in case of unsymmetrical alkyl groups ?
(ii) What Do you understand by Decarboxylation reaction ? Name one powerful drying agent other
than used in it ?

SECTION - (F)

CASE STUDY TYPE :: (34)

Read the passage given below and answer the following questions:

When an electron is added to a gaseous atom in its ground state to convert it into a negative ion, the enthalpy
change accompanying the process is called the electron gain enthalpy (Δeg H). It is a direct measure of the ease
with which an atom attracts an electron to form anion. X(g) + e- ——-> X-(g); ΔH = Δeg H
The most stable state of an atom is the ground state. If an isolated gaseous atom is in excited state,
comparatively lesser energy will be released on adding an electron. So, electron gain enthalpies of gaseous
atoms must be determined in their ground states. Therefore, the terms ground state and isolated gaseous atom
has been also included in the definition of electron gain enthalpy. Like ionisation enthalpy, electron gain
enthalpy is measure either in electron volts per atom or kJ per mole.
The following questions (1-iv) are multiple choice questions. Choose the most appropriate answer :

(A) Why Noble gases have positive electron gain enthalpy?

(B) The electron gain enthalpy of O or F is less than that of S or Cl. It is due to?

(C) (i) Why beryllium has higher ionisation enthalpy than boron ??
(ii) Factors affecting electron gain enthalpy is ?
CASE STUDY TYPE :: (35)

Read the passage given below and answer the following questions.

In chemical thermodynamics, the type of work involved is mostly pressure-volume work that is the work
done when a system (gas) expands or contracts against an external opposing pressure. Hence, work is also
defined as the transfer of energy that can be used to change the height of a mass in the surroundings.

Pressure-volume work: The work W, that is done due to the expansion or compression of a gas against
an external opposing pressure P is called pressure-volume work.

(A) Which of the following statement is correct?

(B) A process in which the system does not exchange heat with the surroundings is known as ?

(C) Which of the following is correct match as far as the thermodynamic processes are involved ?

(D) A gas expands in vacuum. The work done by the gas is ?

••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••