diene

dienophile

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 diene
dienophile

diene dienophile

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 a poor a good a good
dienophile dienophile dienophile

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 diene HOMO + dienophile LUMO dienophile HOMO + diene LUMO

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 no preference between
s-cis and s-trans prefers s-trans

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 Endo orientation forms
product faster
Exo orientation forms
the more stable product
Endo vs Exo

EXO addition is slower but gives the more stable product

ENDO addition is faster but gives the less stable product

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